IIT Section

Subject Topic Grand Test Paper I Date

C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

1

Key Answers:
1. c 2. d 3. a 4. a 5. b 6. b 7. c 8. a 9. abd 10. bc
11. abd 12. bc 13. abcd 14. b 15. c 16. a 17. c 18. a 19. 2 20. 7
21. 8 22. 2 23. 6 24. 2 25. 6 26. 3 27. 1 28. 5 29. c 30. d
31. a 32. b 33. c 34. b 35. a 36. a 37. ac 38. abcd 39. b 40. a
41. acd 42. a 43. b 44. d 45. b 46. a 47. 8 48. 2 49. 7 50. 6
51. 7 52. 5 53. 4 54. 8 55. 3 56. 3 57. a 58. b 59. d 60. b
61. a 62. c 63. a 64. c 65. ab 66. acd 67. cd 68. abcd 69. ac 70. a
71. b 72. b 73. a 74. d 75. 1 76. 2 77. 3 78. 4 79. 3 80. 2
81. 5 82. 4 83. 8 84. 7


Solutions:
Chemistry
1. Hydrogen atoms bonded to phosphorus are readily available as nascent hydrogen to carryout
reduction. Thus, the more the number of such bonds the stronger is the reducing action of the
compound
Compound Formula Number of P H bonds present
Pyrophosphoric acid
7 4 2
H P O O
Hypophosphoric acid
4 2 6
H P O O
Hypophosphorous acid
3 2
2 H PO
Ortho Phosphorous acid
3 3
1 H PO

2.




Let the volume of cylinder (except piston) be V and pressure exerted by piston be
0
P . Now,
1 1
0 1 2 1 2
P P P P P = =
or
1 300 1 300 1 1
4 3
5 5 4 4
R R R T R T
V V V V

= =
| | | | | | | |
| | | |
\ . \ . \ . \ .

or, 1500 (1 ) = 4T (1 1/3)
T = 421.875 K
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

2

3. FeSO4 undergoes cationic hydrolysis slowly with the water of crystalisation as described
below to form Fe(OH)2 which is then oxidised by air to form Fe(OH)SO4 - basic ferric sulphate.
This is why green vitriol invariably contains Fe
+ 3
impurities. It is evident that green vitriol
when exposed to air turns yellowish brown due to formation of basic ferric sulphate. Hence
green vitriol is not used as primary standard during titration.
( )
4 2 2 4
2
4 8 4 4 FeSO H O Fe OH H SO + +
( ) ( )
2 2
2 3
4 2 4 Fe OH H O O Fe OH + +
( ) ( )
2 4 4 2
3
4 4 4 8 Fe OH H SO Fe OH SO H O + +
( )
4 2 2 4
4 2 4 FeSO H O O Fe OH SO + +
However, in the presence of (NH4)2SO4 the above hydrolysis is prevented because
ammonium sulphate being a salt of weak base-strong acid undergoes hydrolysis at a rate faster
than the hydrolysis of FeSO4 and maintains necessary p
H
value to undo the hydrolysis of FeSO4.
As a result, conversion of Fe
+ 2
to Fe
+ 3
is prevented. So, Mohrs salt serves as a better standard
than green vitriol K2Cr2O7 , when dissolved in water, not only dissociates but also undergoes
anionic hydrolysis at p
H
= 7 to establish dichromate-chromate dynamic equilibrium as given
below.
( )
( )
2 7
2
2 2
2 7 4
2 7
2
2
H
OH H O p
H
H H O p
Cr O CrO

>

+
<

Now, since AgOH is basic in nature, when it is added to an aqueous solution of K2Cr2O7 the p
H
of
the solution becomes greater than 7 and the above equilibrium favours to CrO4
-2
side. As a result,
brick red precipitate of Ag2CrO4 is obtained instead of Ag2Cr2O7. Bleaching powder dissociates
as;
( )
cold water 2 1 1
Ca Cl OCl Ca Cl ClO
+
+ +
However, in warm water, ClO

(hypochlorite ion) disproportionates as;

hot water 1 1
3
3 2 ClO Cl ClO

+
Oxidising action of
1
ClO

is more than that of

1
3
ClO

. So, in cold water the oxidising action of bleacing

powder is more. Similarly, a cold aqueous solution of chlorine contains HClO while a warm aqueous
solution of chlorine contains HClO3. Acidic nature of HClO3 is higher than that of HClO.
4. Conceptual
5. Initially
2
2
1
2
H
H S
n
n
=

