) reaction? Give an example. i I t t l l l f l nl r l I l . r l l l | | l i t - l l "I l l / " t l ( , 1, 1 I ' n l ' l l t - v Subj ect code-34' Hax Marks: 70 17. Give the use of following compounds : - , (i) Norethlndrone (ii) Ra1S.d!ne, l2 Ar- \ " \ 1. 1, . : . . 1i . ". = . . - : i , , "i . . i . . . . . , ltjlwhat are non-soapy det-erger-rts?:Gve one example- PART-C IfI. Answer any FilE of the following quqstions : ( Each questionicarrieis' 3 mafks.' ) ' ' :: ('t9.'Oraw a neat labeled diagnm of blast furn.ice. Wiite the equatio.ns for the readions taking place in the temperature r:lnge 500-1073K during the extraction of cast irpn from . - , t . \ . \ . a cl r - gl f "' l ) Av^t a ' ^d 0. l - . 5af=-15 1 . . ' , , { 2+I 2' F 1 t r , l l , t . . , | : , ! : t i , , 1' r 1' - r ! - = t ' l r l r nl l r A, l t , ( ' l l l ( l l ) ' nl l l ) ' l r t s ar i compul sor y' , - , r t l . r l r , ' l . l r r l r l , r l r ' r 1t t ' t l l r r t r r ' t t t t l t l l ' l w l ' r l r <: l cd di agr anr s wl r er ever r equi r ed' 11; = l , , r J t 3| l e: at t ' l r t r i l l r l r | ' l h l l l dl t t l l t l l c( ' ( : ssi l r y' I l l : e r r f r r l . t t l l l i r r . r kt l l . r l ot r l " r r ot l t l l owed ) . , At l l l *r l . l l 11vi 1111; t ; t r . st i or t s t t "UT 10x! =10 , i r t t "v, ' , ; r r r , r l l t r l l r , l l l l l ' 1 t r r l , r l k ) I I t "' , ' , , , , , , , , , , , , r , l v, r r l , r , l . . l r r r , l al i t y over mol ar i t y as t he uni t of concent r at i oni sconcer ned? r ' l r r i r ' "' , r . - ; t i - ^^- - ^r . - . t ^^o. l t ^, r . t "" , . t ' . i l r' , rl wrl l t wl rx. h : ; i l j con can be doped t o gi ve a p-t ype Semi conduct o , l , ; , . , , , , , , , t t , ' , t t , ' , yr st l t r : l eadst or agebat t er yz *E: ' - : ' . : J' t , ' i {i i ' . ' + r t ' l ' ! ' t e t ' i ] , i : j \ . . 1. i , ' *", . , , , . r. rl u, rl ri , n wl ri cl r rrl at cs rat e const aht of a react i on wi t h t emperat ur. e' ! , * I -" I J ' ' t u' " , rr, rrl t ", l , t w f , rr sol ut i on cont ai ni nq a non-vol at i l e sol ut e' "' ' , ' : ' , , ' l r ' , ) f : , r i r ca i n l he nr et al l ur gy of copper ? F- l *>. ne r v c, f t ' f ( t 1) c- . . r \ f C' 1 r ' I ' ' , ' *". 1: , ' , , , , 6ost abundant nobl e gas i n t he at mosph-r. . i r^^1>' -' r r" t -' t r a f st cg . Nr " , ) Ar QOi n , . . . i , r r , r l r r r ol ecul t r r , , - - , u: l l y. r Jn0ci et o; ] enonc, ur hi ci i gi vesycl l cl "pr eci i r i ' Lai ' e' ' r ' i i l r sodi u; - r ^ l ) l o' l 9 u , .^ui,1eand iodine solution? /\ . . tc phe-\ ovle r , f t r ' ' "" r : . . ' r 1 ; r Nq l i ' ' 466r ^ART_B - . , , ey doY FI VE of t he f ol l owi ng quest i ons ; 5x2= 10 i l ' fl l i f questi on carri es 2 marks )' ' (Eu-' ^,' ,,' ,nu' forthe fol l owi ng: i l -i c,1qe r . i r S" Z ' r' r -) t 1. l : , ' ?; ; k. t def ect i s noi f ound i n al l d[ mbt al hal i des' . cl r"1r { . t r\ . , y, \ , lll ..nottky defect l0wers the density of ionic solid' l tt) ' ' ' ' / nhl rausch' s l aw. tz ,]t:J;;;; expre:,sion for molar cohduaivity of potbssium sulphate at inlrnitc dilutiott octtrrtlittr; ] j ' [ oPt rausch' s t aw ' " -rr, nn i s of second order wi t h respect t o a react ant . l Jow i : ; i t l t , t t t : , rf f t : t t ul rf l l x' ^ A ( eou' - t3' A"tniriTration of the reactant is (i) doubled (ii) reduced to ltalf ? ", ^, , n *f ry Ceo* i s a good oxi di zi nq agent whi l e Et rl * i s goocl rci l uci rrq at . ; t : rt t i t r , )(I r(' ot r' , 14 ?l l ' i ^ l o. nr hqr ^or cl e - \ - ! \ t \ \ ^. r - r nL, 1. , r r , , ) , \ , ' v " \ "\ ^| l [ l 0l r' 5v' ' , . rn vou Lol l vert propcne t o proparl -l -ol ? i . ( l i ow u" (i) Plil h,-rs lowcr boiling point than NH:. l\lprence 6'.f . :x1- e tit{-qtcJt c: v^'1'4'rro 6Ond' . r ^4 ( i i ) Al r r xr r n t er nper at r r r c, N2 i s much l ess r eact i ve. <\ . ' gl r"^g Lnt r' rt . \ ' : e^d l a: gI ^. bona (i i ) At rrnm t ernperat urc, N2 rs I nuch l ess react l ve. S\ f eng t r, 6: t (i i i ) l hc st abi l i t y of l 5 oxi &t t i on st at e decreases. dpwn t he 15' n, group. e7' tha nl I ' r . . l . \ \ V, , 7- ' - r l ; c. r c, i ' , c6t 21. (.r) Mt,rrtiorr tlre favourable conditions foi the.conversiol oj S^O3 to SO3 in themanufacture.cf :,rrllrlruric acid by Ciintact process, ?.-.:t * [:, 45O- c V ( l O , vqCE haemat i t e. 20. Explain the following observations : (b) Wri te l he structure of HzS:Oz. ^. ., : - o -S --n, -. sr r F, o. - . _, , ), ). ((, r) Wl rat i s t he act i on of chl ori ne on sul ph' ur di oxi de i n' i queous medi um? ( r , r \ Vl t ) , ; , . l l l . , r . . : ; . : t dl l , : r l l [ i r t a?r i ?O! SSO1' . r t r on?and ! ' r t v". t : ' Ff t el a' ' e L<1v l - ar 5l dr Ecoc. 61\ I t f ' ev' \ ha\ , 4; 2 "t . c' o. l Ef t ^ Lr (o) Why zinc salts are colourless whereas nickel salts a# coloured ? o\ - ci tvqrn s i I i 'r] (l r) l ransi ti on metal s fogn a l arqe number of compl ex compounds. Gi ve reasons- , i r 7 ! ^, 4) , r 1; c[ a" . ' ^c1 l i t i i i - . ' a. ' a"t et ' c** t c' q- ' nV' \ \ s er , r #pl er et hef ol l owi ng. quui , onr . Vdr l ( - f \ \ e- o' ' cl cr : ^r qt 61\ q- o ' 24 Vr r rr,,:- v ( ' i nl , ( 13. (i) Mn04' + C2Oqr- * H* ------' -' -+ .? ( i i ) Cr 2072 + I + H' ? A (i i i ) KMnQ + ? 25. Based on VBI explain the formation, geometry and magnetic proper' ty of hexammine.cobalt (ilI) cation. ( Atomic number of Co = 27 ) 26, Give the IUPAC name of [Co(en)2C12]Cl. Draw the optical isomer for cis-[Co(en)2o2]' r yr i PART-D 3xg=15 .,or anY THREE of the fol l owi ng questi ons : Ao5w"-,,psti on carri es 5 marks ) u l;::;;"'o:i::l:::::::i] ' t'u"^|"^*qX has a o*r,* ,, Q,zlslcrl. If tn. uag" i.nftt "j.SS ,ryt^t-",Il is 400pm, lz. (a) Al :iil;;iil.o; bubic unir cell; ( Motar mass oii=eo9'lm.l, Nr'=.6.022'x 1d23mol' oillT.''i J;fiii';il.;il; "i'x=boe"6J, Ni= 6'022'x 1d23morr 13 . / , \ "/ , l ont l r y Lr r er ! / r e sv' r ' . \ "- ' - - r : : : : - t uv- .,..t Wpe of crystalline so,,O ,, On ice? Name the binding forcps-Present in dry ice' 2 (b)vVhat' rr- p' orii- -- - -!_119_?:"1flj:: in qo ?n nrwarr i vr l "l vc\ ^i po\ Cv Lq' \ u! {r \ \ vr Ls' , rr' e boilinq point of a solution containing 0' 529 of glucose dissolved in B0' 29 of Water' rind u'"..i'r'^i I"'"^J^ I ,"n.r-"r .nrl K" ior water = 0:52 K kg mol-r ) ' 3 zB. (.) f'^l:,I"n.# "7 6i"i,i*;.'r-a,tifiot ana ru ior waier'=-0!sz-K.ke:to''1 ' ( lut' ' "' .^^,;, u^ff ri.|^-l iiiu.r i. fho v2trp nf van' t Hoff fJgtor, for a comp (r,:;"van,t Hoff factor. what is the value of van,t Hoff factor for a compound f ul otlf.""rirs iuttaruiiruiion in-un orgunic solvent? G'? E' 2 fijirgrrn'ttttamerisaiion in an organic solvent? $'? F L ---> - . first-order reaction, the concentration of reactant gets reduced from (b) 1l:r ; 0.2M in 5min. Calculate rate constant of the reaction' 0 or ' ' ' - . ^ .,.ttri, cell is set up at 250c with the following half-cells: 30. (a) A ""*-,4qi (0.001l i ,1) and Cu / Cu2* (0.l M) na' !62lcibre the El'4F or'tne ceit. ('E!as = 0'av and Eocu = 0'34v ) --.-- .^ any twc di fferences behveen el ectroni c conci uctors and el ectrol yti c conductors' ' i r r {' \ : ' ' \ L / ' - 3 7 ^^nne the following terms : ' ' ; ' \ r)cr! ' - ""i i O oi ul vri r (i i i ) Het erogeneous cat al ysi s 3 I t t ol j r) 6; ect roPt rorest s . , rrri t t he drspersed phase and di spersi op nredi unr of t he f ol l owi ng col l oi dal syst enrs' 2 ( Dl ' 1, , q. oke ( i i ) Mi l k (' / -qG" ' l I . . -, 31ry THREE or t i 6?t t owi ng quest i ons 3x5= 15 V. A.n5l;uestions carries 5 marks ) ( tactt "- " ' ; . . . una| i nZai t sev, s( Sayt zef f ) ni t ewi t nanexampl e. u u:,,::_does chlorobenzene react with methyl qhloride in ,presence of aphy.Qrous AEI:? ,. ' .2,, ( b; n"" , , . , . . : i . , , . r ' 1, j . . : ' , . , : : , l : ' . . " I r r " tdentifY tne: . : I (c) Arrange the following in the dereasin"g order of reactivity toWards nucleophilic substitution reactions' ' ,rr" Noz /Na., {,4 l \ - / l I Noz ( I I ) 33. (a) Mention the major products formed in the following reactions. (i) (cHr3 C-o-CH: + HI (ii) oH -_-..