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Bi 1:

1) St nguyn cht co s chuyn i cu tic t lp phng tm khi (BCC) sang lp phng


tm uin (FCC) nhit 912
o
C. Tinh % s thay i th tich ca qu tiinh tin bit ing
912
o
C mng FCC co thng s mng l u.29Snm v mng BCC co thng s mng l u.S6Snm.
2) Biu thc tinh nng lng election ca Biuio co ung:
En=R(
z
n
)
2
(})
Bit bc song cc i tiong uy Balmei l bc song vch B v bng 6S62,8 Amstiong.
a) Tinh R
b) Tinh nng lng ion hoa ca Biuio theo ev v k}mol
c) Khi chiu x cc nguyn t B bng bc x 7unm ngi ta thy e thot ia co ng nng Eu
= 14,S1ev. Cho bit nguyn t B lc ny ang ting thi kich thich n = . .
S) So snh bn gia hai cht tiong tng cp phc cht sau v gii thich ngn gn.
a) |Cu(EBTA)j
2
v |Zn(EBTA)j
2

b) |Ru(bipy)Sj
S+
v |Ru(py)6j
S+

N N
bipy = py =
N

c)




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Bi 2:
1) Phn ng NBS: N2 + SB2 2NBS Suu
o
C co Kp = 1,S.1u
S
. Tnh xem co bao nhiu pha n tim
ho n h p ban a u (N2 + SB2) a chuyen tha nh NBS neu pha n ng c th c hie n Suu atm,
1uuu atm. Cho bit kt qu thu c ph hp vi nguyn l chuyn uch cn bng hay khng.
2) Xt mt binh chn khng hinh lp phng, kin hon ton v cch nhit. Xc nh ui cnh
ti thiu ca binh kin ny sao cho khi thm S,78S L nc lng 2S
o
C vo binh, nc s
tn ti ting thi khi. Chp nhn nhit ca binh bng nhit phong (2S
o
C) tiong sut
qu tiinh. Cho bit: M v J
H
2
0
ln lt l 18,u2 gmol v u,998 gcm
S
, nhit si ca B20
ti 1 atm l 1uu
o
C. Nhit ho hi ca nc lng (gi thit khng ph thuc vo nhit ) l
4u,68 k}mol, v hi nc x s nh khi l tng.

Bi 3:
1) t lu chng ta s ung phng tiinh Aiihenius kho st s bin i ca hng s tc
vi nhit . Nt tiong nhng gi thit tiong vic s ung phng tiinh Aiihenius o l
xem nh nng lng hot hoa khng bin thin theo nhit , v phng tiinh ny l kt
qu ca thuyt va chm. Nt l thuyt khc co th gii thich tt hn mi quan h gia hng
s tc v nhit l phng tiinh Eyiing, l kt qu ca thuyt ting thi chuyn tip
(hay phc cht hot ng). Bng ca phng tiin Eyiing l:
k =
k
B
I
b
cxp _-
0
=
RI
_
Tiong o k l hng s tc , kB = 1.S81u
2S
(hng s Boltzman), u

l bin thin nng


lng t uo cho qu tiinh chuyn t tc cht thnh ting thi chuyn tip. Tun theo l thuyt
nhit ng thng thng, u

= B

TS

.
Tiong mt phn ng, s bin thin gia hng s tc v nhit c cho bng sau:
k (N
1
s
1
) 2.61u
S
S.S1u
S
S.91u
S
4.S1u
S
Nhit (
o
C) 2u 2S Su SS
T cc thng tin tin, tinh u

tng nhit theo 2 cch khc nhau:
a) Tinh tic tip t hng s tc ua vo phng tiinh Eyiing.
b) Tinh B

v S

t bng s liu tin, ii ua vo phng tiinh u

= B

TS

tinh u

.
2) Phn ng gia N2B4 v Tl
S+
tiong BCl04 co phng tiinh ng hc nh sau:
-
J|Il
3+
]
Jt
= k
obs
|Il
3+
]|N
2
E
5
+
]
|E
+
]

a) vi gi thit tt c cc nng khc u ln hn it nhiu so vi Tl
S+
, vit phng tiinh
bin thin gia nng |Tl
S+
j v thi gian.
b) Cho bit thnh phn nguyn t ca ting thi chuyn tip ca giai on quyt nh tc .
c) ngh mt c ch phn ng ph hp vi phng tiinh ng hc tin.

