Lecture 1-1. Lecture Notes from Univerisit Teknologi PETRONAS.
The main reference used is Essentials of Chemical Engineering published by Prentice Hall.
Lecture 1-1. Lecture Notes from Univerisit Teknologi PETRONAS.
The main reference used is Essentials of Chemical Engineering published by Prentice Hall.
Lecture 1-1. Lecture Notes from Univerisit Teknologi PETRONAS.
The main reference used is Essentials of Chemical Engineering published by Prentice Hall.
Design Associate Professor Dr Ku Zilati Ku Shaari May 2014 CHAPTER 1 Course Outline CHAPTER 1 Course Learning Outcomes (CO) 1. Explain the fundamentals of different types of reactors and reactor operations. 2. Apply the principles of chemical reaction engineering in solving reaction engineering problems, both for homogeneous and heterogeneous systems. 3. Interpret and analyze reaction kinetics and reactor systems for optimum reactor performance. 4. Apply reactor design equations for a broad range of conditions including multiple reactions, catalytic reactions and non- isothermal processes. Apply knowledge of mathematics, science and engineering fundamentals and an engineering specialization to the solution of complex chemical engineering problems. Identify, formulate, research literature and analyse complex chemical engineering problems reaching substantiated conclusions using first principles of mathematics, natural sciences and engineering sciences Program Outcomes (PO) CHAPTER 1 Chemical Engineering Program Outcomes (PO) 1. Apply knowledge of mathematics, science and engineering fundamentals and an engineering specialization to the solution of complex chemical engineering problems. 2. Identify, formulate, research literature and analyse complex chemical engineering problems reaching substantiated conclusions using first principles of mathematics, natural sciences and engineering sciences 3. Design solutions for complex chemical engineering problems and design systems, components or processes that meet specified needs with appropriate consideration for public health and safety, cultural, societal, and environmental considerations. 4. Investigate complex chemical engineering problems using research based knowledge and research methods including design of experiments, analysis and interpretation of data and synthesis of information to provide valid conclusions. 5. Use modern engineering and IT tools to evaluate complex chemical engineering activities. 6. Apply reasoning informed by contextual knowledge to assess societal, health, safety, legal and cultural issues and the consequent responsibilities relevant to professional engineering practice. 7. Understand the impact of professional engineering solutions in societal and environmental contexts and demonstrate knowledge of and need for sustainable development. 8. Apply ethical principles and commit to professional ethics and responsibilities and norms of chemical engineering practice 9. Communicate effectively on complex chemical engineering activities with the engineering community and society. 10. Function effectively as an individual, and as a member or leader in diverse teams and in multi- disciplinary settings. 11. Recognise the need for, and have the preparation and ability to engage in independent and life-long learning in the broadest context of technological change. 12. Demonstrate knowledge and understanding of engineering and management principles and apply these to ones own work, as a member and leader in a team, to manage projects and in multidisciplinary environments.
CHAPTER 1 Important Rules and Regulations 1. PUNCTUAL!!! I am very strict about you BEING ON TIME! 2. No make-up Test or Quiz (unless with MC, UTP event approval form or death certificate of immediate family 3. Attendance is compulsory, only 3 absences is accepted
CHAPTER 1: Mole Balances Lecture 1
CHAPTER 1 Objectives- Chapter 1: Define the rate of chemical reaction.
Distinguish the difference in operation of different types of reactor
Apply the mole balance equations to a batch reactor, CSTR, PFR, and PBR. CHAPTER 1 Topics (Chapter 1): Lecture 1:
Chemical Identity Reaction Rate Lecture 2:
General Mole Balance Equation Mole Balance for Different Reactor Types Lecture 3: Mole Balance for Different Reactor Types Examples CHAPTER 1
CHAPTER 1 CHEMICAL REACTION ENGINEERING CHEMICAL REACTION REACTOR DESIGN CHAPTER 1 Basic knowledge: Very important Applications: CHAPTER 1 Application of Chem Rxn Engr (please read page 1-3) Manufacture of polyethylene and ethylene. Plant Safety (Nitroanaline Plant Explosion Exothermic Reactions That Run Away). Oil recovery. Lubricant Design (Effective Lubricant Design Scavenging Free Radicals). Enzyme kinetics and Pharmacokinetics. Cobra Bites (Pharmacokinetics of Cobra Bites Multiple Reactions in a Batch Reactor (body).
