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[1]

Atomic weight
Q.1 One atomic mass unit in kilogram is
(A) 1/N
A
(B) 12 / N
A
(C) 1/1000 N
A
(D) 1000 / N
A
Q.2 The number of g-atoms of nitrogen in its 7 gm is equal to number of g-atoms in
(A) 6 gm Mg (B) 28 gm Fe (C) 30 gm Ca (D) 20 gmHg
Q.3 2 isotopes of an element are present in 1 : 2 ratio of number, having mass number M and (M +0.5)
respectively. The mean mass number of element will be
(A) 3M +1 (B) 1.5 M +0.5 (C) 0.5 M +0.5 (D) None of these
Q.4 A sample of nitrogen contains 90% N
14
and 10% N
15
isotopes. The average number of neutron
per atomis
(A) 14.10 (B) 7.05 (C) 7.10 (D) 14.20
Q.5 From2 mg calcium, 1.2 10
19
atoms are removed. The number of g-atoms of calciumleft is
(A) 5 10
5
(B) 2 10
5
(C) 3 10
5
(D) 5 10
6
Q.6 Three isotopes of an element have mass numbers M, (M+1) and (M+2). If the mean mass number is
(M +0.5), then which of the following ratio of number may be accepted for M, (M+1) and (M+2) in the
order
(A) 1 : 1 : 1 (B) 4 : 1 : 1 (C) 3 : 2 : 1 (D) 2 : 1 : 1
Molecular weight
Q.7 The number of electron in 3.1 mg NO
3
is
(A) 32 (B) 1.6 10
3
(C) 9.6 10
20
(D) 9.6 10
23
Q.8 The number of neutrons in 0.45 g water, assuming that all the hydrogen atoms are H
1
atoms and all the
oxygen atoms are O
16
atoms, is
(A) 8 (B) 0.2 (C) 1.2 10
23
(D) 4.8 10
24
Q.9 A gaseous mixture contains CO
2
(g) and N
2
O (g) in a 2 : 5 ratio by mass. The ratio of the number of
molecules of CO
2
(g) and N
2
O (g) is
(A) 5 : 2 (B) 2 : 5 (C) 1 : 2 (D) 5 : 4
Q.10 Number of oxygen atoms present in 1.61 gmof Na
2
SO
4
.10H
2
O is equal to number of atoms in
(A) 3.0 gm C
2
H
6
(B) 18.0 gm C
6
H
12
O
6
(C) 0.98 gm H
2
SO
4
(D) 8.0 gm SO
3
Q.11 Which of the following contain largest number of carbon atoms?
(A) 15 gm ethane, C
2
H
6
(B) 40.2 gm sodium oxalate, Na
2
C
2
O
4

Mole Concept
[2]
(C) 72 gm glucose, C
6
H
12
O
6
(D) 35 gm pentene, C
5
H
10
Q.12 If the mass of proton is doubled and that of neutron is halved, the molecular weight of CO
2
, consisting
only C
12
and O
16
atoms, will
(A) not change (B) increase by 25% (C) decrease by 25% (D) increase by 50%
Q.13 The shape of Tobacco Mosaic Virus (TMC) is cylindrical, having length and diameter 3000 and
170 , respectively. The density of the virus is 0.08 gm/ml. The molecular weight of TMC is
(A) 3.28 (B) 5.44 10
24
(C) 5.44 10
18
(D) 3.28 10
6
Q.14 If molecular weight of glucose-1-phosphate is 260 and its density is 1.5 g/ml. What is the average
volume occupied by 1 molecule of this compound?
(A) 43 10
23
ml (B) 0.67 ml (C) 0.17 10
23
ml (D) 29 10
23
ml
Q.15 The number of hydrogen atoms in 0.9 gmglucose, C
6
H
12
O
6
, is same as
(A) 0.048 gmhydrazine, N
2
H
4
(B) 0.17 gm ammonia, NH
3
(C) 0.30 gm ethane, C
2
H
6
(D) 0.03 gmhydrogen, H
2
Q.16 The number of g-molecules of oxygen in 6.02 10
24
CO molecules is
(A) 1 g-molecule (B) 0.5 g-molecule (C) 5 g-molecule (D) 10 g-molecule
Concept of mole
Q.17 0.36 gm of a triatomic gas, X
3
, occupies 168 ml at 1 atm & 273 K. The atomic weight of X is
(A) 48 (B) 16 (C) 24 (D) 12
Q.18 What time, it would take to spend Avogadros number of rupees at the rate of 10 lac rupees per second?
