IIT Section

Subject Topic Grand Test Paper I Date

C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

1

Key Answers:
1. b 2. a 3. b 4. a 5. c 6. d 7. a 8. b 9. bcd 10. cd
11. abd 12. acd 13. abc 14. b 15. c 16. a 17. b 18. b 19. 3 20. 4
21. 3 22. 2 23. 9 24. 3 25. 8 26. 6 27. 6 28. 5 29. c 30. b
31. b 32. a 33. b 34. d 35. a 36. a 37. abcd 38. cd 39. ad 40. bd
41. abc 42. d 43. b 44. c 45. d 46. c 47. 3 48. 5 49. 1 50. 9
51. 1 52. 2 53. 9 54. 1 55. 2 56. 2 57. b 58. c 59. c 60. b
61. c 62. d 63. b 64. b 65. a 66. cd 67. abcd 68. acd 69. cd 70. c
71. b 72. b 73. d 74. a 75. 9 76. 1 77. 4 78. 2 79. 3 80. 0
81. 3 82. 3 83. 3 84. 1

Solutions:
Chemistry
1. If
1 2
k k =
1
13
152.3
10 exp
kJmol
RT

| |
|
\ .

1
14
157.7
10 exp
kJ mol
RT

| |
|
\ .

157.7 152.3
exp 10
RT
| |
=
|
\ .

5.4
log log 10
e e
e
RT
| |
=
|
\ .

1
10
5.4
2.303log 10 2.303
kJ mol
RT

= =
3
5.4
2.303
8.3143 10 T

5.4 1000
282
8.3143 2.303
T

= =

K
2.
1
4 4
k
NH OH NH OH
+
+
| |
| |
4
2 3
d NH OH
k NH
dt
=
10 1 1
1
4.0 10 k M s

= (second order kinetics)
Also is protonation of
3
NH
| |
| |
4
2 3
d NH OH
k NH
dt
=
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

2

| |
1 4 2 3
k NH OH k NH
+
( ( =


or
f
c
b
K
K
K
=
f c b
K K K =

5 10 5 1
1.8 10 4 10 7.2 10 s

= =
3. 2.303 log G RT K A =
log
2.303
G
K
RT
A
=
10 K =
Or
2 2 3
3 2 N H NH +

1 2 2
10 100 K K = = =
4. I.
2
CaF (fluorspar) and
3 6
Na AlF (cryolite) reduce melting point of the mixture
2
CaF improves
electrical conductivity of the melting as compared to molten
2 3
. Al O
II. Aqueous solution of
3
Al
+
cannot be taken since
2
H gas is formed in preference to . Al
III. Molten
3
AlCl being covalent is poor conductor. It sublimes at melting point. Hence, cannot be
taken.
IV. Halls process is adopted for the extraction of Al from bauxite.
Thus, III incorrect
5. Due to extended conjugation.
6. When equal volumes are taken, the concentration becomes half

( )
3 5 4
1
10 10 505 10
2
H
+
( = + =

3.3 pH =
7. Hydrogen bonding is stronger in HF followed by
3
NH and
2
H S . So, the boiling point follows the
same order of
3 2
HF NH H S > >
8.
2
2 2
1 1 1
2
H
Balmer
R Z

(
=
(

2
1
4
H
R Z
(
=
(



2
2
1 1 1
3
H
Paschen
R Z

(
=
(

2
1
9
H
R Z
(
=
(


IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

3

Dividing Eq. (ii) by Eq. (i)
1 4 4
9 1 9
Balmer
Paschen

=
9. (a)
3 2
sp d hybridisation requires
2 2
x y
d

and
2
z
d orbitals but not
yz
d and
xz
d orbitals.
(b) All octahedral
2
Ni
+
complexes are outer orbital complexes irrespective of the ligand.
(c) correct because
3
Cr
+
has
3
3d e.c
(d) correct because
2
Mn
+
has 5 unpaired electrons
10. From data it is clear that order with respect to A is zero.
11. Beckmann rearrangement














12.







