AIITS-1, PT4 PAPER-set-A PDF

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PHYSICS, CHEMISTRY & MATHEMATICS
SET A

Time Allotted: 3 Hours

Maximum Marks: 180

Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS

Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-1 is Physics, Section-2 is Chemistry and Section-3 is Mathematics.
4. Each section has one part: Part-A
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Sections.

(i) Part-A (01 08) contains 8 multiple choice questions which have only one correct answer. Each
question carries +3 marks for correct answer and 1 mark for wrong answer.

Part-A (09 16) contains 4 paragraphs with 2 questions based on each paragraph. Each question
has only one correct answer and each question carries +3 marks for correct answer and 1 mark for
wrong answer.

Part-A (17 20) contains 4 multiple choice questions which have one or more than one correct
answer. Each question carries +3 marks for correct answer. There is no negative marking.

Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________

FIITJEE - JEE (Advance)

APT - 4

CODE: 080053.1

AIiTS - 1
AIiTS-PT-I-(Paper-1)-SET-A-CMP-IITJEE/13

2
SECTION 1 (Physics)
PART A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

1. Three small spheres A, B and C of masses 1kg, 2kg and
3kg are rotating with a circular disc with angular velocity 3
radian/sec and are connected with strings to O as shown in
figure. Coefficient of friction between spheres A, B, C and
disc is 0.4, 0.3 and 0.2 respectively.

(A) Friction force acting on sphere B is 6 N.
(B) Tension in the string connecting sphere A and B is 9 N
(C) Tension in the string connecting sphere C and O is 8 N
(D) Data insufficient

A

B

O

C

50cm
50cm
100cm
e =3 rad/sec

2. Two blocks connected with the spring of force constant
100 N/m are given velocities
4i m/s and
3i m/s when
the spring is in natural length as shown in figure

2kg

5kg

4 m/s

3 m/s

(A) The velocity of 2kg block is maximum when 5 kg block is at instantaneous rest.
(B) The maximum and minimum velocities of 2kg block is
7i m/s and
3i m/s respectively.
(C) The maximum and minimum velocities of 5kg block is 4 m/s and zero respectively.
(D) All of the above

3. Two objects were projected simultaneously from the top of hills. One from (0, 0, 0)m, with velocity

15i 4j 3k + + m/s and the other from (15, 0, 0) m with speed 13 m/s. If the two object collides in
mid air. Then which of the following is incorrect (consider acceleration due to gravity in negative
z-direction)
(A) The velocity of other object is

12i 4j 3k + + m/s.
(B) The time after which collision occur is 5 seconds.
(C) The coordinates of point of collision is (75, 20, 110) m
(D) None of the above
Space for Rough work


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3

4. A block of mass 2kg starts moving at t = 0
with speed 2m/s on a smooth horizontal
surface. A horizontal force F is applied in
the direction of velocity which varies with
time shown in figure (b) the speed of
particle at t = 3 seconds (g = 10 m/s
2
)

2kg

2m/s

(a)

F

2N

O
t (sec)

1

2

3

(b)

(A) 2.5 m/s (B) 3.5 m/s
(C) 4.5 m/s (D) none of these

5. A conducting sphere of radius r is carrying a charge Q on its outer
surface. Its inner surface is connected to the ground by means of
a wire of resistance R and a switch K as shown in the figure.
When the switch k is closed the quantity of charge flowing to the
ground equals
(A) Q (B) -Q
(C) zero (D) -Q/2

k
r
Q
R

6. In the figure, two point charges +q and q are placed on the x-
axis at (+a, 0) and (-a, 0) respectively. A tiny dipole of dipole
moment (p) is kept at the origin along the y-axis. The torque on
the dipole equals
(A) zero (B)
2
0
qp
2 a tc

(C)
2
0
qp
4 a tc
(D)
2
0
qp
a tc

P
O -q (-a, 0)
+q (a, 0)
x
y

7. In the figure, a square loop of side a and resistance R is moving in a
uniform and constant magnetic field B with constant velocity V. The
induced emf in the loop is equal to
(A) zero (B) Bav
(C)
1
2
Bav (D) none of the above.

A
B
D
C
x x x
x x x
x x x
x x x
x
x
x
x
x
x
x x x
V
B


4

8. In the figure shown current in the long straight wire varies as
I = I
0
0
0
t t
t
| |
|
\ .
where I
o
is the initial current. The charge flown through
resistance R in time t
0
is
(A)
0 0
bI
2 R
t

(B)
0 0
I b
ln
2 R a
| |
|
t
\ .

