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MALCOLM HALCROW

b. 1966.

2010-(date). Professor of Inorganic Chemistry, University of Leeds.
2005-2010. Reader in Coordination Chemistry, University of Leeds.
2004-2005. Senior Lecturer in Inorganic Chemistry, University of Leeds.
2002-2004. Lecturer in Inorganic Chemistry, University of Leeds.
1998-2002. Royal Society University Research Fellow, University of Leeds.
1995-1998. Royal Society University Research Fellow, University of Cambridge.
1993-1994. Post-Doctoral Research Fellow, Indiana University, Bloomington, Indiana, USA.
1992. Royal Society Exchange Post-Doctoral Fellow, Laboratoire de Chimie de Coordination
du CNRS, Toulouse, France.
1988-1991. Ph.D., University of Edinburgh.
1985-1988. B.A. (Hons), University of Cambridge.

F.R.S.C., C.Chem.









PUBLICATIONS (January 2013)

182. A bis(disulfide)-linked offset cryptophane, M.A. Little, M.A. Halcrow and M.J.
Hardie*, Chem. Commun., submitted.

181. The synthesis of new 2,6-di(pyrazol-1-yl)pyrazine derivatives, and the spin state
behavior of their iron(II) complexes, R. Mohammed, G. Chastanet, F. Tuna, T.L.
Malkin, S.A. Barrett, C.A. Kilner, J.-F. Ltard* and M.A. Halcrow*, Eur. J. Inorg.
Chem., in the press (special issue on Spin Crossover). View paper

180. Four new spin-crossover salts of [Fe(3-bpp)
2
]
2+
(3-bpp = 2,6-bis[1H-pyrazol-3-
yl]pyridine), P. King, J.J. Henkelis, C.A. Kilner and M.A. Halcrow*, Polyhedron, in
the press (special issue for the Alfred Werner Nobel Prize Centenary). View paper

179. Jahn-Teller distortions in transition metal compounds, and their importance in
functional molecular and inorganic materials, M.A. Halcrow*, Chem. Soc. Rev., in
the press (special issue for the Alfred Werner Nobel Prize Centenary). View paper



178. Iron(II) and cobalt(II) complexes of tris-azinyl analogues of 2,2:6,2-terpyridine,
L.J. Kershaw Cook, F. Tuna and M.A. Halcrow*, Dalton Trans., in the press (on-line
collection for D.J. Cole-Hamilton). View paper

177. Structure:function relationships in molecular spin-crossover materials, M.A.
Halcrow* in Spin-crossover materials - properties and applications, ed. M.A.
Halcrow, John Wiley & Sons, 2013, ch. 5, pp. 147169.

176. Spin-crossover materials - properties and applications, M.A. Halcrow* (ed), John
Wiley & Sons, 2013, p. 546 (ISBN: 9781119998679).

175. Suppression of the Jahn-Teller distortion in a six-coordinate copper(II) complex by
doping it into a host lattice, R. Docherty, F. Tuna, C.A. Kilner, E.J.L. McInnes* and
M.A. Halcrow*, Chem. Commun., 2012, 48, 40554057. View paper

174. Photomagnetic studies on spin-crossover solid solutions containing two different
metal complexes, [Fe(1-bpp)
2
]
x
[M(terpy)
2
]
1x
[BF
4
]
2
(M = Ru or Co) G. Chastanet,
C.A. Tovee, G. Hyett, M.A. Halcrow* and J.-F. Ltard*, Dalton Trans., 2012, 41,
48964902. View paper

173. Six new crystalline clathrates of cyclotricatechylene (CTC) including two donor-
acceptor complexes, J.J. Loughrey, C.A. Kilner, M.J. Hardie* and M.A. Halcrow*,
Supramol. Chem. (special issue for the 6
th
International Symposium on Macrocyclic
and Supramolecular Chemistry, Brighton), 2012, 24, 213. View paper

172. Iron(II) complexes of new hexadentate 1,1,1-tris-(iminomethyl)ethane podands, and
their 7-methyl-1,3,5-triazaadamantane rearrangement products, S.A. Diener, A.
Santoro, C.A. Kilner, J.J. Loughrey and M.A. Halcrow*, Dalton Trans., 2012, 41,
37313739. View paper

171. Synthesis and methane binding properties of a disulfide-linked cryptophane-0.0.0,
M.A. Little, J. Donkin, J. Fisher, M.A. Halcrow, J. Loder and M.J. Hardie*, Angew.
Chem., Int. Ed., 2012, 51, 764766. View paper

170. An iron(II) complex exhibiting five anhydrous phases, two of which interconvert by
spin-crossover with wide hysteresis, T.D. Roberts, F. Tuna, T.L. Malkin, C.A. Kilner
and M.A. Halcrow*, Chem. Sci., 2012, 3, 349354. View paper

169. 1D and 2D assembly structures by imidazolechloride hydrogen bonds of iron(II)
complexes [Fe
II
(HL
n-Pr
)
3
]ClY (HL
n-Pr
= 2-methylimidazol-4- yl-methylideneamino-n-
propyl; Y = AsF
6
, BF
4
) and their spin states, T. Fujinami, K. Nishi, N. Matsumoto*, S.
Iijima, M.A. Halcrow, Y. Sunatsuki and M. Kojima, Dalton Trans. (special issue on
Self Assembly in Inorganic Chemistry), 2011, 40, 1230112309. View paper

168. Spin-crossover in [Fe(3-bpp)
2
][BF
4
]
2
in different solvents a dramatic stabilisation of
the low-spin state in water, S.A. Barrett, C.A. Kilner and M.A. Halcrow*, Dalton


Trans. (special issue on Self Assembly in Inorganic Chemistry), 2011, 40, 12021
12024. View paper

167. A hydrogen bond motif giving a variety of supramolecular assembly structures and
spin-crossover behaviors, K. Nishi, N. Matsumoto*, S. Iijima, M.A. Halcrow, Y.
Sunatsuki and M. Kojima, Inorg. Chem., 2011, 50, 1130311305. View paper

166. Structure:function relationships in molecular spin-crossover complexes, M.A.
Halcrow*, Chem. Soc. Rev., 2011, 40, 41194142. View paper

165. Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I)
and Au(I), S. Muoz, J. Pons*, J. Ros, C.A. Kilner and M.A. Halcrow*, J.
Organomet. Chem., 2011, 696, 27362741. View paper

164. Study of the coordination behaviour of (3,5-diphenyl-1H-pyrazol-1-yl)ethanol against
Pd(II), Zn(II) and Cu(II), S. Muoz, J. Pons*, J. Ros, M. Font-Bardia, C.A. Kilner and
M.A. Halcrow*, Inorg. Chim. Acta, 2011, 373, 211218. View paper

163. New insights into the aggregation of silver pyrazolides using sterically hindered
bidentate pyrazole ligands, J.J. Henkelis, C.A. Kilner and M.A. Halcrow*, Chem.
Commun. (on-line collection on Supramolecular Chemistry), 2011, 47, 51875189.
View paper

162. Assembly structures and spin crossover properties of facial and meridional isomers of
tris[benzyl(2-methylimidazol-4-ylmethylidene)amine]iron(II) chloride
hexafluorophosphate, D. Furusho, K. Nishi, T. Hashibe, T. Fujinami, H. Hagiwara, N.
Matsumoto*, M.A. Halcrow, S. Iijima, Y. Sunatsuki and M. Kojima, Chem. Lett.,
2011, 40, 7274. View paper

