Professional Documents
Culture Documents
20050925 .................................................................................................................... 1
PHU LUC ..................................................................................................................... 3
TAI LIEU THAM KHAO MON HOC DANH CHO SINH VIEN ......................................... 4
1
1.1
1.2
2
2.1
2.2
3
3.1
3.2
3.2.4
3.2.5
3.2.6
3.2.7
3.2.8
3.2.9
3.2.10
3.2.11
3.2.12
3.2.13
3.2.14
3.2.15
3.2.16
3.2.17
3.2.18
3.2.19
3.2.20
VD2. FREUNDLICH...................................................................................................................... 13
Bai tap. Freundlich. ........................................................................................................................ 13
Bai tap. Langmuir Freundlich. .................................................................................................... 14
VD3. BET. ...................................................................................................................................... 14
Bai tap. BET. .................................................................................................................................. 14
Bai tap. BET. .................................................................................................................................. 14
VD 4. * Tnh hoc. Can bang vat chat. Xac nh lng chat hap phu. ........................................... 15
VD5. Tnh hoc. * ........................................................................................................................... 15
VD6. Tnh hoc. * ............................................................................................................................ 15
Bai tap. Can bang vat chat. ............................................................................................................ 15
Bai tap . [MODULE 5. ACTIVATED CARBON ADSORPTION]/ Example 4 ............................ 17
Bai tap 4. Tnh hoc. MODULE 5. ACTIVATED CARBON ADSORPTION/ Example 5............ 18
VD. MODULE 5. ACTIVATED CARBON ADSORPTION]/ Example 6..................................... 18
Bai tap. Homework 6 / question 3 .................................................................................................. 18
VD6. ong hoc . CE525. MODULE 5. ACTIVATED CARBON ADSORPTION/ Example 7 .... 19
Bai tap. Thiet ke hap phu CE525. assignment 4 / Question 4 ....................................................... 19
Exam. CE 525/ exam 1/ 2003/ Question 2 (12 marks) FAT. ...................................................... 19
3.2.21
3.2.22
3.2.23
PHU LUC
Chuan so
Ky hieu trong cong thc chuan so
Ky hieu
Bang chuyen oi n v
Cong thc chuyen oi nong o
n v o nhan c t he thong o lng quoc te
Cong thc chuyen oi cac gia tr nhiet o oi vi cac n v o
n v o chieu dai
n v e o o nht ong lc hoc
n v e o o nht ong hoc
n v e o ap suat
Bang tra cac thong so c ban cua vat chat
Hang so Henry
Bang tra tnh toan he so khuech tan
He so tuyen khoi trong cac trng hp n gian
Quan he gia cac dang he so truyen khoi
Khoi lng rieng cac chat long theo nhiet o
Tnh chat vat ly cua mot so chat kh
o nht ong lc cua nc
o nht ong lc cua cac chat long va dung dch phu thuoc nhiet o
Phu luc tra cu tnh toan thiet ke
On tap chng 1 chng 2
TAI LIEU THAM KHAO MON HOC DANH CHO SINH VIEN
CAU HOI
Cau hoi 1
Cau hoi 2
Cho v du cu the.
1.2
BAI TOAN
1.2.1
Cho dung dch axit axetic nong o 10% khoi lng trong nc ieu kien chuan. Hay xac
nh nong o phan mol cua axit (xA), t le mol (XA).
1.2.2
Hon hp long cha 58,8% mol toluen va 41,2% mol tetracloruacacbon (TCC). Xac nh t
so khoi lng cua toluen va nong o khoi lng cua no.
1.2.3
Axeton trong xng sn co nong o 400mg/m3 35 oC. Xac nh nong o phan mol cua
axeton trong khong kh (yA).
1.2.4
Bai tap 2.
Khong kh bao hoa hi nc ap suat thng va nhiet o 34 oC. Xac nh ap suat rieng
phan cua khong kh, phan the tch (phan mol) va phan khoi lng cua hi nc trong hon hp
khong kh hi nc, t so khoi lng. Biet ca hai cau t c xem la ly tng. Ap suat kh
quyen la 745 mmHg. Xac nh khoi lng rieng hon hp khong kh hi nc.
1.2.5
Bai tap 4.
VD5. = Bai tap 2.5. [QTTBT3]/ 25. Toc o khuech tan. Truyen khoi 1 pha
Mot thung hnh tru h co ng knh 2m cha benzen 20oC tiep xuc vi khong kh1i.