(C)
0 0
I a b
ln
2 R a
+ | |
|
t
\ .
(D)
0 0
aI b
ln
2 R
| |
|
t
\ .

b
a
R
I

(Paragraph Type)

This section contains 4 paragraphs. Based upon each paragraph 2 multiple choice questions
have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.

Paragraph for Questions 9 and 10

A driver moving on road ABC applies brakes so as to ensure constant
retardation throughout its motion. His speed is 27 m/s at the bottom (at
A) and 13 m/s at the top (at C). The distance of C from A along ABC is
80 m. The passenger experiences a total acceleration of 4.5 m/s
2
at A
and radius of curvature at C is 130 m. DBE is a straight line
( 8 2.83, 13.94 3.7 = = )

A
D
B
E
C

9. The radius of curvature at A is
(A) 257.6 m (B) 247.6 m
(C) 208.3 m (D) 200.3 m

10. Magnitude of total acceleration at B is
(A) 3.5 m/s
2
(B) 3 m/s
2

(C) 4.5 m/s
2
(D) 3.7 m/s
2



5

If the forces are conservative and potential energy is U then we can find force (F) from potential energy U
as
dU
F
dr
= . If potential energy of a body is minimum at equilibrium then this type of equilibrium is known
as stable equilibrium. When potential energy of the body is constant then equilibrium is called as neutral
and when potential energy becomes maximum at equilibrium it is called as unstable equilibrium.
Equilibrium happens when force on the body becomes zero.

11. If potential energy for a conservative system is given by
2
U ax bx = , where a and b are positive
constants. Then at
b
x
a
=
(A) equilibrium is stable (B) equilibrium is unstable
(C) equilibrium is neutral (D) equilibrium is not possible

12. If force on a body is F = 2x 1, the possible equilibrium is at
(A) x = 1 and stable (B) x = and unstable
(C) x = and stable (D) x = 1 and unstable


Four metallic plates are placed as shown in the figure. Plate 2 is given
a charge Q whereas all other plates are uncharged. Plates 1 and 4 are
earthed. The area of each plate is same.

13. The charge appearing on the right side of plate 3 is
(A) zero (B) +Q/4
(C) 3Q/4 (D) Q/2

14. The charge appearing on right side of plate 4 is

d
1 2 3 4
Q
2d d

(A) zero (B) Q/4
(C) 3Q/4 (D) Q/2


6

A long cylindrical conductor of radius R having a cylindrical cavity of
radius R/2 through out its length is lying with its axis parallel to x-axis.
The distance between the axes of the cylinder and the cavity is R/2. A
constant current I is passed through the cylinder along its length in the
positive x direction. The cross-sectional view of the cylinder is shown in
the figure.

x

y
z

15. The magnetic induction at point on the cavity is
(A)
0
I
( k)
3 R
t
(B)
0
I
(k)
3 R
t

(C)
0
I
( j)
6 R
t
(B)
0
I
( j)
6 R
t

16. A charged particle having specific charge (charge to mass ratio) is
6
0
18
10
I
t

SI unit is projected
from a point on the axis of the cavity along x-axis with the speed of 10
6
m/s. Radius of curvature
of the path of the particle is equal to
(A) R/18 (B) R/9
(C) R/6 (D) R/3

(Multi Correct Choice Type)

(C) and (D) out of which ONE OR MORE may be correct.

17. A conducting wire of length and mass m can slide without friction
on two parallel rails and is connected to capacitance C. Whole
system lies in a magnetic field B and a constant force F is applied to
the rod. Then

(A) the rod moves with constant velocity

C
F
B

(B) the rod moves with an acceleration of
2 2
F
m B c +

(C) there is constant charge on the capacitor.

(D) charge on the capacitor increases with time


7
18. An electric kettle heater has two coils when one coil is switched on, the water in the kettle begins
to boil after 15 minutes, when the other coil is switched on the water boils in 30 minutes.

(A) The waver will boil in 45 minutes if the coils are connected in series.
(B) The water will boil in 10 minutes if the coils are connected in parallel.
(C) Water boils in 22.5 minutes if coils are connected in series.
(D) Water boils in 20 minutes if coils are connected in parallel.