161. Two heptacopper(II) disk complexes with a [Cu
7
(
3
-OH)
4
(-OR)
2
]
8+
core, J.J.
Henkelis, L.F. Jones, C.A. Kilner and M.A. Halcrow*, Inorg. Chem., 2010, 49,
1112711132. View paper

160. Ag(I) organometallic coordination polymers and capsule with tris-allyl
cyclotriveratrylene derivatives, M.A. Little, M.A. Halcrow, L.P. Harding and M.J.
Hardie*, Inorg. Chem., 2010, 49, 94869496. View paper

159. An unusual discontinuity in the thermal spin transition in [Co(terpy)
2
][BF
4
]
2
, C.A.
Kilner and M.A. Halcrow*, Dalton Trans., 2010, 39, 90089012. View paper

158. A trinuclear iron(III) compound with an unusual T-shaped [Fe
3
(
3
-O)]
7+
core, L.F.
Jones, C.A. Kilner and M.A. Halcrow*, J. Cluster Sci. (special issue for M.H.
Chisholm), 2010, 21, 279290. View paper



157. Using one spin-transition to trigger another in solid solutions of two different spin-
crossover complexes, M.A. Halcrow*, Chem. Commun., 2010, 46, 47614763. View
paper

156. Change in electronic structure in a six-coordinate copper(II) complex accompanied by
an anion order/disorder transition, C.A. Kilner and M.A. Halcrow*, Acta
Crystallogr., Sect. B, 2010, 66, 206212. View paper

155. A back-to-back ligand with dipyrazolylpyridine and dipicolylamine metal-binding
domains, C.A. Tovee, C.A. Kilner, S.A. Barrett, J.A. Thomas and M.A. Halcrow*,
Eur. J. Inorg. Chem., 2010, 10071012. View paper

154. The effect of different ligand substituents on the chemistry of a zinc/pyrazole anion
host, J. Day, K.E.R. Marriott, C.A. Kilner and M.A. Halcrow*, New J. Chem., 2010,
34, 5260. View paper

153. Iron(II) complexes of 2,6-di(pyrazolyl)pyridines a versatile system for spin-
crossover research, M.A. Halcrow*, Coord. Chem. Rev., 2009, 253, 24932514.
View paper

152. Co-crystallising two functional complex molecules in a terpyridine embrace lattice,
C.A. Tovee, C.A. Kilner, J.A. Thomas and M.A. Halcrow*, CrystEngComm (special
issue on Crystal Engineering in Molecular Magnetism), 2009, 11, 20692077. View
paper

151. 3-(1H-Pyrrol-2-yl)-1H-pyrazole forms an unusual hydrogen-bonded two-dimensional
(3,4)-connected net, K.E.R. Marriott, C.A. Kilner and M.A. Halcrow*, Acta
Crystallogr., Sect. C, 2009, 65, o506o508. View paper

150. Two new 4,4-disubstituted dipyrazolylpyridine derivatives, and the structures and
spin states of their iron(II) complexes, R. Pritchard, C.A. Kilner, S.A. Barrett and
M.A. Halcrow*, Inorg. Chim. Acta (special issue for S. Trofimenko), 2009, 362, 4365
4371. View paper

149. Thermal and light-induced spin-transitions in iron(II) complexes of 2,6-bis(4-
halopyrazolyl)pyridines: the influence of polymorphism on a spin-crossover
compound, R. Pritchard, H. Lazar, S.A. Barrett, C.A. Kilner, S. Asthana, C.
Carbonera, J.-F. Ltard and M.A. Halcrow*, Dalton Trans., 2009, 66566666. View
paper

148. A cobalt metallacrown anion host with guest-dependent redox activity, L.F. Jones,
C.A. Kilner and M.A. Halcrow*, Chem. Eur. J., 2009, 15, 46674675. View paper

147. Unexpected product distributions in the synthesis of 2,6-bis-(indazolyl)pyridine and 2-
(pyrazol-1-yl)-6-(indazolyl)pyridine, R. Pritchard, C.A. Kilner and M.A. Halcrow*,
Tetrahedron Lett., 2009, 50, 24842486. View paper



146. Pyrazoles and pyrazolides flexible synthons in self-assembly (Perspective article),
M.A. Halcrow*, Dalton Trans., 2009, 20592073. View paper

145. A crystalline hydrogen-bonded network with a poly-catenate topology, A.A.
Salaudeen, C.A. Kilner and M.A. Halcrow*, Chem. Commun., 2008, 52005202.
View paper

144. Cross-link formation of the cysteine 228-tyrosine 272 catalytic cofactor of galactose
oxidase does not require dioxygen, M.S. Rogers, R. Hurtado-Guerrero, S.J. Firbank,
M.A. Halcrow, D.M. Dooley, S.E.V. Phillips, P.F. Knowles and M.J. McPherson*,
Biochemistry, 2008, 47, 1042810439. View paper

143. Mononuclear and dinuclear iron thiocyanate and selenocyanate complexes of tris-
pyrazolylmethane ligands, A.A. Salaudeen, C.A. Kilner and M.A. Halcrow*,
Polyhedron, 2008, 27, 25692576. View paper

142. The influence of ligand conformation on the thermal spin transitions in iron(III)
saltrien complexes, R. Pritchard, S.A. Barrett, C.A. Kilner and M.A. Halcrow*,
Dalton Trans., 2008, 31593168 and 2009, 10622 (correction). View paper

141. Trapping and manipulating excited spin states of transition metal compounds, M.A.
Halcrow*, Chem. Soc. Rev., 2008, 37, 278289. View paper

140. Ammonium, alkylammonium and amino acid complexes of a hexacopper fluoro-
metallacrown cavitand, L.F. Jones, S.A. Barrett, C.A. Kilner and M.A. Halcrow*,
Chem. Eur. J., 2008, 14, 223233. View paper

139. Mononuclear and unsymmetric dinuclear complexes of the tripodal ligand 2-
hydroxyethyl-bis(2-{pyrid-2-yl}ethyl)amine, Q.F. Mokuolu, C.A. Kilner, P.C.
McGowan and M.A. Halcrow*, Inorg. Chim. Acta, 2007, 360, 40254030. View paper

138. Thermal and light-induced spin-crossover in salts of the heptadentate complex [tris(4-
{pyrazol-3-yl}-3-aza-3-butenyl)amine]iron(II), H.Z. Lazar, T. Forestier, S.A. Barrett,
C.A. Kilner, J.-F. Ltard* and M.A. Halcrow*, Dalton Trans., 2007, 42764285. View
paper

137. The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-
donor ligands, M.A. Halcrow*, Polyhedron, 2007, 26, 35233576. View paper

136. A comparison of different methods for fitting susceptibility data of cobalt(II)
coordination polymers in a new cobalt(II)/sulfate 1-D chain, L.F. Jones, C.A. Kilner
and M.A. Halcrow*, New J. Chem., 2007, 31, 15301534. View paper

135. Interplay between kinetically slow thermal spin-crossover and metastable high-spin
state relaxation in an iron(II) complex with similar T

and T(LIESST), V.A. Money,


C. Carbonera, J. Elhak, M.A. Halcrow*, J.A.K. Howard* and J.-F. Ltard*, Chem.
Eur. J., 2007, 13, 55035514. View paper

134. Variable temperature structural and magnetic characterisation of the cubane cluster
[Cu
4
(
3
-OH)
4
(L)
4
][ClO
4
]
4
(L = 5-tertbutyl-3-(pyrid-2-yl)-1H-pyrazole), L.F. Jones*,
C.A. Kilner and M.A. Halcrow, Polyhedron (special issue: Proceedings of the 10
th

