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Chemistry
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 3 marks. A wrong
answer carries a penalty of 1 mark 8 x 3 = 24
1. Identify the final product obtained in the following reaction.
(a) (b)
(c) (d)
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
O
COOC
2
H
5
O
( ) ( )
1)NaH
2)HCHO
X ; X is
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2. The product formed in the reaction is
D
HO
.
OH
18
H
+
(a) (b)
(c) (d)
3. When sulphur is heated with aqueous NaOH , the compounds formed are
(a)
2 2
Na S H O + (b)
2 3 2
Na SO H O +
(c)
2 2 2 3 2
Na S Na S O H O + + (d)
2 2 3 2
Na S O H O +
4.
2
.
Zn
Ag S NaCN X Y + If Y is a metal, then X and Y are respectively.
(a) ( )
2
4
, Na Zn CN Zn (
(b) ( )
2
, Na Ag CN Ag (
(c) ( )
2
4
, Na Ag CN Ag (
(d) ( )
3
4
, Na Ag CN Ag (
.
D
O
18
O
.
O
.
18
O
D
.
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5. A reaction proceeds at a rate five times more at 60 C than it does at 30 C . Then the energy of
activation is approximately
(a)
1
10.8K cal mol
(b)
1
11.8K cal mol
(c)
1
9.8K cal mol
(d)
1
12.8K cal mol
6. A 500 0.01 ml M aqueous solution of
3 2
CH NH (methanamine) is titrated by a 0.005 M HCl solution at
25 C ,
b
K of
3 2
CH NH , at 25 C is
4
4 10
2
H O
?
(a)
(b)
(c) (d)
Comprehension II
When the solute undergoes dissociation or association in solution, the number of particles in solution
increases or decreases and thus, the colligative property changes accordingly. The extent of dissociation
or association of the solute in solution can be expressed in terms of Vant Hoff factor, i.
In case of dissociation, 1 i >
( ) 1 1
1
n
i
o +
=
Similarly in case of association, 1 i >
1
1 1
1
n
i
o
| |
+
|
\ .
=
Et
N
.
Et OH
Et
N
Et
OH
.
Et
N
.
Et OH
.
.
Et
N
OH
Et
. .
.
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17. For the solution of benzoic acid in benzene o is calculated using the expression
( o
is the degree of dissociation or association)
(a)
1
1
i
n
o
=
(b)
1
1
1
i
n
o
=
(c)
1
1
i
n
o
=
+
(d)
1
1
i
i
n
o
=
18. Which of the following solutions will exhibit highest boiling point
(a)
2 4
0.01 M Na SO (b)
3
0.01M KNO (c) 0.015 M urea (d) 0.015 M glucose
Section IV
Integer answers type questions. Each carries 3 marks. No negative marks 10 x 3= 30
19. At equimolar concentrations of
2
Fe
+
and
3
Fe
+
, what must Ag
+
(
be so that the voltage of the
galvanic cell made from / Ag Ag
+
and electrodes equals zero? The reaction is
2 3
Fe Ag Fe Ag
+ + +
+ + . Determine the equilibrium constant at 25 C for the reaction. (Given:
0
/
0.799
Ag Ag
E volt
+
= and
3 2
0
/
0.771
Fe Fe
E volt
+ +
= )
20. 0.789g of crystalline barium hydroxide is dissolved water. For the neutralisation of this solution.
20mL of
3
4
N
HNO is required. How many molecules of water are present in one g mole of this base?
( ) 137.4, 16, 14, 1 Ba O N H = = = =
21. A current of 2amp when passed for 5 hour through a molten salt deposits 22.2g of metal of atomic
mass 177 . The positive oxidation state of the metal in the metal salt is:
22. The dissociation constant of a substituted benzoic acid at 25 C is
4
1 10
. The pH of a 0.01M
solution of its sodium salt is:
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23. At 400K , the root mean square (rms) speed of gas X (molecular mass 40 = ) is equal to the most
probable speed of gas Y at 60K . The molecular mass of the gas Y is
24. For a liquid the vapour pressure is given by:
10
400
log 10 P
T
1
sin , 0
0 , 0
n
x x
f x x
x
.
