Dr. Sangeeta Khanna Ph.

D CHEMISTRY COACHING
CIRCLE
1
1
S:\Mumma\documents\AIEEE_1.doc
TEST 2 (AIEEE)
INSTRUCTIONS:

1. This test consist of 50 questions.

2. The test duration is of 90 minutes.

3. Use blue or black ball-point pen to complete darken the appropriate circle.

4. Fill your particulars correctly and completely on the OMR ANSWER SHEET.

5. Each right answer carries 3 marks and for every wrong answer 1 mark will be deducted.


1. Acetanilide on nitration produces a mixture of o-
nitroacetanilide (minor product) and p-
nitroacetanilide (major product). The constituents
of the product mixture are usually separated by

a. sublimation
b. fractional crystallization
c. fractional distillation
d. steam distillation

2. In Lassaignes test, which of the following
organic compounds would produce a blood-red
colour when its sodium extract is treated with
FeCl
3
solution?

a.


b.


c.


d.


3. The sodium extract of an organic compound on
boiling with HNO
3
and on subsequent treatment
with ammonium molybdate solution gives a
yellow precipitate. Which of the following
elements may be present in the compound?

a. Nitrogen b. Sulphur
c. Phosphorus d. Halogen

4. Which of the following molecules is not stabilized
by resonance?


a. b.

c. CH
2
= CHCH = CH
2
d. CH
2
= CHCHO

5. Give the correct order of decreasing acidity.

a. C
2
H
5
SH > C
2
H
5
OH > C
2
H
5
NH
2
> CH
3
CH
2
CH
3

b. C
2
H
5
OH > C
2
H
5
SH > C
2
H
5
NH
2
> CH
3
CH
2
CH
3

c. C
2
H
5
OH > C
2
H
5
NH
2
> CH
3
CH
2
CH
3
> C
2
H
5
SH
d. C
2
H
5
NH
2
> C
2
H
5
SH > C
2
H
5
OH > CH
3
CH
2
CH
3



6. A solution containing 2g of anhydrous BaCl
2
in
4000 c.c. of water has a specific conductivity
0.0058 ohm
1
. The molar conductivity of this
solution is about: [M. Wt. of BaCl
2
= 208]

a. 0.1 ohm
1
c.c. b. 2.41 ohm
-1
c.c.
c. 2410 ohm
1
c.c. d. 241 ohm
1
c.c.

7. Which of the following pairs of structures do not
represent tautomers?


a. and






b. and






c. and





d. and


8. Which of the following conformation of 1, 2-
ethanediol is not able to form intramolecular
hydrogen bond?



a. b.





c. d.

NH
2

SO
3
H
CO
2
H H
2
N
H
2
N SO
3
H
OH
CHO
O
CHOH
O
CHO
OH
C
N
O
H
O



O

C
O
C
O
OH H
N
OH
H
H

H

OH
H

H

OH
H

HO
OH
H

H

H

H

H

OH
H

H

OH
H

H

OH
H

H

HO
M.MARKS: 150

Dr. Sangeeta Khanna Ph.D
Dr. Sangeeta Khanna Ph.D CHEMISTRY COACHING
CIRCLE
2
S:\Mumma\documents\AIEEE_1.doc



9. Arrange the following compounds in the order of
increasing rate of reaction with HCl


I. II. CH
3
CH = CH
2




III. IV. CH
2
= CH
2



a. IV < II < I <III b. III < IV < II < I
c. III < I < II < IV d. I < II < III < IV

10. Which of the following is correct Match of list I
and List II


List I
(Test)
List II
(For which compound
it is performed)
I. Molish test (i) Protein
II. Biuret Test (ii) Carbohydrates
III
.
Acrolein
test
(iii) Nucleic acid
IV
.
Ninhydrin
Test
(iv) Fats

I II III IV
a. ii (iii) (iv) (i)
b. ii (i) (iv) (i)
c. iii (ii) (i) (iv)
d. (ii) (iii) (i) (iv)

11. CH
2
= CH
2
*
H C Br
KOH . aq
P; P is:
a. CH
2
= CH
2
*
H C OH
b. HO CH
2
CH =
2
*
H C
c. Both (a) and (b)
d. None

12. Coupling of diazonium salts with the following,
takes place in order:





(I) (II) (III) (IV)

a. IV < II < III < I b. IV < III < II < I
c. II < IV < I < III d. I < II < III < IV

13. Which of the following electron transition in a
hydrogen atom will require the largest amount of
energy?

a. From n = 1 to n = 2 b. From n = 2 to n = 3
c. From n = to n = 1 d. From n = 3 to n = 5


14. What is the wavelength of series limit for Lymen
series for hydrogen:

a.
H
R 3
4
= b.
H
R
1
=
c.
H
R
36
5
= d.
H
R =

15. The least polarized anion is:-

a.
2
4
SO b.
2
4 2
O C c.