--_.-.-> I cl -(o Y ( r ) Nou ( ur ) (iii) CHr-CH=CH-CHrCHz-OH . (b) Ao organic compound (P) with the formula. crHoo reacts with cH:cHzM9cl. The product . t:ormed on hydrolysis forms analcohol .(q). Alcohol Q on warming with Lucas reagent forms cloudiness. Name the compounds P and Q. 2 34. (a) How do you bring about the following conversions? 3 (i ) Et hanol t o et hanal (i i ) Et hanal t o but -2-enal (i i i ) Benzal dehyde t o Benzal dehycl e cyal ohydrt n (b) What is formatin? Give one use of it. 2 35. (a)Expl ai n Hi nsberg' s t est f or t he di st i nct i on of pri mary, secondary and t ert i bry ami nes. 3 I -l\ dit. HNor l ( Jl - \-.., pcc i (l l a.t*..n benzenami ne and ammoni a, whi ch i s l ess basi c and why? 36. (a) Write the main struitural difference between DNA and RNA' Name the nitrogen base present only in RNA but not in DNA (b) Give an examPle each for. ' (fiOptically inactive a-amino acid , ''(fl Water soluble vitamin ,- (c) Write the Haworth's stucfure for monomer prgsent in cellulose' fii.f al **. the structure of the moriomer for dEch of the folloiffng polymers' \ - '/ (i) Nylon - 6 (ii) PolYProPene (iii) Natural rubber (b) What are thermosefting polymers? Give one example. I o{) r r t r l '2 . l t"l t il cup.ro.ii,- 1N,T . l M 1M CH: I CH, = C- CH=CH: b) . Thesear et hepol ymer shavi ngext ensi ""c' oss- l i nki ngandcannoj ber emoul - ded' , Emmpte - Bri kel i te i . , : I M 1M i , ' - i I I I ' t Jc (i l l l , )Ml s' l ' l t Y MODI ql , Qt Jl : S' l ' l ON l ' r\ l ' l ' l l l \ ' l TIME : 3 Hrs. l5 minutes I Mi r t r r r r t t t r t Mr t r ks 't0 . _t l nst ruci i ons I t ' Thegdst i odi apl r hNf our par t s: A. B, Cr nd D. Answcr al l t hc pnr t : !D 'Wrilcbalffied chmim! cquatioro urd dnw labcllcrl diagranrs whcr cvcr rc(lor'nl I iiD Uselogtdbleandsimplecalculat6rilnccsary . ' I Ai r swer l al i , t hequest i on! : , , l 0xl =10 I ) On what factor the value ofcolligative property depends '1 2) What happens to the soJubility Ja gas in water on increasing thc tcmpcrature' ) ({q-r( ' aqcf 3) Namb the metal usedin galvanisation.of iron- Z;n<- 4) Hbw many times does,thb ratg generd'lly increase on increasing thg I temperature by lffC ? ' . f- 5) Name the dispersed phase in milk. t ,q..qj 1 Gr ! ;; ;t;; ;; il;t;;i'A;il;J in r.u#ng oruauxite. Q-(t ' -'vi^ hTdr o 't"' ote 7) Wlich qobte gas is radioactive ? I -1ao\ct" 8) CH, - CH = CH, + HCI --+ X. What is ' X' in the reaction ? 9) What is the I.U. P.,a-'.C. name of HCHO ? {tO; ) net*".nNH, aldCH,M,, whichhashigher p{n value ? t' !\-r 3 t PART. B Ansrver any five of the following : I 1) Define : (i) unit cell (ii) space lattice" 12) What are fuel cells ? Give an example I 3 ) What i s hal f l i fe peri od of a rercti on ? I I 5x2=l O . \ - \ *, t 6[ v Oqe^ Or 1ge- n \ I t ' \ v- v I l , t r i r i l i ( i : \ t cd l ( ) nr l ! , , , ; . : , : : r l oi i t l l l si u' \ \ f LL4l 1S\ i c' ) l 17) i 8) order reactibn ? How do lanthanoids reactwith water? Give eqLration. Hou. does di et hyl et her react wi t h excess of h" r; rogen i od i dc ' ) Why is acetic acid weaker than formic acrd ' 1 How are antiseptics differ from disinfectants ' .) i) Cive one adVantage of using synthetic detergcnts. ii) Give an example forartificial Sweetening agent containing peptide bond. : PABTi! III Answer anyf i veof t hef ol l owi ng: ) 5x3=l 5 19) (i) Suggest a method to concenrrate copper fyrites ore. (ii)' How is nickel refined by Mond' s process? 1+2 20) (i) Howdoeszincreactwithdil.HNOr? (ii) Which allotropic form of phosphorus exhibits chemiluminescencc ? 2+1 2l) (i) Give anexampleforamphoteric oxide. (ii) How dogs ozonoreact with nitric oxide ? Ciivc cqtration- l+2 22) (i) Which halogen has higlrest clectron affinity ' / (ii) Horv is hydrogen chloride prcpared in thc lll>or:rtory ' l 1!2 23) Wri t e t he chcmi cal equat i ons i nvol vcd i n t l t c t rr: rt t t rf ; rct t t re of ,potassiurn dichromatc frotn ohrontilc orc. 3 24) (i ) Why do 3d-scri cs cl cmcnt s cxl ri bi t vari l bl t : oxi rl l t i ot t st at cs' / 4l ! ry i i ti on methl i ons are coj oured' ' ' ( i i ) Expl ai n why t r ansr hon met al l ons ur c u: i "' * 25) [ring vBT, expiain the fornratiOn of [NiClJ :' - ^. 26; (i) iive the laPACnarneof[Cr (NIl,), (H' o)j] C!' Answer any Three of t he f ol l orvi ng : ' 3 zif ^l Ciassify the followinginl"iiiftl.' .11 tvnes :l:rvstalline solids' I (i) iodine tiii' sio, (iii) copper nreral (tv) Mgo b) Wfrat is nrpantby co-ordination nrrnrber in so-lids ? What is the co-ordination nttnrber of atoms in (i ) FCCal rangement (i i ) BCCarrangenrent ? . ' 28) a) What are azcotropes ? Give an exampte' b) The boiling poiniof ryarer becomes l{tois10:c t:" l'u.g.fi-, -' z no**lJiiesoluteis dissolved in l00g ofJ1,. Cfo{.ate'eit't:.' r nol ur r nu"' of t hesot ut e( \ of wat er =0' 6K/ kg/ r nol ) ' , ' "- ' ' " 2g) a) Def i nemol u, , ond*t unuL. hnut i si t sS. I . ur r i t ?. b) Calculate the etecJJ" fotential of ZnlZnSO' ' (0' 01M) at?5' (Givbn t;, = -0' 76V) 30) u; M.,ition ony trvo factois affeeting the rateof reaction b) Half life period of a first order reaction is 30 min' Calcnlate the time reqlired to complete 90% of the reaction' 3l ) a) Give any two ditferences between lyophilic and lyophobic pqlioids' ti) Mention ""y ' *of"i;" affecting the adsorption of gases onsolids' l +2 ' trl+2 x5=15 7 : . i Ci u" an exampl e i or het erogeneot t s cat al ysi s r \ nst r cr i t t t t ' I i ot t r of l hc f r r l l or vi ng : l Zi ^l f l ow doos chl or obcnet nc I el ct \ vl l l r ; r cci f i chl or i de I bi Explain delrydrohalogcnatton rvith an cxanrplc' ' . 3 2 2 I \ I = l u 2 7 I 2 A I 3 2 3 2 L I , : 2 j ' 7 2 I 1 7 I c) What i s chi ral carbort i t t ot t t ' 33) a) Gi ve one exampl e cacl t l i r r I ' t t t t pl t ' i r r l ' l r r l r \ cd ct l l L' r s' ' Ui Wri t e chemi cal equat i ons l i i r l l t c crrt t r cr: ; i ot t of ( i ) phenol l opi cr i caci d ( i i ) phcnol t obcnzene . iiil)' ",tt.ne to ethyl alcohol' 34) a) Explain decarboxylation with an exantP,le' , 1' u)' Ho* i, acetone obtained lrqm Acetyl qlloride ? 6b Nu*" ttt" ketone rised inthe preparation o[ tear gas' 35)' Y How is anilineprepared from nitrobenzene ? I b1 llowdo.sr.rr,yr#reiiaittitr,t *..ttoimethyl iodi{e? GivLequations' 36) ,aj Write the Hawgrthslrlc]ure of Ma-ltose' b) Cive an examPleeach tor : (i)l:a' t urib cr -' aniino-acid' (ii) a globular protein' c) Narle the vitanrin lvhose deficiency cauies Rickets' l7) ;j nisiingr' ,istttto*.en thernloplasticand tlrtinrosetting' polyntcrs' t r) (' l rrssi f y t l rc l ol l orvi rrg i nt o pol yanri t l cs and pol yesl crc: Nyl on"( r . ( r , ' l i : t Yl ct t c t ) Nrt t t t r' l l t c l l x)l l (t l l l cf t t ' "t ' ' t ' t t t l t l ' . . . . . 9) , , 1'0) l) 2 3)' . 4\ ' 5) 6) . 7) s) 14) r-5) soturloNs To ivrorini P'aPER - vl . . r , , . . : . P. ART: . A, . , , . , , . . 1, Number of solute pirticles in the solution; ' Solpbilitydecreasei , . Zinc ' Doublies OR increases by tv,ro times tiquid,fat Sodiulnhydroxide : Radon' CHj -Crt-CH- on 2-chl oropropane oR i sopropyl chl ori de' ct Mettfanal.:, : NII, ' . I PART-B (i) It is thesmallegtpossible repeating unit of a crystal la,ttige' l iii Th. three dimeniional 4nange-meiit of the lattice points is called'space Iaiticc Th! cells which convert chemical eriergy of combustion of fuels into electrical energy are called fuel cells' Ex : HJdrggp.ri r.qxygen.fuel.cell' The time required to rgduce the concentration -of the reaclant to liulf o1" itt initii i value i9 called halflife period of a reaction. 