IIT Section

Subject Topic Grand Test Paper II Date

C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

1

Key Answers:
1. c 2. a 3. b 4. d 5. c 6. c 7. 2 8. 1 9. 6 10. 5
11. 4 12. c 13. a 14. a 15. b 16. b 17. a 18. 19. 20. b
21. a 22. a 23. b 24. b 25. d 26. 5 27. 2 28. 3 29. 2 30. 4
31. d 32. c 33. b 34. c 35. d 36. d 37. 38. 39. b 40. a
41. c 42. d 43. d 44. a 45. 5 46. 8 47. 4 48. 3 49. 6 50. d
51. d 52. d 53. b 54. a 55. d 56. 57.

18. A q, B p, C r,s, D -s; 19. A s, B r, C q, D -p;
37. A r, B p, C q, D -s; 38. A r, B p,s, C p,s, D -q;
56. A rs, B p, C rs, D -p ; 57. A r, B qr, C ps, D -qr

Solutions:
Chemistry
1. Coagulation value is inversely proportional to their flocculating power
2. ( )
2
2
2
Ca Lac Ca Lac
+
+ ower.
Concentration of ....after dissociation 2 0.3 0.9 0.54 = =
1 1
14 5.6 7 log0.54
2 2
a
pK = + +
2.8 log0.54
a
pK =
3. Allylic C

is more stable than 1 C

. Hetero atom next to C

makes it very stable. C

+
2 is more
stable than C

1 .
4. For aldose different arrangement of groups in C
1
anomer
Different arrangement of groups other than C
1
epimer
5. (A) ( ) ( )
3 3 3 3
4 4
, Cr NH ClBr Cl AgNO Cr NH Cl Br NO AgCl ( ( + +

(white ppt)
(B) ( ) ( )
3 2 3 3 2 3
4
Cr NH Cl Br AgNO Cr NH Cl NO AgBr ( + + (


(pale yellow)
6.



7. Molarity of
2 4
N H solution
0.16 1000
0.01
32 500
M = =
2 4
N H reacts with water in the following way.
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

2

Let the amount of
2 4
N H reacted with water = o

2 4 2
N H H O +
2 5
N H OH
+
+
Moles at start 0.01 0 0
Moles at equilibrium 0.01 o o o
or
2
6
4 10
0.01
o

= ( ) 0.01 0.01 o ~

2 8
4
4 10
2 10
o
o

=
=

% of
2 4
N H reacting with water
4
2 10 100
2%
0.01

= =
8. The relevant chemical equation is
2
2 3 3
2 Ca Na CO CaCO Na
+ +
+ +

40g 106g
Thus 40g
2
2 3
106 Ca g Na CO
+


Converting these into required units
2
40 2 g Ca
+
equivalents of
2 3
Na CO
Mol.wt 106
No.of Eq= =
Eq.wt 53
(
(


40 1000mg of
2
2 Ca
+
equivalent
2 1000 milliequivalents of
2 3
Na CO
20mg of
2
2 1000
20
40000
Ca
+

= milliequivalents of
2 3
Na CO
= 1 milliequivalents of
2 3
Na CO

Hence, no. of meq. Required to soften 1 litre of sample of water = 1
9. ( ) ( ) ( )
2 2 3
3 2 N g H g NH g +
0 0
3
2 0 0
2 46 92
f
H H NH
kJ
A = A +
= =

Determination of entropy change, we know that

0 0
products Reactants
S S S A =


= | | | | 2 192 191 3 130 + = 384 191 390
Now according to Gibbs Helimholtz equation.

| |
0 0 0
3
92 298 0.197 33.294 33.294 10
G H T S
kJ j
A = A A
= = =

IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

3

Now we know that

0
ln
2.303 log
p
p
G RT K
RT K
A =
=


3
33.294 10 2.030 8.3 298 log
p
K =

3
33.294 10
log 6
2.303 8.3 298
p
K

= =


10.
2 2 2 2 x y y
C H O xO xCO yH O + +
Since oxygen taken is 2x litre and thus x litre
2
O is left at STP after reaction. Also x litre of
2
CO is formed by 1 mole of . . OC
2 2.24 x =
1.12 x = litre
2 2 2
1.12
molee 0.05mole
22.4
CO CO CO = =
Mole of
2
H O formed ( )
0.9
0.05
18
y = =
: 0.05: 0.05 1 x y x = =
1, y = i.e., ratio of x and y
Empirical formula of
2
. . OC CH O =
And Empirical formula wt. of . . 30 OC =
Now Mol. Wt. of compound is derived by Raouls law

s
s
P P w M
P m w

=
0.104
s
P P mm = and 17.5 P mm =

0.104 50 18
150.5
17.396 1000
m
m
= =
Molecular formula ( )
2
5
CH O =
5 10 5
C H O =