International Conference on Molecular Magnets), 2007, 26, 19771983. View paper



133. 2-[5-(2,2-Dimethylpropanamido)-1H-pyrazol-3-yl]pyridinium chloride, C.M. Pask,
C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. E, 2007, 63, o2933. View
paper

132. A hexacopper fluoro metallacrown cavitand and its alkali metal complexes, L.F.
Jones, C.A. Kilner, M.P. de Miranda, J. Wolowska and M.A. Halcrow*, Angew.
Chem., Int. Ed., 2007, 46, 40734076. View paper

131. Zwitterionic 2-(4-pyridyl)malondialdehyde sesquihydrate forms a helical, three-
dimensional hydrogen-bonded lattice, C.A. Tovee, C.A. Kilner, J.A. Thomas and
M.A. Halcrow*, CrystEngComm, 2007, 9, 361363. View paper

130. Four copper(II) pyrazolido complexes derived from reactions of 3{5}-substituted
pyrazoles with CuF
2
or Cu(OH)
2
, Q.F. Mokuolu, D. Foguet-Albiol, L.F. Jones, J.
Wolowska, R.M. Kowalczyk, C.A. Kilner, G. Christou, P.C. McGowan and M.A.
Halcrow*, Dalton Trans., 2007, 13921399. View paper

129. Anion doping as a probe of cooperativity in the molecular spin-crossover compound
[FeL
2
][BF
4
]
2
(L = 2,6-di{pyrazol-1-yl}pyridine), C. Carbonera, C.A. Kilner, J.-F.
Ltard and M.A. Halcrow*, Dalton Trans., 2007, 12841292. View paper

128. Iron(II) complexes with a terpyridine embrace packing motif show remarkably
consistent cooperative spin-transitions, R. Pritchard, C.A. Kilner and M.A. Halcrow*,
Chem. Commun., 2007, 577579. View paper

127. Synthesis of 2,6-di(pyrazol-1-yl)-4-bromomethylpyridine, and its conversion to other
2,6-di(pyrazol-1-yl)pyridines substituted at the pyridine ring, J. Elhak, C.M. Pask,
C.A. Kilner and M.A. Halcrow*, Tetrahedron, 2007, 63, 291298. View paper

126. Homoleptic zinc(II) complexes with first and second coordination shells of 5-tert-
butylpyrazole, S.L. Renard, I. Sylvestre, S.A. Barrett, C.A. Kilner

and M.A.
Halcrow*, Inorg. Chem., 2006, 45, 87118718. View paper

125. Novel hydrogen bond network topologies in complexes of the ditopic ligand 5-amino-
3-(pyrid-2-yl)-1H-pyrazole, L.F. Jones, K.D. Camm, C.A. Kilner

and M.A. Halcrow*,
CrystEngComm, 2006, 8, 719728. View paper

124. An unusual example of a linearly coordinated acetone ligand in a six-coordinate
iron(II) complex, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2006,
62, m437m439. View paper

123. Photomagnetic properties of iron(II) spin crossover complexes of 2,6-
dipyrazolylpyridine and 2,6-dipyrazolylpyrazine ligands, C. Carbonera, J.S. Costa,
V.A. Money, J. Elhak, J.A.K. Howard*, M.A. Halcrow* and J.-F. Ltard*, Dalton
Trans., 2006, 30583066. View paper

122. Synthesis of a new series of ditopic proligands for metal salts: differing regiochemistry
of electrophilic attack at 3{5}-amino-5{3}-(pyrid-2-yl)-1H-pyrazole, C.M. Pask, K.D.
Camm, C.A. Kilner and M.A. Halcrow*, Tetrahedron Lett., 2006, 47, 25312534.
View paper



121. Copper(II) complexes of sterically hindered Schiff base ligands: synthesis, structure,
spectra and electrochemistry, R. Balamurugan, M. Palaniandavar* and M.A.
Halcrow, Polyhedron, 2006, 25, 10771088. View paper

120. Structural diversity in iron(II) complexes of 2,6-di(pyrazol-1-yl)pyridine and 2,6-di(3-
methylpyrazol-1-yl)pyridine, J. Elhak, C.A. Kilner and M.A. Halcrow*, Dalton
Trans., 2006, 823830. View paper

119. Two complexes of copper(II) salts with 5-amino-3-(pyrid-2-yl)-1H-pyrazole, the
prototype for a new class of ditopic ligand, C.M. Pask, K.D. Camm, N.J. Bullen, M.J.
Carr, W. Clegg, C.A. Kilner and M.A. Halcrow*, Dalton Trans., 2006, 662664. View
paper

118. An iron(II) complex of 2,6-di(pyrazol-1-yl)pyrazine that crystallises in three forms,
two of which exhibit an unusual angular Jahn-Teller distortion, C.A. Kilner and M.A.
Halcrow*, Polyhedron (special issue for M.H. Chisholm), 2006, 25, 235240. View
paper

117. The synthesis and coordination chemistry of 2,6-di(pyrazolyl)pyridines and related
ligands versatile terpyridine analogues, M.A. Halcrow*, Coord. Chem. Rev., 2005,
249, 28802908. View paper

116. Copper(II) complexes of thioether-substituted salcyen and salcyan derivatives and
their silver(I) adducts, I. Sylvestre, J. Wolowska, C.A. Kilner, E.J.L. McInnes and
M.A. Halcrow*, Dalton Trans., 2005, 32413249. View paper

115. Copper(II) complexes of tridentate pyridylmethylethylenediamines: role of steric
hindrance on DNA binding and cleavage, A. Raja, V. Rajendiran, P.U. Maheswari, R.
Balamurugan, C.A. Kilner, M.A. Halcrow and M. Palaniandavar*, J. Inorg. Biochem.,
2005, 99, 17171732. View paper

114. An unusual zinc-promoted decomposition of a bis(2-{pyrid-2-yl}ethyl)amine
derivative, Q.F. Mokuolu, C.A. Kilner, S.A. Barrett, P.C. McGowan and M.A.
Halcrow*, Inorg. Chem., 2005, 44, 41364138. View paper

113. Two regioisomers of (pyrid-2-yl)tetrazole which form two-dimensional five- and six-
connected nets through hydrogen bonding, A.T. Rizk, C.A. Kilner and M.A.
Halcrow*, CrystEngComm, 2005, 7, 359362. View paper

112. A structural, magnetic and Mssbauer spectroscopic study of an unusual angular Jahn-
Teller distortion in a series of high-spin iron(II) complexes, J. Elhak, D.J. Evans, C.A.
Kilner and M.A. Halcrow*, Dalton Trans., 2005, 16931700. View paper

111. 2-[Bis(pyrazol-1-yl)methyl]-4-tertbutyl-6-(phenylsulfanyl)phenol, I. Sylvestre, C.A.
Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2005, 61, o294o296. View
paper

110. An unexpected destabilisation of copper(II) phenoxyl radical species by increased
steric protection, I. Sylvestre, J. Wolowska, E.J.L. McInnes, C.A. Kilner and M.A.
Halcrow*, Inorg. Chim. Acta, 2005, 358, 13371341. View paper