11) 12) l 1) . 0.69J t , ; l . . l nt hanoi ci s rcaf t $ i t l : t va. t cl hydrogen gas.. 2Ln + 6H,O-----+2Ln (0H). r' i l J, t Di et hyl el her react s rvi l h excess o1' hYdrogen i odi de Lrndcr drast i c coi l ! i l i l ol rs i (' form etlryl iodide. C2H. - O. C2Hr + 2HI --) 2C, H. . l + H, O Becuuse aceiic acid has an electron releasing - CHr Bro,p rvhich nrakes the O-ll bond 5trongeraninotfavour,the releaseofH' ion easily. But in formic acid there is no such group an{ hence release ofproton;(H *) becomes easy' Antiseptics are applied,on living tissues such is wounds,.cuts etc., but disinfectants are appliedon non-living objects such as floors etc., (i) They produce lioth even with hard water.. (ii) A3partanre on alitame on saccharine. PARr-9 (i) Froth floatation on oil' floatation method" (ii) Inrpure nickel is heared with CO to get volatile nickel tetracarbonyl whibh on furtherheating gives vapours ofpure nickel - Nin 4CO ,r,' -t", Ni (CO), .s,;fl,r , \i * 4CO a) zincreacts tvith dil. HNor to fomr zinc nilrate, waler arld nitrous oxide. 4Zn + l0 HNO. ----' + 4 Zn(NO.)r + 5H,O + N,O , *' . : . . . . r , , . , r r , . . , 1. . ; . . 1, , . r ' l : i i . . , . : . . . t l r j i , ' I i t , . 1, \ r Lr \ L, : ) \ : ' , . . I l 6) l 7) l 8) l e) 20) , i r ) _ ' 33) a) Si mpt e et her Mi xed et her b) OH c) 35) a) i ) ) 36) a) H CH:OH cg{,oIl : .CHr-GCII, taimcthvl cthcr) on Crllr-O--CrH, {di"rhvt trh"d : CofrrtO-g11 (methvl phenyl erher) on CrHr-O-CHl (mcthvtethvlriher) t) O';mvo' r2f4' , 3.ri,O i i i ) CHr=CHr-l HrO . *, ' : sor. ) CHr-CHpH 34) a) Wrcn a carboxylic acid is heated with sodalime' an alkane is formed' This reaction is callcd decarboxy{ation Ex: CHTCOOH+Naorl + cl{rcooNa+HrO clircooNaf NaoII -:'o4 cHo+ Narco, b) Acctone is obtained byareating acetyl chloride with dimethyl cadmium' 2cl ' l r - co -cl +cl l r-Cd-cH' ---r 2 cHr - co - cH' +9661' Acctophenone. Aniline is preparedbf *rereductioncifnitrobenzqne using tin and conc' HCI C6H.NO, + 6[H1 s;c*xt ,C6H5NH2+2H]O \' i.lir1,,l nntin" rcecls *' ith eicess o{meth-vl iodide 1o lonrr dinrcthvl arnrno, t ri rncl i l yl rnri rrcard f i nal l l ' t ct ranret l i i l ont t )i ot t i t -t rl l i t t i i : ' i : cHr - NH, + cHrl ----t {cHr)2 NH + HI (CH.), Nli + CH,l ,--+ (CH,)r N + HI (Cl l r)j N' i -CI l : l . + (CHJ, N. : l . OH ,to. I 1rc, 'y-\1 l oI \z I NO, OB b) c) 37) a) i) Lysine on ii) Haemoglobin and i n i i ) c l ' ol yur r r i <l c I ) 0 l ycst ct c) ( ' l r l or ol l r cr r c ( 2 - chkr o- 1, ' J - br r l at l t cr r c) a+l a+f ' ' l - _. ' -' E-'1: olt bn licating, r cnuut l t l t t l lrpuc l,USmY MODEL QIJESTION PAPER-VII TI ME: 3 Hr s. l 5 Maxintr.rmMarks :70 Ansrver any, live of the folloling : i 5 r 2 = l t l l 3) . I I ) Calculate the number of atoms in the unit cell of body centred cubic crYstai. ,) , 1 f : yg6," ,1tE chemical equationsfor the reactions occur at the electrodes of ncid storage bafterY. l4) Givereason: i) Actionoidsshorvvariableoxiddtion states crf 5 \ ,,Cd ,-+ rt act i ort i s 6-91 >: l i l ' s . cl l cul at ehal f l i l e peri od of a f i rst order react i on i f t l re rat c cor' 1st ' i i l oi -l l i r -....,^ri^- i. ri r)i r: ]lt rt c(]\\/.r:c I c.t) I Actionoids shorv variable oxiddtion states crf 5 t , C d , -+^P ii) cerium shorvs +4 oxidation state . n Cb\e' $A"i I C A\ i? CCy.,n.pclct)\t tsc' i - 5 t ,Cd, Lcbte- QY\" {3ll 1 5 ) ' ' , llxplain Kolbe' s reactron. I 6 ) ii l-lou' do you prepare aldehl' des from prinrarv alcohols' 1 l7) lWhat areantioxidants ? Givean examplel l8) ' What are biodegradable detergents ? Give an examplc' PART-C Anirver any liYe of tlie follorving: 5 x 3 I 9) How is a}minium extracted from purified alumina ? ' 20) a) How is dinitrogen prepared from ammonium dichromate ? b) Write lhe structure ofortho$osphoric acid. 21) Write tbe oquatioris involved in the manufacture of sulphuric acid lrom sulphur dioxide by contact Process. G ive any three anomalous bchaviour'of fl uorine a) Zinc faririly are ndt considered as d'block elenrents- WIil' ? b) Copper(l) compgundsarqcolourlesswhere as Coppcr (lI) cpmp.aun4rSlqgf.loured, Why ? I low is potassium dichromate prepared front qoncentred chromitc orc n l:xpiain tl& saliint.fcatures ofVBT' with respgit to the formrtion of t:o-iirdinatiori compourids.' ' a) Drd thg diagram to gtrow ttre splitting of degenerdted orbitals in an octahedral crYstal field- b) Givc,the solvate isomerof [Cr(HrO)o]Clr- III - 1< . l ) \ J -) l ) r l 2. \ ) ) 4\ 21) ') (r) rAR.T-D 3x5=15 ry AnswerjanY Three 6f the following : ir-' ;il-;; "lement fom's gt!'*:':Il'^unit cell ede'e length being , 260 pm. Calculate thd dcnsty of lhe elenrent' i 7*^1" -""",^f rhp elernerit:Z3dnrol, N,=6 i A;ffi;;',i;t;r'"'"r*"*'* --z:g/nor' N '=6'02T T-] o); ;ficili-i'nu'"n "o'tallirie iol i'ls a'r d T:T::::,: I'l; ' 372 ?8) n)i Di sti +guri l hbetl veencrvstal i l l fl esorru5 -rrru dr' vrvrrwuJ vY"-"' I a),i A solirtion,** p,"pui ov dissolvins' 8*,o|.Y]l'::'^: :l ] : 1f,'1:-';; t * "*' ' lr sur*lrurlrwa l' r ei' s' v- *' r""na to r' l"t ' boiiing point oi I00' 340c' The rbsulting soltttion rvas ^,- - n < r v /L^/ nrnl ;;-#:ilr,',"*"rs"'"::: !5:i;A::"t:llY,if ot' rn, varu+r4rv ' ^' Y^v ; fl rl si gni fi cance' gf Henry' s constant ? State"ft,l em.yi p l aw {hati t ., _,^_,-^r.,^a,r r^, r0 mi n wi rh a il;il;# ff "of p.. .,,lpr' ute is elec tro I vseo f:'' 0, t'll]."]T: *"a;i "ir., o,.,.,p"... lvhat is the mass of copper deposited at the , "1 D)!, l q\ r)i electrode? (atomic masscoppcr' k 63)' - u)' p.nl" ritiii''g 'nll* tut'ductivity- c|,' I{owia1e r3apd*d.;;s ;;;;-"i*"g; s'a 9'*rof the cell re{ated ? l' t*,]l t 30) ;i ino* ,f,u, ttie time requiJtor f%.contnlction oia first order reactron rs I twic6 the time '"q''iJittlne completion 90% otthe reactio'' bJwh; i i ' . | ' . "a"f i r st or der r eact i on?Gi veanexampl e. 31) ^i Writb three applications of adsorption' 3+z U; Wilut is a protective sol ? Cive an example' | 4x5: 20 Anlrvei an1' Four of the follo;wing : 32) t) Explain Fittig's reacl'ion' - - il H'orv do yoll convert edryl alcohot to ethyl chloride ? 2+z+ | c) What is racbrnic mixture ? - 3i ) ^) I r henol s ar e aci di c r "' l r i l c al col i ol s ar e nei t t r al Ci ve r ci i sot t s' i ; Uot " : r r e t he l bl l ou' i n. g cor r t er si ons cr l r r i cd ot l t ' ' i) ketone to seccindarY alcohbl i i ) et hanol t o et hanal . i i i ) di et hyl ct hcr t o ei hl l i ot i i de - - . . , . . , . r . - - , , r . - . , t *' 14) a) Hor v do you pr epar c aci d chl or i ' l c "t ' : i t l l l : *t ' chl ondc' l . Why thi onyl cl rl ori rl e i s betl er rcagent i n the above rcacti orr ' / b) Expiain ardor 1o:;;;41 -l:'l-'i'*o''' 35) a) Completetlrefollowingequatron: i ) R-Co-Nl ,{,++911 ti l tH' ' ' i i ) C6H5NH2+HNO;+IIC] - ? i i i ) ' @- N: N- Cl + @H - e! - - - ' , b) Methyl amine rs strongerbasethan am43nia, Ynt-t. ,-^ 3+7 36) ui Distinguish benveen fbrous proteins and globular proterns' b) What happens rvhen gilucose reacts with^hldro8enl?ft* t 2+2+l - c ) Nanre the n itiogen base,rhich ispresentonly lll:Kr\ rr r 37i oj whutor.l,omopolltng;andco-polymers? ' b) What is vuilcanisattii of.iubber ?' ' : ' c) Give'dnexunlp[iot"yothetibpolynrer ' 2+2+l r ) SOt UTIONS'".tp MoDEL PA PFIR - v I I Pr\RT'.E ."\ solution ,havirig lowcr osnrotic pressure tharr that o I a g ivcn so ltll to rr lry,potorric solution" Oxygcn dissolved in u ater 5nT' It is defined as "thc ratelofths vs3s1isn, rvhen the concctttratton I of cacl r r ci l ( : l i l t l t t ' I _5) 6,) 7) 8) e) l 0) , l , l r l _i ) i l ) BccauSe oftheir porous structure l\,t onrJ 's process Radon 2 . bromo-2-nrethyl ProPane Dui t o t l re associ at i on of mol ecul es i n carboxyl i c aci d t hrot rgh i t l l cr nrol t ' ct t l i t t hydrogenbonding - Vitamin-A , PART-B I Contribution by corner particles, ix8 = I ' d Contribution by bbdy centred particle = I Tot hl nri . of part i cl es/ uni t . gl l = | + I =2 , i \ r anode : Pb+i o, ' 1 -+ Ph. So, +2a- ..