3
NO d.

4
ClO

16. Which of the following has maximum dipole
moment?

a. NCl
3
b. NF
3
c. NH
3
d. NI
3


17. Consider the following statements:

1. Cs
+
is more highly hydrated than the other
alkali metal ions.
2. Among the alkali metals Li, Na, K and Rb,
lithium has the highest melting point.
3. Among the alkali metals only lithium forms a
stable nitride by direct combination.
Of these statements:

a. 1,2 and 3 are correct
b. 1 and 2 are correct
c. 1 and 3 are correct
d. 2 and 3 are correct

18. Which of the following exhibit trigonal
bipyramidal geometry?

1. BrOF
4

2. CH
2
= SF
4

3. SOF
4
4. XeO
4

5. XeF
5
+


a. 1,2, 5 b. 1, 2, 3
c. 2, 3, 5 d. 2, 3, 4

19. What will be the orange coloured compound
formed when a mixture of K
2
Cr
2
O
7
and NaCl is
heated with conc. H
2
SO
4
?

a. CrO
2
Cl
2
b. CrOCl
2

c. Na
2
SO
4
d. CrO
2
Cl

20. Which reaction involves a change in the
electron-pair geometry for the underlined atom?

a. BF
3
+ F

BF
4

b. NH
3
+ H
+
NH
4
+

c. 2SO
2
+ O
2
2SO
3
d. H
2
O + H
+
H
3
O
+


21. The approximate pH of a solution formed by
mixing equal volumes of solution of 0.1 M
sodium propanoate and 0.1 M propanoic acid
CH = CH
2

CH
3
O
O

OH

NH
3


NH
2

CH = CH
2

H
3
C

Dr. Sangeeta Khanna Ph.D
Dr. Sangeeta Khanna Ph.D CHEMISTRY COACHING
CIRCLE
3
S:\Mumma\documents\AIEEE_1.doc
(Ka for propanoic acid = 1.3 x 10
5
mol dm
-3
) will
be:

a. 1.52 b. 3.62
c. 4.89 d. 5.52

22. Match the following:

List I List II
A. AG 1. AE + PAV
B. AG
0
2. nFE
0

C. AS 3.
RT ln
2
1
V
V

D. AH 4.
nR ln
1
2
V
V


Codes:
(A) (B) (C) (D)
a. 2 4 1 3
b. 3 2 4 1
c. 3 1 4 2
d. 2 3 4 1

23. Calculate AG for the reaction below and tell
whether it is spontaneous or nonspontaneous
under standard conditions at 25C.
2S(s) + 3O
2
(g) + 2H
2
O() 2H
2
SO
4
()
AH = -1056 kJ/mol AS = -505 J/mol

a. AG = -1207 kJ and the process is
spontaneous.
b. AG = -1207 kJ and the process is
nonspontaneous.
c. AG = -906 kJ and the process is
spontaneous.
d. AG = -906 kJ and the process is
nonspontaneous.

24. Standard electrode potential data are useful for
understanding the solubility of an oxidant in a
redox titration. Some half cell reactions and their
standard potential are given below:

) aq ( Mn e 5 ) aq ( H 8 ) aq ( MnO
2
4
+ +
+ +
+ 4H
2
O (l) ; E
0
= 1.51 V
) aq ( Cr 2 e H 14 ) aq ( O Cr
3 2
7 2
+ +
+ +
+ 7H
2
O (l); E
0
= 1.38 V
Fe
3+
(aq) + e

Fe
2+
(aq); E
0
= 0.77 V
Cl
2
(g) + 2e

2Cl

(aq); E
0
= 1.40 V

Identify the only incorrect statement regarding
the quantitative estimation of aqueous Fe(NO
3
)
2
:

a. MnO
4

can be used in aqueous HCl

b. Cr
2
O
7
2
can be used in aqueous HCl
c. MnO
4

can be used in aqueous H

2
SO
4

d. Cr
2
O
7
2
can be used in aqueous H
2
SO
4


25. B A CH CH
Ozonolysis
essure Pr
2
) CN ( Ni

A and B are respectively:

a. Benzene, Glyoxal
b. Mesitylene, Methylglyoxal
c. Cyclohexene, Hexanedial
d. Cycloctateraene, Glyoxal