13. Ans: (a,b,c) are correct
14.
2
1
Amount of produced 2
Amount of produced 3
k B M
k A M
= =
C
O
OH
LiH
ether
C
O
OLi
- +
3
CH - Li
L
C
O
CH
3
C
OLi
OLi
CH
3
M
N
+
3
H O

IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

4

4 1 2
2 4
2
2.67 10
3 4 10
k
k s

= =

15.
( )
( )
0.5
4 4
1 2
0.693 0.693
4 10 2.67 10
t
k k

= =
+ +


4
0.693
6.67 10

1039s ~
16.
0.5
1.414
av
t t =

1.414 1039 =


1469s =

17. t back bonding from metal to CO increases electron density on the CO which in turn improves
the ability of the CO to form o donor ligands are attached to metal carbonyl, it results in slightly
greater CO bond length and shorter metal-carbon bond.
3
PEt is more basic than
3
PPh .
18. The stable carbonyl complexes exist only for metals that have filled d orbitals of an energy
suitable for donation to the CO antibonding orbital. Thus s and p block elements cannot form
stable carbonyl complexes.
19. ( ) 186 80 2 26 =
alkene 26 2 28 = + =
20.
1/ n
x
kp
m
=

1
log log log
x
k p
m n
= +
Slope,
1
tan m
n
u = =

1
tan 45
n
=

1
1
n
=
1 n =
Intercept log 0.301 k =
2 k =
( )
1
2 0.2
x
m
=
/ 0.4 x m=
or mass of gas adsorbed by 10 g of adsorbent
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

5

0.4 10 4 x g = =
21.
0 2 2
1 1
1
E E
n
| |
A =
|
\ .

2
1 1
12.1 13.6
1 n
| |
=
|
\ .


2
9 n =

3 n =

Electron is excited to 3
rd
energy level.

No. of spectral lines
( ) 1
2
n n
=

( ) 3 3 1
3
2

= =
22. ( ) ( ) ( )
2 2 3
2 2 SO g O g SO g +
Initial 2 1 0
At equilibrium, ( ) 2 2x ( ) 1 x 2x
4
MnO

oxidises
2
SO to
3
SO in acidic medium.
2 2
4 2 2 4
2 5 2 2 5 4 MnO SO H O Mn SO H
+ +
+ + +

4 2
2 5 mol MnO mol SO

Thus,
4 2
5
0.4 0.4 1
2
mol MnO mol SO

( ) 2 1 1 x =

0.5 x =

| |
3
2
1
x
SO M
V
= =

| |
( )
2
2 1
1
x
SO M
V

= =

| |
2
1
0.5
x
O
V

= =

| |
| | | |
2
3
2
2 2
c
SO
K
SO O
=

1
2
1 0.5
= =

IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

6

23.
18
4 2
10 NH NH
+
( ( =



9
2
10 NH

( =



2
9 pNH

=
24.
3
log of 2.699 1.99 10 H anti
+
( = =


H
+
(

becomes
3
0.99 10

3
log of 0.99 10 pH

=
5 log99 =
5 1.99 =
5 2 3 = =
25. KCN HCN
Volume ' ' x mL = Volume 10mL =
Molarity 5 = Molarity 2m =

| |
| |
salt
log log
acid
a
pH K = +

( )
( )
10
5 / 10
9.6020 log5 10 log
20 / 10
x x
x

+
= +
+

9.6020 9.3010 log
4
x
= +
log 0.3010 log2
4
x
= =
8 x mL =
26. Ans: 6
27.
2
0
2 ,
n n
n
r n r r
z
t = =

2
2 0.529 n t n = 16.5
0
0
1
0.529
z
r A
= (
(
= =




2
16.5
5
2 3.14 0.529
n = =


similarly
1
2 n =
maximum number of spectral lines
( )
| |
2 1
1
6
2
n n
n n n
+
= =
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

7

28. Each coordinating group can be trans

to one like it






If two pairs are trans the third pair also must remain as trans.
The ammonia molecule can be trans to each other but the
2
H O and Br cis

to groups like
themselves.