\t cath<ide : PbO. + SOI: t. lIt' +2e- -+ PbSQn+2H tO Chcmi cal f onrrt rl a of rt rst i s Fe, O, t t l ' O 0.693 0 691 i . = - - * , I r r l I ( i 91, I t t r) Duc t o conrparabl c crrergi es ol 5f , 6t j and 7s subshel l s' r i ) Ccri unr has nobl c gas conl -rgurat i on rn +4 oxi dat i on st at c' \ \ ' l t cn i l ry soi l i unr phcrl rrc rs l rci rred rvi t h co, al 1. i 0"(' i l n(l 6-7 i l t l -l l osl rl rcri c l ) l csst l r c- socl i t t t t r si t l t el i l t l c r s l or r ncd r i l l t ' l l r ' t t aci dl l l cat r or l ut r cs si t l t e r I t c "et t i ' l ' hi s r cl ct i or r i s cal l t t l Kol l r c' s r t l t cl i on t ' ) l I f.r) ,-\-a'coor *- t/ + ^ta''l \\jlrcn .prirnaty algoholS ilr' c li.-ated rvith acidified pgtassitrnr dichrotrtlit c sr) itrl I Urr irklchrrlcs are lorrtretl. R - ( - - H; - Ol l +' [ OJ ] . - : - : : - : i "11 r R- CHO+H, O , l . : r (l Ft . -CH. -Ol ' l ' l ()i . --' : f l : l : \ ""' r CH, -Cl l O r t l ' () ct hanol - cl h: t nl rl ' I 5: Sr r 6sl i r ' ccl r , l r i ct l t , , l i ' , , r l f t i r et i r r d( t l cl i t 1, ) osr r l l r t r , r r r i sc: r l l c<l i l t t l i , r r t r l i t t t l t : r : [ ] . l l , \ . ( ) t { l }. 11. l . ( ) R vi l mi r r - l : t 7) Ti me: 3Hi 15mi n N PUC - CHEMI.STRY : MODEL QUESTION PAPER -vru . l ' : : . ' - : . . . r ", , , 1 ' .Giye an exanipli; foq ttie cdrryiound ofManganese where Man!;anese shows l-7 oxidation state. Calculate the magnetic moment of a divalent ion, M' 2 in aqueous solution, if the atomic.number of M is 25.- 1 + 2 G ' ' Subject _gode.-:c Max Marks: 70 21' 4 b) PART_A I A. ns\ ' erALl l he quest i ons. Each quest i ons carri es ONE mark: I Ci ve anexampl c l or a sol i d sol t rt i on i n ra' hi ch sol vent i s a sas' ]: What annypertonic solutions ? 1;; The question papelhas four Parts - A, B. C'and D- Atl parts are comPulsory' 2;t Write balancedlchemical iquations and draw labeled d'ragrams wherever required' 3.r us bg tabl es and si mpte cal cul ator i f necessary' ( Use ot scientific calculatori is not allowed ) 24, a) :dmsng aqueous solutions bf Cu'2 and Zn*2 , which one is colotrred and why ? b) Name the ferrorhagnetig element in the first transition s#es. 2 + | 25. Write any three postulates of \,Lternei'S.theory | 3 26. ir) Wharaie ligands ? bive anexample for anionic bidenlate ligand. ' PART_D IVAnswer any THREE questions. Each.question carries Frl/E marks : 3 x 5 : I 5 27. a) Silver crystallises in fcc lattice. If edge length of the cell is 4.07 x lFt cm . anddensi tyofsi l veri s 10.5gcm-r, cal cul atetheatomi cmassofsi l ver. - 2 b) What is a semiconductor ? What type df extrinsic seririconductor is formed when Si l i coni sdopedwi t hBoron? . 2 What i st hepacki ngef f i ci encyi ri Bec? ' . . 1 'What is ieriri prmeable mbmbrane ? Give an example. 2 Write the mathematical formof Raoult's law of RLVP, Explain thesymbols. 2 Define molal defressionconstant. 1 Write the diagram, half cell representation and halfcell reabtion ofSHE. 3 What is corrosion of metals ? Mention any two methods of preventign of it. 2 At 250 C, rat e const ant of a chemi cal react i on i s 2. 4 x l 0r s-] . Cal cul at e t he ener gyof act i vat i on, i f i t sr al econst ant i s l x l 0- 3s- r at 400C. ( R- 8. 314Jl mol / KB Explain the cffect ofcAtalyston rate ofa reactibn. 2 What are adsorbate and adsorbenl? ' .) Expl ai n t he pr upar at i on i ' t r r ; ei ul so] : : l . r ' I r l r , : r i r ". cl cct r r cal nr ci hor l ( Ji r e i i i , i cr t i i r r r l : l c l L; hoi l r , : ' , ur r cr r i r ! . l l . r l - \ . ) , . , r I x 10 = "I' od"nq "n t 0 F.J l!' 3' ) write rdl s.L.urlit of rnolar conductivity. 4-. Flalf li$lxriod of a'firsi order,reaction is 3 min. What is the time required for the compl#ion rif 99.9% olthe same rebction 2 AmonqAl l ' and Ca2, , whi ch of t hese i s t hc besl coagul at i ng agent t ocoagul at e bl ood' l Gi ve ai erampl c f or a hal i de ore of al umi ni unr. C-r . 4 6r \ -, t ' c N a3A[ i ' c Wi i t concuse of hcl i um. F' , r \ : -4 t a\ \ con f l WritctlnIUPAC name of the comfound (Cl' tr)rCHCHCl, hcctone is convcrted into propane in the presence of Zn-Hg and conc llCl' t t : r nr c of l hi s r eact i on' ! 5. 6. 7. 8. 9 What i s t he 5 r l {) : 2{) 2i A llorvs 5 x 3: 15 ..- 0 28. a) b) c) 29. a) b) 30. a) b) 31. a) b) c) 1, t , ' : i I ,] I i 1 I 1; I 0 Nanrc lhc vitamin rvhich causes tbe dise ase beri-beri due to rts deficicncy I'AP.T_ B 1I i sl \ f l ' f l nr f i YI - t r ucsl i on: : . l : . r r cl r qt r t s{i or l c: t i ' r i cs' f \ \ ' O nr : r r ks ; 1 1 ' Draw adi auranr' of uni t cel l oJ' bcc. ] l o*' nr: i rl )' at onl s are pi esent i n i t 1 I 2. Calculatc rhe tinre required to deposit 1.3 g chronrium rvhen a cuneni of I t l r r oughasol ut i on of chr onr i t t r r r ( l l l I sul phat c. ( cq. nr ass of Cr = l i l i ) l t . 14. l - 5. 16. l't . 18. 20 l )cl l neordcrof a rcrl ct l on. (. i i vc l n cxl i rl l pl c i L)f l cl o or(i er I cact l 0l l Wri t c anv t rvo propert i cs ol ' l ant hanords. Crvg mxxnnl pl g cach I br l i t ri hydri c phcnol ant l a nri xet l ct hcr' Explain Etard' s reacrion. Whaiarcantiseptics ? Give an exarnple Explainsaponification. i - VAnsrver any FOUR quest i ons. Each quest i on carri cs I i I VE mark : 32. a) \ \ t ri t e anv t \ \ , o di f f erencc-. bet i vccn S. r and Snrrcrct rons. b) Lr pi ai n l : r i cr i cl - Cr al i ' s l ur cl i oi r \ \ r i l r r ( sl ) ! et r r r i hl ur u1r anr . , , . . c) Gi vean exarnpl e f or a gerni nal di hal i dc. 33. a) Horv i s phenol nranuf act ured f ronr cunrcne' l b) How does ethanol reacl with ethanoic acid ?bive equation. c) Write the general equation forWilliamson' s ether synthesis. ., 34. a) Give two tests to distinguish bewben aldehydes and ketones. . b) How does acetic acid react with a Ajnmonia ? Give equation. c) Among chloro, .fluorb, bromo acetic acids, which is most acidic ? 35, a) Explain Ho{Thann' s Bromamide reaction. : b) Explain carbylamine reiction. c) Give the gerieral fomrula of diazonium saltsl 36" a) Write Haworth strtrcture of a non -reducing sugar. b) What is denaturation ofproteins ? , c) What are nucleic acids ? Writq thq biological role of I-RNA. 37 a) Mention the monomers and partialstructure of terylene. b) How is buna-N rubber prepared ? G ivc equation. c) Give an example for a natural pol1.' nier. 4x5 20 I 2 2 ".,.. I 2' ' z ' 1 2 z I 2 I 2 2 2 I PAITT- C I I I Ansrver any. FI VI I quest i ons. [ , ach q uest i on ca rri cs ' f t I REE Marks : 19. a) Name t he f l ux usecl i n t hc cxt ract i on ol cast i ron f rom haenrat i t c ore. b) Erpl ai n zone ref i ni ng nre-t l rod f or t l rc pt rri f i cat i on of nret al s' ' a) Howdoes PCl , react wi t l t rvat cr 2 b) \ . l t i t e t he l onl ul a o{' t hc cont pl cx t on f orrrt ecl by t he conrbi nal i ori of Cu' i on anr. i amnron i a nt ol cct rl cs l - t 2 2 I 2 I 2 I 2l a) Howdoes conc. I -l , SO, reai t ri ' i t h coppcr' ' / Ci vc cqLri rt i orl . . . b) Name the producr lon' ccl u,hen su l' hur tl iox itlc reacts rvith clrlorine gas L2' r, ) Howi schi ori ; i e prcpal cd f ronr pot assi Lt m pct nrat t garl at c' / ' b) Wliar is aquaLegia ? $L 63 EF{EM] sTRY Time: 3 Hours 15 Minutes General Instructions: il The question paper has four parts A, B, C and D. iil Write balanced chemical equations and draw labelled diagrams wherever necessary. Max. Marks: 70 Il AnswerAllof the following. Each question carries one mark. [Answer each question in one word orin onesentence] 1l Whatis osmotic pressure? 