2 2 8
8 8 H S H S +
Initial moles : 2 1 -
moles at equil : 2x 1+x -
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

3

At equilibrium :
2
2
1
2
2
H x
x
H S
n
n
+
= =

Hence x = 1

8 8
2 1 256
P
K = =

6.
Total
1 3
512 344
4 4
P = +
= 128 + 86 (3)
= 386 mm < given value hence the solution shows + ve deviation from Raoult's law
( ) , OH ve OV ve = + = +
7.
2 3
( ) ( ) Z X
B F BF + ;
( )
3 2 6 4
8 6 6
Y
BF LiH B H LiBF + +

8. Hint:
3
NO

and
2
3
CO

both have same number of electrons (32 electrons) and central atom in each
being
2
sp hybridized.
3
SO - 40 electrons
3
ClO

= 42 electrons



Structure of
2
3
CO

Structure of
3
NO

9. Crystals with F-centres - unpaired electrons are present and hence paramagntic. In Frankel defect
ions are dislocated from the normal sites to interstitial sites. The unit cell of diamond that follows
ZnS structure, there are eight carbon atoms and not four. The electrical neutrality is maintained
due to Schottky defects since pairs of ions are missing.


10. PCl6
-1
exists but not PBr6
-1
due to large size of Br. So, solid PBr5 exists as PBr4
+ 1
and Br
-1
. Non-
existence of PH5 against PF5 may be due to any one of the following reasons;
(i) Higher oxidising power of F over H
(ii) Higher strength of P-F bonds over P-H bonds
(iii) Higher electronegativity of F over H
Because of all the above reasons, when hydrogen atoms are around phosphorus the
C
O
-
O
O
N
-
O O
O
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

4

energy difference among 3s, 3p and 3d orbitals of phosphorus atom do not get minimised to
enable the central atom to achieve sp
3
d hybridisation. Because of high oxidising power of F it
stays penetrated towards Bi and forms strong bond that releases energy sufficient enough to
overcome the resistance offered by inert pair effect of Bi. Hence Bi shows + 5 state with fluorine.
BiCl3 and SbCl3 readily undergo hydrolysis to form HCl that responds chromyl chloride test. The
hyrolysis of BiCl3 and SbCl3 are given below;
3 2
2 BiCl H O BiOCl HCl + +
3 2
2 SbCl H O SbOCl HCl + +
11. Alcohol behaves as a base. 3 alcohol, pKa value more farm white turbidity very fast. 1 alcohol
react with NO , readily 1 alcohol give red colour in Victor Meyer test and at 0 Ea = , on surface
of catalyst 0 Ea = it is law
12. At infinity temperature
13.
2
CaH (hydrolith) is used for production of
2
H .
BeO is covalent but has high melting point due to high lattice energy

2
CaCl when mixed with ice gives a freezing mixture ( 54 )
o
C .
2
Be C (beryllium carbide) reacts with water to give methane.
2 2 2 4
2 ( ) Be C H O Be OH CH + +
All the above statements are correct.
14. The magnitude of + ve charge on the carbonyl carbon of acid chloride is maximum and
nucleopphile attacks easily. It is a better leaving group. Due to + M effect of oxygen the
magnitude of + ve charge is less in others and decrease from anhydrides to amides, leaving group
ability of z also decreases gradually.
15. It is Claisen condensation reaction
16. Triple bond is also affected and partially reduced to cis.
17. NO2 ligands at cis-position only are exchangeable
18. When NO2 at trans position ligand exchange is not possible.
19.
2
2 2 Mg Ag Mg Ag
+ +
+ +
2
cell cell
2
0.0591
log
Mg
E E
n
Ag
+

+
(

=
(


or
2
cell cell
2
0.0591
log
Mg
E E
n
Ag
+

+
(

=
(


In 1
st
case,
( )
cell cell
2
0.0591 0.1
log
2
0.5
E E

=
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

5

In 2
nd
case,
( )
cell cell
2
0.0591 0.01
log
2
0.25
E E

=

( )
( )
2
2
2
0.1
0.0591
log
2
0.5
=
(



( )
2
0.0591 0.1
2log 2
2
0.5
= = times
20. ( ) ( ) ( ) ( ) ( )
3 3 2 6 14
2 2
CH CHN NCH CH g N g C H g = +
Initial pressure 5 atm 0 0
After 1 hour
40
5 5
100
2 atm 2 atm
5 2 = atm 3 = atm
Total pressure after one hour 3 2 2 7 = + + = atm
21. 5 moles of
4
FeSO react with 1 mole of
4
KMnO

