IIT Section

Subject Topic Grand Test Paper I Date

C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

1

Key Answers:
1. a 2. d 3. c 4. b 5. a 6. b 7. c 8. c 9. ab 10. ac
11. ac 12. a 13. d 14. a 15. b 16. b 17. b 18. a 19. 3 20. 8
21. 3 22. 8 23. 4 24. 9 25. 8 26. 6 27. 3 28. 5 29. c 30. a
31. b 32. a 33. b 34. a 35. a 36. d 37. abc 38. ad 39. abc 40. bc
41. ad 42. a 43. c 44. b 45. b 46. c 47. 2 48. 6 49. 7 50. 1
51. 4 52. 2 53. 2 54. 1 55. 4 56. 3 57. b 58. a 59. b 60. d
61. c 62. a 63. b 64. a 65. acd 66. a 67. ad 68. acd 69. ac 70. b
71. a 72. c 73. a 74. d 75. 6 76. 2 77. 7 78. 2 79. 2 80. 5
81. 6 82. 3 83. 6 84. 1



Solutions:
Chemistry
1.













2. Tertiary carbocation is formed first, which undergoes D

1,6- migration to give, more resonance

stablised carbocation, and it undergoes deprotonation in the last step.
3.
2 2 3 2 2
6 4 2 3 NaOH S Na S O Na S H O
A
+ + +
4. ( )
2
X Na Ag CN ( =

Y = Ag
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

2

5. log
.
a
E

(
=
(

3
1 1
5
303 333
2 303 2 10


( )
3
1
log5 303 333 2.303 2 10
10.82
333 303
a
E k cal mol

= =

6.
2
w
h
b
H
K
K
K C
+
(

= =
2
14
4 3
10
4 10 3.3 10
h
H
K
+

(

= =


6.5 pH =
7.
th
E H A of graph (c) >
th
E H A of graph (d)
8.
.
. l

=
30 6 273
22 4
373

9. In the first reaction, tertiary carbocation intermediate in formed and the product in a tertiary
bromide. In the second reaction 1
N
S hydrolysis takes place to give same carbocation
intermediate and the product is a monohydric alcohol.
10. Neighboring group participation of t -bond pair of electrons of benzene ring.
11. ( )
3
Bi OH ppt is formed, but ( )
2
3
4
Zn NH
+
(

soluble complex is formed.
Ferrous hydroxide green ppt, Ferric hydroxide brown ppt are formed.
12. O.N of Nickel in the complex is zero. Two electrons of 4s orbital are shifted to 3d - orbital so
that
3
sp hybridistion occurs.

13. Hint
No.of disintegrations per sec
Total no. of atoms in one gram of Ra
=
0.693
1600 365 24 60 60
=


or No. of disintegrations per sec
23
0.693 6.023 10
1600 365 24 60 60 226

=


14. Double inversion is taking place to give retention in the configuration, because OH group
present in C | atom



IIT Section

Subject Topic Grand Test Paper I Date
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IIT GT 08
12
th
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3


15.









16.





17.
( )
n
nC H COOH C H COOH
n
o
o

6 5 6 5
1

n
i
o
| |

|
\ .
=
1
1 1
1

n
n
o

=

1
1
1

18. In (a) . m= 0 03
b
T m o A
19.
2 3
0 0 0
/ /
cell
Fe Fe Ag Ag
E E E
+ + +
= +
0.771 0.799 0.028volt = + =
At equilibrium, 0
cell
E =
3
0
2
0.0591
0 log
1
cell
Fe
E
Fe Ag
+
+ +
(

=
( (


H
5
C
2
S
CH
2

CH CH
3
Cl
H
5
C
2
S CH CH
3
CH
2 OH
-
C H
2
CH SC
2
H
5
CH
3
OH
(H
5
C
2
)
2
N CH C
2
H
5
CH
2 OH
-
C H
2
CH N(C
2
H
5
)
2
C
2
H
5
OH
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

4

0
1
0.0591log
cell
E
Ag
+
=
(


0.34 Ag
+
(
=


0
log
0.0591
3.0
nE
K
K
=
=


20. Let the molecular formula be ( )
2
2
Ba OH xH O
Mol. Mass of ( ) ( )
2
2
. 137.4 2 16 2 1 18 Ba OH xH O x = + + +
171.4 18x = +
Equilibrium mass of ( )
2
2
171.4 18
.
2
x
Ba OH xH O
+
=

