You are on page 1of 6

TUGAS NERACA MASSA

HALAMAN 352 ILUSTRATION 19


Olaf A Hougen




Oleh :
GALANG SETYOKO 0612 4041 1468


Dosen Pembimbing : Ir.Arizal Azwan,M.T,.



PROGRAM STUDI TEKNIK ENRGI
POLITEKNIK NEGERI SRIWIJAYA
2013 /2014
Ilustration 19.
For the production of sulfuric acid by the contact procces, iron pyrites ,FeS2, is
burned with air in 100% excces at 25
o
C of that required to oxidize all iron to
Fe2O3 and all sulfur to SO2. It may be assumed that the combustion of the
pyrits is the complate to form there product and that no SO
2
is formed in the
burner. SO
2
leave from burner at 400
o
C Assumed the RH 65%.

4FeS
2
+ 11O
2
2Fe
2
O
3
+ 8SO
2


Calculate H total ...
Answer :
Knowing : - First temperatur : 25
0
c
- Finally temperatur : 400
0
C
- Air excess : 100 %
- RH : 65 %
- Mean specific heat :
1) FeS
2
= 0,136 gr cl/ gr mole
0
C
2) SO
2
= 10,94 gr cl/ gr mole
0
C
3) H
2
O = 8,409 gr cl/ gr mole
0
C



Question : H total ??



Neraca Massa page 352 . ilustration 19

FeS
2



T = 25
0
C

T= 400
0
C

Air excess 100%








Basis : 4 gr-moleof FeS
2

4FeS
2
+ 11O
2
2FeO
3
+ 8SO
2


Oxygen supplied for 100% excess = 11 x 2 = 22 gr-mole
Air introduced =

= 104,8 gr-mole
N
2
introduced = 104,8 22 = 82,8 gr-mole
Excess O
2
in burner = 22 11 = 11 gr-mole




BURNER
SO
2
NO
2
O
2
H
2
O

FeO
3

Menghitung H
2
O dari udara.
T = 25
o
C
RH = 65%
From fig 20 found the Hm = 0,0815
H
2
O supplied from air = 0,0815 x 104,8 = 1.93806 gr mole
H
2
O in flue gas = H
2
O supplied from air
= 1,93806


Composition of gas leave the burner
SO
2
= 8 gr-mole x 32 = 512 gr
N
2
= 82,89 gr-mole x 28 = 2320,92 gr
O
2
= 11gr-mole x 32 = 352 gr
H
2
O = 1,93806 gr-mole x 18 = 34,88508 gr +
= 3219,8051 gr







Q
input
= Q
FeS2
+ Q
H2Ofrom the air
+ Q
air

= (4) ( 0,136 ) (400 25 ) + ( 0,0183 ) ( 8,904 ) ( 400 25 ) + 0
= 204 + 57,706
= 261,706 cal


Q
output
= Q
SO2
+ Q
H2O
+ Q
dry air
+ Q
FeS2

= 8 ( 10,94 ) ( 400 25 ) + (1,43806 ) ( 8,409 ) ( 400 25 ) + 0 +0
= 3041,025 + 6111,429
= 9152,454 cal

H = Q
input
- Q
output
= 261,706 cal 9125,454 cal
= - 8890,748 cal








Neraca Massa
Input total Output Total
FeS
2



Air
480


3039,2
SO
2

N
2

O
2

H
2
O
Fe
2
O
3

512
2320,92
352
34,88508
302,39492
3519,2 3519,2

You might also like