19. Coefficient of friction between the two blocks is 0.3
whereas the surface AB is smooth. (g =10 ms
2
)

(A) Acceleration of the system of masses is 5.86 ms
2

(B) Tension T
1
in the string is 17.7 N
(C) Tension T
2
in the string is about 41.4 N
(D) Acceleration of 10 kg mass is 7.55 ms
2

T
2

10kg
3kg
2kg
T
1

A
B

20. Two projectiles are thrown at the same time from two different points. The projectile thrown from
the origin has initial velocity

3i 3j + with respect to earth. The projectile has initial velocity

ai bj +
with respect to earth thrown from the point (10, 5). (
i is a unit vector along horizontal,
j along
vertical). If the projectiles collide after two second, then the
(A) value of a is -2 (B) value of a is
1
2

(C) value of b is
1
2
(D) value of b is 2


8
SECTION 2 (Chemistry)
PART A

1. Give the correct increasing order of acid strength.

OH
OH
OMe
OH
NO
2
OH
Cl
(I) (II)
(III)
(IV)

(A) III > IV > I > II (B) IV > III > I > II
(C) IV > I > II > III (D) I > II > III > IV

2. Which of the following will easily decarboxylate on heating?
(A)
OH
O
C H
3

(B)
O
CH
3
OH
O

(C)
C H
3
C H
3
O
OH

(D)
O H
O
OH
OH



9

3.
C
O
NH
2
( )
4 10 3
2 3 2
P O CH MgBr Yellow ppt. with
Ca OH , I H O
W X Y Z
+
A

Final product Z will be
(A)
C
O
CH
3

(B) COOH

(C)
C
O

(D)

4. 3
CH OH+
O
CH
3
H
A(major product)
+
. The product (A) is

(A) H
3
C CH CH
2
OH
OCH
3

(B)
H
3
C CH
CH
2
OH
OCH
3

(C) H
2
C CH
2
CH
2
OCH
3
OH

(D)
H
3
C CH CH
2
OH OH

5. Which of the following is Tshaped?
(A)
2
XeOF (B)
3
XeO
(C)
4
XeOF (D)
6
XeF

6. Equal masses of
2 4 2
SO , CH and O are mixed in empty container at 298K, when total pressure
is 2.1 atm. The partial pressure of
4
CH in the mixture is
(A) 0.5 atm (B) 0.75 atm
(C) 1.2 atm (D) 0.6 atm


10
7. If the radius of first Bohr orbit is x, then de Broglie wavelength of electron in 3
rd
orbit is nearly.
(A) 2tx (B) 6tx
(C) 9x (D)
x
3

8. If 10 ml of H
2
O
2
solution of volume strength x, required 10 ml of
4
N
MnO
0.56

solution is acidic
medium then x is
(A) 0.56 (B) 5.6
(C) 0.1 (D) 10

(Paragraph Type)



Hybridization in the mixing of atomic orbitals belonging to the same atom but having slightly different
energies so that a redistribution of energy takes place between them resulting in the formation of new
orbitals of equal energies and identical shapes.
Hybridization is used for explaining the geometry molecules. There are several type of hybridization like
sp, sp
2
, sp
3
, sp
3
d, sp
3
d
2
, sp
3
d
3
etc.

9. Among the compounds BF
3
, NCl
3
, H
2
S, SF
4
& BeCl
2
identify the ones in which the central atom
has the same type of hybridization
(A) BF
3
, NCl
3
(B) H
2
S and BeCl
2

(C) SF
4
and BeCl
2
(D) NCl
3
and H
2
S

10. Pair of species having identical shapes for molecule is
(A) CF
4
, SF
4
(B) BF
3
, PH
3

(C) XeF
2
, CO
2
(D) PF
5
, IF
5



11

The salts of alkali metals are ionic and soluble in water. The solubility of an ionic compound depends on
two factors: (i) Lattice energy and (ii) Hydration energy. These two factors oppose each other. If hydration
energy is high, the ions will have greater tendency to be hydrated and therefore the solubility will be high.
The smaller the cation, the greater is the degree of its hydration. Hydration of ions is an exothermic
process. Higher is the energy released if greater is the degree of hydration. Reducing power of alkali
metals in solutions is also dependent on the hydration energy besides other factors.

