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Instructions: BEFORE YOU BEGIN, MARK YOUR NAME, USF ID NUMBER, SECTION NUMBER,
AND FORM LETTER ON YOUR SCANTRON SHEET. FAILURE TO DO THIS WILL RESULT IN A
PENALTY.
For each problem determine the best answer and mark the appropriate place on your scantron sheet. The exam
consists of 20 questions and you will be given 50 minutes.
1 2
1 H
1.008
Periodic Table He
4.003
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
3 Na Mg Al Si P S Cl Ar
22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.61 74.92 78.96 79.90 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57* 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.3 138.9 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 (209) (210) (222)
87 88 89** 104 105 106 107 108 109 110 111 112
7 Fr Ra Ac Rf Db Sg Bh Hs Mt
(223) 226.0 227.0 (261) (262) (263) (262) (265) (266) (269) (272) (277)
!
58 59 60 61 62 63 64 65 66 67 68 69 70 71
*Lanthanides Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.1 140.9 144.2 (145) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0
90 91 92 93 94 95 96 97 98 99 100 101 102 103
**Actinides Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
! 232.0 231.0 238.0 237.0 (244) (243) (247) (247) (251) (252) (257) (258) (259) (260)
0
FORM B
CHM2045: Fall 2000—Exam #3 Form B November 4, 2009
1. The following species all have the same number of electrons (we call this “isoelectronic”). Which would be
expected to have the largest atomic radius?
(A) O2-
(B) F -
(C) Na+
(D) N3-
(E) Mg2+
2. Before Mendeleev, elements were listed in the order of their atomic weights (molar masses). When he set
up the periodic table he deviated from this rule by listing Te (127.60 g/mol) before I (126.90 g/mol). What
was the reason for this?
(A) Iodine resembles F, Cl, and Br in its chemical properties; Te is much more like S and Se.
(B) Ga and Ge had not yet been discovered; their absences misaligned the columns.
(C) Mendeleev showed that the atomic weights of I and Te were incorrect.
(D) Iodine is a solid whereas fluorine and chlorine are gases and bromine is a liquid.
(E) Iodine is a metal whereas tellurium is a nonmetal.
3. The length of an H-H bond is 74 pm and that of an I-I bond is 266 pm. What is the most reasonable
estimate for the length of an H-I bond?
(A) 340 pm
(B) 170 pm
(C) 192 pm
(D) 148 pm
(E) 158 pm
4. Consider the following sets of quantum numbers, n, l, ml, and ms, respectively. Which of these, if any, is
not allowed for an electron in an atom?
(A) n = 1 l = 0 ml = 0 ms = +1/2
(B) n = 8 l = 7 ml = -6 ms = -1/2
(C) n = 3 l = 3 ml = -2 ms = +1/2
(D) n = 2 l = 1 ml = -1 ms = -1/2
(E) All the above are allowed.
5. For a hydrogen atom, which pair of energies (listed according to their n values) would have the greatest
difference in energy?
(A) n = 3 and n = 4
(B) n = 5 and n = 10
(C) n = 3 and n = 100
(D) n = 1 and n = 2
(E) Cannot be determined.
1
FORM B
CHM2045: Fall 2000—Exam #3 Form B November 4, 2009
6. Which is NOT directly determined by the principal quantum number, n, of the electron in a hydrogen atom?
(A) The energy of the electron.
(B) The minimum wavelength of the light needed to remove the electron from the atom.
(C) The size of the corresponding atomic orbital(s).
(D) The shape of the corresponding atomic orbital(s).
(E) All of the above are directly determined by n.
7. What period 3 element is described by the following ionization energies (all in kJ/mol)?
IE1 = 1012 IE2 = 1900 IE3 = 2910 IE4 = 4960 IE5 =6270 IE6 =22,200
(A) Mg
(B) Si
(C) P
(D) S
(E) Cl
8. How many inner shell (core) electrons do the following elements have, respectively?
Hydrogen, Helium, Lithium, and Beryllium
(A) 1, 1, 1, 1
(B) 0, 0, 1, 1
(C) 0, 0, 2, 1
(D) 0, 0, 2, 2
(E) 2, 2, 2, 2
10. How much total energy (in MJ/mol) would it take to remove the electrons from a mole of hydrogen atoms?
The ionization energy for a hydrogen atom is 2.178 x 10!18 J.
(A) 3.617 x 10 –42 MJ
(B) 1.312 MJ
(C) 2.765 MJ
(D) 1.312 x 106 MJ
(E) 2.765 x 1035 MJ
2
FORM B
CHM2045: Fall 2000—Exam #3 Form B November 4, 2009
12. The faster an electron is moving, the ________ its kinetic energy, and the __________ its wavelength.
(A) higher, shorter
(B) higher, longer
(C) lower, longer
(D) lower, shorter
(E) More than one of the answer choices will result in a true statement.
13. Elements in the same family exhibit similar chemical properties because:
(A) their atomic masses increase proportionally.
(B) they exhibit identical core electron configurations.
(C) they exhibit identical valence electron configurations.
(D) they are in the same periodic table block and exhibit identical core electron configurations.
(E) they are in the same periodic table block and exhibit similar valence electron configurations.
15. Calculate the wavelength of the red light emitted by a neon sign with a frequency of 4.74 ! 1014 Hz.
(A) 633 nm
(B) 158 nm
(C) 142 nm
(D) 704 nm
(E) 466 nm
3
FORM B
CHM2045: Fall 2000—Exam #3 Form B November 4, 2009
20. Which energy gap in the Bohr Model would be associated with the longest wavelength?
(A) from n = 2 to n = 1
(B) from n = 6 to n = 5
(C) from n = 10 to n = 9
(D) from n = 11 to n = 10
(E) They have the same wavelength.
21. Choose the orbital diagram that represents the ground state of N.
(A)
(B)
(C)
(D)
(E)
4
FORM B
CHM2045: Fall 2000—Exam #3 Form B November 4, 2009
23. In the Born-Haber cycle for Mg(s) + Cl2(g) " MgCl2(s), which step(s) is (are) exothermic for the formation
of crystalline solid? (The following may not be balanced equations, but describe reaction processes.)
(1) Mg(g) + 2Cl (g) ! Mg2+(g) + 2Cl (g)
(2) Mg2+(g) + 2Cl(g) ! Mg2+(g) + 2Cl– (g)
(3) Mg(s) + Cl2(g) ! Mg(g) + Cl2(g)
(4) Mg(g) + Cl2 (g) ! Mg(g) + 2Cl (g)
(5) Mg2+(g) + 2Cl– (g) ! MgCl2(g)
24. Which of the following concepts/models/phenomena are related to “quantized energy levels”?
(A) Fireworks
(B) Neils Bohr’s model for the atom
(C) the “line spectra” of helium emission
(D) Both (b) and (c)
(E) All of the above.
25. Which one does not have a completely full quantum level?
(A) Na+
(B) O2
(C) O2–
(D) He
(E) The quantum levels are completely full in all of the above.
5
FORM B