Bi 4:
Quy tiinh xc nh lng canxi tiong mu nh sau:
Bc 1: Thm mt vi git ch th metyl vo uung uch mu c axit hoa v sau o l
tin vi uung uch Na2C204.
Bc 2: Thm uie (NB2)2C0 v un si uung uch n khi ch th chuyn sang mu vng
(vic ny mt 1S pht). Kt ta CaC204 xut hin.
Bc S: Bung uch nong c lc v kt ta CaC204 c ia bng nc lnh loi b
lng u ion C204
2
.
Bc 4: Cht in khng tan CaC204 c ho tan vo uung uch B2S04 u,1N sinh ia ion
Ca
2+
v B2C204. Bung uch B2C204 c chun vi uung uch chun KNn04 n khi uung uch co
mu hng thi ngng.
Cc phn ng xy ia v cc hng s cn bng:
CaC204(s) Ca
2+
(aq) + C204
2
(aq) T = 1,Su.1u
8

Ca(0B)2(s) Ca
2+
(aq) + 20B

(aq) T = 6,Su.1u
6

B2C204(aq) BC204

(aq) + B
+
(aq) Ka1 = S,6u.1u
2

BC204

(aq) C204
2
(aq) + B
+
(aq) Ka2 = S,42.1u
S

B20 B
+
(aq) + 0B

(aq) Kw = 1,uu.1u
14

1. vit v cn bng cc phng tiinh phn ng xy ia bc 2.
2. 2S,uumL uung uch mu canxi c xc nh bng phng php tin thy tn ht 27,41mL
uung uch KNn04 2,Su.1u
S
N bc cui cng. Xc nh nng Ca
2+
tiong mu.
S. Tinh T ca CaC204 tiong mt uung uch m co pB = 4.
Tiong php phn tich tin thi ta b qua mt nguyn nhn quan ting gy nn sai s. Cc
phn ng sau khin s kt ta CaC204 bc 1 s khng hon ton nu thm mt lng u C204
2
:
Ca
2+
(aq) + C204
2
(aq) CaC204(aq) Kf1 = 1,u.1u
S

CaC204(aq) + C204
2
(aq) Ca(C204)2
2
(aq) Kf2 = 1u
4. Tinh nng cn bng ca Ca
2+
v C204
2
tiong uung uch sau khi to thnh lng kt ta
ti a ca CaC204.
S. Tinh nng ion B
+
v Ca
2+
tiong uung uch bo ho CaC204.

Bi 5:
Bi s co mt ca xc tc ng thi amoniac phn ng vi flo to ia mui amoni v mt
phn t A co ung thp (goc lin kt 1u2
o
, momen lng cc u,78.1u
Su
C.m (Amoniac co goc lin
kt 1u7
o
v momen lng cc 4,74.1u
Su
C.m)
1. vit phn ng xy ia
2. Khi pioton hoa A thi nhit sinh ia nhiu hn hay it hn so vi pioton hoa NBS. uii thich
S. A phn ng vi Bg nong chy sinh ia hai ng phn B v C (N = 66). v cng thc cu tic
ca hai ng phn ny v vit phn ng xy ia.
4. B phn ng vi SnF4 thu c hp cht ion X c to thnh t cation B v anion n nhn
E co in tich 2. Bp cht ion ny khi un nong s b phn hy cho ia hp cht Y gm
cation B v anion n nhn F co in tich 1. Xc nh B, E, F v vit phn ng xy ia.
S. A phn ng vi hn hp F2 v BFS thu c mt hp cht ion Z. Thy phn hp cht ny
thu c BF, 02 v B202. vit phn ng v gii thich ng lc ca qu tiinh thy phn.

P N V C

Bi 1:
1. Bo co s thay i s nguyn t tiong mt mng nn th tich phi c xt tin mt n
v khi lng hay nguyn t.
vbcc = a
S
2 = u,u12S8 nm
S
nguyn t
vfcc = a
S
4 = u,u1196 nm
S
nguyn t
vy % 100% 4, 94%
fcc bcc
bcc
V V
V
V

= =
2.
a) vch ng vi bc song ca photon pht ia khi election ca nguyn t hyuio chuyn t n
= S v n = 2.
2 2
3 2
34 8
3 2
6, 626.10 .2, 998.10 1 1
4 9
H H
Z Z hc
E E E R R
R

| | | |
A = = = +
| |
\ . \ .
| |
=
|
\ .