11. The radius of which ion (hydrated) is lowest?
(A) [Li(aq.)]
+
(B) [Na(aq.)]
+

(C) [K(aq.)]
+
(D) [Cs(aq.)]
+

12. Strongest reducing agent amongst alkali metals in aqueous solutions is
(A) Li (B) Na
(C) K (D) Cs


12

Aldehydes undergo disproportionation reaction in presence of aqueous NaOH. Simultaneous oxidation
and reduction of a compound is scientifically called as disproportionation.
Aldehydes having no o-hydrogen show this reaction called Cannizzaros reaction. Few exception are also
there to this generalization.
The reaction may be represented as:
NaOH
6 5 6 5 6 5 6 5 2
C H CHO C H CHO C H COONa C H CH OH
A
+ +
Answer the following questions:

13. The product formed in the following reaction will be

CHO
CHO
NaOH
Product

(A) CH
2
OH
CH
2
OH

(B) CH
2
OH
COONa

(C) COONa
COONa

(D) All of these

14. Which of the following compounds gives intramolecular Cannizzaro reaction?

(A)
H
5
C
6
CH
2
C
O
H

(B)
H
5
C
6
C
O
CHO

(C)
CHO
CHO

(D)
CHO
H
2
C CHO



13

A reaction characteristic of vicinal diols is their oxidative cleavage on treatment with periodic acid (HIO
4
).
The carbon-carbon bond of the vicinal diol unit is broken and two carbonyl groups result. Periodic acid is
reduced to iodic acid (HIO
3
).

C C
R
OH
R'
OH
R R' + HIO
4
C O
R
R
+ C O
R'
R'
+
HIO
3
+ H
2
O

Cyclic diols react to give dicarbonyl compounds. The reaction are faster when the hydroxyl groups are cis
than when they are trans but both stereoisomers are oxidized by periodic acid. Periodic acid cleavage of
vicinal diols is often used for analytic purposes as an aid in structure determination. By identifying the
carbonyl compounds produced, the constitution of the diol may be deduced.

15. Which of the following compound(s) is/are obtained when the following compound is oxidized by
HIO
4
?
CH
OH
C
CH
3
OH
CH
3

(A)
C
O
H

(B)
C H
3
C
O
H

(C)
C
O
CH
3

(D)
C H
3
C
O
H

16. Which of the following products is/are obtained when glycerol is treated with HIO
4
?
(A) HCHO (B) HCOOH
(C) HIO
3
(D) All of these


14


17. Which of the following molecules is/are tetrahedral?

(A) XeF
4
(B)
4
NH
+

(C) CCl
4
(D) CH
4

18. Which of the following ethers are cleaved by hot conc. HI?
(A)
O
CH
3

(B)
O

(C)
O

(D)
O

19. Which of the following amines can be resolved into two enantiomers?
(A)
N
H
(A)

(B)
N
H
(B)

(C)
N

(D)
C
H
NH
2

20. Mixture of C
6
H
5
CHO and HCHO is treated with NaOH then Cannizzaro reaction involves

(A) oxidation of HCHO (B) reduction of HCHO
(C) oxidation of C
6
H
5
CHO (D) reduction of C
6
H
5
CHO


15
SECTION 3 (Mathematics)
PART A

1. An equilateral triangle is inscribed in a circle of radius r. P is any point inside triangle.
Perpendiculars are dropped from P to the sides. The sum of the lengths of the perpendiculars
is
(A) 3r (B)
3
2
r
(C) 9r (D) none of these

2. The set of solution |x
2
+ x| = x
2
+ x is given by

(A) (-, -1) (B) [0, )
(C) [-1, 0] (D) (-, -1] [0, )

3. The chords of contact of the pair of tangents drawn from each point on the line 2x + y = 4 to x
2
+
y
2
= 1 pass through the point
(A) (1, 2) (B)
1 1
,
2 4
| |
|
\ .

(C) (2, 4) (D) none of these

4. Let y = f(x) be a continuous and differentiable curve. The normals at (1, f(1)), (2, f(2)) and (3, f(3))
make angles , and
3 4 6
t t t
with positive x-axis respectively. Then value of
( ) ( ) ( ) ( ) ( )
2 3
1 2
f x xf x dx f x f x dx ' ' '' + +
} }
is equal to
(A) f'(2) + f(1) + 1 (B) 2f(2) f(1) + 1
(C) f(3) f(2) + 1 (D) none of these

5.
( )
2
1
x 0
tan sec x
lim
xsin x
t
is equal to

(A) t (B) t
(C) 0 (D) none of these


16
6. If ( )
1
sin / 4
0
4sin
t
t u
}
sin 2u ln (1 + tan (sin u)) du is k, then
3
960k
ln2 t
is equal to
(A) 11 (B) 10
(C) 12 (D) none of these

7. If A cos x = cos (x + ) + B is an identity in x, then the number of values of ordered triplet (A,
cos, B) is
(A) 0 (B) 1
(C) 2 (D) 3

8. Let f(x) = | x | {x} (where {.} denotes the fractional part of x) and X, Y and its domain and range
respectively, then
(A) f : X Y y = f (x) is one-one function (B) ) x e | )
1
, 0,
2
| (

(
\
and Y e
1
,
2
|
|
.