2l Whatisaprimarycell? 3] How does tr,, of a second order reaction vary with initial concenffation of the reactant? 4l Name the catalyst used for the oxidation of ammoniato nitric oxide and water. 5l Givethecompositionofmalachite. [Each question ca 1U Whatare F centres? Explainwithanexample. 121 Write the Nemst equation for the Daniell cell and indicate the terms involved. 131 The concentration of a reactant X decreases from 0. 1M to 0.025M in 40 minutes. ff the reaction f ol l ows I order ki net i cs, what wi l l be the rate of the reaction when the concentration of X i s 0. 01M? 6f What is the structure of XeF6? What are enantiomers? How many particles are present in each unit cell of aFCCcrystallattice? 9l Write the IUPAC name of the organic product formed when bromoethane is heated with ethanolicKCN. 101 What.does the secondary structure of a protein specfy? 7l 8l rries two marksl 141 Givereasons: il The majority of transition elements exhibit catalytic properties. iil Most of the d-block elements form coordination compounds. l5l What is Hinsberg's reagent? How is it useful for distinguishing between primary, secondary and tertimvamines? 161 An alkyl halide is heated with sodiumin dryether. Name the reaction. Give the general equation. iil AnswerAI{Y F'[VE of the following @n 171 What are functions. "Histamines"? Give some of its l8l \\-hat is copolymenzation? Illustrate with an eramDie.t iiil AnswerANY FM of the follouing [Each question carries 3 marks] 1el 201 2rl 22) Explain the terms calcination and roasting with suitable examples. Dry chlorine (in a limited supply) is passed over heated white phosphorous to form a compound X. X is made to react with ethanol to form an organic compoundY. Yis heated with an alcoholic solution of KOH to form an organic compound Z.Identrfy X, Y and Z.Wite equations for the reactions involved. How is ozone layer useful? Explain two factors that pose threat to the ozone layer. Complete the following equations: I Fz+ZCl - - + i i l 2Ca( OH) 2+ZC12- - > iiil NH3+3 C/2(excess) -+ 231 il Calculate the magletic moment of Fer+ ion' iil The electroruc configuratio nof Cr rs 3d5 4sr instead of 3d4 4s? ' Give reasons' iiil Name a transition metal that does not exhibit variable oxidation states. Write ionic equationfor the reaction of permanganatewith il Oxalateions in acidic medium i) Fez* ions in acidic medium UsingVBT, account for the geomeny and magnetic property of INiCI+1Z- given atomic number of Ni = 28. 241 2s) 261 Give the IUPAC name of lPtCI2@n) 2lCl2' Draw cis andtrans isomers sllPtCl2@n)zl2* ion and the dextro and laevo forms of the cis form' AnswerANY THREE of thefollowing' [Each question carries 5 marks] 271 Whatis a crystal tattice? Draw the unit cell of a body centred cubic lattice and calculate the packing efficiencyintheBCC crystal lattice' t5l 281 al Thevapourpressureofpure A isT0mmof Hg at 25 "C.It forms an ideal solution with B in which the mole fiaction of A is 0'8' If the total vapour pressure of the mixture is 84mmof Hgat25 "C, whatwillbethe vapour pressure of pure B at the same temperature? bl What happens to the solubility of a gas in a liquid with increase in pressure? Write the name and statement of the law on which your answer is based. 13+21 29) a] Calculatethe standard emf of the celi at 298K in which the cell reaction rs: Cul r ; , +2Ag' , , , qt + C, r l - - r - l - {gt r ) Given the equilit' nurrl .-trlf i-r:]l ' ' l the reaction i s 3. 91' l o15' bl \\-hat i: lin::::": Ktrhln:*x: ' ": * l.rrli [*f':!::r : : , ' -i : - : ; *-: i r i t i ' ? St at e . ; *-riE:rL,J,;:: migfatiOn Of c * -"-l ' ..-:'-.:tr1e example. E@ 13 +21 301 a] The velocityconstantofafirstorderreaction \+' as found to be 1.2 x l o-a s-l ancl 2. 4x10as- l at 300K and at 3l 0K respectively. Caiculate the activation energy given R = 8.3 14,IK-r mol-r bl Prove thatthehalftifb pcriod *fafirstorder reacti on i s i ndependent of the i ni ti al concentration cfthe reactarrts. L3 +2] 3 I I a] What is peptisation? Describe the preparation of a positively chargedAgl scl and a negatively charged. AgI sol from .4gN03 solution and Klsolution. bl Explain tlte temrs electricai double layer and zeta potential. [ 3+2] 32] a] Mention the rnajor product formed in the followingrcactions: d Propene is treated with diborane follolved by oxidation using hydrogen peroxide in an alkalinemediurn. iil Nitriles are hydrolysed in the presence of an acid. iifl Sodium phenate is heated iodomethane. bl Write the structural representation of Sp 2 mechanism using the hydrolysis ,rf methyl bromide as an example. [ 3+2J Answer AITY FOUR of the following. [Eaeh question carries 5 marksl 3sj al 361 al b] Givercasons: il Aryl halides are extremely iess reactive towards nr:cleophilic srrbstifirtion. i{ An elecmrr withdrawing group increases the aeid strength of phenol. [ 3+2] A ketone is treated with hydrazine to form a cornpound X. X is boiled with KOH in ethylene glycol to formY. What are X andY? Name the reduction. furange tlre fallowing in the inereasing oider E'rf their acidic skength in aryreous tnediurn: Acetic: acid, moncchloroacetic acid arid propanoic acid. Give one reason for the trend *bserved. {3 4- 2} Mention trryo differences in the structures of am;viose zurci amylopectin. Write the I Iaworth's structure of the monomer of starch. Give ar"l exeimple for each ofthe following: il asulphurcontaining u- anr.ino acid. bl 331 aI 3al al bj tiVrite equations for each ofthe following: ij ReirnerTiemannreacticn iii Flttigreaction Oxidation ofacompound P givcs aproduct Q r.r'hich reacts wittr phenyl hydrazin* but does not ans'wer the silver mirrar test. Name the conrpounds I) and Q. [3 + 2] Write equalions for each of the fnilowing: i.l Roscninund reduction ibr tbre preparaticn of benz-aldeh,vde. iii Aldol cernri*nsaticn trrking ethanal as an example. a iiil Decarbcxylation. d a globular protein. 37] aj lixplain iruith anexample, the formationaf li anaddition pe-"lymer. ii] a condensa'rion pol}rm*r' Iriame the rnonci-ners of Buna- S. (iive an exarnple of a thermoplasti*. bl [ 3+2] [3 +2J roE EMI STRY EI il f Vax. Marks: 70 Ti mc: 3 Fl ours 15 Mi nutes Generul Instructions? i] The question paper iras four parts A, B,.C and D. ii] Write balanced chemical equations and draw labelled diagrams wherever necessary. Il Ansn'erALL ofthe following. Each question carries one mark [Answer each question in oneword orin one sentencel I I What is the unit ofthe rate constant for a first order reaction? 21 Give an example ofa network polymer. 3l Define afrrel cell. 4l What is the dispersion phase in a gel? 5l WritetheIUPACnameof lcr1unr1, @2o\f ch. Why is l-lelium used in filling air ships and balloons for wcalher shrdyz What is the gencral electronic configuration ofthe 3d series? Name the most suitable oxidising reagent for the conversion of a primary alcohol to an aldehyde. Give an example ofa non-narcotic drug. Which vitamin deficiency causes pernicious amemia? 6l 1l el l 0l 8l iil Answer AI{Y FIVE of the following [Each question carries two marks] I l] Calculate the number of particles per unit cell offcc? What is the osmotic pressure of a 5%o (#v) solution ofcane sugar at 288 k (mol. mass ofcane sug,r:342 gmol-r, R: 0.0821it atm k-r mol-' ). Write the symbolic representation and cell reaction forthe Daniel cell. l5l Write the modified Arrhenius rate equation and explaintheterms involved in it. Mention an)'nvo uses of phenol. How <io ,vou prepare benzaldehyde by the Gatterman-Koch reacti on? 18] In what u'av is sucrt-1a-qe a superior sweetening agent than aspar.:-me' t2l l 6l 17l Explain the extaction of Ni by Mond's process. l 3l iiilAnswerAIIY FM of the following [Each question carries 3 marksl : 01 ' 1 1l - r I , 9] Describe the extraction of Aluminium from purified Alumina Explain the laboratory method for the preparation ofdinitrogen. Explain whytransition mctals and their compounds show paramagnetic behaviour and also calculate the,magnetic moment ofa divalent ion in aqueous solution ifits atomic number is 26. 