Lp khong kh1i tren be mat benzen xem nh ng yen co be day 5mm. nong o cua benzen
ben kia lp mang khong kh la khong ang ke. Ap suat hi cua benzen 20oC la 100mmHg.
Xac nh khoi lng benzen that thoat moi ngay. Cho biet khoi lng rieng cua benzen la
880 kg/m3, he so kuech tan cua benzen trong khong kh ieu kien chuan la 7,710-2 cm-2/s.
1.2.10 Xem VD 2.1 [QTTBT3]/18;
Oxy khuech tan qua monoxit cacbon khong khhuech tan trang thai on nh. Ap suat tong
cong la 1 at, nhiet o 0oC. Ap suat rieng phan cua oxy tai 2 mat phang cach nhau 0,2 cm lan
lt la 100 va 50 mmHg. He so khuech tan cua hon hp la 0,185 cm2/s. tnh thong lng
khuech tan cua oxy theo mol/s.cm2.
1.2.11 Xem VD 2.4 [QTTBT3]
Qua trnh hap thu NH3 trong thiet b truyen khoi co he so truyen khoi theo pha kh Ky = 1
kmol/h.m2.at. Vao cung mot mot thi iem, ngi ta o c tai mot v tr trong pha kh co
nong o 8% mol NH3, va nong o NH3 trong pha long CA = 0,065 kmol/m3. 85% tr lc
truyen khoi nam trong pha kh. Hang so Henry H = 9,28.10-3 at/(kmol/m3). Tnh he so truyen
khoi trong moi pha va nong o NH3 trong moi pha tai dien tch tiep xuc pha.
1.2.13 Xem VD 4.1. [QTTBT3]/ 44;
1.2.14 Xem VD 4.2. [QTTBT3]/45.
1.2.15 Bai tap 5. Phng trnh ng lam viec
Thiet lap phng trnh va ve dang ng lam viec cho cac trng hp sau
He gom n oan lien tuc cung chieu
He gom n oan giao dong
He gom n oan nghch dong
1.2.16 VD5.
Cho bnh tru h ng H2SO4. Ngi ta thoi tren mieng bnh h mot lng khong kh chay
tang nhiet o 20oC, o am tng oi la 50%. Kch thc bnh nh hnh ve. Hay tnh lng
hi nc co cha trong khong kh va b H2SO4 hap thu. Coi tr lc trong pha long la khong
ang ke. Ap suat cua he 101,3 kPa
Khong kh
1m
0,5 m
5lit nc can bang vi hon hp khong kh cha CO2 ap suat rieng phan 0,3 atm, hang so
Henry la 2 g/L.atm. Tnh xem co bao nhieu g CO2 hoa tan trong nc?
1.2.18 Bai tap 3. Hang so Henry
Khong kh cha 21% the tch la oxy. Tnh o tan cua oxy trong nc 0oC, 1 atm. Biet
hang so Henry = 19,3106mmHg. Tnh nong o bao hoa trong pha kh.
1.2.19 VD 3. ng can bang
25
30
35
40
M = y*/x
2,02
2,64
3,41
4,33
3. Tieu chuan cho phep axeton trong moi trng khong kh khu vc lam viec la 200mg/m3
nen phai x ly axeton. Vay co the x ly bang phng phap hap thu bang nc hay khong?
1.2.20 Bai tap 1. ng can bang he kh - long. Dang 1. Henry
Ve ng can bang long hi cua axeton va nc nhiet o 30 oC. Biet d lieu can bang
cho nh sau
T (oC)
25
30
35
40
M = y*/x
2,02
2,64
3,41
4,33
Ve ng can bang cua hi NH3 va nc 30oC Trong khoang nong o pha kh 100
mg/m3 (25oC).
Biet hang so Henry nh sau
T (oC)
H (mmHg)
10
20
25
30
50
70
90
Ve ng can bang cua CO2 va monoetanolamin (MEA) 27oC Trong khoang nong o
CO2 20% trong khong kh
Biet d lieu can bang nh sau
PCO2 (mmHg)
11,1
45,2
X (mol/mol)
97,9
110,0 254,1
Ve ng can bang cua CO2 va dung dch K2CO3 25oC trong khoang t nong o CO2
20% trong khong kh.