109. An iron(II) complex salt that crystallises in three forms, one of which undergoes a
sterically controlled incomplete spin-state transition on cooling, J. Elhak, C.A. Kilner
and M.A. Halcrow*, CrystEngComm, 2005, 7, 151157. View paper

108. Stereocontrol in asymmetric phospho-aldol catalysis. Chirality relaying in action,
T.D. Nixon, S. Dalgarno, C.V. Ward, M. Jiang, M.A. Halcrow, C. Kilner, M.
Thornton-Pett and T.P. Kee*, C. R. Chimie (special issue on Main Group Compounds
in Catalysis and Coordination Chemistry), 2004, 7, 809821. View paper

107. Iron complexes of 3-(pyrazinyl)-1,2,4-triazole derivatives, F.E. Bradford, L.P.
Connor, C.A. Kilner and M.A. Halcrow*, Polyhedron, 2004, 23, 21412151. View
paper

106. A photomagnetic study of three iron(II) compounds containing ligands from the 2,6-
di(pyrazol-1-yl)pyridine series, V.A. Money, J. Snchez Costa, S. Marcn, G.
Chastanet, J. Elhak, M.A. Halcrow, J.A.K. Howard and J.-F. Ltard*, Chem. Phys.
Lett., 2004, 391, 273277. View paper

105. The thermal and light induced spin transition in [FeL
2
](BF
4
)
2
(L = 2,6-dipyrazol-1-yl-
4-hydroxymethylpyridine), V.A. Money, J. Elhak, M.A. Halcrow and J.A.K.
Howard*, Dalton Trans., 2004, 15161518. View paper

104. Cofactor processing in galactose oxidase, S.J. Firbank, M. Rogers, R. Hurtado-
Guerrero, D.M. Dooley, M.A. Halcrow, S.E.V. Phillips, P.F. Knowles and M.J.
McPherson*, Biochem. Soc. Symp., vol. 71: Free Radicals: Enzymology, Signalling
and Disease, eds. C. Cooper, M. Wilson and V. Darley-Usmar, Portland Press, London,
2004, 1525. View paper

103. Reactions of copper(II) salts with 3{5}-tertbutylpyrazole. Double-cubane complexes
with bound exogenous anions, and a novel pyrazole coordination mode, X. Liu, J.A.
McAllister, M.P. de Miranda, E.J.L. McInnes, C.A. Kilner and M.A. Halcrow*, Chem.
Eur. J., 2004, 10, 18271837. View paper

102. [Tris-(4-{1H-pyrazol-3-yl}-3-aza-3-butenyl)amine]iron(II) diperchlorate
monohydrate, M.J. Hardie, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect.
C, 2004, 60, m177m179. View paper

101. Temperature dependence of the electronic ground states of two mononuclear, six-
coordinate copper(II) centres, M.A. Halcrow*, C.A. Kilner, J. Wolowska, E.J.L.
McInnes and A.J. Bridgeman*, New J. Chem., 2004, 28, 228233 and 2004, 28, 887
(correction). View paper

100. An X-ray powder diffraction study of the spin-crossover transition and structure of
bis(2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate, V.A. Money, I. Radosavljevic
Evans, J. Elhak, M.A. Halcrow and J.A.K. Howard*, Acta Crystallogr., Sect. B, 2004,
60, 4145. View paper

99. A crystallographic, EPR and theoretical study of the Jahn-Teller distortion in [CuTp
2
]
(Tp

= tris-{pyrazol-1-yl}hydridoborate), C.A. Kilner, E.J.L. McInnes, M.A. Leech,


G.S. Beddard, J.A.K. Howard, F.E. Mabbs, D. Collison, A.J. Bridgeman and M.A.
Halcrow*, Dalton Trans., 2004, 236243. View paper



98. A study of the thermal and light-induced spin transition in [FeL
2
](BF
4
)
2
and
[FeL
2
](ClO
4
)
2
L = 2,6-di(3-methylpyrazol-1-yl)pyrazine, V.A. Money, J. Elhak, I.
Radosavljevic Evans, M.A. Halcrow and J.A.K. Howard*, Dalton Trans., 2004, 65
69. View paper

97. Antisymmetric exchange in two tricopper(II) complexes containing a [Cu
3
(
3
-OMe)]
5+

core, X. Liu, M.P. de Miranda, E.J.L. McInnes, C.A. Kilner and M.A. Halcrow*,
Dalton Trans., 2004, 5964. View paper

96. Di--hydroxobis({bis[2-(pyrid-2-yl)ethyl]amine-N
3
}copper(II)) dichloride
hexahydrate, S.A. Leaver, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect.
C, 2004, 60, m1m3. View paper

95. Monocopper oxygenases, M.A. Halcrow* in Comprehensive Coordination
Chemistry II From Biology to Nanotechnology, eds. J. McCleverty and T.J. Meyer,
Elsevier, Oxford, 2003; vol. 8 (eds. L. Que jr. and W.B. Tolman), ch. 8.16, pp. 395
436. View paper

94. Interpreting and controlling the Jahn-Teller structures of six-coordinate copper(II)
centres When is a compression really a compression? (Perspective article), M.A.
Halcrow*, Dalton Trans., 2003, 43754384. View paper

93. A new synthesis of bis(2-{pyrid-2-yl}ethyl)amine (L
H
) from bis(2-{pyrid-2-yl}ethyl)-
hydroxylamine (L
OH
), and a copper-dependent reduction of L
OH
to L
H
, S.A. Leaver, M.
Palaniandavar, C.A. Kilner and M.A. Halcrow*, Dalton Trans., 2003, 42244225.
View paper

92. Cofactor processing in galactose oxidase, S.J. Firbank, M. Rogers, R. Hurtado-
Guerrero, D.M. Dooley, M.A. Halcrow, S.E.V. Phillips, P.F. Knowles and M.J.
McPherson*, Biochem. Soc. Trans., 2003, 31, 506509. View Paper

91. The spin-states and spin-crossover behaviour of iron(II) complexes of 2,6-dipyrazol-1-
ylpyrazine derivatives, J. Elhak, V.A. Money, S.A. Barrett, C.A. Kilner, I.
Radosavljevic Evans and M.A. Halcrow*, Dalton Trans. (special issue on Ligand
Design for Functional Complexes), 2003, 20532060. View paper

90. The structures and decomposition products of palladium(II) and platinum(II)
terpyridine phenoxide complexes, X. Liu, S.L. Renard, C.A. Kilner and M.A.
Halcrow*, Inorg. Chem. Commun., 2003, 6, 598603. View paper

89. (
2
-Tetracyanoethene)bis(triphenylphosphine-P)palladium dichloromethane (1/0.7),
Z. Shackleton, C.A. Kilner, G.D. Reid and M.A. Halcrow*, Acta Crystallogr., Sect. C,
2003, 59, m136m138. View paper

88. Iron(II) complexes of (pyrazol-3-yl)pyrazine. Anion-dependent formation of a
hydrogen-bonded, chiral nanoporous lattice, R.J. Smithson, C.A. Kilner, A.R. Brough
and M.A. Halcrow*, Polyhedron (special issue on Supramolecular Chemistry), 2003,
22, 725733. View paper

87. Copper enzymes and models, M.A. Halcrow* in Encyclopedia of Catalysis, ed. I.T.
Horvth, John Wiley and Sons, New York, 2003; vol. 2, pp. 669706. View paper