150.5
5
30
n = =
11. Volume of the unit cell
( )
3
8
5A 5 10 cm

| |
= =
|
\ .
24 3
125 10 cm

=
22 3
1.25 10 cm

=
Density of FeO
3
4.0g cm

=
Mass of the unit cell
22 3 3
1.25 10 4 cm g cm

=

22
5 10 g

=
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

4

Mass of all molecules of FeO=
23
72
6.22 10


22
1.195 10 g

=
No. of FeOmolecules/units cell
22
22
5 10
1.195 10
g
g

4.19 4 = ~
12. Fe
+ 2
in
1
8
of T.V. One Fe
+ 3
in another th
1
8

of T.B. and one Fe
+ 3
in th
1
4
of O.V.
13. Divalent cation
2
Zn
+
occupy
1
8
th of tetrahydral voids
14. Charge
2
O

= charges of
8
3
X

ions
( )
8
4 2
3
n
| |
=
|
\ .

3 n =
4 3 1 = (ionic vacancy)
15. R.D. step is the formation of C

16. This reaction is intramolecular rearrangement. Benzyl C

is more stable than alkyl C

.

17.


18. Conceptual
19. ( ) ( ) ( )
2 2 4
5 5
( )
:
Violet Colour
A S Na Fe CN NO Na S Na Fe CN NOS
( (
+


( ) ( )
3
3
( )
: 3
Blood red colour
B R NaSCN FeCl Fe SCN NaCl + +
( ) ( ) ( )
3
4 4
6 6
3
( )
: 3 4 12
Blue colur
C Q Na Fe CN Fe Fe Fe CN Na
+ +
( (
+ +


( ) ( ) ( )
3
3 4 4 4 4 4 3
2 3
( )
: 12
HNO
Yellow ppt
D P Na PO NH MaO NH PO MoO +

C H
3
CH
3
OH
CH
3
N
2
+
CH
3
C H
3
CH
3
O
CH
3
CH
3
H
C H
3
CH
3
O CH
3
CH
3
-N
2
+
-H
+
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

5

Mathematics
20. Put 1 28 t A B C D E = + + + + =
Put 0 39 t E = =
67 A B C D E + + + + =
21. 0 0 y > A < ( ) ( )( )
2
64 5 4 16 7 5 0 a a + < ( ) 15, 2 a e
( ) n s =length of the interval | | 20, 0
( ) 20 n s =
( ) n A = length of the interval | | 15, 2
13 =
( )
13
20
P A =
22. ( )( ) ( ) ( )
3 2 2
1
2 1 2 3 1 2 f x x x x = + ( ) ( )( )
2
2 1 5 7 x x x =





max at 1 x = & min at
7
5
x =

23. Equation of BC is
b
y x
a
= ________(1)
Equation of OA

is
a
y x
b

= ________(2)
Put
2 2 2
in y x y r + =
( )
( )
2
2 2 2 2 2 2 2
2
1 , liesan
a
x r a b a b x y r
b
| |
+ = = + + =
|
\ .


2 2
x b =
x b =
y a =
( ) ( ) , or , A b a b a =
24.
4 4 4 2 2 2 2 2 2 2 2
2 2 2 3 a b c a b c a b c b c + + + =
( )
2
2 2 2 2 2
3 b c a b c + =

-
-
-
-
( ) , a b
( ) , a b
O
A
B
C

+
+

+
1
7
5

IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

6

2 2 2
3
2 2
b c a
bc
+
=
3
cos
2
A =
1
sin
2
A =

25.
( )
, a b is obtuse . 0 a b <
2
14 8 0, x x x + < also
( )
,
6
b k
t
<
2
2 0 x x <
( ) 2 1 0 x x <
( )
1
0, ______ 1
2
x
| |
e
|
\ .

(1) & (2) have no common x
( )
>
3
cos ,
2
b k
>
+
2
3
2
53
x
x

( )
2 2
2 3 53 x x > +
( )
2 2
2 3 53 x x > +
( )
2
159______ 2 x >

26. Let 0.4, 0.6, 11 p q n = = =
1 p q + = it follows binomial distribution
require the porosities ( ) ( ) 5 6 p x p x = = + =
( ) ( ) ( ) ( )
5 6 6 5
11 11
5 6
0.4 0.6 0.4 0.5 c c = +
( ) ( ) | |
5 5
11
5
0.4 0.6 0.6 0.4 c = +
( )
5
11
5
0.24 c =
0.37 = =
5000 1850 = 370 , 5 k k = =

IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

7


27.