.
. x

= =
+
3
0 789 2 20 10
171 4 18 4

x = 8
Thus, 8g moles of water molecules are present in one g mole of the base
21.
.
.
x
x

= =
2 5 3600 22 2
2 97 3
96500 177

22. pH of salt after hydrolysis may be calculated as,
| |
1
log
2
w a
pH pK pK C = + +

( )
| |
4
1
14 log10 log0.01
2
1
14 4 2
2
8

(
= + +

= +
=

23.
3 2
x x
RT RT
m m
| | | |
=
| |
\ . \ .

3 400 2 60
40
4 30
30
4
R R
m
m
m
=

=
=

24. log P

= + =
400
10 9
373

x
P x = = =
9
10 10 9
IIT Section

Subject Topic Grand Test Paper I Date
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IIT GT 08
12
th
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5

25.
SO Cl
P
SO Cl
p p
K
p

=
2 2
2 2

SO
p

= =
2
10 1
5
2

Total pressure
SO Cl SO Cl
p p p = + +
2 2 2 2

= + + = 5 2 1 8
26. Hint:
| |
6 5 2 6 5 2 2
6 2
Nitrobenzene Aniline
C H NO H C H NH H O + +

So, 6 n =
27. Hint:
1000
;
A
f
A B
w
T K A solute B Solvent
m w

A =

1200 1000
6 1.86
62
B
w

6000
B
w g =
weight of ice
I = total weight of
2
H O - weight of
2
H O at 6 C
9000 6000 3000g = =

3 kg ice =

28. Hint: Original solution
1
500
283..............( )
760
w
V S i
m
=
After dilution
2
105.3
298......................( )
760
w
V S ii
m
=
or
2
1
105.3 298
500 283
V
V
=
or
2
1
298 500
5
283 105.3
V
V
= =
i.e., the solution is diluted to the extent that
2
V is five times the original volume ( )
1
V


IIT Section

Subject Topic Grand Test Paper I Date
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IIT GT 08
12
th
May 2014
I20140508

6

Mathematics
29. Let ( ) , z x iy x y = + =
( ) , z x y =
( ) , iz y x =
( ) , z iz x y y x = +
( )
2 1 2 1 2 2 2
1 3 1 3
1 1 3
3
2 2 2
x x y y
x y z
x x y y

A = = + =


30. Solving two equations
( ) ( )
2 2
1 2 3 1 1 0 x x x x + + = + + =
Only one root 0 A =
( )( )
2
4 1 1 0 + =
( )
2
2 0 2 + = =
31. Total number of triangles
3
10
C
=
number of triangles with one side common
1
10 6
C
=
number of triangles with two sides common 10 =
3 1
requirednumber of traingles 10 10 6 10
C C
=
32. Continuous at
0
1
0 lim sin 0 0
n
x
x n d
x
| |
= >
|
\ .

not differentiable at ( )
1
0 0 x f =

does not exist

( ) ( )
1
0 0 0
1
sin
0 1
lim lim lim sin
0
n
n
x x x
x
f x f
x
x
x x x

| |
|

| | \ .
= =
|

\ .

does not exist ( | 1 0 1 0, 1 n n n s s e



33.



( )
2 2
4, 1, 3 x y P + = =
TN TA AN = +


-
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
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7

1
3
m

=
1
1
y
y m
m
= +
( )
2
1 1
3 3
2 3

A =
1
2
PTN TN AP A =
2 3 =
1
1 1
1
2
y
y y m
m
| |
= +
|
\ .


2
1
1
2
y
m
m
= +
34.






1
P

be image of P

in
1
, , P A Q are collinear
1 1
13
5
AP QP
m m a = =
35. ( )
2
1 ________ 1 x t t = + + by eliminating t
( )
2
1 ________ 2 y t t = +
2
x y
x t x t td

= + =
( )
( )
( ) ( )
2
2
1 1 2 2
4 2
x y x y
x x y x y

= + + = +
. . 2 L L R =
36. cos2 sin 2 7 x a x a + =
2
1 2sin sin 2 7 x a x a + =
( )( )
( )
2
4 2 2 3
sin
2 2
a a a
x

=
4
sin or 2
2
a
x

=
1 sin 1 x s s
4
1 1
2
a
s s
2 6 a s s
axis x
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
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37.
1 1 1 1 2 1 1
b a c b b a c
= = +
( )( )
2
2 1 1 2 1
. ________ 1 G E a
c b b bc b
| || |
= =
| |
\ .\ .