( )
3.04
56 96 +
of
4
FeSO react with
3.04
152 5
of
4
KMnO
3.04
0.5
152 5
V =

3
8 10 8 V l ml

= ~
22.
4 3 3 4 3 2 2
BrownSolid RedSolid
; 2 2 ; KAgF BF AgF KBF AgF Xe AgF XeF + + + +
Xe has 2 + oxidation state in
2
XeF
23.
3
2 6
[Al(H O) ] ; C.N 6
+
=


24.


25. At low temperature,
3
AlCl exists as a close packed lattice of Cl

ions with
3
Al
+
ions occupying
octahedral voids. Thus,
3
Al
+
ions has 6 Cl

ions around it. Hence, its coordination number is 6

26.
3 3 2
60 31
CH COOH CH NH
60 1.55
3
31

=
O
CH
3
IIT Section

Subject Topic Grand Test Paper I Date
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IIT GT 06
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th
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6

27. ( ) ( )
4 11 4 9 2 3 2 3
3 3
1 amin
3 alcohol
C H N C H NH CH C NH CH COH

28.



C C
CH
3
H H
CH
3
X = or
C C
CH
3
H CH
3

H
CH
3
CH
2
CH CH
2
Br
2
/ CCl
4
Br
2
/ CCl
4
Br
2
/ CCl
4
CH
3
CH
3
H Br
Br H
+ enanti omer
CH
3
CH
3
Br H
Br H
CH
3
C
H
CH
3
CH
2
Br + enantiomer
meso
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

7

Mathematics
29. On simplification the conic reduces to
2 2
2 2
1
1 1
x y
r r
r r
+ =
| | | |
+
| |
\ . \ .

Which is ellipse.
The distance is
2 2
2 a b
2
2 2
1 1
2 r r
r r
| | | |
= +
| |
\ . \ .


2 2 4 = =
30. (1) ( )
2
16
0 9 4 1 4 0 or 0
7
m m m m m A > + > < >
(2)
( )
3
1 1 1 or 2
2 2 1
b m
m m
a m
> > < >
+

(3) ( ) ( ) ( ) 1 0 1 1 0 a f m f > + > ( )| |
1
1 2 1 0 1 or
2
m m m m + + > < >
From above we can conclude ( )
16
, 2,
7
m
| |
e
|
\ .

31. Usual conversions
32. For infinite solutions
1 2 3
0 A = A = A = A =

Here 0 A = ; now


1
0 A =
2
3 2 0 1, 2 K K K K + = = =

For these values of k,
2, 3
A A are also zero

There are two values of K.
33. Any normal to the parabola meets at

2
( 2 ) am am

Here

1, 2 m a = =

(2, 4) is the point.
34. The derivative of
3
7
x
x x + +

is the given integral

35. The given equation is


1
cos ( ) xy xdy ydx dx
x
+ =

1
cos ( ) xyd xy dx
x
=

Integrating

sin log xy x c = +

IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

8

36. Condition of tangent to an ellipse or eliminate y from the two equations. 0 A = for the obtained
equation. We get
2 2
1
a b
c d
+ =
37.
( )
10
2
log 5 3 6
3 2
10
x
T C x x = =
10
2log 3 5
10
x
x x =
10 10 10
3log 2log log 5 x x x + =
( )( )
10 10
log 1 2log 5 0 x x + =
5
2
10 or 10 x x

= =
38. Let ( ) P A x =
,
( ) P B y = A and B independent

1
( ). ( )
6
P A P B =

Now
1
1 1
( ) ; ( )
6 3
P A B P A B = =

1
1 ( )
3
P A B =

2
( )
3
P A B =

2
( ) ( ) ( )
3
P A P B P A B + =


2
,
3
x y xy + =

5
,
6
x y + =

1
6
xy =

39. ( ) ( )
2 5
7 2 E x x = +
( ) ( ) ( ) ( )
4 4 3 5
7 5 2 4 7 2
dE
x x x x
dx
= + +
0 3
dE
x
dx
= = since ( ) 2, 7 xe
( ) ( ) ( )
3 4
7 2 9 27
dE
x x x
dx
= +
By wavy curve method,
dE
dx
changes from positive to negative at 3 x =
E attains maximum at 3 x =
40. Solving