86. Hexa--chloro-
4
-oxotetrakis{[5-(2,4,6-trimethylphenyl)pyrazole-N
2
]copper(II)},
X. Liu, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2003, 59, m100
m102. View paper

85. Interpretation of the temperature dependence of the crystal structure of [CuL
2
][BF
4
]
2

(L = 2,6-dipyrazol-1-ylpyridine), G.S. Beddard, M.A. Halcrow*, M.A. Hitchman*,
M.P. de Miranda, C.J. Simmons and H. Stratemeier, Dalton Trans., 2003, 10281032.
View paper

84. Bis{2,6-bis[3-(2,4,6-trimethylphenyl)pyrazol-1-yl-N
2
]pyridine-N}cobalt(II)
dinitrate at 290 and 150 K, M.A. Halcrow* and C.A. Kilner, Acta Crystallogr., Sect.
C, 2003, 59, m61m63. View paper

83. Light induced excited high spin-state trapping in [FeL
2
](BF
4
)
2
(L = 2,6-di(pyrazol-1-
yl)pyridine), V.A. Money, I. Radosavljevic Evans, M.A. Halcrow, A.E. Goeta and
J.A.K. Howard*, Chem. Commun., 2003, 158159. View paper

82. A cyclic hexacopper(II) fluoro complex that encapsulates two fluoride anions, X. Liu,
A.C. McLaughlin, M.P. de Miranda, E.J.L. McInnes, C.A. Kilner and M.A. Halcrow*,
Chem. Commun., 2002, 29782979. View paper

81. Carbaborane salts of [ZnCl(Hpz
tBu
)
3
]
+
, a host for inorganic anions (Hpz
tBu
= 5-tert-
butylpyrazole), S.L. Renard, A. Franken, C.A. Kilner, J.D. Kennedy and M.A.
Halcrow*, New J. Chem., 2002, 26, 16341637. View paper

80. Supramolecular anion binding by the [ZnCl(Hpz
tBu
)
3
]
+
cation (Hpz
tBu
= 5-tert-
butylpyrazole), S.L. Renard, C.A. Kilner, J. Fisher and M.A. Halcrow*, J. Chem.
Soc., Dalton Trans., 2002, 42064212. View paper

79. Dissecting an enzyme model compounds for the galactose oxidase radical site,
M.A. Halcrow*, Heteroatom Chem. (special issue: Proceedings of the 6
th
Anglo-
German Inorganic Chemistry AGICHEM Conference), 2002, 13, 494500. View
paper

78. Bis[-3{5}-(2-pyridyl)pyrazolido]bis[(acetonitrile)copper(II)] diperchlorate, M.J.
Hallam, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2002, 58, m445
m446. View paper

77. [2,6-Bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine]iodocopper(I) dichloromethane
solvate, M.A. Halcrow* and C.A. Kilner, Acta Crystallogr., Sect. C, 2002, 58, m424
m426. View paper

76. Tetrakis(5-tertbutyl-pyrazole-1N
2
)-tetrachloro-1Cl,2
3
Cl--oxo-1:2
2
O-
diiron(III), X. Liu, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2002,
58, m290m291. View paper

75. Control of the spin state of Fe(II) 2,6-di(pyrazol-1-yl)pyridine complexes by distal
ligand substitution, J.M. Holland, S.A. Barrett, C.A. Kilner and M.A. Halcrow*,
Inorg. Chem. Commun., 2002, 5, 328332. View paper



74. Steric effects on the stereochemistry of copper complexes of 2,6-bis(pyrazol-1-yl-
methyl)pyridines, C.L. Foster, C.A. Kilner, M. Thornton-Pett and M.A. Halcrow*,
Polyhedron, 2002, 21, 10311041. View paper

73. 3,4-(4-Methoxybenzo):8,9-benzobicyclo[4.4.1]undeca-3,9-dien-11-one ethylene
acetal, X. Liu, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2002, 58,
o218o219. View paper

72. Copper(II) complexes of 2,6-bis(3-tert-butylpyrazol-1-yl)pyridine, N.K. Solanki,
E.J.L. McInnes, D. Collison, C.A. Kilner, J.E. Davies and M.A. Halcrow*, J. Chem.
Soc., Dalton Trans., 2002, 16251630. View paper

71. 3{5}-Tertbutylpyrazole is a ditopic receptor for zinc(II) halides,

X. Liu, C.A. Kilner
and M.A. Halcrow*, Chem. Commun., 2002, 704705. View paper

70. A crystallographic and EPR study of the fluxional Cu(II) ion in [CuL
2
][BF
4
]
2
(L = 2,6-
dipyrazol-1-ylpyridine), N.K. Solanki, M.A. Leech, E.J.L. McInnes, F.E. Mabbs,
J.A.K. Howard, C.A. Kilner, J.M. Rawson and M.A. Halcrow*, J. Chem. Soc., Dalton
Trans., 2002, 12951301. View paper

69. Supramolecular templating of the double-cubane [{Cu
3
(Hpz
tBu
)
6
(
3
-Cl)(
3
-
OH)
3
}
2
Cu]Cl
6
(Hpz
tBu
= 5-tert-butylpyrazole), X. Liu, J.A. McAllister, M.P. de
Miranda, B.J. Whitaker, C.A. Kilner, M. Thornton-Pett and M.A. Halcrow*, Angew.
Chem., Int. Ed., 2002, 41, 756758. View paper

68. Stereochemical effects on the spin-state transition shown by salts of [FeL
2
]
2+
[L = 2,6-
di(pyrazol-1-yl)pyridine], J.M. Holland, J.A. McAllister, C.A. Kilner, M. Thornton-
Pett, A.J. Bridgeman* and M.A. Halcrow*, J. Chem. Soc., Dalton Trans., 2002, 548
554. View paper

67. Bis[2-(pyrazol-3-yl)phenolato-
2
N
2
,O]copper(II) dimethanol solvate, X. Liu, C.A.
Kilner, M. Thornton-Pett and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2002, 58,
m10m11. View paper

66. Syntheses of new hydroxy-[3.3]orthocyclophanes as models for the galactose oxidase
Tyr-Cys cofactor, X. Liu, S.A. Barrett, C.A. Kilner, M. Thornton-Pett and M.A.
Halcrow*, Tetrahedron, 2002, 58, 603611. View paper

65. Crystal structure of the precursor of galactose oxidase: an unusual self-processing
enzyme, S.J. Firbank, M.S. Rogers, C.M. Wilmot, D.M. Dooley, M.A. Halcrow, P.F.
Knowles, M.J. McPherson and S.E.V. Phillips*, Proc. Natl. Acad. Sci. USA, 2001, 98,
1293212937. View paper

64. Two complexes of CuBr
2
with 5-tertbutylpyrazole, X. Liu, C.A. Kilner, M.
Thornton-Pett and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2001, 57, 12531255.
View paper

63. Metal complexes of 4-(3-phenylpropoxy)-2,2:6,2-terpyridine and 4-(3-propoxy)-
2,2:6,2-terpyridine, X. Liu, E.J.L. McInnes, C.A. Kilner, M. Thornton-Pett and
M.A. Halcrow*, Polyhedron, 2001, 20, 28892900. View paper



62. Steric effects on the electronic and molecular structures of nickel(II) and cobalt(II)
2,6-dipyrazol-1-ylpyridine complexes, J.M. Holland, C.A. Kilner, M. Thornton-Pett
and M.A. Halcrow*, Polyhedron, 2001, 20, 28292840. View paper