Then ( ) f x
is continuous but not differentiable at 0 x =
,
if
(a) ( | 0, 1 ne (b) | ) 1, ne (c) ( | , 0 ne (d) 0 n =
33. The area of the triangle formed by the positive x axis, the normal and tangent to the circle
2 2
4 x y + = at the point
( )
1, 3
is
(a) 3 sq. units (b) 2 3 sq. units (c) 4 3 sq. units (d) none of these
34. A ray of light coming from the point ( ) 1, 2 is reflected at a point A on x axis and then passes
through the point ( ) 5, 3 . The coordinates of the point A are
(a)
| |
|
\ .
13
, 0
5
(b)
| |
|
\ .
5
, 0
13
(c) ( ) 7, 0 (d) none of these
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35. The length of latus rectum of the parabola whose parametric equations are
2 2
1, 1, x t t y t t = + + = + where e t R,
is equal to
(a) 2 (b) 4 (c) 8 (d) none of these
36. The equation cos2 sin 2 7 x a x a + =
possesses a solution for
(a) all a (b) 6 a > (c) 2 a < (d) | | 2, 6 ae
Section II
Multiple Choice Questions with one or more correct answer. A correct answer carries 3 marks.
No negative mark 5 x 3 = 15
37. If , , a b c
are in H.P, then the value of
1 1 1 1 1 1
b c a c a b
| | | |
+ +
| |
\ . \ .
is
(a)
2
2 1
bc
b
(b)
2 2
1 3 2 1
4 ca c a
| |
+
|
\ .
(c)
2
3 2
ab
b
(d) none of these
38. If n is a positive integer and
( )
2 1
3 3 5
n+
+ = + o | , where o
is an integer and 0 1, | < < then
(a) o
is an even integer
(b) ( )
2
o | +
is divisible by
2 1
2
n+
(c) the integer just less than
( )
2 1
3 3 5
n+
+ is divisible by 3
(d) o
is divisible by 10
39. A bag contains four tickets marked with 112, 121, 211 and 222 . One ticket is drawn at random
from the bag. Let ( ) = 1, 2, 3
i
E i
denote the event that the
th
i
digit on the ticket is 2 . Then
(a)
1
E and
2
E are independent (b)
2
E and
3
E are independent
(c)
3
E and
1
E are independent (d)
1 2 3
, , E E E are independent
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40. A parallelogram is constructed on the vector o | o | = = + 3 , 3 a b .
If o | = = 2
and angle
between o
and |
is
3
t
, then the length of the diagonal of the parallelogram is
(a) 4 5 (b) 4 3 (c) 4 7 (d) none of these
41. If = = = =
} } } }
2 3 2 3
1 1 2 2
1 2 3 4
0 0 1 1
2 , 2 , 2 and 2
x x x x
I dx I dx I dx I dx , then
(a)
1 2
I I > (b)
2 1
I I > (c)
3 4
I I > (d)
4 3
I I >
Section III
Comprehension type questions. A correct answer carries 3 marks. A wrong answer carries a
penalty of 1 mark 5 x 3 = 15
Comprehension I
Let p be a prime number and n
be a positive integer. If the exponent of p in ! n
is denoted by ( ) !
P
E n ,
then
( )
( ( (
= + + +
( ( (
( (
2
!
p
K
n n n
E n
p p p
where
+
< <
1 k k
p n p and | | x
denotes integral part of x .
Every natural number n
can be uniquely expressed as
o o o
o =
3 1 2
2 3 5 ,
i
n
are whole numbers.