1 2 1 2
3 10 c c r r = = +

41. Given expression ( ) ( )
2 2
2 0 2 a c a b a b + = = andc a =
IIT Section

Subject Topic Grand Test Paper I Date
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IIT GT 06
08
th
May 2014
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9

the sides are 2 , , 2 b b b
triangle is isosceles
Again,
2 2 2
1
cos
2 4
b c a
A
bc
+
= =
2 2 2 2
2
7 7
cos
2 8
8
a c b b
B
ac
b
+
= = =
42.
1 31 2 32 3 33
b C b C b C + +
2 3 1 3 1 2
1 2 3
2 3 1 3 1 3
0
a a a a a a
b b b
b b b b b b
= + =
43. Value of the new determinant
3
2 8 = A = A
44.
3 13 3 23 3 33
a M b M c M +
3 13 3 23 3 33
a C b C c C = + + = A
45. & 46.
, , a b c are in A. P.
0 ax by c + + = will pass through the point ( ) 1, 2
Orthocenter ( ) 2, 4 H = =
Slope of 3 AH =
Slope of
1
3
BC =
Slope of 6 BH =
Slope of
1
6
AC =
1 1
3 6
tan 0
1 1
1
3 6
C
| |

|
\ .
= <
| || |
+
| |
\ .\ .

90 C >
47. , o | are roots of
2
4 1
4 1 0 , Ax x
A A
o o + = + = =
, | o are roots of
2
6 1
6 1 0 , Bx x
B B
| o |o + = + = =
, , , o | o are in H. P.
1
2
2 1
4
2
A
A
o
|
o
= = =
+


( ) 1, 1 A
( ) 1, 2 B
( ) 2, 4 H
C
IIT Section

Subject Topic Grand Test Paper I Date
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IIT GT 06
08
th
May 2014
I20140508

10

1
2
| = is a root of second equation
2
1 1
6 1 0 8
2 2
B B
| | | |
+ = =
| |
\ . \ .

48. K is an integer
( )
2
2
5
1 2
3
1
K
K
K
= =
+

49. For Hyperbola
2
2
2
81 225 15 5
1 1
144 144 12 4
b
e e
a
= + = + = = =
( )
2
144
Foci are ( , 0) 3, 0
25
a ae = =
For ellipse 3 ae = or
2 2
9 a e =

2
2 2
2
1 9 7
b
a b
a
| |
= =
|
\ .

50. Cosine rule in ABC and in ADC


Area of ABC +Area of ACD =

4 3


1 1
.10.sin60 . .sin120 4 3
2 2
cd + =


5 3 1 3
. . 4 3
2 2 2
cd + =


5 8
2
cd
+ =


6 cd =
51. Drs of median

5 8
,1,
2 2


Since median is equally inclined to axes: drs equal

5
1 7
2

= =

52. The line is Parallel to the plane

is
r
K distance from

( ) 2, 2, 3

to 5 5 0 x y z + + =

2 10 3 5 10
1 25 1 3 3
K
+
= =
+ +



3 3 3 3 10
5
2 2
2 3
K = =


A B
C
D
x d
c
2
5
60
o
200
o
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

11

53.
2 4
b c b c
D E
+ +
= =

Equation of BF is

4
b c
r b b
| |
+
= +
|
|
\ .

AC is

0 r c = + and the point of intersection

1
3
F c =

1 1
4
3 3
AF
AF AC a b
AC
= = + =

54. Given ( ) ( ) 2 3 2 7 2 (1) f x f x + + + =

Replace

x

by 1 x + ,

( ) ( ) 2 5 2 9 2 (2) f x f x + + + =

Replace x

by

2 x + , ( ) ( ) 2 7 2 11 2 (3) f x f x + + + =

(1) (3) (2 3) (2 11) f x f x + = +

put
3
( ) ( 8)
2
x
x f x f x

= = +

Period is 8
55. ( ) ( )
1 1
,
4 2
P A P A B = =
( )
( )
( )
( ) ( )
( )
1
1 3
c
c
c
P B A
P A B P A
P B A K
P A
P A

= = = =

1
3
K
=
56. ( ) ( ) ' 2cos 1 3sin f x x x = +
( )
1
1
' 0 , sin
2 3
f x x x
t

= = =
( ) '' 2sin 6cos2 f x x x =
'' 4 0
2
f
t | |
= >
|
\ .