Similarly, the water molecules or Br

can be trans to each other with other groups cis to groups

like themselves.
Finally, each group can be cis to one like itself.
Total five geometrical isomers are possible

IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

8

Mathematics
29. 4 5 6 8 5 10 8 BC BA AC i k i j k i j = + = + + =
41, 125, 164 AB AC BC = = =
Length of median through
2 2 2
1
2 2
2
A b c a = + 42 =
30. 3sin 4cos 5 x x + =
2
2 2
2tan 1 tan
2 2
3 4 5
1 tan 1 tan
2 2
x x
x x
( (

( (
+ =
( (
( (
+ +


2
9tan 6tan 1 0
2 2
x x
+ =
1
tan
2 3
x
=

2
1 1
135tan 90tan 975 135 90 975
2 2 3
x x
a
| | | |
+ = +
| |
\ . \ .
960 =
31. Tangent to
2
4 x y = is ( )
2
...... 1 y mx m =
(1) is tangent to ( )
2
2
3 9 x y + =
2
2
3
3 3
1
m
m
m

= =
+

3 3, 3 3 y x y x = =
3 3 0, 3 3 0 x y x y = + + =
3 3 x y is not a tangent to 2nd circle.
32. x x x =
1
lim lim
2 2
x
x
x x
x x
x x

| |
| |
=
|
|
|
+ +
\ .
\ .
( )
1
1
lim
2
x
x
x
x

=
| |
|
+
\ .

lim lim
1
1
2 2
1 1 1
x x
x x
x
x x
e
e
e e


( (

( (
+ +
= = = =
33. ( ) ( ) 7 3 7 2 11 100 x f f = + = ______(1)
( ) ( ) 11 3 11 2 7 140 x f f = + = ______(2)
( )
( )
( ) ( )
( ) ( )
1 3 7 2 11
5
2 3 11 2 7 7
f f
f f
+
=
+
componendo and dividendo
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

9

( ) ( )
( ) ( )
5 7 5 11
12
6
7 11 2
f f
f f
+
= =


( ) ( ) ( ) ( ) 5 7 5 11 6 7 6 11 f f f f + = +
( ) ( ) 11 7 11 f f =
( )
( )
11
11
7
f
f
=
34. 3 0 3 x x > >
2 2 3 0 x x >
2 2 3 & 2 2 3 x x x x > >
( ) 2 2 3 x x
ve ve
>
+ +

( ) ( ) ( )
2 2 2
2 4 3 8 16 0 4 0 x x x x x x R > + = > e
Domain [3, ) =
35.
3
2sin3 8sin 6sin sin
6
a
x x a x a x + = = =
No solution 7 a =
36. A.M> G.M
3 3 4 4 4
2 2 2 2 2 2 3 3 3
a a a a b b c c c
a
+ + + + + + + +

1/9
3 3 4 4 4
. . . . . . . .
2 2 2 2 2 2 3 3 3
a a a a b b c c c | |
>
|
\ .

1/9
4 2 3
2 3 4
9 3
a b c a b c
| |
+ +
> |
|
\ .

4 2 3
4 2 3
1 3
3
a b c
a b c s s
37. ( )
2
1
sin
2
f x x
t
=
( )
2
2
cos
2
f x x
t
=
( )
2
3
cos
2
f x x
t
=
( )
2
4
sin
2
f x x
t
=
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

10

( )
4
1
2 2
i
i
f x t
=
=

( ) ( ) ( ) ( ) ( ) ( )
4
1 2 3 4
1
1 0
i
i
i
f x f x f x f x f x
=
= + + =

( )
| |
( ) ( ) ( ) ( ) ( )
4
/3
1 2 3 4
1
1 0
i
i
i
f x f x f x f x f x
=
= + =

( ) ( )
2 2
1 2
sin cos f x f x x x > >
2 2
cos sin 0 cos2 0 x x x > >
38.
2
2 2 2
1 1 1 1 1 1 1 1 1
2
| o o| o | o |
| | | | | |
+ + = + + + +
| | |
\ . \ . \ .