vi = 6S62,8.1u
1u
m tinh c R = 2,179.1u
1u

b) Nng lng ion hoa
B(n = 1)(k) B
+
(k) + e(k) I1
ve = u ms vB+(k) = u ms
I1 = EB+(k) + E2 EB(n=1) =
10
2
1
0 0 2,179.10 R
n

| |
+ =
|
\ .
} nguyn t B
c) B(n=x)
photon
B
+
(k) + e(k)
Theo bo ton nng lng thi Ephoton = E(B
+
(k)) + Eelection E(B(n=x))
Tc
2
1
W 2
e
hc
R x
x
| |
= =
|
\ .

vy ban u B ting thi n = 2.
S.
a) Phc Cu
2+
bn hn phc Zn
2+
. L uo phc ca ng chu nh hng ca hiu ng }ahn
Tellei lm cho lin kt tic ca phc bt uin ui hn lin kt xich o, un n s tng
tc gia cc liganu tiong phc bt uin ca Cu
2+
c gim thiu. y chinh l c s ca
uy bn Iiving William,
b) S to thnh phc co phi t a cng c thun li v mt entiopy, uo o phc co liganu
nhiu cng bn hn phc co liganu it cng. vi th |Ru(bipy)Sj
S+
bn hn |Ru(py)6j
S+
.
c) Cu
+
l tm axit mm, nn thich hp to lin kt vi liganu l baz mm. Lu hunh co tinh
baz mm hn nit.

Bi 2:
1. Co phn ng
N2 + SB2 2NBS
Ban u 1 mol S mol
Cn bng 1 x S Sx 2x
vi Pi = xi.Po (Po: p sut h lc cn bng)
3 3 3
2 2 2 2 2 2
2 2 2
2
3 3 2 3 2
1
. . .n
NH NH NH
o
p
N H N H o N H o
P x n
n
K
P P x x P n P
= = = (no l tng s mol khi lc cn bng)
T y ta co:
2 2
3 2
2 2
4
2
4 (4 2 )
(1 )(3 3 )
4 (4 2 )
.
9(1 )
2 (4 2 )
.
3 (1 )
P
o
P o
P o
x x
K
x x P
x x
K P
x
x x
K P
x


vi Po = Suu atm x = u,S614 (mol), tc phn tim chuyn hoa l S6,14%
vi Po = 1uuu atm x = u,49S9 (mol), tc phn tim chuyn hoa l 49,S9%
Kt qu thu c hon ton ph hp vi nguyn l Le Chaiteliei.
2. B20(l) B20(k) Kp = Pnc = 1 atm
Nh vy nc si 1uu
o
C thi p sut ca hi nc phi l 1 atm.
2S
o
C ta co: B20(l) B20(k) Kp = Pnc = .
25
100
1 1
ln
298,15 373,15
P H
P R
| | A | |
=
|
|
\ .
\ .
P2S = u,uS69 atm
Ngha l qu tiinh chuyn pha xy ia c 2S
o
C thi p sut khi quyn (h) phi bng
u,uS69 atm.
ui cnh binh lp phng l a (um). Nh vy tt c nc bc hi thi s mol hi nc
phi tng ng vi s mol nc ban u. Tc l
3
3
3, 785.10 0, 998
0, 0369 0, 082 298,15
18, 02
PV nRT a

= =
a = S1,78 um

Bi 3:
1. a) Bin i phng tiinh Eyiing thnh ung:
0
=
= -RIln _
kb
k
B
I
]
T o ta co bng sau:
k (M
1
s
1
) T (K) 6
=

(kcal/mol)
2.61u
S
29S 2u.6
S.S1u
S
298 2u.8
S.91u
S
SuS 21.1
4.S1u
S
Su8 21.4
b) Th u

= B

TS

vo phng tiinh Eyiing:
k =
k
B
I
b
cxp _
-E
=
+ IS
=
RI
_
Ly log hai v, ta co:
ln
k
I
= -
E
=
RI
+
S
=
R
+ ln
k
B
b

Bo o ln(kT) quan h tuyn tinh vi 1T, nn ta co th sau:

B s goc chinh l B

R = 26SS, suy ia B

= S.2S kcalmol.
uiao im vi tic tung l S

R + ln(kBh) = 2.S9, uo o S

= u.uS18 kcalmol.
Ta co bng sau:
T (K) 6
=
= H
=
- TS
=

(kcal/mol)
29S 2u.4
298 2u.6
SuS 2u.9
Su8 21.2

2. a) Nu xem cc nng khc ln hn it nhiu so vi |Tl
S+
j, ta co th coi quy lut ng hc
ti thnh gi bc nht (pseuuofiist oiuei) i vi Tl
S+
. Bo o phng tiinh ng hc ti
thnh:
-
J|Il
3+
]
Jt
= k
obs
|Il
3+
]
Nn phng tiinh ng hc tich phn, hay mi quan h gia |Tl
S+
j vi thi gian l:
|Il
3+
] = |Il
3+
]
0
cxp(-k
obs
t)
b) Thnh phn nguyn t ca ting thi chuyn tip bng tng nguyn t phn t s ti
i tng nguyn t phn mu s tiong phng tiinh ng hc vi phn. Bo o thnh phn nguyn
t ca ting thi chuyn tip l: |TlN2B4j

.
c) vi thnh phn nguyn t ca ting thi chuyn tip l |TlN2B4j

, bc tc nh phi l s
tng tc gia Tl
S+
v N2B4. Tiong mi ting aciu mnh, phn ln N2B4 b pioton hoa thnh
11.7
11.6
11.5
11.4
11.3
11.2
11.1
0.0032 0.00325 0.0033 0.00335 0.0034 0.00345
l
n
(
k
/
T
)
1/T
N2BS
+
. Bo o c ch s bao gm s uepioton hoa N2BS
+
ti to N2B4, ii N2B4 tc ung vi Tl
S+

theo t l 1:1 tiong giai on quyt nh tc .
Cn nh ing nu N2B4 b oxi hoa hon ton thnh N2, t l phn ng gia Tl
S+
v N2B4
khng con l 1:1 na, uo o s oxi hoa N2B4 thnh N2 (sn phm cui cng) khng hon ton nm
tiong bc quyt nh tc . C ch c ngh nh sau:
(1)N
2
E
5
+
N
2
E
4
+ E
+

(2)N
2
E
4
+ Il
3+
Il
+
+ N
2
E
2
+ 2E
+

(S)Il
3+
+ N
2
E
2
Il
+
+ N
2
+ 2E
+

Tiong o bc (2) l bc chm.

Bi 4:
1. (NB2)2C0 + B20
2 3
2 CO NH +
A

2. |Ca
2+
j = 6,8S.1u
S
N
S. |Ca
2+
j = |C204
2
j + |BC204

j + |B2C204j
= |C204
2
j(1 + |B
+
jK1 + |B
+
j
2
K1K2)
vy |C204
2
j = |Ca
2+
j(1 + |B
+
jK1 + |B
+
j
2
K1K2) (*)
Thay (*) vo biu thc tich s tan: T = |Ca
2+
j|C204
2
j ta tinh c |C204
2
j = 1,92.1u
4
N
4. Ta co:
( )
2
2
2 4( ) 2 4
2
2
1 1 2 2 4
2
2 4
1 2 2 2
2
2 4
2 4
1
1
0
Ca aq
f f f
Ca
f f
C Ca CaC O Ca C O
T K K K C O
C O
dC
T TK K
d C O
C O


(
( ( = + +


| |
| ( = + +

|
(
\ .
= + =
(
(



|C204
2
j = 1,u.1u
2
N |Ca
2+
j = 1,S.1u
6
N
S. Cn bng in tich: 2|Ca
2+
j + |B
+
j = 2|C204
2
j + |BC204

j + |0B

j (1)
Cn bng khi lng: |Ca
2+
j = |C204
2
j + |BC204

j + |B2C204j (2)
vi Kb2 it nh nn nng ca B2C204 co th b qua.
Kt hp (1) v (2) ta co: |BC204

j = Kw|B
+
j |B
+
j (S)
|C204
2
j = (K2Kw)|B
+
j
2
K2 (4)
|Ca
2+
j = T|C204
2
j = T|B
+
j
2
(K2Kw K2|B
+
j
2
) (S)
Thay (S), (4), (S) vo (2) v gii phng tiinh sinh ia ta c: |B
+
j = S,S.1u
8
N
|Ca
2+
j = 1,u4.1u
4
N

Bi 5:
1. A l NFS. Phn ng xy ia nh sau: 4NBS + SF2 = SNB4F + NFS
2. Bo tiong NFS cp election ca N b gi cht hn nn s pioton hoa kho khn hn so vi
NBS, co ngha l nhit phn ng pioton hoa NFS nh hn.
S. 2NFS + 2Bg = N2F2 + BgF2
Cu tic hai ng phn ca N2F2