22] How does acidified grotassium permanganate react wittr d lron(II)ion if Oxalateion rnl HzS Write ionic cquations for the reaction. 231 Mention the conditions required to maximise the yield of ATf3 and write the flow chart for its manufacture. 24] Write any three postulates of Wemer's theory of co-ordination compounds. 25] On the basis ofthe valence bond theory explain why [co( NH)o]3* forms an inner orbital complex. 261 Explain why F2 has a smaller enthalpy of dissociation compared to that of C I 2? Answer AI\Y THREE of the following. [Each question carries 5 marksl 271 al Calculate the packing efficiency in a body centered cubic crystal (bcc). bl \Vhattype of stoichiometric defect is strown byZnS? [ 4+ 1] b] Calculate the equilibriurn constant of the reacrion Cu6.1 + ZAg* + Cu(iq1 + 2Ag6y Given E\utt =A.46V [ 3+2] 301 al A first order reaction takes 40 minutes for 30% decomposition. Calculxe t i. b] Define threshold energy" [4 + I ] 3l ] a] Describe sorne features ofcatalysis by zeolites" bl Give reason: Finely divided substances are rnore effectively absorbent than their crvstalline form. [ 3+2] 281 aj bl 2e) al State l{enry's law and mention twc important applications. Give two differences between an ideal and non-ideal solution. 13 + 21 Suggest any three methods ofpreventing the rustingofiron. Answer ANY F'OUR of the following. [Each question carries 5 rnarksl How do biphenyl? you convert chloro benzene to Name the reaction. b] Explain Finkelstein'sreactionwithanexample. [ 3+2] E! E 321 al 33_l al Write the rnechanism of dehydration of alcoh ol. bl How is anisole prepared from phenol? [3 - 2J 3a] a] Explain',vlry mo*ochloroacctic acid is a shonger acid than acetic acid. bJ Vttrat is cross aldol conclensation? prring cross aidol condenraiio& since tle reactents contain cr Hatcnrs, lxrw many produc,ts will be fsrmed ir:alrrixfire? c.l F-lanne the reagent used in Clemmenson reducti on. [2+2+l j (iirc a rcason: Although the arnine group is an O ad P directing group, aniline on nitration Eats a r$stantia! arnount of M-niftoaniline. De$nt'e tbe carbylamine reaction. .frra:g the tbliowing in the increasing order ofrtbbasc strength c6/ / < l H: , cl i 3j i H2, i #/ : . 12+2+l ) \lrite tre ]Ia*orth stn-lc,h:Je for sucrose. Mention the biologiel importance of RNA. [ 2+3] Write a note on tlre vulcanisation of rubber. Define thermoplastics and thermosetting pobrners. [ 3+21 caralysed l5l 4 361 al bl 371 al bl i. EHEMI STTRY Time: 3 Hours 15 Minuts Gmeral Instruellons: il The questioa paper has fuur parts A, B, C and D. iil Write balanced chemica! equations and draw labelied diagrams wherever necessary. Max. Marks:70 Il Answer ell of the folliowing. Each question earries one merk, [Answer etch qir$tion in one word or in one sntcncel 1l StateRaoult'sLawotRelativstowerirgof\iryour pressure. 2l Narne the organic product formed wtren phenol is treated wittr excess ofbromine rvater. 3] Silicon ard germanirmn are rcfirrcd by ...........-... 4l Write the IUPAC name of acetaphenonc. 5l Wluarehomollpticcomplexes? 6] Whichistlre sbongestredrrcing ageata.mongtl* hydrides of Soup I 5 elements? The SRP values of AL and Ag af,e * 1.56V and +0.80V respectively. Which of these is a more powerful reducing agent? What will happen to the half life period of a first order reaction ifthe temperature is incpssed? What type of magnetic behavior is shown by tk sc3+ ion? Name avitamin, the defieiency ef which gives riseto scurw? n 8I el l0i iil Ann+'creny FIVE ofthefollowing [Erch guestion carries two marksl 1U Wrise the IUPAC names ofeach ofthe following iJ [Co(ivrl3 )6 ] [Ci(CN)6 j and iil ffa3[Co(Or):] Explain linkage isomerisrn with an exannple" [-low is methanol canverted inta ethanoX? Caleulate the number of particles present in eaeh unitcell ofaBCC crystai lattiee" Give reasons foreaeh ofthe following: { Benzaide}r}'de r-rndergres Cannizzaro's rwiion ir] Acetophenons does not react with sodium bisulphite solution. Write the Nernst equation and indicate the terms involvd. What are analgesics? Give an example. FIow is phenol com'erted into salicyfic acid? Write the sfiucfurai sequence. t2l l 3l 141 r6l !7j 181 l sl HTE iiilAnsw'er en1. F[\T sf L! fnilm:mE , [Each questbns cerrics -1 rri'*, 20) 2rl 19] Write the postulates of Werner's theory of coordination compounds. Descri be t he shape and st ruct ure of IC o{N fu) 6J3* ion using the Valence bond theory. Predict its magnetic properly. Draw a neat labelled diagram ofthe Blast fumace and explain the reactions involved inthe extraction ofcast iron from haematite. 22] With the help of a florv chart, outline the various steps which are involved in the manufacture of sulphuric acid by the Contact process. :-1] Ii.' ; -; ;.::a.: *- :,;:tromate prepared from Pu:.:+:;,-: n:-- :' fY 24] Name ihe ::-e-' : : *is - ' :"-'''*. Eransition series that i] does not d.isp.a-e :: J-r-J_ieii rom dilute acids ii] forms colourless i31r l:i is -l oxidation state iid canexhibit+Z oxi.t"tion Eate 25] Complete the following equanons: il 3clz + 6NaOH (hot and conc.) -+ 4 XeF6 +3II2A -+ f, SOz + Cl2 -+ 261 Describeeachofthefollowing: il Passivi$'ofaiw'ninium iil Brownringtest 271 al bl 28] al 2e) al Calculate the packing effrciency in a simple cubiccrystal lattice. Give an example of metal deficiency defect. t 4+11 q The molal elevation constant of water is 0.520lkg. Ifa solution of 3.759 ofa non-volatile solute in 50g of water has a boiling point of I 00.95C, what will be the molar mass ofthe solute? Describe any two applications of Henry's Law. [ 3+2] With the heip of a schematic diagram, describe the working ofa hydrogen-oxygen fuel cell. Answerany THREE ofthefollewing" [Each questions carries 5 mark! 30"1 al bl 311 al bl State Famday's First {"aw ofelecfiolysis. [ 3+2] Derive a* integrated rate equation for the velocity constantofa first order reaction. A first order reaction takes I 00 seconds to be 50olo complete. Calculate the rate constant and the tinne required for the reaction to be 75olo connplete. [ 3+2] Bring out any three differences betrveen lyophilic colloids and lyophobic colloids. fr4ention any four characteristics of enzyme bl bl E@ catal,vsis. [ 3 +2) i ::] a] Mention the major product formed in the followingreactions: ilA haloalkane is heated with an alcoholic solution of silver acetate. iilAcid chloride is treated with dialkyl cadmium. i i r] Acet one i s oxi di zed usi ng sodi um hypoiodite. Answer any FOUR of the following. [Each questions carries 5 markl 361 al bl il Aromatic amines cannot be prepared by the Gabriel phthalimide synthesis 13 +21 351 al Describethesynthesisofeachofthefollowing starting from benzene diazonium chloride. i] benzcne ii] iodobenzene iiii pHydrox y azobrrzene bl Howisbenzamideconverted into aniline? t 3 +2J Describe the formation of a nucleoside and nucleotide. What is a zwitterion? Write its general structure. Name an amino acid hormone . 12 + ?+' 1l What are thermosetting plastics? Name the monomers of Buna-N and write its oartial strucfure. What is saponification? Write the equation. 13 +21 bl 331 al 3al al bl cl 371 al bl How do aldehydes react with monohydric alcohols inthe presence ofdryHCl? Write equations for each ofthe following: i] Swartsreduction. ii] Stephenreduction. iil Etard'sreaction. Complete the following equations : I ROH + SOCI2 + il RCHO + NH2OH --> Describe Gabriel phthalimide synthesis. Give reasons for each ofthe following: d Aniline does not undergo Friedel-Craft reaction. bl EE EHEMI ETRY Time: 3 Hours 15 Minutcs G en e rsl Intitrueticns : i] The questi{tn paper has four parts A, ts, C and D" iil Write balanced chemical equations and draw labeiled diagrams wherer.er :t3:e:.sa- Max. Marks: ?0 trl Answer ALL of the following. lj DefineVantHoffsfactor' 2l WhatisaPrimarycell? 