( ) 2
2 2
o |
o|
o|
+ +
= =
Also,
1
1
2
| o o|
| o o|
o|
+ +
= + + =
( ) ( )
2
2 2 2
2 6 o | o | | o o| + + = + + + + =
Lastly
3 3 3
3 o | o| + +
( )( )
2 2 2
o | o | | o o| = + + + +
39. ( )
1
3 3 1
6 6 4
P E

= =

( )
2
6 1
36 6
P E = =
( )
3
3 1
36 12
P E = =
( )
1 2
3 1
36 12
P E E = =
( ) ( ) ( ) ( )
1 2 1 2 1 2
P E E P E P E P E E + = +
12
36
=
( ) ( ) ( )
2 3 2 2 3
6 1 5
36 36 36
P E E P E P E E = = =
( ) ( )
1 2 2 3
17
36
P E E P E E + + =
( )
( )
( )
1 3
3 1
1
1
/
9
P E E
P E E
P E

= =
( ) ( ) ( )
1 2 1 2
1
2
P E E P E P E = =
( ) ( ) ( )
1 2 3
, , P E P E P E are in A.P
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

11

40. ( )
2
2
2 2 2
cot 1
tan cot 2
cot

o | o| o|

(
= + + + (
(

(


( )
( )
2
2 2
2
1 cot cot 1
cot cot

o | o| o|

( (
+
= + ( (
( (


( )
2
o | = +
41. ( ) ( ) ( ) ( ) ( ) ( )
2 1 11 2 1 11
1 2 2 3 f x x xg g g x x xf f = + + = + +
( ) ( )
1 1
2 1 f x x g = + ( ) ( )
1 1
2 2 g x x f = +
( )
11
2 f x = ( )
11
2 g x =
( ) ( )
1 1
1 1 2 1 x f g = = + ( ) ( )
1 1
1 2 2 g f = +
( ) ( )
1 1
1 4 2 f f = +
( ) ( )
1 1
2 2 4 1 x f g = = + ( ) ( ) ( )
1 1 1
2 4 2 8 1 g f g = + = +
( ) ( )
11 11
2 3 2 2 4 g f + = + =


Passage - 1

42. The points at which o | = possible at the point of contact of two circles as they touch at
11 13
5
i

43.
2 2
max 41 3 OC r | = + = +
1 1
max 2 2 OC r o = + = +
3
1 2
max max
2 2 41 3 2 164 18 k k | o

= = =
1 2
146 k k =




44.
max 1 2 1 2
max
AB C C r r o | = + +
5 2 3 = + +
10 =


IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

12

Passage 2
Let ( )
1
0
a f t dt =
}

( ) g x x a =
( ) ( )
3 3 2
0 0
1 1
2 2 2
x
x
x x t
f x x t a dt x at
(
= + = + (
(

}

( )
3 2
2
1 1
2 2
x x
x ax f x ax
(
= + = + (
(


( )
( )
1
2
0
1 x a g x x at dt = = +
}

1
3
a
x a x
| |
= +
|
\ .

2 3
1
3 2
a
a = =

( ) ( )
2
3 3
1 ,
2 2
x
f x g x x = + =
45. ( ) ( ) ( )
1 11
3 , 3 0 0, f x x f x x f x = = > = has min and f has no max.
46. ( )
3
2
y g x x = =
Cuts y axis at
3
2
x =
47. ( ) ( ) 1 2 1 8 4 2 3 7 f f b c b c b c = + + = + + + =
1
4
0 16 8 3 0 5, 8
3
f b c b c
| |
= + + = = =
|
\ .

100 500 800 2500
3
1100 1100
c b +
= =
48. ( )
1
sin
0 sin 0, 0
x
f x x x
x
= = =
x nt =
( ) , 2 , 3 , 4 , 5 0,16 x t t t t t = e
Number of points = 5.
49. Given integral
2
15
2sin sin
2 2
5
1 2 1 2sin
2
x x
dx
x
| |

|
\ .
=
| |
+
|
\ .
}

IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

13

3
2
5 5
2 3sin 4sin sin
2 2 2
5
3 4sin
2
x x x
dx
x
(

(

=

}

5
2 sin sin
2 2
x x
dx =
}
( )
sin3 sin 2
cos 2 cos3
3 2
x x
x x dx C = = + +
}

3, 2 a b = =
( )
( )
4
4
9
6561
1
6561 6561 6561
b
a
= =

50. ( ),
x
y n x e y e

= + =
( ) log
x
x e e

+ =
( )
0
1 0
log
x
e
A x e dx e dx

= + +
} }
2 4
1 1 2 6 6 1296,144 1296 k = + = = = =

9 k =



51. tan y v =
2
sec
dv dv
y
dx dx
=
( ) ( )
3
2
dv
x v x LDE
dx
P Q
+ =
+ +
2
pdx
x
IF e e
}
= =
( ) ( ) . is GS v IF Q IF dx c = +
}