3 2 1
. G E
b a b
| || |
=
| |
\ .\ .

( )( )
2
3 2
___________ 2 c
ab
b
=
1 1 1 1 1 1 1 1 1 1
.
2 2
G E
a c c a c a c a
( ( | | | | | | | |
= + + + +
| | | | ( (
\ . \ . \ . \ .

( )( )
2 2
1 3 2 1
________ 3
4
b
ac c a
(
= +
(


38.
( )
2 1
3 3 5 , 0 1
n
o | |
+
+ = + < <
Let
( )
2 1
3 3 5 , 0 1
n

+
= < <
Consider o | +
( )
( )
+ (
=
(

2
2 1
1
2 3 3 5 .........
n
n
C
| | 10 K o | + =
also 1 1 | < < and an integer | | is an interger o
0 | | = =
10K o o =

is even
( )
( )
2 1
2
2 1
2 26 15 3
n
n
o |
+
+
+ = +

not divisible by
2 1
2
n+

39. ( ) ( ) ( )
1 2 3
1
2
P E P E P E = = =
( ) ( ) ( )
1 2 2 3 3 1
1
4
P E E P E E P E E = = =
( )
1 2 3
1
4
P E E E =
40.



AC a b = +

A
B
C D
a
b
IIT Section

Subject Topic Grand Test Paper I Date
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IIT GT 08
12
th
May 2014
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= + +
2
2 2
AC a b a b
o | o | = + + =
2 2
16 4 16 112
4 7 AC =
also BC a b =
4 3 BC =
41. 0 1, 1 2 x x < < < <
2 3 2 3
x x x x > <
2 3
3 4
2 2
x x
I I > <
1 2
I I >

42.
( )
( )
50 2
100 !
100
50 !
C
=
(


( )
7
2
100 100
100 ! 16
7 7
E
( (
= + = (
( (


( )
7
2
50 50
50 ! 8
7 7
E
( (
= + = (
( (


Exponent of
50
7 in100 0
C
=
43. ( )
2
108 ! 104 E =
( )
5
108 ! 25 E =
member of zeros = exponent of 10 = min{ } 104, 25 25 =
44. ( ) =
18 8 4 2 1 1 1 1
20 ! 2 3 5 7 11 13 17 19

{ }
=
4 14 8 2 1 1 1 1
10 2 3 7 11 13 17 19
It ends with 4 as non-zero digit
Exponent of 12 = 48
The D.E. for
3 1 2
1 2 3
m x m x m x
y c e c e c e = + + is
( ) ( ) ( )
+ + +
= = =
+ + + + + =
3 2
1 2 3 1 2 2 3 3 1 1 2 3
3 2
0 7 6
0
b c d
d y d y dy
m m m m m m m m m m m m y
dx
dx dx

1 a =

45. order=3, degree=1
46. 1 0 6 7 a b d + + = + + =
IIT Section

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IIT GT 08
12
th
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47.
( )( )
2 2 2 2
2 2
1 2 1 2 1 2
az bz bz az a b z z + = + +
2 2 2 2
15 13 a b = + = +
225 169 = +
394 =

+ +
=
1 1 1
2 4 8

=
=394 197k = , 2 k =
48. ( )
2 1000
1000
. 1 1 .......
1 1 1
x x x
GE x
x x x
(
| | | |
= + + + + (
| |
+ + +
\ . \ .
(


( )
1000
1000
1
1
1
1
1
x
x
x
x
x
(
| |
(
|
+
\ .
(
= +
(
| |

( |
+
\ .
(


( )
( )
( )
1001
1001
1001
1001
1
1
1
x x
x
x
(
+
( = +
( +

( )
1001
1001
1 x x = +
coefficient of
( )
( )
50
50
1001 !
1001
50! 951 !
C
x = =
1001, 50, 951 V = = =
R.V 1001 100 28543 = + + =3954 659 6 k k = =
49.
2
5 7 A A I =
( )
3 2
180 35 A A A A I = =
( )
( )( )
5 3 2
18 35 5 7 A A A A I A I = =
149 385 A I aA bI = = +
149, 385 a b = =
= = = 2 3 1453, 207 7 a b k k

50. ( ) 1
n
f x x = +
( ) 10 1001 f =
3
1 10 1
n
x + = +
3 n =
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 08
IIT GT 08
12
th
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11

( )
3
20 20 1 8000 1 f = + = +
= 8000 1 k k
51. L.H.L = . .
2
f R H L
t | |
=
|
\ .