61. The effects of distal ligand substitution on the copper(II)/bis-(2,6-dipyrazol-1-yl-
pyridine) centre, N.K. Solanki, M.A. Leech, E.J.L. McInnes, J.P. Zhao,

F.E. Mabbs, N.
Feeder, J.A.K. Howard, J.E. Davies,

J.M. Rawson and M.A. Halcrow*, J. Chem. Soc.,
Dalton Trans., 2001, 20832088. View paper

60. Bis[tris(3-cyclohexylpyrazol-1-yl)hydridoborato]copper(II) dichloromethane
disolvate, M.A. Halcrow*, C.A. Kilner and M. Thornton-Pett, Acta Crystallogr., Sect.
C, 2001, 57, 711713. View paper

59. Chiral bis(oxazoline) complexes. Synthesis, structure and application in chiral
phospho-transfer, M. Jiang, S. Dalgarno, C.A. Kilner, M.A. Halcrow* and T.P. Kee*,
Polyhedron, 2001, 20, 21512162. View paper

58. Copper proteins in the transport and activation of dioxygen, and the reduction of
inorganic molecules, M.A. Halcrow*, P.F. Knowles and S.E.V. Phillips in Handbook
on Metalloproteins, eds. I. Bertini A. Sigel and H. Sigel, Marcell Dekker, New York,
2001; ch. 15, pp. 709762.

57. An unusual abrupt thermal spin-state transition in [FeL
2
][BF
4
]
2
[L = 2,6-di(pyrazol-1-
yl)pyridine], J.M. Holland, J.A. McAllister, Z. Lu, C.A. Kilner, M. Thornton-Pett and
M.A. Halcrow*, Chem. Commun., 2001, 577578. View paper

56. 1-(Dibromomethyl)-4-methoxy-2-methylbenzene, X. Liu, C.A. Kilner, M. Thornton-
Pett and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2001, 57, 317318. View paper

55. Chemically modified amino acids in copper proteins that bind or activate dioxygen,
M.A. Halcrow*, Angew. Chem., Int. Ed., 2001, 40, 346349. View paper

54. Amine oxidases and galactose oxidase, M.A. Halcrow, S.E.V. Phillips and P.F.
Knowles* in Subcellular Biochemistry, vol. 35: Enzyme-Catalyzed Electron and
Radical Transfer, eds. A. Holzenberg and N.S. Scrutton, Plenum Press, London, 2000,
183231.

53. Complexes of 2-hydroxy-5-methyl-1,4-benzoquinone as models for the TPQ-on
form of copper amine oxidases, C.L. Foster, X. Liu, C.A. Kilner, M. Thornton-Pett
and M.A. Halcrow*, J. Chem. Soc., Dalton Trans., 2000, 45634568. View paper

52. Bis{2,6-bis[3-(2,4,6-trimethylphenyl)pyrazol-1-yl-N
2
]pyridine-N}zinc(II)
diperchlorate bis(nitromethane) solvate, M.A. Halcrow*, C.A. Kilner and M.
Thornton-Pett, Acta Crystallogr., Sect. C, 2000, 56, 14251426. View paper

51. An intramolecular - interaction has no effect on the lifetime of an aryl radical
cation, X. Liu, L.M.L. Chia, C.A. Kilner, L.J. Yellowlees, M. Thornton-Pett, S.
Trofimenko and M.A. Halcrow*, Chem. Commun., 2000, 19471948. View paper

50. Copper complexes of 2,6-bis(iminomethyl)pyridine derivatives and of 1,3-bis-
(pyridin-2-yl)pyrazole. Effects of ligand bulk and conformational strain on the ground
state of a six-co-ordinate copper(II) ion, J.M. Holland, X. Liu, J.P. Zhao, F.E. Mabbs,


C.A. Kilner, M. Thornton-Pett and M.A. Halcrow*, J. Chem. Soc., Dalton Trans.,
2000, 33163324. View paper

49. 4-Vinyl-2,2:6,2-terpyridine, X. Liu, C.A. Kilner, M. Thornton-Pett and M.A.
Halcrow*, Acta Crystallogr., Sect. C, 2000, 56, 11421143. View paper

48. Copper(II) complexes of hydroquinone-containing Schiff bases. Towards a structural
model for copper amine oxidases, P. Li, N.K. Solanki, H. Ehrenberg, N. Feeder, J.E.
Davies, J.M. Rawson and M.A. Halcrow*, J. Chem. Soc., Dalton Trans., 2000, 1559
1565. View paper

47. Bis[N,N-bis(2,4,6-trimethylphenyl)-1,2-ethanediylidenediamine]copper(I) tetrafluor-
oborate, C.L. Foster, C.A. Kilner, M. Thornton-Pett and M.A. Halcrow*, Acta
Crystallogr., Sect. C, 2000, 56, 319320. View paper

46. Syntheses, structures and electrochemistry of [Zn(L
1
)
2
](BF
4
)
2
2H
2
O and
[Zn(L
1
)(Tp
R
)]BF
4
(L
1
= 1-{pyrid-2-yl}-3-{2,5-dimethoxyphenyl}pyrazole; [Tp
R
]

=
tris-{3-aryl-pyrazolyl}-borate), L.M.L. Chia, A.E.H. Wheatley, N. Feeder, J.E. Davies
and M.A. Halcrow*, Polyhedron, 2000, 19, 109114. View paper

45. 2,6-Bis-(3-trifluoromethylpyrazol-1-yl)pyridine, M.A. Halcrow*, C.A. Kilner and
M. Thornton-Pett, Acta Crystallogr., Sect. C, 2000, 56, 213214. View paper

44. Steric control of the reactivity of moderately hindered tris(pyrazolyl)borates with
copper(II) salts, L.M.L. Chia, S. Radojevic, I.J. Scowen, M. McPartlin and M.A.
Halcrow*, J. Chem. Soc., Dalton Trans., 2000, 133140. View paper

43. The ground state of a tetragonally compressed copper(II) complex, A.J. Bridgeman*,
M.A. Halcrow, M. Jones, E. Krausz and N.K. Solanki, Chem. Phys. Lett., 1999, 314,
176181. View paper

42. A solid-state phase transition at 41 K involving the cooperative ordering of a fluxional
pseudo-Jahn Teller Cu
II
system, M.A. Leech*, N.K. Solanki, M.A. Halcrow, J.A.K.
Howard and S. Dahaoui, Chem. Commun., 1999, 22452246. View paper

41. Electronic structures of copper(II) complexes of tetradentate hydroquinone-containing
Schiff bases, E.H. Charles, L.M.L. Chia, J. Rothery, E.L. Watson, E.J.L. McInnes,
R.D. Farley, A.J. Bridgeman, F.E. Mabbs, C.C. Rowlands and M.A. Halcrow*, J.
Chem. Soc., Dalton Trans., 1999, 20872095. View paper

40. Syntheses, structures and electrochemistry of copper(II) salicylaldehyde/tris-(3-
phenylpyrazolyl)borate complexes as models for the radical copper oxidases, M.A.
Halcrow*, L.M.L. Chia, X. Liu, E.J.L. McInnes, L.J. Yellowlees, F.E. Mabbs, I.J.
Scowen, M. McPartlin and J.E. Davies, J. Chem. Soc., Dalton Trans., 1999, 1753
1762. View paper