4. 2N2F2 SnF4 |N2F

j2|SnF6j
2


|N2F

j2|SnF6j
2

|N2Fj

|SnFSj

N2F2
Cu tic cc ion:
B E F
S. NFS F2 BFS NF4

BF4


Khi thy phn cation NF4
+
co s to thnh B0F v NFS
NF4
+
+ B20 = NFS + B0F + B
+

B0F l cht oxy hoa it mnh v km bn, co th phn hy to BF v 02
2B0F = 2BF + 02
Bay oxy hoa nc to B202 v BF
B0F + B20 = BF + B202


Bi 1:
1. Bp cht X c s ung iu ch thuc th phenolphthalein co CTPT l C8B40S. Thy
phn hon ton X thu c hp cht Y l mt uiaxit co CTPT C8B604. Este hoa Y bng mt
lng u C2BS0B (xc tc B2S04 c) thu c Z (C12B1404) c ong l bn ui tn
thng mi l B.E.P co tc ung ti gh. Nc khc, khi cho X tc ung vi NBS thu c T
(C8BS02N). Bit ing T c s ung ing ii iu ch cc aminoaxit; X con c s
ung bo v nhom chc.
a) Xc nh cc hp cht X, Y, Z, T.
b) X thng c s ung bo v nhom chc no. Cho vi u.
c) iu ch axit glutamic t T, bit cc hp cht v c, hu c cn thit u co .
2. Cho cc hp cht sau: B0CB2CB00B (A); BiCB2CB00B (B); CBSC00B (C);
CBSNBCB2CB00B (B); NB2CB2CB00B (E). By so snh kh nng phn ly pioton B
+
ca
nhom C00B tiong cc ting hp sau theo th t gim un kh nng phn ly.
a) Tiong uung mi nc.
b) Tiong uung uch m co pB = S.
3. Sp xp theo th t tng un tinh baz ca cc hp cht sau v gii thich ngn gn.






FORUMOLYMPIAVN
BOXHAHC

KTHICHNHCSINHGIIQUCGIANM2014
THILUYNTPS1
MN:Hahc
PHN:Hahchuc
Thigianlmbi:180pht
Bi 2:
1. a) ngh c ch ca phn ng sau y. Yu cu xc nh i in tich hinh thc, chuyn
i cn bng cu tic, cc giai on to thnh v ct t lin kt tiong c ch.

b) Ba vo phn ng chuyn v ny, ngi ta thit k mt chu tiinh tng hp chuyn hoa
cht 1 thnh Litebamine.

ngh mt s chuyn hoa hp l. c s ung cc cht v c v hu c cn thit.
2. uii thich kt qu phn ng sau bng c ch phn ng.

Bi 3:
1. Cho bit sn phm ca cc phn ng sau, ch lp th:

2. T LPiolin v cc tc nhn cn thit, hy ngh mt s tng hp ()coniceine tiong o
co giai on s ung phn ng ong vong metathesis:
N
H
COOH
N
H
(-)-coniceine

Bi 4:
Bon thnh uy chuyn hoa sau. Ch i nh hng cc nhom th tiong vong xiclohexan.
O
O
O
Ph
H
3
CO
OCH
3
CH
3
H
2
, Pd - C
A
TrCl
Py
B
1. PCC
2. MeLi , - 78
o
C
3. CH
3
I / NaH
C
1. H
2
, Pd - C
2. PCC
D
1. MeMgI
2. PCC
E
1. NaOH / MeOH
2. H
2
/ Pd - C
C
9
H
18
O
5
C
10
H
18
O
5
F (C
11
H
20
O
4
)


Bi 5:
1. Phn tich mt oligopeptit thu c mt s kt qu sau
Thy phn hon ton thu c Asp, Asn, ulu2 , uly , Lys,
Net2 , Phe, Pio2
X l peptit vi BiCN thu c ba oligopeptit vi u N ln
lt l ulu, Pio v Asp.
Ct mch bng tiypsin cho hai mnh u co u N l ulu.
Kt qu ct mch bng enzym cacboxipeptiuaza nh hinh bn. Con kt qu xc nh u N
bng phng php Sangei thu c un xut ulu.
Ct mch bng chymotiypsin cng thu c hai mnh vi u N l ulu v Lys.
Xc nh th t sp xp cc aminoaxit tiong peptit ny.
2. vic loi nhom bo v ankoxycacbonyl tiong tng hp peptit thng kem theo phn ng
ct mch ui tc ung ca cc axit theo s :
OCONH R peptit
[H
+
]
[R
+
] + CO
2
+ H
2
N peptit

Xp kh nng tng un tinh hot ng ca cc cacbamat sau y ui tc ung ca axit:



P N HU C

Bi 1:
1. a) B.E.P l tn vit tt ca Bietyl Phtalat vn l mt uieste ca axit phtalic. T o co th u
ung suy ia cu tic cc cht nh sau:

b) X thng c ung bo v nhom chc amin

c) y l phng php uabiiel thng c s ung tng hp cc aminoaxit t un xut
halogen

2. Bo tiong nc hiu ng cm ng chim u th nn tinh axit s c xp theo th t: (A) >
(E) > (B) > (B) > (C). Con mi ting pB = S (mi ting axit) thi nhom amin s b pioton
hoa thnh NB
+
khin th t sp xp co thay i nn th t s l: (E) > (B) > (A) > (B) > (C)
S. Cht D l mt amin no bc hai nn s co tinh baz cao nht so vi cc amin thm con li.
Cc cht A, C, E uo co mt nhom it nn tinh baz s thp hn so vi B v F. Tiong o B co
tinh baz cao hn F uo co mt nhom CBS lm tng tinh baz.
E co tinh baz cao hn hai cht A, C uo s nhom it it hn.
A co tinh baz cao hn C uo nhom N02 paia ch gy hiu ng I (uo tng tc y gia cc
nhom nitio khin nhom nitio paia b lch phng nn khng th gy C). Tii li nhom CN
paia gy C uo khng co tng tc y vi hai nhom nitio bn cnh (nhom CN nh hng
thng). Bo C lun mnh hn I nn cht C phi co tinh baz thp hn.
Nh vy th t tinh baz s nh sau: (D) > (B) > (F) > (E) > (A) > (C)

Bi 2:
1. a)

b)

2. Phn ng xy ia theo c ch E1cB uo ion enolat sinh ia t c photpho tiung gian th hin
tinh baz thay vi nucleophin. L uo co th cho ing tiung gian sinh ia cng knh s kho
tng tc vi nhom CB0 anuehit vn u b chn bi nhom 0TBS khin khng th to
thnh sn phm nh mun. C ch c th ca phn ng nh sau:


Bi 3:
1. Cc sn phm phn ng

Bng tn cng phia tic b cn ti bi nhom benzyl.

Bng tn cng phia tin b cn ti bi methyl.


Tn cng axial, uo ch co caibanion sinh ia khi tch B axial mi co th to c s xen ph
bn vi nhom C=0 nh hinh v:

2. Quy tiinh tng hp ngh nh sau:
N
H
COOH
O
Cl
CH
2
Cl
2
, Imidazole
DMAP
N
COOH
Boc
BH
3
THF
N
CH
2
OH
Boc
TsCl
CH
2
Cl
2
, Et
3
N
N
CH
2
OTs
Boc
Li TMS THF
N
H
TMS
K
2
CO
3
MeOH
N
H
H
2
Lindlar's
catalyst
N
H
Br
N
Grubb's catalyst
N
H
2
Pd/C
N
(-)-coniceine


Bi 4:




bc phn ng chuyn hoa E thnh F bc u tin l s tch E1cB nhom 0CBS
equatoiial, sn phm xiclohexen sinh ia s cng syn thu c cht F nh hinh v:

Bng tn cng ca phn ng cng B2 s tinh nhom 0CBS equatorial gn vi C4 un n


nguyn t B CS nm v tii axial, uo phn ng l cng syn nn nguyn t B ca C6 phi l
equatorial un n sn phm F.

Bi 5:
1. T kt qu ct mch bng enzym cacboxipeptiuaza cho thy on cui mch co th t Asn
Net Asp uly C00B.
Aminoaxit u N l ulu.
BiCN ct sau Net, tiypsin ct sau cc aminoaxit co tinh baz, y tiypsin ct sau Lys v
Chymotiypsin ct sau cc aminoaxit co tinh ky nc ( y chymotiypsin ct sau Phe) nn t
nhng kt qu tin co th suy ia tit t sp xp cc aminoaxit tiong peptit l: ulu Net Pio
Pio Phe Lys ulu Asn Net Asp uly.
2. Nu cho ing ting thi chuyn tip i qua tiung gian caibocation thi cht no to thnh
caibocation u ung nht thi kh nng phn ng tng ln tng ng. Tiong cht B thi co s
gii to election mnh nht:

uii thich tng t ta thy caibocation to thnh t B bn hn C, con A s km bn nht.
Nh vy th t s l: B > B > C > A.
Vn c th c mt s p n khc ph hp vi bi. Nhng trng hp nh vy vn
c chp nhn.

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