Biet d lieu can bang CO2 tren he K2CO3 KHCO3 - H2O
PCO2 (kg/cm2)
0,02
0,04
0,06
0,08
0,10
012
0,14
016
0,18
8
[CO2] (g/lit)
26,4
32,0
34,6
35,6
37,0
37,5
38,0
38,6
38,6
2 HAP THU
2.1
CAU HOI
1. Lng dung moi toi thieu: khai niem, y ngha kinh te ky thuat.
2. So sanh cau tao, u nhc iem cac loai thap; mam chop, mam xuyen lo, thap em.
3. Cac che o dong chay trong thap hap thu dang em, sui bot
2.2
2.2.1
BAI TOAN
VD 1. VD 4.4. [QTTB T3]/57.
Amoniac c hap thu t khong kh 20 oC, 1 at trong thap chem hoat ong cung chieu,
dung nc tinh khiet 20 oC lam dung moi. Suat lng pha kh i vao thap la 41,6m3/h.
neu nong o amoniac c giam t 3,52 con 1,29 % theo the tch, lng nc s dung
bang 1,37 lan lng nc toi thieu. Xac nh
a) T so Ltr/Gtr toi thieu.
b) Suat lng nc s dung
c) Nong o cua pha long.
Cho biet d kien can bang cua he 20 oC, 1 at nh sau:
X, t so mol
0,0164 0,0252 0,0349 0,0455 0,0722
Y, t so mol
0,021 0,032 0,042 0,053 0,080
2.2.2
2.2.3
VD 2. VD 5.12. [QTTBT10]/248. He so truyen khoi. Phng phap chuan so. Thap em.
Sunphua dioxit (SO2) la mot kh o nhiem thuoc nhom chat oc loai A. Nguon thai kh nay
c thu gom va x ly trc khi thai vao moi trng. Trong trnh toan thiet ke thiet b
hap thu x ly kh sunphua ioxit trong kh thai, he so truyen khoi la mot thong so quan
trong e tnh van toc hap thu. Thap dang em dung e hap thu sunphua dioxit trong kh
tr (nitrogen) lam viec che o mang, di ieu kien nhiet o 20oC, ap suat kh quyen.
Van toc bieu kien cua pha kh trong thap la 0,35m/s. Vat chem la cac thoi than co =
42m2/m3 va Vtd = 0,58m3/m3. Yeu cau xac nh he so truyen khoi cho pha kh trong thap.
2.2.4
VD 3.
Axeton ((CH3)2CO) la mot kh oc hai cho con ngi va co nguy hiem chay. Hi axeton
phat thai vao moi trng trong cong nghiep do no c s dung lam dung moi trong san
xuat mc in, nha, sn, keo Mot thap dung e hap thu hi axeton t khong kh vi
dung moi la nc co suat lng 3000 kg nc/h. Nhiet o trung bnh trong thap la 20oC.
Hon hp khong kh axeton co nong o axeton la 6% the tch c a qua thap ap
suat thng. Pha kh co lu lng la 1400m3/h khong kh tinh khiet ieu kien chuan.
Thap hap thu 98% axeton. Phng trnh ng can bang la Y* = 1,68 X. Vi X, Y c
bieu dien theo kmol axeton/kmol cau t tr (nc hoac khong kh).
Tnh ng knh va chieu cao cua thap chem. Vat lieu chem la vong rasig co kch thc
25253mm. Thap hoat ong che o van toc kh bang 75% van toc ngap lut. Biet he so
truyen khoi tong quat Ky = 0,4 kmol axeton/m2.h (kmol axeton/kmol khong kh). Gia s
vat chem tham t hoan toan.
10
2.2.5
Bai tap 2.
Khong kh ap suat 765 mmHg cha 14% (theo the tch axetylen (C2H2) va nc cha
axetylen hoa tan vi nong o. (a). 0,290.10-3kg/kg nc; (b). 0,153.10-3kg/kg nc
c lan lt cho tiep xuc 25 oC. Xac nh
1. Pha au va pha cuoi cua axetylen
2. ong lc cua qua trnh chuyen pha tai thi iem ban au theo t so mol.
Cac nong o can bang pha long va pha kh c xac nh theo nh luat Henry.
2.2.6
Bai tap 3.
Mot thap hap thu dung e hap thu NH3 bang dung moi la nc ap suat thng. Ham
lng NH3 ban au trong pha kh la 0,03 kmol/kmol kh tr. Hieu suat hap thu la 90%.
Dung dch ri thap hap thu co nong o la 0,02 kmol NH3/kmol nc. Thap c duy tr
nhiet o khong oi.