CHAPTER 1 Reaction rate, -r A What does it tell??? How fast a number of moles of one chemical species are being consumed to form another chemical species (identity). CHAPTER 1 Chemical Identity Identity of a chemical species is determined by the kind, number and configuration of the species atom C C H H CH 3 CH 3
Cis-2-butene C C H H CH 3
CH 3
Trans-2-butene Considered as 2 different species due to the different configuration even when the numbers of atoms of elements are the same CHAPTER 1 Chemical Identity A reaction is said to occur when a species lost its identity and assumed a new form either by: Change in the number of atoms in the compound Change in structure of the compound Change in configuration of atoms
CHAPTER 1 3 ways of losing chemical identity: Decomposition
Combination
Isomerisation Chemical Identity 2 2 2 3 3 CH C H H CH CH NO 2 O N 2 2
2 3 2 2 5 2 CH C CH CH CH H C CHAPTER 1 Reaction rate Defined as the rate at which a chemical species reacts (or formed) per unit volume Expressed as: Rate of reactant disappearance Rate of product formation CHAPTER 1 Example: A B Rate of reaction is given by: -r A = rate of disappearance of A r B = rate of formation of B For heterogeneous reaction, rate of reaction is express in terms of catalyst volume or catalyst weight Reaction rate CHAPTER 1 Reaction rate is an intensive properties depends on concentration, temperature, pressure, or type of catalyst, present in a system Reaction rate is NOT influence by type of reactor used!! Reaction rate is expressed as: -r A = kC A n
NOTE: dC A /dt is not the definition for reaction rate
Reaction rate CHAPTER 1 Reaction rate: Example: Is NaOH reacting?
CSTR - operated at steady state; inlet flow rate = outlet flow rate Perfectly well mixed system; concentration of samples taken at 10 a.m is the same as concentration taken at 5 p.m Therefore: dC A /dt = 0
Does this mean that -r A = 0; i.e. no reaction occurs? The answer is NO!
dt dC r A A
CHAPTER 1 For any species A: r A is the rate of formation of species A per unit volume [e.g. mol/dm 3. s] r A is a function of concentration, temperature, pressure, and the type of catalyst (if any) r A is independent of the type of reactor (batch, plug flow, etc.) r A is an algebraic equation, not a differential equation Reaction rate CHAPTER 1 Types of Reactor: 1. Batch reactor 2. Continuous-Stirred Tank Reactor (CSTR) 3. Plug Flow Reactor (PFR) or Turbular Reactor 4. Packed Bed Reactor (PBR) CHAPTER 1 Industrial reactors Types of reaction Liquid phase reaction Gas phase reaction Semi batch reactor, CSTR
Tubular reactor CHAPTER 1 Different types of reactor: 1) Batch reactor Physical shape: Tank Used for: small scale operation process that is not suitable for continuous operation. Advantage: High conversion longer residence time Disadvantage High cost Product variability Not for large-scale operation CHAPTER 1 Different types of reactor: 2) Continuous-Stirred Tank Reactor (CSTR) Physical shape: Tank Continuous Flow, Steady state, Perfectly mixed Used for: Liquid phase reaction process that is suitable for continuous operation. Advantage: Continuous operation Disadvantage Not for non-ideal mixing CHAPTER 1 Different types of reactor: 3) Plug Flow Reactor (PFR) Physical shape: Cylindrical pipe Continuous Flow, Steady state, Perfectly mixed Used for: Gas phase reaction Reaction rate varies axially NOT radially. Reactant Product CHAPTER 1 Different types of reactor: 4) Packed Bed Reactor (PBR) Physical shape: Cylindrical Continuous Flow, Steady state, Perfectly mixed Used for: Fluid-solid heterogeneous reaction (catalyst) Reactant Product CHAPTER 1 Photos of real reactor systems Batch reactor CHAPTER 1 CSTR Photos of real reactor systems CHAPTER 1 Photos of real reactor systems PFR CHAPTER 1 Dr. KuZee May 2014 CCB3043-Kinetics & Reactor Design