(A) 6.023 10
17
sec (B) 1.909 10
10
year
(C) 1.673 10
14
hour (D) all of these
Q.19 Ethanol, C
2
H
5
OH, is the substance commonly called alcohol. The density of liquid alcohol is 0.7893 g/
ml at 293 K. If 1.2 mole of ethanol are needed for a particular experiment, what volume of ethanol
should be measured out?
(A) 55 ml (B) 58 ml (C) 70 ml (D) 79 ml
Q.20 Which of the following will occupy greater volume under the similar conditions of pressure and tempera-
ture?
(A) 6 gmoxygen (B) 0.98 gmhydrogen
(C) 5.25 gmnitrogen (D) 1.32 gmhelium
Q.21 n mol of N
2
and 0.05 mol of Ar are enclosed in a vessel of capacity 2 L at 1 atm and 27C. Find n
(R =0.082 L atm mol K
1
)
(A) 0.30 (B) 0.10 (C) 0.03 (D) 0.06
Q.22 The volume of water at 277 K is 18 ml. One ml of water contains 20 drops. The number of molecules
in one drop of water will be
(A) 1.07 10
21
(B) 1.67 10
21
(C) 2.67 10
21
(D) 1.67 10
20
[3]
Q.23 How many mole of electron weight one kilogram?
(A)
023 . 6 108 . 9
1

10
8
(B)
108 . 9
1
10
31
(C)
108 . 9
1
10
54
(D) 6.023 10
23
Q.24 112.0 ml of NO
2
at 1atm & 273 K was liquefied, the density of the liquid being 1.15 gm/ml. Calculate
the volume of and the number of molecules in the liquid NO
2
.
(A) 0.10 ml and 3.01 10
22
(B) 0.20 ml and 3.01 10
21
(C) 0.20 ml and 6.02 10
23
(D) 0.40 ml and 6.02 10
21
Fill in the blank:
Q.25 For the reaction,
2x +3y +4z 5w
Initially if 1 mole of x, 3 mole of y and 4 mole of z is taken. If 1.25 mole of w is obtained then % yield of
this reaction is _______.
Q.26 The vapour density of a mixture of gas A (Molecular mass =40) and gas B (Molecular mass =80) is 25.
Then mole % of gas B in the mixture would be ________.
Q.27 For the reaction
2A +3B +5C 3D
Initially if 2 mole of A, 4 mole of B and 6 mole of C is taken. With 25% yield, moles of D which can be
produced are _________.
Single Correct:
Q.28 One gramof the silver salt of an organic dibasic acid yields, on strong heating, 0.5934 g of silver. If the
weight percentage of carbon in it 8 times the weight percentage of hydrogen and one-half the weight
percentage of oxygen, determine the molecular formula of the acid. [Atomic weight of Ag =108]
(A) C
4
H
6
O
4
(B) C
4
H
6
O
6
(C) C
2
H
6
O
2
(D) C
5
H
10
O
5
Q.29 Mass of sucrose C
12
H
22
O
11
produced by mixing 84 gm of carbon, 12 gm of hydrogen and
56 lit. O
2
at 1 atm & 273 K according to given reaction, is
C(s) +H
2
(g) +O
2
(g) C
12
H
22
O
11
(s)
(A) 138.5 (B) 155.5 (C) 172.5 (D) 199.5
Q.30 40 gmof a carbonate of an alkali metal or alkaline earth metal containing some inert impurities was
made to react with excess HCl solution. The liberated CO
2
occupied 12.315 lit. at 1 atm& 300 K. The
correct option is
(A) Mass of impurity is 1 gm and metal is Be
(B) Mass of impurity is 3 gmand metal is Li
(C) Mass of impurity is 5 gmand metal is Be
(D) Mass of impurity is 2 gmand metal is Mg
Q.31 The percentage by mole of NO
2
in a mixture of NO
2
(g) and NO(g) having average molecular mass 34 is :
(A) 25% (B) 20% (C) 40% (D) 75%
[4]
Q.32 The minimummass of mixture of A
2
and B
4
required to produce at least 1 kg of each product is :