( ) f x is minimum at
2
x
t
=
2
f
t | |
=
|
\ .
minimum value 3 =
A
B
C
D
E
F
2
1
1

o
( ) a
( ) b
IIT Section

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th
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12


l
O C B u
X
Y
A
coso u
o
Physics
57. Point A moves towards B with the speed v at any instant. At the same time B moves away from
A with the speed cos u o where

o is the < of inclination of line AB.
AB distance reduces at the rate ( cos ) v o


[o changes with time]





Initial separation between A & B was l . separation decreases at this rate and is reduced to zero.
Let A & B meet after time t then
0
( cos )
t
v u dt l o =
}
..(1)
Along OX i.e., the line along which B moves, the distance described by B in time t is u t.
Parallel to OX the velocity of a is cos v o .
distance travelled by A along OX is
0
cos
t
v dt o
}

When they meet it is required that
0
cos
t
v dt ut o =
}

0 0
cos cos
t t
ut
v dt ut dt
v
o o = =
} }
(2)
0 0 0
cos cos
t t t
v dt u dt l vt u dt l o o = =
} } }

From (2),
2
2 2
( )
u t lv
vt l t
v v u
= =

58. Just after collision velocities of both the balls will be 2gh in opposite directions. Relative
acceleration between the two balls is zero and relative velocity of approach is 2 2gh .
Hence they will collide after a time
1
2 2
t
gh
= .. (i)
IIT Section

Subject Topic Grand Test Paper I Date
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IIT GT 06
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th
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at the time of collision just after collision
At the time of collision of two balls relative velocity of approach 2 2gh =
Hence relative velocity of separation will also be 2 2gh (collision is elastic)
Hence the string becomes tight after the same time,
2 2
l
t
gh
=
Hence the total time will be 2t or
2
l
gh


59.








Applying equations of motion using F.B.D. (Free Body Diagram)
1
3 T f ma = ..(1)
2
2 . 2 f R T R mR o = ..(2)
2
mg T ma = ...(3)
2 1
a a Ro = ...(4)
1
(2 ) a R o = ...(5)
Solving the above equations, we get,
1 2
2 1
,
15 15
a g a g = =






2 = v gh
2 = v gh



2 = v gh
2 = v gh

N
T
f
3mg

1
a
2
a
mg
T
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60. Since electrostatic force in a vertical direction. Hence the two spheres and their centre of mass
(COM) will always lie on a same vertical line.
The net acceleration of COM will still be g with initial velocity v in horizontal direction.














l
t
V
=
During this time t, COM will fall through a height
2
2
1 1
2 2
l
h gt g
V
| |
= =
|
\ .
(1)
/ 2
COM
h H = (COM will always remain the centre point of spheres 1 and 2 throughout the
motion)
1 2
2 2
h h H
h
+ | |
=
|
\ .

2
1 2 1 2
( ) 2
l
H h h h h h g
V
| |
= + +
|
\ .

Alternative
( )
1 1 2 2
1 2
com
m h m h
X
m m
+
=
+

( ) ( )
1 2
1 2
0
com
m m H
X h
m m
+
=
+






2
h
1
h
H
COM
2
2
1
COM
V
V
V
1

1
+
2
2

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th
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15

Where
2
2
2
1 1
2 2
l
h gt g
V
= =
On solving
2
1 2
2
l
H h h g
V
= +

61. Induced emf = Blv
R is the internal resistance of the seat of emf which is the conductor here and the other two
resistance are in parallel.
Total resistance
1 2
1 2
R R
R
R R
= +
+

1 2
1 2
Blv
i
R R
R
R R
=
+
+


62. Lens formula
1 1 2
1 1 1
( 1)
f R R

| |
=
|
\ .

1 2
1.5, 10 , 20 R cm R cm = = + = +
1
1 1 1 1
(1.5 1)
10 20 40 f
| |
= =
|
\ .

2 1 2
1 1 1
( 1)
f R R

| |
=
|
\ .