On the basis of above information answer the following
42. The exponent of 7 in
100
50
C
is
(a) 0 (b)1 (c) 2 (d) 3
43. The number of zeros at the end of 108! is
(b) 10 (b)13 (c) 25 (d) 26
44. The last nonzero digit in 20!
must be equal to
(a) 2 (b) 4 (c) 6 (d) 8
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Comprehension II
The differential equation corresponding to
3 1 2
1 2 3
m x m x m x
y C e C e C e = + + , where
1 2 3
, , C C C
are arbitrary
constants and
1 2 3
, , m m m
are roots of
3
7 6 0 m m + =
is
+ + + =
3 2
3 2
0, , , ,
d y d y dy
a b c d a b c d
dx dx dx
are constants, then
45. The order and degree of the differential equation respectively are
(a) 3, 2 (b) 3, 1 (c) 3, 3 (d) 1, 3
46. The value of a b d + + =
(a) 0 (b) 6 (b) 7 (d) 5
Section IV
Integer answers type questions. Each carries 3 marks. No negative marks 10 x 3= 30
47. If
1
z
and
2
z are complex numbers such that
( )
+ = +
2 2 2 2
1 2 1 2 1 2
15 13 13 15 z z z z z z , then the
value of
must be equal to 197 k , where k =
48. The coefficient of
50
x
in the polynomials after like terms have been collected in the expansion
( ) ( ) ( ) + + + + + + +
1000 999 998
2 1000
1 1 1 x x x x x x is >
!
,
! !
m
p n
n p
. Then the value of + + 2 3 m n p is
659k , where k =
49. Suppose a matrix A
satisfies
2
5 7 0 A A I + = . If
5
A aA bI = + ,
then the value of 2 3 a b is equal to
207k ,
where k =
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50. A polynomial ( ) f x satisfies the condition ( ) ( )
| | | |
= +
| |
\ . \ .
1 1
f x f f x f
x x
and ( ) 10 1001 f = .
Then
( ) 20 f
is 8000k , where k =
51. Let ( )
( )
( )
3
2
2
1 sin
,
2
3cos
,
2
1 sin
2
2
x
x
x
f x a x
b x
x
x
t
t
t
t
<
= =
>
If ( ) f x is continuous at
2
x
t
= ,
then the value of
| |
|
\ .
5/3
1
8
b
a
is
52. If ( ) ( ) = + = cos sin , sin cos x a t t t y a t t t , and
t
=
| |
= |
|
\ .
2
2
3
t
d y
b
dx
, then the value of t 120 ab
is 1440k ,
where k =
53. Let the greatest and least values of the function ( )
3 2
6 9 1 f x x x x = + +
on the interval | | 0, 2
be
and respectively. If the value of
4 8
+
is 313k , then k =
54. If
| |
=
|
\ .
1
1
, , >0 , 1, 2, 3, 4
i
i
m m i
m
are four distinct points on a circle, then the value of
=
[
4
1
i
i
m is
equal to
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55. If the lines
1
4 6 1
:
3 5 2
x y z
L
+ +
= =
and
2
: 3 2 5 0 2 3 4 L x y z x y z k + + = = + +
are coplanar, then k is
equal to
56. If
1 1 1
3
sin sin sin
2
x y z
t
+ + = ,
then the value of ( )
3 3 3
216
2500 x y z
x y z
+ +
+ +
is 2476 k . The value
of k is
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Physics
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 3 marks. A wrong
answer carries a penalty of 1 mark 8 x 3 = 24
57. A liquid of density and surface tension T is filled in the tube and the tube is rotated with angular
velocity e about the given axis. Contact angle is 0 . The difference in heights of liquid in two
columns is
(a)
2 2
2
l w R T
Rg
(b)
2 2
4
4
l w R T
Rg
+
(c)
2 2
4
2
l w R T
Rg
(d)
2 2
l w R
Rg
58. A particle of mass ' ' m is attached to a massless spring of initial length
0
' ' L
and spring constant ' ' K
.