4
5
o |
| o
+ =



2 2
1 2 1 2
2 1 1 2


+
+ =
127 , 2 k k = =
28. 3, 10
dx
x
dt
= =
2
3
4
A x =
( )( )
3 53
2 20 3 15 3 6
4 4
dA dx
x
dt dt
= = = =

5 3 225 = 75 , 3 k k = =
29. | | ( )
| |
3
1
x
x x dx =
}

( ) ( )
2 3
1 2
1 2
1 2 x dx x dx = +
} }
( ) ( )
2 3
2 3
1 2
1 2
2 3
x x
( (

= + ( (
( (

1 1
0
2 3
= +
5
6
=
1296
5
1296
6

| |
=
|
\ .
( ) 216 5 1080 540 , 2 k k = = = =
30. Point of intersection
12 12
,
7 7
Q
| |
=
|
\ .


Coefficient of AB

with P as its mid-point is
1 1
2,
x y
x y
+ = but Q liesan it
1 1
12 12
2
7 7 x y
+ = ( )
1 1 1 1
6 7 x y x y + =

locus of P is
( )
12
7
7
xy x = +
12
7
k =
343 49 12 588 k = = 147 p = = 4 p

o |

o|

+ =
=
1
5
|
|
2
16 1 0 + =
( )
( )
1____ 1
3 4
1____ 2
4 3
x y
x y
+ =
+ =
o
|
( )
2
1 5 0 x x + + =
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

8

31.
( )
2
0
sin 2 2
lim
3 3
t
x x
x

=
32.
0 0
1
lim
sin
cos sin 2
cos
t t
t t
Lt
t
t t t
t t
t

=
+
+

33.
( ) ( )
lim
1
x
a
t a
xf x f t dt

(
+
(
(
(
(
(

}
( ) af a =
Passage - 1
( )
2
______ 1 xy c =
Point an (1) can be ( ) , , ,
i i i
i
c c
P ct x y ct
t t
| |
| |
=
| |
\ .
\ .

Consider of normal at P to (1) is

4 3
0 ct t x ty c + =
it passes through ( ) , o |


34.
i i
x c t c
c
o
o
| |
= = + =
|
\ .


35.
1
i
i
y c c
t c
o
o
| |
= = + =
|
\ .



1 2 3 4
1 1 1 1
c
t t t t
(
= + + +
(


3
4
/ s c
c c
c
s
c
|
|
(
( (
= = =
( (

(


36. ( ) xi cti t t = | |
4
1 2 3 4
c t t t t =
4
c
c
c
(
=
(

4
c =
4
1 2 3 4
1
yi c
t t t t
t
(
=
(

( )
4
1 c =
4
c =
37. (A)
( ) ( )
a b c d = a c d c a b c d ( (


a c d b a b c a R ( ( =


(B) ( ) ( )
a c b d a c d b a c b d ( ( = +

a c d b a b c d P ( ( = +


(C)
( ) ( )
a d b c a d c b a d b c ( ( = +

a b c d d b c a Q ( ( =


4 3
0 ct t t c o | + =
1
t
2
t
3
t
4
t
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

9

(D)
( ) ( )
a d c b a d b c a d c b S ( ( =


38. (A)
( )
2 2
1
1
x x
x
x
dx e e dx
I
e
e

= =
+
+
} }


x x
e t e dx td

= =
( )
2
1
t dt
I
t

=
+
}
( )
2
1
log 1
2
t c = + +

( )
( )
2
1
log 1
2
x
e c R

= + +
( )
( )
2
1
log 1
2
x
x e c T d = + +
(B)
( )
2
2
log 1
1
dt
I t t c
t
= = + + +
+
}

( )
( )
2
log 1
x x
e e c P d = + + +

( )
( )
2
log 1 1
x
x e c s

= + + + +
(C) ( ) ( )
/2
2
,
1
1
x x
x
x
x
e e
dx dx P S
e
e
e
=
+
+
} }

(D)
( ) ( )
2 2
2 2
1 .
1 1
x
x x x
e dx
I dx
e e e
= =
+ +
} }

Put tan
x
e u =

2
sec
x
e dx d u u =
( )
2
2
2
sec
tan sec
a d
I
u u
u u
=
}

3
cos
sin
I d
u
u
u
=
}

2
1 sin
cos
sin
d
u
u u
u

=
}
( ) cot sin cos d d u u u u u =
} }

( )
2
sin
log sin
2
c
u
u = +
2
2
2 1
1
log
2 1
x x
x
x
e e
c
e
e
+
| | | |
= + | |
| |
+
\ . \ .

( )
( )
2
2
1 1 1
log 1
2 2 1
x
x
x e c Q
e
| |
= + + +
|
+ \ .


IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

10

Physics
39. Net external torque on the system is zero. Therefore, angular momentum is conserved. Force
acting on the system is only conservative. Therefore, total mechanical energy of the system is also
conserved.
40. f v T
2
AB CD
f f =
4
AB CD
T T = (1)
Further 0
p
t =

( ) ( )
AB CD
T x T l x =
or 4x l x = (as 4
AB CD
T T = )
or / 5 x l =
41. From Y to X charge flows to
plates a and , b
( ) ( ) 0, 27
a b a b
i f
q q q q C + = + =
27 C charge flows from Y to
. X
Correct option is (c).
42. When
3
S is closed, due to
attraction with opposite charge, no flow of charge takes place through
3
S . Therefore, potential
difference across capacitor
plates remains unchanged or
1
30 V V = and
2
20 V V = .
Alternate Solution
Charge on the capacitor is
( )( )
1
30 2 60 q pC = = and
( )( )
2
20 3 60 q pC = =
or
1 2
q q q = = (say)
The situation is similar as the two capacitor in series are first charged with a battery of emf 50V
and then disconnected.
When
3
S is closed,
1
30 V = V and
2
20 V = V

IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

11

43. Net magnetic field due to both the wires will
be downward as shown in the figure.
Since, angle between v

and B

is 180
Therefore, magnetic force
0 m F q v B

| |
= =
|
\ .

44. Momentum of striking electrons
h
P

=
Kinetic energy of striking electrons

2 2
2
2 2
P h
K
m m
= =
This also, maximum energy of X -ray photons. Therefore,
2
2
0
2
hc h
m
= or
2
0
2m c
h

=
45. Normal reaction in vertical direction
1
N mg =
Normal reaction from side to the groove
2
sin37 N ma =
Therefore, acceleration of block with respect to discs
1 2
cos37
r
ma N N
a
m

=
Substituting the values we get,
2
10 /
r
a m s =
46.
2
2
net
e Bvl Bvl
i
R r r
= = =
Here, ( )( ) 1 2 r t
t
2 | |
= = O
|
\ .

( ) ( )( ) 2 1 2 4 i A = =
16
m
F ilB N = =
47. Electron passes undeviated. Therefore,
e m
F F

=
or eE eBv =
or
/ E V d
B
v v
= = (V = potential difference between
the plates)
or
V
B
dv
=
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

12

Substituting the values, we have
3 6
1200
2
0.3 10 2 10
B T

= =


Further, direction of
e
F

should be opposite of
m
F

. or e E e v B

| |
|+
|
\ .

E v B

|+
Here, E

is in positive x direction.
There v B

should be in negative x direction or B

should be in negative z direction (or

perpendicular) to paper inwards, because velocity of electron is in positive y direction
48. Using Kirchhoffs first law at junction a and , b we have found the current in other wires of the
circuit on which currents were not shown.
Now, to calculate the energy stored in the capacitor we will have to first find the potential
difference
ab
V across it.
3 5 3 1 3 2
a b
V V + =

a b ab
V V V = =12 volt

2
1
2
ab
U CV =
( )( )
2
6
1
4 10 12 0.288
2
J mJ

= =
49. If we assume that mass of nucleus >> mass of mu-meson, then nucleus will be assumed to be at
rest, only mu-meson is revolving round it.
In
th
n orbit the necessary centripetal force to the mu-meson will be provided by the electrostatic
force between the nucleus and the mu-meson. Hence,

( )( )
2
2
0
1
4
Ze e
mv
r r tc
= (1)
Further, it is given that Bohr model is applicable to the system also.
Hence,
Angular momentum in
th
n orbit
2
nh
t
=
or
2
h
mvr n
t
=
We have two unknowns v and r (in
th
n orbit). After solving these
two equations, we get

2 2
0
2
n h
r
Z me
c
t
=
Substituting 3 Z = and 208 ,
e
m m = we get
2 2
0
2
624
e
n h
r
m e
c
t
=
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

13

The radius of the first Bohr orbit for the hydrogen atom is:
2
0
2
e
h
m e
c
t

Equating this with the radius calculated in part (i), we get
2
624 n ~

or 25 n ~
50.
qE
a
m
= or
q
a
m
o
51.
2
2
y
y
u
h
a
= . Here
y
qE
a
m
= and 100sin30 .
y
u =
52.
2
,
y
x x
y
u
R u T u R
a
| |
= = |
|
\ .
will increase when
y
a will decrease.
Here .
y
qE
a
m
=
53.
mv
r
Be
= (i)
2
nh
mvr
t
= (ii)
Solving these two equations, we get

2
hn
r
Be t
=

and
2
2
nhBe
v
m t
=

4
nhBe
K
m t
=
54. Ans: (a)
55.
( )
( )
( )
2 2
2 /
e e
M iA r r
T r v
t t
t
| |
= = =
|
\ .

2 4
evr neh
m t
= =
Now, cos180
4
nehB
U MB
m t
= =
56. If fork loaded with wax the frequency may increase or decrease.
If the tension in the string increases then the frequency may increase or decrease.
If fork is filed or string tension decreases then the beat frequency always increases.
57. Draw the ray diagrams