( )
( )
3
2 2
2 2
1 sin
1 sin
Put 2
3cos
2 x y
b x
x
Lt a Lt x y
x
x
t t
t
t

= = =

( )
( )
( )( )
2
2
0
2
1 cos
1 sin 1 sin sin
2
3 1 sin 1 sin y
x
y
b
x x x
Lt a Lt
x x
y
t

( + +

= =
+ ( )
1
3 4
3 2 2
a b
| |
|
\ .
= =
1 1
2 8 2
4
b
a a
b
= = =
=


( )
| |
= = =
|
\ .
5/3
5/3
8
1 32
4
8 8 8
b
a

52. ( ) cos sin x a t t t = +
( ) sin cos y a t t t =

( )
| |
cos sin cos
sin cos sin
a t t t t dy
dx a t t t t
+
=
+ +

sin
tan
cos
dy at t
t
dt
at t
dx
dt
= = =

2
2 2
2
1
sec sec
cos
d y dt
t t
dx at t dx
= =
3
sec t
at
=

2 2
2 2
/3
8 24
120 24 120
3
t
d y d y
a
a dx dx
a t
t
t t
=
| |
= = = |
|
| |
\ .
|
\ .
= = = 2880 1440 , 2 k k
53. ( )
1 2
3 12 9 0 f x x x = + =

2
4 3 0 x x + =
| | 1, 3 but 3 0, 2 x e
( ) 0 1 f =
( ) 1 1 6 9 1 5 f = + + =
( ) 2 8 24 18 1 f = ++ + 3 =
5, 1 = =

4 8
625 1 626 313 2 k k + = + = = =

IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 08
IIT GT 08
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th
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54. Let
2 2 2
x y a + = be the circle
2 2 2
0 x y a + =
Put
2 2
2
1 1
, 0 mi mi a
mi mi
| |
+ =
|
\ .


1 2 3 4
1 m m m m =



55. Let ( ) 3 4, 5 6, 2 1 P r r r + be a point in the first line. This lies on both planes of second line
( ) ( ) ( ) 3 3 4 2 5 6 2 1 5 0 r r r + + + =

2 r = ( ) 2, 4, 3 P = in 2 3 4 0 x y z k + + = 4 12 12 0 k + =
4 k =
56.
1 1 1
sin sin sin 2 1
2
x y x y z
t

= = = = = =
P.V ( )
216
2500 3
3
= 7500 72 = = = = 7428 2476 , 3 k k

4 2 2
1 0 mi a mi + =
1
m
2
m
3
m
4
m
IIT Section

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th
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Physics:
57.
2
2
1
2 4
2 2
l
w
T
Po h pg
R

| |
|
\ .
+ = +
2
2
2
3
2 4
2 2
l
w
T
Po h g p
R

| |
|
\ .
+ = +

Solving we get
2 2
2 1
4
4
l w R T
h h
prg
+
=
58. When spring extended by x
( )
2
0
m L x kx e + =

2
0
2
m L
x
K m
e
=
e

The new length L will be

0
L L x = +

Tension in the spring ( )

2
0
T m L x = e +
2
2
0
2
1
m
m L
K m
(
e
= e +
(
e (


2
0
2
m KL
T
K m
e
=
e


59. Emf induced Blv =
Q Cv =
Q CBlv =
60. I max
2
R
c
= at 0 t =
I
R
c
= at t =so charge on the capacitor is Cc , when current is 50% of maximum current.
61. Let the length of edge be ' ' x
Net magnitude of displacement from A to 3 D x =
Total time
1 2 3
x x x
v v v
= + +
Average velocity
1 2 3 1 2 3
3 3
1 1 1 x x x
v v v v v v
= =
+ + + +