( )
2 2
3 x x
v e x e dx =
}

( )
( )
2 2
2
1
2
2
x x
v e x e x dx =
}

2
x t =
( )
1 1
2 2 2
t t t t t
c
ve te dt ve te e = = +
}

( ) 2 1
t
v t ce

= +

( )
2
2
2tan 1 1
x
y x ce

= + =
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

14

52. ( ) ( ) ( ) ( ) , 1 , 0,3 , 2, 0 , 6,1 P A B C +
P is interior to ABC A
PAB PBC PAC ABC A +A +A = A
7 6 8 12 4 22 + + + + =




If ( ) ( ) ( )
5
4 7 6 8 12 4 22
4


< + + = = not possible.
If ( ) ( )
6
4 7 6 8 12 4 22
7
< < + + + =
6
7

= not possible.
If ( ) ( )
6 3
7 6 8 12 4 22
7 2
< < + + + =
6 3
, 0,1
7 2

| |
e =
|
\ .

If
3 3
2 2
> = not possible number of integral values of 2 =
53. Axis of parabola is
1
2
x =
Vertex
1
, 4
2
| |
=
|
\ .

Equation of parabola is
( )
2
1
4 4
2
x a y
| |
=
|
\ .
_______(1)
It passes through (0,0) ( )
1 1
4 4 ,
4 64
a a = =
(1) ( )
2
1 1
4 4
2 64
x y
| | | |
=
| |
\ . \ .

( )
2
1 1
4
2 16
x y
| |
=
|
\ .
it passes trough
6
3 729
, 3 9
4 81 81
E


| |
= = =
|
\ .

54. 2 2 5 0 x y z + + = _________(1)
2 2 8 0 x y z + = ___________(2)
Distance
1 2
2 2 2
13
13
3 1 4 4
C C
a b c

= = =
+ +
+ +

IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

15

81 351
1
351 351
=

55. Let the plane be 1
x y z
a b c
+ + =
( ) 0, 0, 0 O =
( ) , 0, 0 A a =
( ) 0, , 0 B b =
( ) 0, 0, C c =
Let ( )
1 1 1
, , , ,
4 4 4
a b c
a x y z
| |
= =
|
\ .
( ) ( )
1 1 1
, , 4 , 4 , 4 a b c x y z =
2 2 2 2 2 2 2 2
1 1 1
2 2 2
1
1 1 1 1 1 1 1 1
1 1 1 16 16 16
P
a b c P x y z P
a b c

= + + = = + + =
+ +

locus is
2 2 2 2
16 x y z p

+ + =
16
2
8 8
= =

56. 1 2 3 1 3 2 z z z z z z + + = + +
1 3 2 z z z > + + = 2


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IIT GT 09
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Physics
57. Due to long straight wire
Force on the current wire ln5. correct option is (b)
58. Velocity of efflux.
Velocity of top layer
Acceleration top layer

1
2
2
A dh
g
Av dt h

Correct option is (c)
59. Electric potential due to a charged disc at its centre is
0
2
R o
e
. The potential will be same for n
th
part
of the disc is
0
2
R
n
o
e
.
60. ( ) ( )
0 0
, , y x t y x t =
( )
0 0
x x v t t = +
0
0
x x
t t
v

=
0
0
x x
t t
v

=
( )
0
0
, ,
x x
y x t y x t
v

| |
=
|
\ .
0
1
cos
x x
A t
T v

| |
=
|
\ .
0
cos
x t x
A
T VT VT
| |
= +
|
\ .