So lieu nong o can bang cua NH3 trong pha kh va pha long cho bang sau. Xac nh so
n v truyen khoi. D lieu can bang nh sau:
X, kmolNH3/kmol nc
0
0.005
0,10
0,0125
0,015
0,020
0,023
0
0,0045
0,0102 0,0138
0,0183 0,0273 0,0327
Y, kmolNH3/kmol kh tr
2.2.7
Bai tap 4.
Tnh thap hap thu loai em e hap thu kh sunfur (SO2) trong hon hp vi khong kh
bang nc. Biet cac so lieu sau: nhiet o cua qua trnh 30oC, ap suat cua hon hp
760mmHg. Hon hp i vao thap hap thu 120.000m3/ngay, nong o SO2 7% (theo the tch).
Kh SO2 thap i ra khong ln hn 0,3% (theo the tch). Ap suat rieng phan cua SO2 tren
dung dch 30oC tren dung dch 30oC tra trong so tay nhu sau:
% trong lng SO2 trong nc, %
Ap suat rieng phan cua SO2, mmHg
0,02
0,6
0,05
1,7
0,10
4,7
0,15
8,1
0,20
11,8
0,30
19,7
0,50
36,0
0,70
52,0
1,00
79,0
1,50
125,0
2,50
216,0
em than coc co kch thc trung bnh dd = 25mm. ac tnh cua em nh sau: be mat
rieng d= 120 m2/m3, the tch t do vd = 0,53m3/m3, khoi lng rieng d = 600kg/m3.
11
CAU HOI
BAI TAP
VD1. ng can bang hap phu Langmuir.
Mt nghien cu hap phu c thc hien trong phong th nghiem bang cach cho them mot
lng than hoat tnh xac nh vao 06 bnh tam giac cha 200mL nc thai cong nghiep. Mot
bnh tam giac na cha 200mL nc thai khong cho them than c dung lam mau trang. Ve
ng can bang hap phu va xac nh cac he so trong phng trnh Langmuir.
STT
1
2
3
4
5
6
7
3.2.2
Th nghiem hap phu thc hien bang cach cho them cac lng than hoat tnh khac nhau vao
mot day 7 bnh tam giac cha mot the tch nc 500mL bang nhau co ham lng ban dau cua
TOC la 2,0mg/L. Bnh cha c khuay tron trong 14 gi, ham lng chan va TOC trang thai
on nh c xac nh va ke trong bang sau.
Ve o th ng ang nhiet hap phu Langmuir va Freundlich cho cac d lieu thc nghiem
di va cac nh cac he so trong phng trnh tng ng.
STT.
2.0
4.4
1.7
9.7
1.4
14
1.2
28
1.0
56
0.9
140
0.8
12
3.2.3
Tnh cac he so trong phng trnh ang nhiet Langmuir hay Freundlich cho than hoat tnh
hang bot trong qua trnh kh chat methylene blue lam sach nc. So lieu cho tren hnh sau
1/(x/m)
0.018
0.012
y = 0.232x + 0.0108
R2 = 0.9288
0.006
0
0
3.2.4
0.005
0.01 0.015
1/Ce
0.02
0.025
VD2. FREUNDLICH.
Sau ay la bang d lieu thc nghiem trong nghien cu qua trnh hap phu gian oan. Ve
ng hap phu ang nhiet Freundlich va xac nh cac he so cua phng trnh. Biet the tch
nc em th nghiem moi bnh la 500mL va nc thai co nong o au COD la 100 mg/L.
STT
1
2
3
4
5
6
7
3.2.5
Nc thai nhiem phenol co nong o 0,400g/L tnh theo tong chat hu c (TOC) c x ly
bang than hoat tnh dang hat. Th nghiem tren mo hnh hap phu dang pilot hoat ong gian
oan e xac nh ng can bang hap phu cho ket qua nh sau:
Lng than, m, g/L
TOC sau x ly, Cc,
g/L
0,52
0,322
2,32
0,117
3,46
0,051
3,84
0,039
4,50
0,023
5,40
0,012
6,67
0,0061
7,60
8,82
0,0042 0,0011
1. Yeu cau xac nh cac he so trong phng trnh hap phu ang nhiet.
2. Ve ng can bang hap phu ang nhiet cua phenol tren than hoat tnh dang hat trong
trng hp nay.