3] Write the ciremical fonnular fbr the rate equation 4l lV1ention ihe method by which Nickel can be puified. i51-) woUle gases have very low meiting and bciling pints, why? 6] What is the condition iur arr eiement to shou' pararnagnetic pmperiies ? 71 WhatareEua:itiomers? Sl Whichbp* ofaidefu''d* underg+es Cannir*r*'s rea4.?i*nT 9j Why e:irt'i vigalni* C be stored i*';ur body? 1 0] \\hat a'e ?r*. .'.+*ilir$:rs? orrater** -]r#=#=fi# II] Answerany FIVE +f thefcllawing' 1U r 1t t Ll What are interstitial defocts a'ld tefahedral voids? State and explain Kcthirauseh's law of Indepienclent Migration trf lons. Write the Nernst equation r'vith an oxidation- reduction reaction for the c*ll t ^, t l hrg(.,.) i1u g;i, iic u;., 1c u 14] ldenti{r the rea*iicn order from the following rate cff$ta5fis: { K"- 2. 3 r: l t J 5 Lmol r$*r n] K=' l x t f t + 5- t I 5l \foh3, is Cr:' rer-iucing and ll{nr. oridising l'r na'iure w'hen both have a d{ cor'figrnati**? 16j tlxplaln lViliiamsc-:n's ether s;:elhesis wish ;rn exampi*. 131 E@ Explaigrhe su6tr,. tel l n CHr ' C=N*CHr - Mg- Br @f t ' > A rf/s:o , g IdentiftAandB. method of bleaching Alumina from 201 Write the reactions involved in the manufactuie of Sulphuric acidby Contact Process. 2l] Describe the preparation of ozonised oxygen. Name the oxidized product obtained when ozone reacts with lead sulphide. 221 Explain the large scale preparation ofNitric acid byOstwald's process. What is chemotherapy? Write the name of the medicine usd for the fieatrnent ofpneumonia. 23] E AlainthepreparationofPotassiumpennanganat from MnO, \ 24] Write any three similarities benveen tanthanoids andActinoids. 251 [ Explainhydrate isomerismwith ane:<ample. ifl Write the IUPAC name of Kr[CO(NOr)ul 26] Discuss the nature of bonding and magnetic reaction ofTenaryaonickelate (tr) ion, [Ni(CI$)4F- on thebasis ofthe valance bond theory. IIII Answer any X'IVE of the following 271 What is packing efficiency in a crystal? Draw the unit cell ofa bcc stnrcture and calculate the packing efficiency in a bcc lattice. 281 al 45 gofethylene glycol (CrI{uOr; is mixedwith 600 g of water. Calculate: d the freezingpointdepressionand iil the fieezing point ofthe solution b] State Henry's laws and give anytwo applications ofthe law. 291 4 Calculate the emf of the cell in which the following reaction takes place. Also represent thecell. MB'+ 24.9.(0.0001 M) + Mg2-(0. 130 M) + 2Ag,u 3x5=15 bl A solutionofNi(NOr), is electolysed between platinum electrodes using a current of 5 A for 20 minutes. What mass of Ni is deposited at the cathode? [Given atomic mass ofNi: 58.4 301 al Explain the effect ofacatalyst on therate ofa reaction bl The rate constant of a first order reaction is 1.5 x l0{ S-r. What is its half life period? 3ll al Distinguishbetween Lyophobic and Lyophilic colloids. bl Whatisfoam? cl Descri be Bredi g' s arc method for the preparation of gold solution. IVf Answerrny THREEof the following questions @E Vf Ansrcr rry tWldt- - L3!- 4x5=20 321a] Expl ai nS*l mechani smwi t hanexar npk. i l . . t *wsr ysr eact i onwi t hasui t abl e bl Explain the action of alc. AgCN on haloalkanes ,. witiranequalion. 33] a] Expl ai n the conversi on of propene to 2-propanol with an equntion. b] Name the major product fonned when acetone is heated with tr-iAll'{4. c] Explain Reimer-Tiemann reaction. 3al al l{ow do you prepare carboxylic acid from Gri.gnard's reagent? Write the reaction. bl tlhat is the llell-Volhard-Zelinsky reaction? Giveanexample. srTfn" bl f-riE tu LB{C re ofAniline. clBplirffitoaniline withaneryalx- 361 al What isaZwiuerfurr?Gireitssuucture. b] What is the ditrerence berurcen a nwleoside and anucleotide? c] Write the Llaworth stmctune of stuose. 371 al Describe the free radical mechanism for polymerisation of Etlrcne. b] How is Nylon 6, 6 manufactured? ,r[,E E! HEMI gI TFI Y Time: 3 Hours 15 Minutes General Inslructionsi i] The question paper has four parts A, B, C and D. iil Write balanced chemical equations and draw labelled diagrams wherever necessary. Max. Marks: 70 Il Answer ALL of the following: U Whatare isotonic solutions? 2l StateHenry'slaw. 3] Define zero orderreaction. 41 State Faraday's 2nd law ofelectrolysis. 5] What is sorption? 6j What is tlre role of lfune stone in the exh'action of iron? 7l Helium is used to fill ainhips and ballons why? 8] Narnethe Ileteroeyclicnitrogenbasepresentonly in DNA butn<rt irr RNA. 9l Mentionthe majorproductinttre followingreaction C2 I'IsBv +AgCNsu1.., -ie!-t tOl Aldehydeshave lowboitingpoirf than alcohols of comparable molecular mass. Why? iil AnswerANY- FIYE of the following ru t2l Explain F'renkel detbct. Name the factors influencing electrolytic conduclance. What is apseudo unimolecularreaction? Give an examplc. What is Lanthanoid contraction? What is the common oxidation state shorvn by Lanthanoiclcs. Explain Kolbe's reaction with an exarnple. Explain nitration of Anisole with an equation. Give cquations forthe reactions ofaldelryde with hydroxylamine and Sodir:m bisulfite. What are tranquilizers? Give an example. l sI l 6l t7l l 3l l 8l r41 @E iiil AnswerAl\fY FTIII of tlc ffri4 1 9.1 Explainthe extraction ofaluminium from purified bauxite by Hall-Heroult process. 20] Mention thrce anamolous bchaviours offluorine. 2ll Describethemanufactr;re ofnitic acidby Ostwald process. al Explainthe actionof conc. HrSOo on oxalic acid crystals with an equation. bl Write the structure oforthophosphoric acid. a] Explain linkage isomerism with an example. a] Calculate the percentage of making efficiency inabcc unitcell. bl A metal crystallizes as fcc lattice with edge lenglh 450 pm. Ifthe molar mass ofthe metal is 50g mol'-r, find the density ofthe metal. 13 +21 a] Derive an expression for first order rate constant of areaction. b] Ihe rate of a reaction increases 4 times when the temperature changes from 300k to 320k. Calculate the activation energy (R:8.314 J/IV mol). 291 ^lCalculate std. free energy change for the reaction Znlg +2Ag@d + Z 12+ + 2Ag6y Eo cell : 1.56V and F : 96.500 C mol-r. b] r*tat is a Mptic mmPlex? 241 Using LtsT. erplarn IiEgoomeq'andmagnetic property of [Co {\I{ t.f comPlex. a] Transition metals ard tbeir compounds are good catalysts. Explain. b] Give the outer electronic configuration of Manganese. (At.No.25) al HowdoesKMnO4 reacts withlls in neutral medium?Giveequation. b] What are intrstitial compilrnds? b] Give equations for the cell reactions taking place at anode and cathode in a button cell. c]Whatiselecfochemicalseries? 12+2+11 301 al The b.p. of benzene is 353.3k. When 2gof a non-volatile solute was dissolved in l00g of benzene the b.p. increases to 3 54.2k. Calculate the molar mass ofthe solute. (\ for benzene: 2.53K kg mol-r) bl What is a non-ideal solution? Give an example. [ 3 +2) 3 1] a] Explainthemechanismof,en4ane catalysis. bl What is (i) peptisation (i i) electrophore sis 13 +21 zsl 221 231 261 271 281 AnswerAhlY TIIREE of the following. E@ AnswerAIYY FOUR of the following : 321 331 a] Write the S*2mechanism forthe conversion of bromomethane to ethanol. bl Explain Wurtz-Fittig reaction with an o<ample. cl WhatisDDT? a] LIow is phenol manufactured from Cumene? bJ Complete the following reactions: il R- cHzoH c' o' >? 