26. MnO
4
2
(1 mole) in neutral aqueous medium is
disproportionate to:

a. 2/3 mole of MnO
4

and 1/3 mole of MnO

2

b. 1/3 mole of MnO
4

and 2/3 mole of MnO

2

c. 1/3 mole of Mn
2
O
7
and 1/3 mole of MnO
2

d. 2/3 mole of Mn
2
O
7
and 1/3 mole of MnO
2


27. For the reaction A + B C+D. The variation of
the concentration of the products with time is
given by the curve:

a. X
b. Y
c. Z
d. W



28. XeF
6
is conducting in HF due to the formation of:

a. XeF
5
and HF
2
+
b. XeF
5
1
and F
+

c. XeF
5
+
and HF
2

d. None of these

29. An aqueous solution of NaCl freezes at
0.186
0
C. Given that 512 . 0 K
O
2
H
b
= K kg mol
-1
and 86 . 1 K
O
2
H
f
= K kg mol
-1
, the elevation in
boiling point of this solution is:

a. 0.0585 K b. 0.0512 K
c. 1. 864 K d. 0.0265 K

30. The number of P O P bridges in the structure
of phosphorus pentoxide and phosphorus
trioxide are respectively:

a. 6, 6 b. 5, 5 c. 5, 6 d. 6, 5

31. C
2
H
6
(g) + 3.5 O
2
(g) 2CO
2
(g) + 3H
2
O (g)

AS
vap
(H
2
O,l)= x
1
cal K
-1
(b.p.T
1
)
A H
f
(H
2
O, I) = x
2

A H
f
(CO
2
) = x
3

A H
f
(C
2
H
6
) x
4


Hence AH of the above reaction is:

a. 2x
3
+ 3x
2
x
4
b. 2x
3
+ 3x
2
x
4
+ 3x
1
T
1

c. 2x
3
+ 3x
2
x
4
3x
1
T
1
d. x
1
T
1
+ x
2
+ x
3
x
4


Y
Z
W
X
Time

Dr. Sangeeta Khanna Ph.D
Dr. Sangeeta Khanna Ph.D CHEMISTRY COACHING
CIRCLE
4
S:\Mumma\documents\AIEEE_1.doc
32. Which of the following benzene ring is more
reactive towards electrophile:




a. A b. B c. C d. Both a & c

33. Which of the following statements is incorrect?

a. Activation energy for the forward reaction
equals activation energy for the backward
reaction
b. For a reversible reaction, an increase in
temperature increases the reaction rate for
both the forward and the backward reaction
c. The larger the initial reactant concentration,
for a second order reaction, shorter its half
life
d. When At is infinitesimally small, the
average rate equals the instantaneous rate

34. Plot of log t
0.5
vs log a is a straight line. What
conclusions can be drawn from the plot:



log t
0.5


Log a

a. n = 1 , t
0.5
=
ka
1
b. n = 2 , t
0.5
=
a
1

c. n = 1 , t
0.5
=
k
693 . 0
d. None of above

35. If a mixture of weak and strong acid is titrated
with NaOH, variation of conductance (y-axis)
with addition of NaOH (x-axis) will be:


a. b.


c. d.



36. According to the adsorption theory of catalysis,
the speed of the reaction increases because:

a. adsorption produces heat which increases
the speed of the reaction
b. adsorption lowers the activation energy of
the reaction
c. the concentration of reactant molecules at
the active centres of the catalyst becomes
high due to adsorption
d. in the process of adsorption, the activation
energy of the molecules becomes large

37. A solution containing 1 mole per litre each of
AX, BX
2
, CX
2
and DX
2
is electrolysed using
inner electrodes. The value of standard potential
for reducing reaction of A
+
/A, B
2+
/B, C
2+
/C and
D
2+
/D are 0.8,+ 0.34, -0.76 and 1.66 volts
respectively. The correct sequence in which
these metals will be deposited on cathode is:

a. A, B, C, D b. D , C, B, A
c. A, C, B, D d. D, B, C, A

38. The correct arrangement of KHSO
3
, Na
2
SO
4
,
(NH
4
)
2
S
2
and S
8
in increasing order of oxidation
state of S in them is:

a. KHSO
3
< Na
2
SO
4
< (NH
4
)
2
S
2
<S
8

b. S
8
< (NH
4
)
2
S
2
< KHSO
3
< Na
2
SO
4

c. (NH
4
)
2
S
2
< S
8
< KHSO
3
< Na
2
SO
4

d. Na
2
SO
4
< KHSO
3
< (NH
4
)
2
S
2
< S
8


39. For the reaction:




Bond energies are given as under:

(i) C C , 346 KJ/ mol
(ii) C H , 413 KJ/ mol
(iii) H H , 437 KJ/mol and
(iv) C = C , 611 KJ/mol
What will be the value of AH 25
0
C for the above
reaction:

a. 289 KJ mol
-1
b. 124 KJ mol
-1

c. +124 KJ mol
-1
d. +289 KJ mol
-1


40. The structure of an o - amino acid, H
COOH
C H N
R
|
|
3

+

Will exist at pH:

a. 0 b. 7 c. 12 d. 14

41.

duction Re
O
2
H
3
O
) A (
14 7
) B ( H C


3 2
|
3
|
3
CH CH H
OH
C H
CH
C CH
A and B in the above reaction are:

a.






b.
.
H
H
+ H H
H
H
H
H
CH
3
CH
2
CH
HC CH
CH
3

CH
3

(A)
CH
3

CH
3

C = O
(B)
CH
3
CH
2
C = CH
2

CH
CH
3

CH
3

(A)
CH
3
CH
2
C
CH
CH
3

CH
3

O
(B)
A
B C

Dr. Sangeeta Khanna Ph.D
Dr. Sangeeta Khanna Ph.D CHEMISTRY COACHING
CIRCLE
5
S:\Mumma\documents\AIEEE_1.doc





c.


d. None of these



42.




The IUPAC name of this compound is

a. 2, 2, 6-trimethyl-4-(1-methylpropyl) nonane
b. 4, 8, 8-trimethyl-6-(1-methylpropyl) nonane
c. 3,6-dimethyl-4-(methylene tertiarybutyl)nonane
d. 6,6-dimethyl-2-propyl-4-(1-methylpropyl) heptane

43. A square planar complex represented will show:






a. Geometical isomers b. Optical isomerism
c. Linage isomerism d. No isomerism

44. Match list I (Hybrid bond orbitals) with list II
(species ) and select the correct answer:
List I List II
A. sp
3
1. ICl
4


B. dsp
2
2. TeCl
4

C. sp
3
d 3. MnO
4

D. sp
3
d
2
4. Ni(CN)
4
2-


A B C D
a. 4 3 1 2
b. 4 3 2 1
c. 3 4 1 2
d. 3 4 2 1

45. The two molecules are indicated below are
capable of intramolecular bonding. Which in the
likely to form more stable hydrogen bonds:









a. I b. II c. equal
d. No intramolecular hydrogen bonding

46. The atomic number of potassium is 19 and that
of manganese is 25. Although the colour of
MnO
4

is dark violet, yet the K

+
is colourless.
This is due to the fact that:

a. Mn is a transition element ; while K
+
is not
b. [MnO
4
]

is negatively charged ; while K

+
has
a positive charge
c. the effective atomic number of Mn in [MnO
4
]
-

is 26; while for K
+
, the atomic number is 18
d. The Mn in a high positive oxidation state
allows charge transfer transitions


47. In the production of Mg by the electrolytic
method it is a molten mixture of MgCl
2
, NaCl
and CaCl
2
that is electrolysed. The function of
NaCl and CaCl
2
is as follows:

a. They act as electrolysis and products of their
electrolysis reacts with MgCl
2
to yield Mg
b. The presence of these help MgCl
2
to melt at
lower temperature and there by save much
of electricity
c. they increase the density of the molten mass
d. all

48. Consider the following statements. In diborane :
1. Boron is approximately sp
3
hybridized
2. B H B angle is 180
0

3. There are two terminal B H bond for each
bond atom
4. There are only 12 bonding electrons
available
of these statements

a. 1,2 & 4 are correct b. 1,2 & 3 are correct
c. 2,3 & 4 are correct d. 1,3 & 4 are correct

49. Consider following transformations

I. XeF
6
+ NaF [Na]
+
[XeF
7
]
-

II. 2PCl
5
(s) [PCl
4
]
+
[PCl
6
]

III. [Al(H
2
O)
6
]
+3
+H
2
O Al(H
2
O)
5
OH]
+2
+H
3
O
+

Possible transformations are:

a. I b. II c. III d. All

50. End products of following sequence of reaction:





a. b.


c. d.