1 2
1.6, 20 , R cm R = = + =
2
1 1 1 3
(1.6 1)
20 100 f
| |
= =
|

\ .

for the oil-glass combination
1 2
1 1 1 1 3 11
40 100 200 f f f
= + = + =
18.18 f = cm
So, (c) will be the answer.
63. Steady state current in
0
1
E
L i
R
= = Energy stored in
2
1
1
2
E
L L
R
| |
=
|
\ .
= heat produced in
2
R during
discharge
2
2
1
2
LE
R

IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

16

64. Protons move towards each other till their relative velocity becomes equal to zero. At the closest
distance of approach both the protons will be moving the same velocity.
As Columbian repulsive force is internal for the system of protons, we can apply the law of
conservation of momentum.
0
2 mv mv =
Change in K.E.
2
2 0
0
1 1
2
2 2 2
v
mv m
| |
=
|
\ .

This change in energy is equal to the electrical potential energy
2
2 2
0 0
0
2 2 4
mv v e
m
r tc
| |
=
|
\ .

2
2
0 0
e
r
mv tc
=
65.
( ) 1
6 4
2
n n
n

= =
If the initial state were 3, in the emission spectrum,
no wavelengths shorter than
0
would have
occurred. This is possible if initial state were 2 n =
66. 1 0 = . R m, 1.0 M kg =
Velocity of COM V =
Angular velocity of disc e =

I is the instantaneous centre.
tan 45
o
OI
R
=

tan45 OI R =

1.0 R = =

2 2 IC R = =

5
2
C
V
IC
e = = rad /sec

5
( ) (1, 0)
2
V OI e
| |
= =
|
\ .


5
2
= (m / sec)
67.
2
V aT =
2 dV aTdT = .(1)

5 / m s
C
O
45
o
V e
I
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

17


2
nRT nRT nR
P
V aT aT
= = =

nR
PdV dV
aT
| |
=
|
\ .

From Equation (1)

.(2 ) 2
nR
P dV aT dT nRdT
aT
= =

1
2
2
T
W PdV nRdT = =
} }

(2 )( ) nR T = A
(2)(1)( )(100) R = 200R =
68. For a charged conducting sphere of radius
0
R , the curve given in the question is appropriate.
Thus, charge q is distributed on the surface of the conducting sphere. All options are correct.
69. Flux linked with loop due to its own magnetic field

2 0 0
( )
2 2
i ri
r
r
t
| t = =
EMF induced
0
2
r d di
e
dt dt
t |
= = =
0
2
r e di
i
R R dt
t
= =

0
0
0
2
.
i t
i
di R
dt
i r t
=
} }

or
0
2 /
0
Rt r
i i e
t
=
Now,
0
2
3
0 0
10
Rt
r
i i e
t

=
Which gives
2
10
3 ln10
10
t
t
= second
70. the central maxima will always lie on Y -axis at
0
M with velocity at any time as
10 4 40 v gt = = = (m/s) ( Y + axis)
71. Path difference relative to point M
sin tan x d d u u A = ~

'
dx
D
=
For second maxima, 2 x A =
So,
2 ' D
x
d

=
IIT Section

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C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
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The coordinates of central maxima are (0, ') D or
2
1
0, '
2
D gt
| |
+
|
\ .

The coordinated of second maxima are
2 '
, '
D
D
d
| |
|
\ .

Velocity of second maxima relative to central maxima
2 1

0 2
2
gt i
d
| |
= +
|
\ .

2

gt i
d
| |
=
|
\ .

(3.6)i = (cm/sec)
Alternative
2 2 2
l x y = +
2 2 2
dl dx dy
dt dt dt
= +
Given
dy
gt
dt
=
Where
n D
x
d
'
=
2
1
1
2
n gt
d

(
+
(

=
2
1
1
2
n gt
d
gt
dt d

u
( | |
+
|
(
\ .
( = +
(
(


72. The coordinate of 3
rd
maxima are
3 '
, '
D
D
d
| |
|
\ .

The coordinates of other 3
rd
maxima are
3 '
, '
D
D
d
| |

|
\ .

Required acceleration
3 3

.
g
g i
d d
( | |
=
| (
\ .


2
6

. 0.036 ( / )
g
i i m s
d

= =
73. & 74.
Molecular weight of mixture,
A A B B
A B
n M n M
M
n n
+
=
+


(1)(4) 2(32)
22.67
1 2
+
= =
+

Speed of sound in a gas,
RT
v
M

=
IIT Section

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th
May 2014
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1/ 2
3
(19 / 13)(8.31)(300)
22.67 10

(
=
(

401 ~ m/sec

1/ 2
v KT = (1)

1/2 1
.
2
dv
KT
dT

=
2
dT
dv K
T
| |
=
|
\ .