13
3.2.6
1. Th nghiem hap phu vi 6 coc chc 500mL nc thai cong nghiep co nong o TOC ban
au la 150mg/L. Khuay tron coc th nghiem trong 4 gi, e lang, o TOC. Ve ng can
bang Langmuir va Freundlich cho cac d lieu th nghiem sau ay va xac nh cac he so
tng ng.
STT.
3.2.7
150
75
105
175
70
250
54.5
500
28.3
1000
12.5
VD3. BET.
S dung d lieu thc nghiem VD1, ve ng can bang hap phu BET va tnh cac he so
trong phng trnh.
3.2.8
1. So lieu th nghiem sau ay trong nghien cu hap phu gian oan e thu hoi vang trong
nc thai dung dch ma co nong o au la 15mg Au /L. Sau bnh th nghiem chcs 250 mL
mau nc va c th nghiem vi cac lng than hoat tnh khac nhay. Bnh th nghiemt h
bay c dung lam mau trang se khong cho than vao. Hay xac nh gia tr cac he so torng
phng trnh BET.
STT.
1
2
3
4
5
6
7
3.2.9
Au cuoi (mg/l)
0.35
0.6
1.1
1.5
2.5
3.5
15
2. Sau ay la d lieu th nghiem hap phu gian oan oi vi nc thai cong nghiep co
nong o COD ban au la 150mg/L. 6 bnh cha 250 mL nc thai va o lng than hoat tnh
cho va moi bnh. Bnh th bay la mau trang khong cho than hoat tnh. Xac nh gia tr hang
so trong phng trnh BET.
14
STT.
2837
3.6
1285
6.0
465
10.5
287
13.5
103
24.0
52
33
150
3.2.10 VD 4. * Tnh hoc. Can bang vat chat. Xac nh lng chat hap phu.
Thiet b loc bang than hoat tnh dang hat co lu lng be mat 0,152 m/phut, thi gian tiep
xuc la 5,5 phut. Xac nh chieu cao lp hap phu ly thuyet.
3.2.11 VD5. Tnh hoc. *
Thiet b hap phu dung than hoat tnh dang hat e kh clobenzen t nong o 12g/L
en2g/L. Hay tnh lng than s dung.
3.2.12 VD6. Tnh hoc. *
Mc o nhiem cc ai cho phep oi vi tricloetyle la 0,005 mg/L. Tnh lng than hoat tnh
dang bot PAC toi thieu e x ly tricloetylen t 33g/L en gii han cho phep.
3.2.13 Bai tap. Can bang vat chat.
ng ang nhiet hap phu Freundlich di ay c trnh bay vi nong o phenol can
bang n v g/L va x/m bieu dien nong o g phenol/mg than hoat tnh.
a) Neu gii han cho phep thai cua phenol la 0,2g/L va nguon thai co cha 30g/L, tnh
lieu lng than hoat tnh dang bot can dung e x ly.
b) neu thay v dung toan bo lng than nay mot lan, than c cho hai lan. Lan au cho
than vao e x ly en nong o 3g/L va sau o cho than vao x ly trong be hap phu th hai
en nong o yeu cau. Tnh lng than can e x ly.
c) Co the giam thieu lng than can x dung khi x ly hai bac khong?
15
16
2. xac nh kha nang hap phu cua than nong o au ra (at this level of effluent
quality),
3.
4.
(1)
(2)
(3)
(4)
Flask No.
m Mass of
Volume
carbon (mg)
Solution in
(mg/l)
Final
Flask (mL)
COD
(5)
(6)
x Mass con-
x/m Adsorbate
centration of
adsorbate
of carbon (mg/mg)
adsorbed (mg)
1
200
75
50
200
44
6.2
0.124
100
200
30
9.0
0.089
200
200
17.5
11.5
0.0575
500
200
6.75
13.65
0.0272
800
200
3.9
14.22
0.0177
1000
200
3.0
14.4
0.0144
17
3.2.15 Bai tap 4. Tnh hoc. MODULE 5. ACTIVATED CARBON ADSORPTION/ Example 5.
A small industrial plant generates 200 000L of waste water during an 8 h operating day.
The waste water contains 100mg/L of phenol, which must be reduced to 1.0mg/L prior to
discharge. An adsorption isotherm for this waste water is shown in Figure 9. Design a batch
adsorption system for treating this waste water.
A laboratory column 10cm in diameter and 4m deep, is found to produce good results in
COD removal when operated at a flow of 40L/h. Calculate the following:
1.