Correct option is (B)
61. Observer at A observes constant apparent frequency (more than actual frequency when sources
approaches and less than actual frequency when source moves away), therefore graph 1 is
correct representation. When observer moves perpendicularly away from the track the
separation between the two lines in the graph 1 moves towards each other.
62. Tension at any point is dependent on square of angular velocity.
63. Clockwise moment about ' ' O =anticlockwise moment about O
cos sin
2 2
l l
mg ma u u =
0 1
2
I
r

t
=
2
1
5
0 1 2
2
r a
r a
I I
dx
r

t
=
=
=
}
0 1 2
2
I I
t
=
2 v gh =
0
2
AV A
gh
Av A
= =
2
d A
gh
dx Av
(
=
(

0 0
1
2 2
2
A A
g gh
A A h
=
2
0
A
g
A
| |
|
\ .
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IIT GT 09
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th
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tan
g
a
u =
10
tan
40 3
u =
3
tan
4
u =
( )
1
tan 3 4 u

=
37 =
64. PV

= constant,
7
,
5
dP P
dV V

= = (diatomic gas)

5
3
= (monoatomic gas)
65. ( )
4
4 4
2 16 Q AT A T AT o o o = = =
66. Mass is frame independently for v c <<
67. ( ) sin y A t kx e =
( ) sin y A kx t e =


( ) sin y A t kx e =
( ) sin y A kx t e = +

All travelling along positive x - axis.

68. Time taken by front end to reach the line AB
100
10sec
10
S
t
V
= = =
To avoid accident the speed of the girl should be
10
1 /
10
S
V m s
t
= = = (or) above
Time taken by rear end to reach the line AB
110
11sec
10
S
t
V
= = =
To avoid accident the speed of the girl should be
6
0.54 /
11
S
V m s
t
= = = (or) below.


-
ma
u mg
O



x


x
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th
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69. For 2kg block,
0.2 2 10 4 f N = =
Resultant force 6 4 2 F f N = = =
For 1kg block,
0.3 1 10
3
f mg
N
=
=
=

The contact force between the two blocks is 2 N
The maximum friction force on the block is more than applied force, therefore system is at rest
The resultant applied force on 1Kg block is 1N , therefore the friction on 1Kg block is 1N
70. 71. & 72.
Q Q A =
4
Q
W A =

3
4
Q
U A =

3 3 3
4 2 4 2
v
Q Q Q
nc T n R T n T
R
A = A = A =
2
2
Q Q R
C R
n T Q
A
= = =
A

Also
3
2
2
p dV
C R R
n dT
= + =
2
RT dV R
V dT
+ =
1
2
dV dT
V T
=
1
ln ln ln
2
V T C = +

ln ln
V V
C
T T
= =constant
AS pV nRT =
V
PV
nR
= constant P k V = P V o .
73. & 74.
Total energy of particle =
5
KQq
a
= (constant)
At A
2
1
2 4 5
A
KQq KQq
MV
a a
=
10
A
KQq
V
Ma
=
AT B 4
A B
MV a MV a =
4 4
10
B A
KQq
V V
Ma
= =
Radius of curvature R is given by

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IIT GT 09
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th
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2
2
B
MV KQq
R a
=

2
16 8/ 5 .
10
Ma KQq
R a
KQq Ma
= =

8
5
R a =
75.
2
3 12 3
dx
v t t
dt
= = +

2
2
6 12
d x
a t
dt
= =
76. ( ) 1 cos d R u =

sin
a
R
u =

2
2
1 1
d a
R R
=

2 2
2
a d
R
d
+
=

2 2
1 / sec
2
a d
p qB kg m
d
(
+
= =
(


77. ( )( ) ( )( ) 76 80 76 80 x x = + ,solve for x
78. (i) Since, the angle of prism and the angle of incidence are also small, the deviation is given by
( ) 1 A o = , (the subscript c represents crown glass and f represents flint glass)
1.51 1.49
1.5
2
c

+
= =
1.77 1.73
1.75
2
f

+
= =
In the prism, since final refracted ray always bends towards the base, means angle of deviation is
always towards base.
( )
net C F
o o o = a.c.w
For the crown glass ( ) 1
C C
A o = a.c.w
a
v
d
u
u
R
IIT Section