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th
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62. When frequency is less
1
wl
wc
>
As frequency increases, capacitive reactance decreases but inductive reactance increases. So phase
difference decreases. Then L e becomes greater than
1
c e
. Now as frequency increases, the
magnitude of phase difference again increases.
63.
2
T V =
2
TV C

=
or
1
PV C

=
1 =
| |
2 1
1
nR T T
W

450 W R =
64. Let at any time the speed of the block along the induce up wards be V . from 2 N L
sin cos
p mdv
mg mg
v dt
u u =
The speed is maximum when 0
dv
dt
=

max
sin cos
p
V
mg mg u u
=
+

65. Charge of
1
l is
1 1 1
q l r d u = =
Charge of
2
l
2is
2 2 2
q l r d u = =
1 1
2 2
q r
q r
=
1 1
1 2 2
1 1 1
kq k r d k d
E
r r r
u u
= = =
2 2
2 2 2
2 2 2
kq k r d k d
E
r r r
u u
= = =
So net electric field cant be zero
1
E is more, so direction is towards
2
l
Potential due to
1
l is
1 1
1
1 1
kq k r d
v k d
r r
u
u = = =
Potential due to
2
l

is
2 2
2
2 2
kq k r d
v
r r
u
= =
2
v k d u =
1 2
v v =
IIT Section

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th
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66. EMF across
2
2
Bwl
PR =
EMF across
2
2
Bwl
PQ =
So emf across 0 QR =
67. At
1, max z x = = Upper end open lower end closed.
0.99 , min z m x = =

left
2 2
0.8
0.8
m

H H
= =

0.99 0.01 1m = + =
5
, 5 five half loops Second overtone
4 4
l
l

| |
= =
|
\ .

68. Velocity is more in rarer medium
v f = , where f is constant.
69. ( ) sin X A t e =
1
2
sin
2
A
A t
T
t
=
1
12
T
t =
( )
1 2
2
sin
2
A
A t t
T
t
=

1 2
8
T
t t =
70. FBDof small section of ring subtending angle du at center of ring is as shown
,
2 2 2
N N md
Td g
u
u
t
= =

2
mg
T
t
=
71.
T
v =

2
2
mg
gR
m
R
= =
| |
|
\ .
t
t

72. Since there is no friction between ring and cone the tension in the ring will remain same
73.
2 1
3
4
v v =
We know that
IIT Section

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th
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16

1
2
i r i
v
A A A
v
= (1)
2 1
2 1
r i
v v
A A
v v
| |
=
|
+
\ .
and
2
2 1
2
i i
v
A A
v v
| |
=
|
+
\ .
(2)
From equation (1) and (2), 1: 7
r
i
A
A
=
74. 6 : 7
i
i
A
A
=
75. Let x be the temperature of block in steady state
10 5 3
0 6
x x x
x C
R R R

+ + = =
76.
1 0
s
v v
n n
v v
(
=
(

77.
1 2 3
0 Q Q Q + =
1 2
0
2
Q Q
IR
c c

+ =

3 2
2 0
2
Q Q
IR
c c
+ =
1 2 3
5 7
, and
4 2 4
IRC
Q IRC Q Q IRC = = =
78. When S is closed
1
t RC =
When S is opened
1
2
2
3 2
2 3
t RC
t
t
= =
79. Y bright
n D
d

=
Y Dark
1
2
D
n
d
| |
= +
|
\ .

80.
2
2 2
1 2
1 1
13.6 E z
n n

=
`
)

2
2 2
1 1
47.2 13.6 5
2 3
z z

= =
`
)

81. 5 12 12 3 8
C B
V V + + =
6
C B
V V V =


82. 17 h ev v =
IIT Section

Subject Topic Grand Test Paper I Date
C + M + P Grand Test 08
IIT GT 08
12
th
May 2014
I20140508

17

Now for metal max h KE v = C+
17 2 ev ev = C+
15ev C=
3 K =
83. In steady state let T be the temperature of all the three blocks
{ } { } { } 10 2 5 2 5 0 mc T mc T mc T + + =
84. Considering reflection at the curved surface
1 2
3
; 1
2
= =
20 ; 10 u cm v xcm = =
20 R cm = +
from
2 1 2 1
v u R

=
1 3 0.5
10 40 20 x

=


1 1 3
10 40 40 x

=
10 10 x =

1 x =