Now it is rotated in a horizontal plane with an angular velocity ' ' e
by fixing its other end. The
tension in the spring is given by
(a)
2
0
2
m KL
K m
e
e
(b)
2
2
0
K m
m KL
e
e
(c)
2
0
2
m KL
K m
e
+ e
(d)
2
2
0
K m
m KL
+ e
e
59. A capacitor ' ' C is connected to a conducting rod of length
l the loop starts entering a transverse magnetic field ' ' B as
shown in diagram, when the loop is entering the field,
what will be the charge developed across the capacitor?
(a) zero (b) BlvC (c)
2
BlvC
(d)
3
BlvC
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60. If at 0 t = the switch
w
S is closed, then the charge on capacitor in the given circuit (initially
uncharged) when the current through battery becomes 50%of its
maximum value is (assume battery is ideal)
(a)
3
CE
(b)
2
CE
(c)
4
CE
(d) CE
61. Starting from one corner of a cube an insect has to travel to the diagonally opposite corner. The
insect travels along the edges. It traverses the first edge AB with constant velocity
1
V , the second
edge BC with constant velocity
2
V and the third edge CD with constant velocity
3
V . The average
velocity of the whole path.
(a)
1 2 3
3
1 1 1
V V V
+ +
(b)
1 2 3
3
V V V + +
(c)
1 2 3
3
1 1 1
V V V
+ +
(d)
1 2 3
2
1 1 1
V V V
+ +
62. In a series LCR circuit, as the frequency of the voltage source increases, the magnitude of phase
difference between current and voltage.
(a) increases
(b) decreases
(c) first decreases, then becomes zero at a particular frequency, then increases
(d) remains constant
63. One mole of an ideal monoatomic gas undergoes process
2
T V = and temperature of gas changes
from 300K to 1200 K . Then Work done by the gas is ( R is universal gas constant)
(a) 400R (b) 450 R (c) 900 R (d) 600 R
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64. A block of mass ' ' m is being pulled up the rough incline by an agent delivering constant power p .
The coefficient of friction between the block and the incline during the course of ascent is
(a)
sin cos
p
v
mg mg u u
=
+
(b)
sin cos
p
v
mg mg u u
=
(c)
2
sin cos
p
v
mg mg u u
=
(d)
3
sin cos
p
v
mg mg u u
=
Section II
Multiple Choice Questions with one or more correct answer. A correct answer carries 3 marks.
No negative mark 5 x 3 = 15
65. A positively charged ring having uniform charge density is
shown in the figure. Two elements of ring of length
1
l and
2
l
subtend same angle (very small)at a point A point A is in the
plane of ring but not at the centre. The elements
1
l and
2
l are
at distance
1
r and
2
r respectively from the point ( ) A
(a) The ratio of charges of elements
1
l and
2
l is
1
2
r
r
(b) Net electric field at point is zero
(c) The elements
1
l and
2
l produce same potential at A
(d) The direction of net electric field at A towards
2
l
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66. A bent conducting rod ( ) PQR PQ QR l = = is rotating about its end P , with equal speed in a
region of transverse magnetic field of strength ( ) B
(a) emf induced across the rod is
2
2
Bwl
(b) emf induced across the rod is
2
8
Bwl
(c) Potential difference between points Q and R on the rod is
2
2
Bwl
(d) Electric field from P to Q is
8
Bwl
67. In an organ pipe (which may be closed or open) of 99cm length, standing wave is set up whose
equation is given by longitudinal displacement.
0.3 X = mm | |( ) cos 2 / 0.8 0.01 ] cos 400 z m t t +
Where z measured from the top of tube in meters and t is in
seconds.