CH
3
CH
2
CH = C
CH
3

CH
2
CH
3

(A)
CH
3
CH
2
CH = O
(B)
CH
3
CH
2
CH
2
CH CH
2
CH CH
2
C CH
3

CH
3
CHCH
3
CH
3

CH
2
CH
3

CH
3

H
2
N
CH
2

CH
2

H
2
N
H
2
N
H
2
C
H
2
C
H
2
N
M
C
H
H
H
CH
3

H
3
C
C C
O
H
(II)
O
CH
3

H
H
O
C
C
C
H
3
C
O
(I)
Br
Alc. KOH
A
O
3
/H
2
O
B
BaO
C
O
OH
O
HOOC COOH

Dr. Sangeeta Khanna Ph.D
Dr. Sangeeta Khanna Ph.D CHEMISTRY COACHING
CIRCLE
6
S:\Mumma\documents\AIEEE_1.doc












TEST 2 (AIEEE) ANSWERS

1. B 2. D 3. C 4. A 5. A 6. C 7. D 8. C 9. A 10. B
11. C 12. A 13. A 14. B 15. D 16. C 17. D 18. C 19. A 20. A
21. C 22. B 23. C 24. A 25. D 26. A 27. B 28. C 29. B 30. A
31. B 32. B 33. A 34. C 35. C 36. B 37. A 38. C 39. B 40. A
41. B 42. A 43. D 44. D 45. A 46. D 47. B 48. D 49. D 50. C


TEST 2 (AIEEE) ANSWERS

1. B 2. D 3. C 4. A 5. A 6. C 7. D 8. C 9. A 10. B
11. C 12. A 13. A 14. B 15. D 16. C 17. D 18. C 19. A 20. A
21. C 22. B 23. C 24. A 25. D 26. A 27. B 28. C 29. B 30. A
31. B 32. B 33. A 34. C 35. C 36. B 37. A 38. C 39. B 40. A
41. B 42. A 43. D 44. D 45. A 46. D 47. B 48. D 49. D 50. C


TEST 2 (AIEEE) ANSWERS

1. B 2. D 3. C 4. A 5. A 6. C 7. D 8. C 9. A 10. B
11. C 12. A 13. A 14. B 15. D 16. C 17. D 18. C 19. A 20. A
21. C 22. B 23. C 24. A 25. D 26. A 27. B 28. C 29. B 30. A
31. B 32. B 33. A 34. C 35. C 36. B 37. A 38. C 39. B 40. A
41. B 42. A 43. D 44. D 45. A 46. D 47. B 48. D 49. D 50. C


TEST 2 (AIEEE) ANSWERS

1. B 2. D 3. C 4. A 5. A 6. C 7. D 8. C 9. A 10. B
11. C 12. A 13. A 14. B 15. D 16. C 17. D 18. C 19. A 20. A
21. C 22. B 23. C 24. A 25. D 26. A 27. B 28. C 29. B 30. A
31. B 32. B 33. A 34. C 35. C 36. B 37. A 38. C 39. B 40. A
41. B 42. A 43. D 44. D 45. A 46. D 47. B 48. D 49. D 50. C


TEST 2 (AIEEE) ANSWERS

1. B 2. D 3. C 4. A 5. A 6. C 7. D 8. C 9. A 10. B
11. C 12. A 13. A 14. B 15. D 16. C 17. D 18. C 19. A 20. A
21. C 22. B 23. C 24. A 25. D 26. A 27. B 28. C 29. B 30. A
31. B 32. B 33. A 34. C 35. C 36. B 37. A 38. C 39. B 40. A
41. B 42. A 43. D 44. D 45. A 46. D 47. B 48. D 49. D 50. C


TEST 2 (AIEEE) ANSWERS


Dr. Sangeeta Khanna Ph.D
Dr. Sangeeta Khanna Ph.D CHEMISTRY COACHING
CIRCLE
7
S:\Mumma\documents\AIEEE_1.doc
1. B 2. D 3. C 4. A 5. A 6. C 7. D 8. C 9. A 10. B
11. C 12. A 13. A 14. B 15. D 16. C 17. D 18. C 19. A 20. A
21. C 22. B 23. C 24. A 25. D 26. A 27. B 28. C 29. B 30. A
31. B 32. B 33. A 34. C 35. C 36. B 37. A 38. C 39. B 40. A
41. B 42. A 43. D 44. D 45. A 46. D 47. B 48. D 49. D 50. C