(Given At. mass of 'A' =10 ; At. mass of 'B' =120)
5A
2
+2B
4
2AB
2
+4A
2
B
(A) 2120 gm (B) 1060 gm (C) 560 gm (D) 1660 gm
Q.33 74 gm of a sample on complete combustion gives 132 gm CO
2
and 54 gm of H
2
O. The molecular
formula of the compound may be
(A) C
5
H
12
(B) C
4
H
10
O (C) C
3
H
6
O
2
(D) C
3
H
7
O
2
Q.34 An iodized salt contains 0.5 % of NaI. A person consumes 3 gm of salt everyday. The number of iodide
ions going into his body everyday is
(A) 10
4
(B) 6.02 10
4
(C) 6.02 10
19
(D) 6.02 10
23
Q.35 The mass of CO
2
produced from 620 gm mixture of C
2
H
4
O
2
& O
2
, prepared to produce maximum
energy is (Combustion reaction is exothermic)
(A) 413.33 gm (B) 593.04 gm (C) 440 gm (D) 320 gm
Q.36 In the quantitative determination of nitrogen, N
2
gas liberated from 0.42 gm of a sample of organic
compound was collected over water. If the volume of N
2
gas collected was
11
100
ml at total pressure
860 mm Hg at 250 K, % by mass of nitrogen in the organic compound is
[Aq. tension at 250 K is 24 mm Hg and R =0.08 L atm mol
1
K
1
]
(A)
3
10
% (B)
3
5
% (C)
3
20
% (D)
3
100
%
Q.37 The mass of P
4
O
10
produced if 440 gm of P
4
S
3
is mixed with 384 gm of O
2
is
P
4
S
3
+O
2
P
4
O
10
+SO
2
(A) 568 gm (B) 426 gm (C) 284 gm (D) 396 gm
Q.38 Calculate percentage change in M
avg
of the mixture, if PCl
5
undergo 50% decomposition.
PCl
5
PCl
3
+Cl
2
(A) 50% (B) 66.66 % (C) 33.33 % (D) Zero
Q.39 The mass of Mg
3
N
2
produced if 48 gm of Mg metal is reacted with 34 gm NH
3
gas is
Mg +NH
3
Mg
3
N
2
+H
2
(A)
3
200
(B)
3
100
(C)
3
400
(D)
3
150
Q.40 The number of carbon atoms present in a signature, if a signature written by carbon pencil weights
1.2 10
3
g is
(A) 12.04 10
20
(B) 6.02 10
19
(C) 3.01 10
19
(D) 6.02 10
20
Q.41 The average atomic mass of a mixture containing 79 mole % of
24
Mg and remaining 21 mole % of
25
Mg
and
26
Mg , is 24.31. % mole of
26
Mg is
(A) 5 (B) 20 (C) 10 (D) 15
[5]
Assertion Reason:
Q.42 Statement -1 : 2A +3B C
4/3 moles of 'C' are always produced when 3 moles of 'A' & 4 moles of 'B' are
added.
Statement -2 : 'B' is the liming reactant for the given data.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.
More than one correct:
Q.43 Given following series of reactions:
(I) NH
3
+O
2
NO +H
2
O (II) NO +O
2
NO
2
(III) NO
2
+H
2
O HNO
3
+HNO
2
(IV) HNO
2
HNO
3
+NO +H
2
O
Select the correct option(s):
(A) Moles of HNO
3
obtained is half of moles of Ammonia used if HNO
2
is not used to produce HNO
3
by reation (IV)
(B)
6
100
% more HNO
3
will be produced if HNO
2
is used to produce HNO
3
by reaction (IV) than if
HNO
2
is not used to produce HNO
3
by reaction (IV)
(C) If HNO
2
is used to produce HNO
3
then
4
1
th
of total HNO
3
is produced by reaction (IV)
(D) Moles of NO produced in reaction (IV) is 50% of moles of total HNO
3
produced.
Comprehension:
Q.44 A 4.925 g sample of a mixture of CuCl
2
and CuBr
2
was dissolved in water and mixed thoroughly with a
5.74 g portion of AgCl. After the reaction the solid, a mixture of AgCl and AgBr, was filtered, washed,
and dried. Its mass was found to be 6.63 g.