2.
3.
The volumetric flow rate, Vb, in bed volumes per hour, associated with this residence
time.
4. The application rate that would yield the same residence time in a production column
that was 3m in diameter and 10m tall.
Solution
3.2.17 Bai tap. Homework 6 / question 3
A laboratory column 10cm in diameter and 3m deep, is found to produce good results in
COD removal when operated at a flow of 50L/h. Calculate the following:
a.
b.
c.
The volumetric flow rate, Vb, in bed volumes per hour, for this residence time.
d. You need to design a GAC system consisting of two columns in series for treating the
same water at a rate of 0.5 ML/d. Practical considerations limit the diameter of the columns
to 3m. Calculate the required height of the columns allowing for sufficient backwash space.
18
3.2.18 VD6. ong hoc . CE525. MODULE 5. ACTIVATED CARBON ADSORPTION/ Example 7
A batch adsorption study was conducted to investigate the removal of COD from a refinery
wastewater by using activated carbon. Results of the study indicate that the Freundlich
0.77
x
isotherm can be described by = 0. 004C .
m
use has an apparent density of 600kg/m and a packed density (bed density) of 550kg/m .
The value of Ka has been found to be 292 kgm-3s-1 at a temperature of 20C.
3.2.19 Bai tap. Thiet ke hap phu CE525. assignment 4 / Question 4
A batch adsorption study was conducted to investigate the removal of COD from a refinery
wastewater by using activated carbon. Results of the study indicate that the Freundlich
0.77
x
isotherm at 20C can be described by = 0. 004C .
m
The wastewater has an initial COD of 60mg/L, which must be reduced to 20mg/L prior to
3
discharge. The carbon selected for use has an apparent density of 600kg/m and a packed
3
density (bed density) of 550kg/m . The value of Ka has been found to be 272 kgm-3s-1 at a
temperature of 20C.
Design a 6m deep by 1m diameter fixed-bed, continuous-flow adsorption column to treat
wastewater at a rate of 10 m3/h.
3.2.20 Exam. CE 525/ exam 1/ 2003/ Question 2 (12 marks) FAT.
A batch adsorption study was conducted to investigate the recovery of phenyl mercuric
acetate (PMA) from electronics manufacturing wastewater by using granular activated
carbon. Results of the study indicate that a Freundlich isotherm best describes the equilibrium
at 20C as x/m = 0. 005C0.7.
The wastewater has an initial [PMA] of 160mg/L, which must be recovered prior to
discharge. No effluents with [PMA] higher than 10 mg/L may be discharged.
The carbon selected for use has a bulk density (bed density) of 550kg/m3 and an apparent
density of 600kg/m3 packed density. The value of Ka has been found to be 270 kgm-3s-1 at a
temperature of 20C.
The GAC must be used in a fixed-bed, continuous-flow adsorption column to treat
wastewater at a rate of 10 m3/h. The PMA will be extracted in a subsequent process and the
GAC reused. It would be convenient and economical to extract the PMA from the GAC on a
weekly basis when all production stops for a general clean-up.
a) Determine quantity of GAC required; expected solid phase [PMA] at exhaustion and
fraction of GAC fully utilized.
b) Specify dimensions for the GAC column, taking into account that suitable standard
diameters for such columns are 2, 3, 4 or 6 feet, due to limitations in the production of dished
ends.
19
20
C A = 535 kg/m3.
Bai tap 1:
X A = 0,853;
Bai tap 2:
Chng 2.
Bai tap 1:
D = 0,084 cm2/s;
Bai tap 2:
D = 0,215 cm2/s;
Bai tap 3:
D = 0,097 cm2/s; D = 0,092 cm2/s;
VD4: ky = 1,176 kmol/h.m2 at; kx = 0,062 kmol/h.m2 (kmol/m3);
CAS = 1,35 kmo/m3; PAS = 0,012 at
21
GIAI V DU CHNG 3
3.2.21 VD 1. VD 4.3. [QTTB T3]/ trang 56
Amoniac c hap thu t khong kh 20 oC, 1 at trong thap chem hoat ong cung chieu,
dung nc tinh khiet 20 oC lam dung moi. Suat lng pha kh i vao thap la 41,6m3/h.
neu nong o amoniac c giam t 3,52 con 1,29 % theo the tch, lng nc s dung
bang 1,37 lan lng nc toi thieu. Xac nh
1. T so Ltr/Gtr toi thieu.
2. Suat lng nc s dung
3. Nong o cua pha long.
Cho biet d kien can bang cua he 20 oC, 1 at nh sau:
X, t so mol
0,0164 0,0252 0,0349 0,0455 0,0722
Y, t so mol
0,021 0,032 0,042 0,053 0,080
Bai lam
3.2.21.1 Tom tat
Nc tinh khiet: x = 0;
Ltr = 1,37Lmin.
ng can bang: X Y.