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C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
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For the flint glass ( ) 1
F F
A o = c.w
( ) 1.5 1 6
net
o = a.c.w ( ) 1.75 1 + c.w
1.5a.c.w 3 = a.c.w 0.75A + c.w
1.5a.c.w 3 = a.c.w 0.75A + a.c.w
0.75 1.5 2 A A = =
79. ( ) ( ) ( ) ( ) ( )
2 2 2 1 1 1 2 1 2 1 1 2 1 2
x S P t t S P t t x S P S P t t t t A = + + A = +
We know that, ( )
2 1
yd
S P S P
D
= at point C 0 y = Hence,
2 1
0 S P S P = at point , C
Then, ( ) ( )
2 1 2 2 1 1
x t t t t A =
1
1.25
15
x um
| |
A =
|
\ .
;
2
3
air
x
t t
|

| |
A = A =
|
\ .

Intensity at a point . C
2
0 0
4 cos 3
2
c c
I I I I
A
= = (since,
3
t
| A = )
Ratio
0
max 0
3 3
4 4
c
I I
I I
= = =
80. Minimum kinetic energy of photoelectrons,
min
0 K =
81. We have ( )
2
2
2
0
1
1
4
p
n
n
m v
ze
r
r
tc
=
The quantization of angular momentum gives,
2
p n
nh
m vr
t
= ( ) 2
Solving equations (1) and (2), we get
2 2
0
2
2
p
n h
r
m e
c
t
=
Substituting 100
p
m m =
Where m= mass of electron and 4 z =
We get,
2 2
0
2
400
n
n h
r
me
c
t
=
(b) As we know,
1
13.60
H
E eV = and
2
2
n
z
E m
n
| |
|
|
\ .

For the given particle,
( )( )
( )
2
4
2
13.60 4
100 1360
4
E eV

= = and
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

21

( )( )
( )
2
2
2
13.60 4
100 5440
2
E eV

= =
4 2
4080 E E E eV A = =
(in )
12375 12375
3.0
(in ) 4080 E eV
= = =
A

82. As we have derived in the theory,
2 2
0
[ ]
2
p
V a H H
o
c
= +
Potential at centre, ( ) O will be ( )
0
0
0
2
a
V H
o
c
= =
(a) Particle is released from P and it just reaches point . O Therefore, from conservation of
mechanical energy decrease in gravitational potential energy = increase in electrostatic potential
energy ( A KE 0 = because 0
i f
K K = = )
| |
O P
mgH q V V = or ( )
2 2
0
1
2
q
gH a a H H
m
o
c
| |
| |
(
= + +
| |
(

\ .
\ .

0
4 g q
m
c
o
=
0
2
2
q
g
m
o
c
=
Substituting in equation (1), we get
2 2
2 gH g a H a H
(
= + +
(

or
( )
2 2
2
H
a H a H = + + or
2 2
2
H
a H a = + or
2
2 2 2 2 2
4
H
a H a H a aH + = + = + + or
2
3
4
H aH = or
4
3
H a = and 0 H =
( ) 4 / 3 H a =
83. Let
1
R = resistance of ammeter and
2
R = combined resistance of ammeter and voltmeter
In the first case, current in the circuit, ( )
2
6
1 i
R
= and voltage across voltmeter 6 V = voltage
across ammeter or
1
6 V iR = or
1
2
6
6
R
V
R
=
In the second case, reading of ammeter becomes two times, i.e., the total resistance becomes half
while the resistance of ammeter remains unchanged. Hence,
IIT Section

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IIT GT 09
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th
May 2014
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22

2 2
6 12
/ 2
i
R R
' = = and ( )
1
6 V i R ' ' = or
1
2
12
6
R
V
R
' =
Further, it is given that
2
V
V' = or
1 1
2 2
12 3
6 3
R R
R R
= or
1
2
1
3
R
R
=

84.
A
A
dN
C N
dt
= +

0 0
ln
A
N
t
A A
A
dN C N
dt t
C N C

= =

} }


( )
1
t
A
C
N e

=

( )
no. of decayed 1
t
B A
C
N N Ct e

= =

1
1
at
B
C C Ce
t N

= = +

6
1 6 100 10
0.37 1 10
37
C
e

= = 1 x =