(a) % By mass of CuBr
2
in original mixture is
(A) 2.24 (B) 74.5 (C) 45.3 (D) None
(b) % By mass of Cu in original mixture is
(A) 38.68 (B) 19.05 (C) 3.86 (D) None
(c) % by mole of AgBr in dried precipate is
(A) 25 (B) 50 (C) 75 (D) 60
(d) No. of moles of Cl
r
ion present in the solution after precipitation are
(A) 0.06 (B) 0.02 (C) 0.04 (D) None
[6]
Q.45 NaBr, used to produce AgBr for use in photography can be self prepared as follows :
Fe +Br
2
FeBr
2
....(i)
FeBr
2
+Br
2
Fe
3
Br
8
....(ii) (not balanced)
Fe
3
Br
8
+Na
2
CO
3
NaBr +CO
2
+Fe
3
O
4
....(iii) (not balanced)
(a) Mass of iron required to produce 2.06 10
3
kg NaBr
(A) 420 gm (B) 420 kg (C) 4.2 10
5
kg (D) 4.2 10
8
gm
(b) If the yield of (ii) is 60% & (iii) reaction is 70% then mass of iron required to produce 2.06 10
3
kg
NaBr
(A) 10
5
kg (B) 10
5
gm (C) 10
3
kg (D) None
(c) If yield of (iii) reaction is 90% then mole of CO
2
formed when 2.06 10
3
gm NaBr is formed
(A) 20 (B) 10 (C) 40 (D) None
Q.46 Preparation of cobalt Metaborate involves the following steps of reactions:
(i) Ca
2
B
6
O
11
+Na
2
CO
3
(aq)
Boiled
CaCO
3
(insoluble) +Na
2
B
4
O
7
+2NaBO
2
(ii) Na
2
B
4
O
7

NaBO
2
+B
2
O
3
(iii) CoO +B
2
O
3

Co(BO
2
)
2.
(a) Mass of Ca
2
B
6
O
11
in kg required to produce 14.5 kg of Co(BO
2
)
2
, assuming 100% yield of each
reaction is
(A) 32.2 (B) 40 (C) 28.2 (D) 30
(b) If the yield of reaction (i), (ii) & (iii) is 60%,
3
200
% & 32.2 % respectively, then mass of Ca
2
B
6
O
11 1
in
kg required to produce 14.5 kg of Co(BO
2
)
2
is
(A) 250 (B) 200 (C) 190 (D) 150
Q.47 Water is added to 3.52 grams of UF
6
. The products are 3.08 grams of a solid [containing only U, O
and F] and 0.8 gramof a gas only. The gas [containing fluorine and hydrogen only], contains 95 % by
mass fluorine. [Assume that the empirical formula is same as molecular formula.]
(a) The empirical formula of the gas is
(A) HF
2
(B) H
2
F (C) HF (D) HF
3
(b) The empirical formula of the solid product is
(A) UF
2
O
2
(B) UFO
2
(C) UF
2
O (D) UFO
(c) The percentage of fluorine of the original compound which is converted into gaseous compound is
(A) 66.66 % (B) 33.33 % (C) 50 % (D) 89.9 %
[7]
Match the column :
Q.48 Match the following :
Column I Column II
(A) C
12
H
22
O
11
(P) 8 N
A
atoms / mol
(B) CH
3
COOH (Q) 14 N
A
atoms / mol
(C) Ca(OH)
2
(R) 45 N
A
atoms / mol
(D) CH
3
COOC
2
H
5
(S) 2 N
A
of O-atoms / mol
Q.49 Match the following:
Column I Column II
(A) Gramatompresent in one atom (P) 2 N
A
(B) N
A
gramatomcontains atom (Q)
A
N
1
(C) No. of protons in 1 gm molecule of H
2
(R) 4 N
A
(D) No. of electrons added to 32 gm O (S) N
A
2
atom to convert it into O
2
Q.50 One type of artifical diamond (commonly called YAG for yttriumaluminiumgarnet) can be represented
by the formula Y
3
Al
5
O
12
.[Y = 89, Al =27]
Column I Column II
Element Weight percentage
(A) Y (P) 22.73%
(B) Al (Q) 32.32%
(C) O (R) 44.95%
[8]
ANSWER KEY
Q.1 C Q.2 B Q.3 D Q.4 C Q.5 C Q.6 B Q.7 C
Q.8 C Q.9 B Q.10 C Q.11 D Q.12 B Q.13 D Q.14 D
Q.15 C Q.16 C Q.17 B Q.18 D Q.19 C Q.20 B Q.21 C
Q.22 B Q.23 A Q.24 B Q.25 50% Q.26 25% Q.27 0.75
Q.28 B Q.29 B Q.30 B Q.31 A Q.32 A Q.33 C Q.34 C
Q.35 C Q.36 A Q.37 B Q.38 C Q.39 A Q.40 B Q.41 C
Q.42 C Q.43 A,C,D
Q.44 (a) C, (b) A, (c) B, (d) A Q.45 (a) B, (b) C, (c) B
Q.46 (a) A, (b) A Q.47 (a) C, (b) A, (c) A
Q.48 (A) R, (B) P,S (C) S (D) Q,S
Q.49 (A) Q (B) S (C) P (D) R
Q.50 (A) R, (B) P, (C) Q

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