Yeu cau
Ltr/Gtr toi thieu = ?
Suat lng nc s dung: L= ?
Nong o cua pha long: xAc = ?
3.2.21.2 Cong thc ap dung
Y Yc
L tr
= d
Xc - Xd
G tr
L tr
G tr
min
Yd Yc
X * (Yc ) - X d
Y = 0,0365; Yc = 0,0131; X = 0;
iem au vao P (X = 0; Y = 0,0365)
Nong o can bang X*(Yc = 0,0131) = 0,01;
iem au ra thiet b theo ly thuyet: Q (X* = 0,01; Yc = 0,0131)
3.2.21.5 (Ltr/Gtr)min = 2,34.
3.2.21.6 Lu lng pha long
Xc = 0,00730
3.2.21.8 anh gia nong o pha long co at tieu chuan thai khong
C=
X A M A dd
XAMA + MB
C=
0,00730 17 1000
= 6,85g / lit
0,00730 17 + 18
Tieu chuan thai vao nguon loai B: ham lng amoniac quy ve N = 1 mg/lit/.
TCVN 5945-1995.
C = 6,8510314/17 = 5,64 103mg/lit. > tieu chuan cho phep thai.
23
3.2.22 VD 2.
Sunphua dioxit (SO2) la mot kh o nhiem thuoc nhom chat oc loai A. Nguon thai kh nay
c thu gom va x ly trc khi thai vao moi trng. Trong trnh toan thiet ke thiet b
hap thu x ly kh sunphua ioxit trong kh thai, he so truyen khoi la mot thong so quan
trong e tnh van toc hap thu. Thap dang em dung e hap thu sunphua dioxit trong kh
tr (nitrogen) lam viec che o mang, di ieu kien nhiet o 20oC, ap suat kh quyen.
Van toc bieu kien cua pha kh trong thap la 0,35m/s. Vat chem la cac thoi than co =
42m2/m3 va Vd = 0,58m3/m3. Yeu cau xac nh he so truyen khoi cho pha kh trong thap.
3.2.22.1 Tom tat
Phng trnh chuan so oi vi thap hap thu dang em, che o mang
Shy = 0,407 Rey0,655 Scy0,33.
Sherwoods: Sh =
k'c .l
u.l
; Reynolds: Re =
;
Schmidt: Sc =
;
D
Pha kh gom SO2 N2 . Tnh he so khuech tan cua kh SO2 trong N2 khong khuech tan.
D AB =
P(VA
1/3
1/2
1
1 , cm2/s.
+
1/3 2
+ VB ) M A M B
4,3.10 3 T 3/2
The tch mol (bang tra): VSO2 = 44,8 cm3/mol; VN2 = 31,2 cm3/mol;
Ap suat tong : P = 1 at;
Nhiet o T = 293 oK;
Phan t lng: MSO2 = 64g/mol; MN2 = 28g/mol
Thay so
24
D AB =
4,3.10 3 2933/2
1(44,81/3 + 31,21/3 ) 2
1
1
+
64
28
1/2
= 0,109cm 2 / s
Chieu dai tnh toan, kch thc ac trng ng vi khoang trong gia cac vat em.
Cong thc phan phu luc
l=
4Vd 4 0,58
=
= 0,55m
d
42
Van toc thc, van toc qua cac khe rong gia cac vat em
o nht: xet he la N2
Tra bang
20 oC
3/ 2
= 17,9.10 6 Ns / m 2
Tra bang
20 oC
17,9.10 6
Sc y =
17,9.10 6
=
= 1,42 ;
D 0,109.10-4 1,16
25
3.2.23 VD 3. VD. 5.8. [QTTB T10]/ 241. Tnh ng knh, chieu cao thap. Biet Ky.
Axeton ((CH3)2CO) la mot kh oc hai cho con ngi va co nguy hiem chay. Hi axeton
phat thai vao moi trng trong cong nghiep do no c s dung lam dung moi trong san
xuat mc in, nha, sn, keo Mot thap dung e hap thu hi axeton t khong kh vi
dung moi la nc co suat lng 3000 kg nc/h. Nhiet o trung bnh trong thap la 20oC.