39. Syntheses, structures and magnetism of homoleptic complexes of 4-{pyrid-4-yloxy}-
2,2,6,6-tetramethyl-1-piperidinoxyl, a new spin-labelled pyridine, M.A. Halcrow*,
L.M. Rodriguez-Martinez, E.K. Brechin, J.E. Davies, I.J. Scowen and M. McPartlin, J.
Organomet. Chem. (special issue for B.F.G. Johnson), 1999, 573, 171179. View
paper



38. Structural variations in dicopper(I) double helicate complexes, N.K. Solanki, A.E.H.
Wheatley, S. Radojevic, M. McPartlin and M.A. Halcrow*, J. Chem. Soc., Dalton
Trans., 1999, 521523. View paper

37. Spectroscopic characterisation of a copper(II) complex of a thioether-substituted
phenoxyl radical: a new model for galactose oxidase, M.A. Halcrow*, L.M.L. Chia,
X. Liu, E.J.L. McInnes, L.J. Yellowlees, F.E. Mabbs and J.E. Davies, Chem. Commun.,
1998, 24652466. View paper

36. Co-ordination chemistry of bis(ferrocenylcarbaldimine) Schiff bases, P. Li, I.J.
Scowen, J.E. Davies and M.A. Halcrow*, J. Chem. Soc., Dalton Trans., 1998, 3791
3799. View paper

35. The noble metals, M.A. Halcrow*, Annu. Rep. Prog. Chem., Sect. A, 1998, 94, 255
288. View paper

34. Steric control of the electronic ground state in six-coordinate copper(II) complexes,
N.K. Solanki, E.J.L. McInnes, F.E. Mabbs, S. Radojevic, M. McPartlin, N. Feeder, J.E.
Davies and M.A. Halcrow*, Angew. Chem., Int. Ed., 1998, 37, 22212223. View
paper

33. Complex chemistry of 2,2,6,6-tetramethyl-4-{2,2:6,2-terpyridin-4-yloxy}-
piperidin-1-oxyl, a spin-labelled terpyridine, M.A. Halcrow*, E.K. Brechin, E.J.L.
McInnes, F.E. Mabbs and J.E. Davies, J. Chem. Soc., Dalton Trans., 1998, 24772482.
View paper

32. Metal complexes of sterically hindered pyrazolylpyridines. The single crystal X-ray
structure of [Cu(L
1
)
2
]BF
4
(L
1
= 1-{pyrid-2-yl}-3-{2,5-dimethoxyphenyl}pyrazole),
M.A. Halcrow*, N.L. Cromhout and P.R. Raithby, Polyhedron, 1997, 16, 42574264.
View paper

31. The noble metals, M.A. Halcrow*, Annu. Rep. Prog. Chem., Sect. A, 1997, 93, 241
267. View paper

30. Nickel-dependent redox enzymes, M.A. Halcrow* in Comprehensive Biological
Catalysis, ed. M.L. Sinnott, Academic Press, 1997; vol. 3, ch. 36, 359376.

29. Urease, M.A. Halcrow* in Comprehensive Biological Catalysis, ed. M.L. Sinnott,
Academic Press, 1997; vol. 1, ch. 13iii, 506515.

28. Syntheses, structures and electrochemistry of [CuL
1
(L
R
)]BF
4
[L
1
= 3-(2,5-
dimethoxyphenyl)-1-(2-pyridyl)pyrazole; L
R
= tris(3-arylpyrazolyl)hydroborate] and
[CuL
1
2
][BF
4
]
2
. Effects of graphitic interactions on the stability of an aryl radical
cation, M.A. Halcrow*, E.J.L. McInnes, F.E. Mabbs, I.J. Scowen, M. McPartlin, H.R.
Powell and J.E. Davies, J. Chem. Soc., Dalton Trans. (special issue on Bioinorganic
Chemistry), 1997, 40254035. View paper

27. The reactivity of CuX
2
(X

= Cl

, Br

, MeCO
2

) salts towards tris-pyrazolylborates of


differing steric requirements. The single crystal X-ray structure of
[CuCl(pz
Ph
H)(HB{pz
Ph
}
3
)]CH
2
Cl
2
, M.A. Halcrow*, J.E. Davies and P.R. Raithby,
Polyhedron, 1997, 16, 15351541. View paper



26. The noble metals, M.A. Halcrow*, Annu. Rep. Prog. Chem., Sect. A, 1996, 92, 247
265. View paper

25. One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of
[Bu
n
Sn(NC
5
H
4
-N,C)
3
MBr] (M = Li, Cu), M.A. Beswick, C.J. Belle, M.K. Davies,
M.A. Halcrow, P.R. Raithby, A. Steiner and D.S. Wright*, Chem. Commun., 1996,
26192620. View paper

24. Synthesis, molecular structure and palladium(II) and platinum(II) complex chemistry
of 3-(ferrocen-1-yl)-1-(pyridin-2-yl)pyrazole, R.J. Less, J.L.M. Wicks, N.P.
Chatterton, M.J. Dewey, N.L. Cromhout, M.A. Halcrow* and J.E. Davies, J. Chem.
Soc., Dalton Trans., 1996, 40554061. View paper

23. Role of bifunctional N/S bridging in the association of metals; syntheses and
structures of heterobimetallic [(Ph
3
P)
2
CuL
2
Li(thf)
2
]thf and tetrameric [{CuL(PPh
3
)}
4
]
(L = 1,3-benzoxazoline-2-thionate, thf = tetrahydrofuran), M.A. Beswick, C. Brasse,
M.A. Halcrow, P.R. Raithby, C.A. Russell, R. Snaith, A. Steiner and D.S. Wright*, J.
Chem. Soc., Dalton Trans., 1996, 37933797. View paper

22. Tautomerism in 3{5}-(dimethoxyphenyl)pyrazoles, M.A. Halcrow*, H.R. Powell
and M.J. Duer, Acta Crystallogr., Sect. B, 1996, 52, 746752. View paper

21. Structural and magnetic properties of [Ni
4
(
3
-OMe)
4
(dbm)
4
(MeOH)
4
] and [Ni
4
(
1
,
3
-
N
3
)
4
(dbm)
4
(EtOH)
4
]. Magnetostructural correlations for [Ni
4
(X)
4
]
4+
cubane
complexes, M.A. Halcrow, J.-S. Sun, J.C. Huffman and G. Christou*, Inorg. Chem.,
1995, 34, 41674177. View paper

20. [Mn
6
O
2
{O
2
C-3,5-(NO
2
)
2
-C
6
H
3
}
10
(C
5
H
5
N)
2
{(CH
3
)
2
CO}
2
].2(CH
3
)
2
CO.2(C
2
H
5
)
2
O and
[Mn
6
O
2
(O
2
CC
6
H
5
)
10
(CH
3
CN)
4
], M.A. Halcrow, W.E. Streib, K. Folting and G.
Christou*, Acta Crystallogr., Sect. C, 1995, 51, 12631267. View paper

19. The structure of the D. gigas [NiFe] hydrogenase and the nature of the hydrogenase
nickel complex, M.A. Halcrow*, Angew. Chem., Int. Ed., 1995, 34, 11931195. View
paper

18. A nickel (II) azide cubane: characterization of the magnetic exchange interactions
mediated by a triply-bridging azide group bound end-on, M.A. Halcrow, J.C.
Huffman and G. Christou*, Angew. Chem., Int. Ed., 1995, 34, 889891. View paper