(C) X e | )
1
, 0,
2
| (

(
\
and Y e [0, ) (D) none of these

(Paragraph Type)



A triangle ABC is given where vertex A is (1, 1) and the orthocenter is (2, 4). Also sides AB and BC are
members of the family of lines ax + by + c = 0 where a, b, c are in A.P.

9. The vertex B is

(A) (2, 1) (B) (1, 2)
(C) (1, 2) (D) none of these

10. The coordinate of the circumcentre is
(A) (6, 1) (B)
17 1
,
2 4
| |
|
\ .

(C)
17 1
,
2 2
| |
|
\ .
(D) none of these


17

A circle C whose radius is 1 unit, touches the xaxis at point A. The centre Q of C lies in first quadrant.
The tangent from origin O to the circle touches it at T and a point P lies on it such that AOAP is a right
angled triangle at A and its perimeter is 8 units.

11. The length of QP is
(A)
1
2
(B)
4
3

(C)
5
3
(D) none of these.

12. Equation of circle C is
(A)
2 2
{x (2 3)} (y 1) 1 + + = (B)
2 2
{x ( 3 2)} (y 1) 1 + + =
(C)
2 2
(x 3) (y 2) 1 + = (D) none of these.


Let n be a positive integer such that I
n
=
n 2 2
x a x dx
}
, then answer the following questions:

13. The value of I
1
is
(A)
( )
1/ 2
2 2
2
a x
3
(B)
( )
3/ 2
2 2
1
a x
3

(C)
( )
3/ 2
2 2
2
a x
3
(D)
( )
3/ 2
2 2
1
a x
3

14. If I
n
=
( )
3/ 2
n 1 2 2
n 2
x a x
kI
n 2

+
+
, then the value of k is
(A)
n 1
n 2
+
(B)
n 2
n 1
+

(C)
2
n 1
a
n 2
| |
|
\ + .
(D)
2
n 2
a
n 1
+ | |
|
\ .



18

If f(x) is a differentiable function wherever it is continuous and f'(c
1
) = f'(c
2
) = 0, f(c
1
) . f(c
2
) < 0,
f(c
1
) = 5,
f(c
2
) = 0 and (c
1
< c
2
).

15. If f(x) is continuous in [c
1
, c
2
] and f(c
1
) f(c
2
) > 0, then minimum number of roots of f'(x)
= 0 in [c
1
1, c
2
+ 1] is

(A) 2 (B) 3
(C) 4 (D) 5

16. If f(x) is continuous in [c
1
, c
2
] and f(c
1
) f(c
2
) < 0, then minimum number of roots of f'(x)
= 0 in [c
1
1, c
2
+ 1] is

(A) 1 (B) 2
(C) 3 (D) 4



19


17. Two circles C
1
and C
2
intersect at two distinct points P, Q in a plane. Let a line passing through P
meets the circles C
1
and C
2
in A and B respectively. Let Y be the mid point of AB and QY meet
the circles C
1
and C
2
in X and Z respectively, then
(A) Y is the mid point of XZ (B)
XY 2
YZ 1
=
(C) YX = YZ (D) XY + YZ = 3YZ

18. If x
1
and x
2
are positive numbers between 0 and 1, then which of the following is/are true?
(A)
1 2 1 2
x x sinx sinx
sin
2 2
+ + | |
s
|
\ .
(B)
1 2 1 2
x x tanx tanx
tan
2 2
+ + | |
s
|
\ .

(C)
1 2 1 2
x x logx logx
log
2 2
+ + | |
s
|
\ .
(D)
2
2 2
1 2 1 2
x x x x
2 2
+ + | |
s
|
\ .

19. If u
R
e[0, t] for 1 s k s 10, then the maximum value of
10
2 2
R R
R 1
(1 sin )(1 cos )
=
+ u + u
[
is
(A)
10
3
2
| |
|
\ .
(B)
10
9
4
| |
|
\ .

(C)
20
3
2
| |
|
\ .
(D)
5
9
4
| |
|
\ .

20. If y is a function of x given by 2log(y 1) log x log(y 2) = 0, then

(A) domain is [4, ) (B) domain is (0, )
(C) range is (2, ) (D) range is (0, )


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i is a unit vector along horizontal,

. The product (A) is

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