Hon hp khong kh axeton co nong o axeton la 6% the tch c a qua thap ap
suat thng. Pha kh co lu lng la 1400m3/h khong kh tinh khiet ieu kien chuan.
Thap hap thu 98% axeton. Phng trnh ng can bang la Y* = 1,68 X. Vi X, Y c
bieu dien theo kmol axeton/kmol cau t tr (nc hoac khong kh).
Tnh ng knh va chieu cao cua thap chem. Vat lieu chem la vong rasig co kch thc
25253mm. Thap hoat ong che o van toc kh bang 75% van toc ngap lut. Biet he so
truyen khoi tong quat Ky = 0,4 kmol axeton/m2.h (kmol axeton/kmol khong kh). Gia s
vat chem tham t hoan toan.
Bai lam
3.2.23.1 Tom tat
Nc tinh khiet: x = 0;
Lu lng nc: Ltr = 3000kg/h.
D=
4V
.w y
w th 2 d y
L
0,16
(
)
=
lg
.
A
B
x
3
G
g.Vd x
CA
H=
K y S d C y ln
0,25
0,125
d = 195 m2/m3.
26
Vd = 0,75 m3/m3.
4Vd 4 0,75
=
= 0,0154m
195
d
He so tham t:
= 1;
= 62,5 kmol/h.
G tr = 1400 1,205
= 1687 kg/h.
=
=
=
=
3,91 kmol/h.
227 kg/h.
2,41 kg/m3.
94,2 m3/h.
= 64,4 kmol/h.
= 1800 kg/h.
= 1447 m3/h.
L tr = 3000 kg/h.
= 3,006 m3/h.
Vtr = 3000 / 998
Ltr = 3000/18
= 166,7 kmol/h.
Lu lng trung bnh
Ltb = Ltr + CA/2 = 166,7 + 3,91/2
x = 0
xc =
= 3114 kg/h.
X = x/(1-x) = 0
mA
MA
L tr
mA
+
M A M H 20
227
58
=
= 0,0229 Xc = x/(1-x) = 0,0235
227 3000
+
58
18
ong lc pha kh
ay thap
nh thap
= 168,6 kmol/h.
= 0,0395
=0
27
Yln =
Yday Ydinh
Yday
ln
Ydinh
0,0243 0,0012
= 0,00768
0,0243
ln
0,0012
w 2
lg th 3d
g.Vd
0,25
0,125
.( x )0,16 = A B y
G
0,25
0,125
w th 2 195 1,205
3114 1,205
0,16
lg
Van toc kh
wy = 0,75 wth = 0,75 1,59 = 1,19 m/s.
ng kh thap
4V
4 1447 / 3600
D=
=
= 0,430 = 0,66m = 0,66m
.w y
.1,19
3.2.23.6 Tnh chieu cao thiet b theo phng trnh truyen khoi
H=
CA
3,91
=
= 19,3m = 19,3 m
K y S d C y ln 0,4 0,338 195 1 0,00768
H = N0y H0y.
Chieu cao mot n v truyen khoi Hoy tnh theo cong htc nh nghia.
G tr
62,5
H 0y =
=
= 2,37m
K y S 0,4 0,338 195 1
3.2.23.8 Tnh chieu cao thap theo phng phap so n v truyen khoi dung o th
Noy = 7,71
H = 7,71 2,37 = 18,3m (sai so 5,3%)
3.2.23.9 Tnh van toc pha kh khi thiet b hoat ong cac che o khac nhau
0 , 43
G
Re y = 0,045 Ar ,
L
3
l ( x y ) y .g 0,0154 3 (998 1,205) 1,205 9,81
Ar =
=
= 144.10 6
2
-6 2
y
(17,3.10 )
w y l y w y 0,0154 1,205
Re =
=
= 1073w y
y
17,3.10 -6
0,57
6 0,57
1073wy = 1589
wy = 1,48 m/s.
1800
3114
0 , 43
L y
0,16
.( x ) = 0,079 1,75
lg
3
G
g.Vd x
x
0,25
0,125
w y 2 195 1,205
3114 1,205
0,16
lg
Y=
2
w s d y
3
g.Vd x
1/4
1/8
L y
X = . = 0,495
G x
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