17. Biomimetic chemistry of nickel, M.A. Halcrow* and G. Christou, Chem. Rev., 1994,
94, 24212481. View paper

16. Synthesis, characterization and molecular structure of the new S
2
O complex
Mo(S
2
O)(S
2
CNEt
2
)
3
Et
2
O, M.A. Halcrow, J.C. Huffman and G. Christou*, Inorg.
Chem., 1994, 33, 36393644. View paper

15. Synthesis of cationic half-sandwich rhodium (I) complexes of 1,4,7-trithiacyclononane
([9]aneS
3
). The single crystal structures of [Rh([9]aneS
3
)(C
2
H
4
)
2
]PF
6
,
[Rh([9]aneS
3
)(C
8
H
12
)]BF
4
and [Rh([9]aneS
3
)(C
4
H
6
)]PF
6
0.25OEt
2
, A.J. Blake, R.O.
Gould, M.A. Halcrow and M. Schrder*, J. Chem. Soc., Dalton Trans., 1994, 2197
2208. View paper



14. Organometallic macrocyclic chemistry: synthesis of cationic half-sandwich iridium (I)
complexes of 1,4,7-trithiacyclononane ([9]aneS
3
). Crystal structures of
[Ir([9]aneS
3
)(C
2
H
4
)
2
]PF
6
, [Ir([9]aneS
3
)(C
8
H
12
)]PF
6
and
[Ir([9]aneS
3
)(C
4
H
6
)]PF
6
0.5Et
2
O, A.J. Blake, M.A. Halcrow and M. Schrder*, J.
Chem. Soc., Dalton Trans., 1994, 16311639. View paper

13. Nickel thioether chemistry: syntheses and crystal structures of [Ni
2
(L)
2
(-Cl)
2
][BF
4
]
2

(L = 1,4,7,10-tetrathiacyclododecane, 1,4,8,11-tetrathiacyclotetradecane or 1,5,9,13-
tetrathiacyclohexadecane), A.J. Blake, M.A. Halcrow and M. Schrder*, J. Chem.
Soc., Dalton Trans., 1994, 14631470. View paper

12. Nickel thioether chemistry: synthesis, structures and electrochemistry of five-
coordinate nickel(II) complexes of [9]aneS
3
. Crystal structures of
[Ni([9]aneS
3
)(dppm)][PF
6
]
2
, [Ni([9]aneS
3
)(dcpe)][PF
6
]
2
.1.25MeCN and
[Ni([9]aneS
3
)(tdpme)][PF
6
]
2
{[9]aneS
3
= 1,4,7-trithiacyclononane, dppm =
Ph
2
PCH
2
PPh
2
, dcpe = (C
6
H
11
)
2
PC
2
H
4
-P(C
6
H
11
)
2
, tdpme = CH
3
C(CH
2
PPh
2
)
3
}, A.J.
Blake, R.O. Gould, M.A. Halcrow and M. Schrder*, J. Chem. Soc., Dalton Trans.,
1993, 29092920. View paper

11. Conformational studies on [16]aneS
4
. Structures of - and -[16]aneS
4
([16]aneS
4
=
1,5,9,13-tetrathiacyclohexadecane), A.J. Blake, R.O. Gould, M.A. Halcrow and M.
Schrder*, Acta Crystallogr., Sect. B, 1993, 49, 773779. View paper

10. Selective aromatization of the A-ring of steroids through CC, CH and CO bond
activation by an electrophilic ruthenium complex, F. Urbanos, M.A. Halcrow, J.
Fernandez-Baeza, F. Dahan, D. Labroue and B. Chaudret*, J. Am. Chem. Soc., 1993,
115, 34843493. View paper

9. Crystal structure of (1,4,7-trithiacyclononane)(1,2-
bis(diphenylphosphino)ethane)nickel(II) bis(tetrafluoroborate),
C
32
H
36
NiP
2
S
3
(BF
4
)
2
(H
2
O)
0.4
, A.J. Blake, M.A. Halcrow and M. Schrder*, Z.
Kristallogr., 1993, 205, 295299.

8. Tris-pyrazolyl-borate dihydrogen complexes of ruthenium, M.A. Halcrow, B.
Chaudret* and S. Trofimenko, J. Chem. Soc., Chem. Commun., 1993, 465467. View
paper

7. Aromatization of the B-ring of 5,7-dienyl steroids by the electrophilic ruthenium
fragment [Cp*Ru]
+
, M.A. Halcrow, F. Urbanos and B. Chaudret*, Organometallics,
1993, 12, 955957. View paper

6. [Rh([9]aneS
3
)(CO)(PPh
3
)]
+
.PF
6

, A.J. Blake, M.A. Halcrow and M. Schrder*, Acta


Crystallogr., Sect. C, 1993, 49, 8587. View paper

5. Nickel thioether chemistry: a re-examination of the electrochemistry of
[Ni([9]aneS
3
)
2
]
3+
. The single-crystal X-ray structure of a nickel(III) thioether complex,
[Ni
III
([9]aneS
3
)
2
][H
5
O
2
]
3
[ClO
4
]
6
([9]aneS
3
= 1,4,7-trithiacyclononane), A.J. Blake,
R.O. Gould, M.A. Halcrow, A.J. Holder, T.I. Hyde and M. Schrder*, J. Chem. Soc.,
Dalton Trans., 1992, 34273431. View paper



4. Tri--chloro-bis(1,4,7-trithiacyclononane)dinickel(II) tetrafluoroborate acetonitrile
solvate, A.J. Blake, M.A. Halcrow and M. Schrder*, Acta Crystallogr., Sect. C,
1992, 48, 18441846. View paper

3. Nickel thioether chemistry: syntheses of nickel(II) complexes of tetra- and pentathia
macrocyclic ligands. The single crystal structures of [Ni([16]aneS
4
)(OH
2
)
2
][BF
4
]
2
and
[Ni([15]aneS
5
)][PF
6
]
2
([16]aneS
4
= 1,5,9,13-tetrathiacyclohexadecane, [15]aneS
5
=
1,4,7,10,13-pentathiacyclopentadecane), A.J. Blake, M.A. Halcrow and M.
Schrder*, J. Chem. Soc., Dalton Trans., 1992, 28032808. View paper

2. Synthesis, structure and reactivity of cationic rhodium(I) and iridium(I) thioether
crowns: structures of [M([9]aneS
3
)(cod)]
+
(M = Rh, Ir; cod = cycloocta-1,5-diene) and
[Rh([9]aneS
3
)(C
2
H
4
)
2
]
+
([9]aneS
3
= 1,4,7-trithiacyclononane), A.J. Blake, M.A.
Halcrow and M. Schrder*, J. Chem. Soc., Chem. Commun., 1991, 253256. View
paper

1. The kinetics of crystal growth in the presence of tailor-made additives, S.N. Black,
R.J. Davey* and M. Halcrow, J. Crystal Growth, 1986, 79, 765774. View paper



Book Reviews

184. Introduction to coordination chemistry (G.A. Lawrance, J. Wiley & Sons, 2010),
M.A. Halcrow, Chemistry World, 2010, 7(8), 6061. View paper

185. Molecular orbitals of transition metal complexes (Y. Jean, Oxford University Press,
2005), M.A. Halcrow, Chemistry World, 2005, 2(8), 54. View paper

186. Metal sites in proteins and models: phosphatases, Lewis acids and vanadium (eds.
H.A.O. Hill, P.J. Sadler and A.J. Thomson, Springer Verlag, 1997), M.A. Halcrow,
Appl. Organomet. Chem., 1999, 13, 480. View paper