Take end correction 1 cm = choose the correct statements
(a) The upper end and lower end of tube are open and closed respectively
(b) The upper end and lower end of tube are closed and open respectively
(c) The air column is vibrating in third harmonic
(d) The air column is vibrating in second overtone
68. The path of a ray is shown in the figure. It could be the path of a wave whose
(a) Velocity in water is less than velocity in air
(b) Velocity in air is less than velocity in water
(c) Frequency does not change
(d) Wave length changes
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69. A particle excretes S.H.M according to sin x A t e = . The time taken by it to move from 0 x = to
2 x A = is
1
T and from 2 x A = to 2 x A = is
2
T then
(a)
1 2
T T > (b)
1 2
T T = (c)
1 2
2 T T = (d)
2 1
2 T T =
Section III
Comprehension type questions. A correct answer carries 3 marks. A wrong answer carries a
penalty of 1 mark 5 x 3 = 15
Comprehension I
A ring of mass mand radius R rests in equilibrium on a smooth cone of semi vertical angle 45 as
shown. The radius of the cone is 2R , the radius of circular cross section of the ring is | | r r R <<
Answer the following questions
70. What will be the tension in the ring?
(a)
2 2
mg
t
(b)
2
mg
t
(c)
2
mg
t
(d)
2 mg
t
71. What will be the speed of transverse wave on the ring
(a) gR (b) 2gR (c)
1
2
gR (d) 2 gR
72. If the cone is rotated about its axis with angular velocity . what will be the tension in the ring now ?
(a)
2
( )
2
m
g w R
t
(b)
2
( )
2
m
g w R
t
+ (c) / 2 mg t (d)
2
mgw R
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Comprehension II
When a progressive wave enters from one medium to another medium, some of its energy gets
transmitted and the remaining of its energy reflected at the boundary of separation.
The energy of incident wave = The energy of reflected wave + The energy of transmitted wave
A progressive wave travels in a medium
1
S and enters into another medium
2
S in which its speed
decreases to 75%. What is the ratio of the amplitude of the
73. Reflected and the incident waves
(a) 1: 7 (b) 1:1 (c) 6: 7 (d) 8: 7
74. Transmitted and the incident waves
(a) 1:1 (b) 1: 7 (c)
8: 7 (d) 6: 7
Section IV
Integer answers type questions. Each carries 3 marks. No negative marks 10 x 3= 30
75. A metallic block of mass 1 kg and specific heat 1 cal gm C is connected to
three identical rods as shown in diagram. Temperature of , A B and C are
maintained at 10 , 5 C C and 3 C respectively. Find the final temperature of
1 kg block on Celsius scale. (Neglect any heat loss due to radiation)
76. A siren placed at a railway platform is emitting sound of frequency 5 KHz . A passenger sitting in a
moving train A records a frequency of 5.5 KHz while the train approaches the siren. During his
return journey in a different train B he records a frequency of 6.0 KHz while approaching the same
siren. The ratio of the velocity of train B to that of train A is?
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77. In the network of capacitor and resistances shown in figure,
steady current I enters at junction (a) and same current leaves
junction (b) charge on capacitor
3
C with shown polarity is
4
KIRC
find K . Initially all capacitors were uncharged
78. The capacitor is charged by closing the switch ' '. S The switch is then opened and the capacitor is
allowed to discharge.
1
t and
2
t be the time constant of
the circuit during the charging and discharging of the
capacitor(
1 2 3
R R R R = = = ).
If the ratio of
1
2
1
t n
t n
=
+
, then the value of n is?
79. In double slit experiment, the slits are 0.5 mm apart and interference is observed on a screen placed
at a distance of 100cm from slits. It is found that 9
th
bright fringe is at a distance of 8.835 mm from
the 2
nd
dark fringe from the centre of fringe pattern. If the wavelength of light used is
7
3.398 10 n m
then ? n =
80. A single electron orbits a stationary nucleus of charge Ze + where Z is a constant and e is the
magnitude of the electronic charge. It acquires 47.2 eV to excite the electron from the second Bohr
orbit to third Bohr orbit. Find the value of Z .
81. Potential difference
C B
V V in volts is
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82. A mono chromatic light is just able to ionise a hypothetical one electron atom in its ground state
having energy levels defined by
2
17
n
E
n