2
dv K dT
v v T
| |
=
|
\ .
[From (1)]

1 1
2 2
dT dT
T T T
| |
= =
|
\ .
[From (1)]
1
100 100
2
dv dT
v T
| |
=
|
\ .

1 1
100 0.167
2 300
| |
= =
|
\ .

Percentage change in speed = 0.167%
75.
2 2
2 v u gs =

2
0 (2)(10) u = will give 10 u = m/sec.
Further, v u gt =
0 10 (10)t = gives 1 t = second.
76. For , A T kx =
For , 2
2
kx
B T mg + =
From eqns. (1) and (2),
2 (2)(3)(10)
5 5(10)
mg
x
k
= =
1.2m =
If v is the speed of block A
2 2
2 2
1 1 1 1
2 2 2 2 2 2
v x
mv m kx k
| | | |
+ + +
| |
\ . \ .

2
x
mg
| |
=
|
\ .

On solving
1/ 2
8 10(1.2) 3(10)(1.44)
3 2 8(3)
v
( | |
=
( |
\ .


A T
V
kx
x

B
mg
/ 2 x / 2 V
2
2
+
kx
T
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
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08
th
May 2014
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20


2
4.8 2.4I v = = (in
2 2
m / s ) where 2 t =
77. The block B will stop in 2 seconds. The block A will stop in 4 seconds. From 0 to 2 seconds
equal force of friction are acting on the blocks in opposite directions and thus system will remain
conserved as net force is zero.
At 0 t = ,
1 1 2 2
1 2
(1)(4) (1)( 2)
2
CM
mV m V
V
m m
+ +
= =
+
= 1 m /sec
Upto 2 t = second,
CM
V is constant
1
(1)(2) 2
CM
d V t m = = =
After 2 t > second, retardation of centre of mass
2
0.1(10) 1
/
2 2 2
g
a m s

= = =
2 2
2
(1)
1
2 2(1/ 2)
Cm
V
d m
a
= = =
Total distance 2 1 3m = + =
78. Dots will be aligned again after time t , if slower disc makes one rotation less than the other disc.

2
1
2
2 2
n t
t
t
| || |
=
| |
\ .\ .
..(1)
and
2
1
2 ( 1)
2 4
n t
t
t
| || |
=
| |
\ .\ .
. (2)
By dividing,
2
( 1) 1
n
n
=

or 2 n =
From Eqn. (1), 4 t = sec.
79. No change of temperature
So,
1 2 1 2
( ) ( )
i f
n n n n + = +
1 1 2 2 1 2
PV PV PV PV
RT RT RT RT
+ = +
So,
1 1 2 2
1 2
PV PV
P
V V
+
=
+


0 0
(4 ))3 ) (1.5 )(2 )
5
P V P V
V
+
=

0 0
3P IP = = (given)
So, 3 I =
80. For magnification +2, , 2 u x v x = = and 2.0 f =
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

21

From
1 1 1
v u f
= , we have
1 1 1
2 2 x x
+ =

1.0 x m =
For magnification of 2, , 2 , 2.0 u y v y f m = = + =

1 1 1
2 2 y y
+ =
3.0 y m =

( ) 2.0 y x m =

81. C is the capacity of capacitor with insulator and
o
C is the capacity without insulator.

o
C KC =
Charge is constant
2
2
q
U
C
= .(1)
2
4 / 2
o
U U q C + = . (2)
on solving, 5
o
C
K
C
= =
82. 0
E
V = and 0
D
V =
2
B
V V = and 10 2 12
C
V V = + =
12 6 6
A
V V = = and ( ) 6 2 4
A B
V V V = =
( ) 12 0 12
C D
V V V = =
Current through 3O resistor
12
4
3
A = =
83.
2
4 q t =
At 3 t = sec, q is positive
2
dq
i t
dt
= = and 2
di
dt
=
At 3 t = sec, 5 q C = and 6 i A =

A B
q di
V L iR V
C dt
=

A B
q di
V V L iR
C dt
= + +

5
(0.5)(2) (6)(1) 8
5
V = + + =
84. x and y are number of o -decays and | -decays respectively
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

22

92 2 85 x y + =
or, 2 7 x y = (1)
similarly, 238 4 210 x = .(2)
7 x =