11cH' - c- cl n clHl a] Explainthe following reactions with an example. f, Aldolcondensation i[ Gattermann - Koch reaction b] Give equation for the conversion of acetic acid to acetamide. l2+2+lj 351 al How do you convert nitrobenzene to amhnel Giveequation. b] Explain carbylamine reaction. c] Methylamine is a shong base than ammoaia Cne reason. L; . - -- . - -qu- " 573k' 361 371 a] Write the Hawortlr strucnre ofMaltose. bJ What is a peptide linkage? How many peptide bonds are present in aheptapeptide? c] Name the vitamin responsible for ccagulation ofblood 12+2+ 1l a] What are thermosetting polymers? Give one example. b] Explain vulcanization of rubber. cl What are biodegradable polyrners? l2+2+ ll 341 EE ,l'i fi ,:i: :r::'ili I .ti: t ,, -ili j.:i ,'' '""iii " ij li 'f',-,t4',,lr;i t: o, j j ]#F' ,_,., , t j i l l l : . , . . 1l I ' hJr. l :;{ I @l E 1l What is osmotic pressure? Ans: The extra pressure that must be applied on the solution to just stop the flow of solvent from i t s si de t o t he sol ut i on si de t hr ough a semipermeable membrane is called osmotic pressure. 2l What i s a pri mary cel l ? Ans: In a primary cell, the reaction occurs only once and al' ter its use over a period of time the battery becomes dead and cannot be reused agai n. 3l I-Iorv does t,., of a sccond order reaction var y r vi t h i ni t i al concent r at i on of t hc rcact ant ? Ans: t 172 of a sccond or der r eact i on wi l l be i nver sel y pr opor t i onal t o t he i ni t i al concentration of the reactant. 4l Namc t hc cat al yst used f or t he oxi dat i on of ' ammonia to nitric oxide and water. Ans: Pt/Rh gauge. 5l Give the composition of malachite. Ans: CuCO3.Cu(OH)2 / CU2CQ(OH)2 6l What is thc structure of XeF5? Ans: Distorted octahedrai. 7l What are cnantiomers? Ans: St er eoi somer s r el at ed t o each ot hcr non-supetimposable mirror images arc t:rr l, enantiomers. 8l l l orv many part i cl cs arc prcscnt i n ci rch rrrr cell of a FCC crystal latticc? Ans: 4 9l Write thc IUPAC namc of thc organic pror lrrr f ornrcd when bromoct hane i s hcat crl r' ' i l ethanolic KCN. Prnnaneni t ri l e What docs t he secondary st ruct ure (, 1 protein speciry? The secondary structure ofa protein rclbls t r t l r shape i n whi ch a l ong pol ypept i dc cl , rr can exist. Ans; \ 101 i Ans: l l l What are F cent res? Expl ai n wi t h an example. Ans: F+entres (from the German word Farbenzneter for colour centre) are anionic sites occupied by rupaired electrons. They arise as aresultofmetal excgss defect due to anionic VacAncies For examplc, if crystals of NaCI are heated in an atrnosphere ofsodium vapour, the sodium atoms are deposited on the surface ofthe crystal. 'Ihe CY- ions diffirse to the surface ofthe crystal and combine with Na atoms to give NdCl. 121 Write the Nernst equation for the Danicll cell and indicate the terms irrvolved. Ans: The Nemst equation for the Daniell's ccl I r:rrr r lr expressed as: F- r +J r; .. = Fo .. ^ RT ,,,V:) ". ' el l - ccl l - "' f r, 1 nr LCr, ) E. ux i s emf of t he cel l -n L" rr11 i s st andard enrl ' of t hc ccl l . R is universal gas constant. T is absolute temperature. r number of clectrons transfcrrcd itt lltr' , ,' reaction which is 2 for the Danic:l ct' ll F is the Faraday constant. , , , , , [ 7- n2*1 1! t heconcen! "at i ot *. 1i T, 10*, r lcuz t'f is theconcentralionof copP0r ions, : . ' : , 1 . , ), : : ijt l' hc conccntration ofa rcactant X dccreascs frorn 0' 1M to 0' 025M in 40 minutcs' If the reaclion follolvs I ordcr kinetics, what will bc t hc r at c of t hc r bi ct i on r vhcn t he concent l a(i on of X i s 0' 0l M? Ans: 0. 025M i s l / 4' r' of 0. l M' I n ot her words' t he rsactiorl is 3/4' h complele or 75o/o complele' l:'or a first order reaction, l7so1i =2t112 = 40 mins [given]' l' hcrefore, 1172 = 20 rnins k .,.!Lf!-= ii:l = 0.03465 nrin-l t t i z 20 mi n' t Iior a first ot' der reaction, Rat e = ' t [ R] = 0' 03465 mi n-r x 0' 01 M = 0. 0003465M mi n-r = 3' 465 x 10-aM rni n-' ' 14] Gi vc reasons: i l -l ' he maj ori t y of t ransi t i on cl cment s exhibit catalYtic ProPcrtids' Ans: i l Most of t hc d' bl ock el ement s f orm coordination comPounds. The catalytic properties of transition metals: ii ascribed to th9ir ability to adopt multiole oxidation stdtb5' and' to form : con]plexes. Tr ansi t i on met al s f or m comPl ex comoowrds dueto tle comparatively smaller sizes of the metal ions, their high ioniccharges l9l Explain the terms calcination and roasting with suitable examPles. Ans: Cal ci nat i on i s a process of heat i ng t he concentrated ore in tlre absence of air' The volatile matter escapes leaving behind the metal oxide. For example, when ZnCO3 is calcined CO2 escapcs leaving behind Zr0 ' ZnCO3 -+ ZnO+CO2 ' /::i l.ly i i l and the availabilily ofd orbitals for bqnd formation. t5l What is Hinsbcrg' s rcagent? Horv is it uscful f or di st i ugui shi ng bct wccn pr i mar y' sccondary and tcrtiary amincs? Ans: I -l i nsbcrg' s rcaget rt i s benzene sul phonyl I chloride. Wi t h a pr i mar y ami ne i t f onns a whi t e precipitate which is soluble in an alkali' Wi t h a secondary ami nc i t l brnrrs a whi t c precipitate which is insolublc in art' al-kali' With a tertiary aminc it does no1 form any precipitate. 16] An al kyl hal i dc i s hcat cd wi t h sodi um i n dr1' ct hcr. Narnc t hc rcact i on' Gi ve t hc gcncral cquat i on' Ans: Wurtz reactlon 2utr 1' 2Nu -+ R- lt t 2Nd' l 7l What arc "l l i st ami nes"? Gi vc somc of i t s functions. Ans: Histarnine is a potcnt vasodilator' It contracts the smooth muscles in thc bronchi and gut and relaxes other muscles such as those in the walls of fine blood vessels. @1 *nu, is copolymelization? Illustrate {vith an cxamPlc? Ans: Copolyrnerisation involves polymerization of di f f erent monomers. For exampl e, t he polymerization of Buta-1, 3-diene with -styrene resulting in the formation of Buna-S is copolYmerization' Roast i ng i s a process of heat i ng t he concenhated ore in a regular supply ofair at a temperature below the melting point of the metal. Generally, sulphide ores are subjected to roasting. For example: ifzinc blende (Zn$is roasted, it gets oxidised to ZnO givingoff SO2 which escapes as a gas 2ZnS +3O2 -+ZZnO +25O2' iEESI @E 201 Dry chlorinc (in a limitcd supply) is passcd ovcr heated whitc phosphorous to form a compound X. X i s madc t o r cact wi t h ethanol to form an organic compound Y, Y is heated with an alcoholic solution of KOI' I to form an organic compound Z. Idcntify X, Y and Z, t #r i t e cquat i ons f or t he rcactions involvcd. Ans: X is PCh,Y is chloroethanc and Z is ethene Po + 6 C12 -+ 4PCl3 3C2H50H + PC' lj -+3C2FI5(' l+ H{O3 C2H5C| + KOH -+C2Ha+ KCI+ FI2O 2ll How is ozone laycr uscful? Explain hvo factors that pose threat to thc ozonc layer, Ans: The ozone layer protects thc earth's surlace f r om excessi ve concent r at i on of l - l V radiations. Nitrogen oxidcs (particularly nitric oxidc) emitted from exhaust systems of supersonic l et s mi ght be sl owl y de pl et i ng t he concentration ofthe ozone layer. Another tfueat to the ozone layer is probably posed by the use offreons which are used in aerosol sprays and as refrigerants. 221 Completc the following cquations: il Fr+ZCl- -+ i i l 2Ca(OH)2+2C12 -+ iiil NHj + 3 C/2(excess) -> Ans: i l F, +2Cl - - +Qr +2F- iil 2Ca(OH)2+2C12 -+ Ca(OCl)2 +CaCl t +2t l 2O iiil N//r +3C12-+ NCls+' .l.flCl 231 i l Cal cul at e t he magnet i c momcnt of - 1. r , 1, e - toD. i i l The cl ect roni c conf i gurat i on of (i . i s 3r l 54s1 i nst cad of 3cl 4 4. t z . Ci vc rcasons. i i i l Name a t ransi t i on met al t hat docs not .exhibit variablc oxidation states. Ans: rl tt="[,fu*r=!qs.A =Jts =s.gzau irl 3ds4rl has extrastabilitydueto halffilled subshclls iiiJ Zinc or Scandium [any one] 241 Wri t e i oni c equat i on f or t he rcact i on of permanganatc rvith i | Oxal at e i ons i n aci di c mcdi uur iil Fe2+ ions in acidic mcdium --> 2Mn2+ + 8I{.,o + loco2 iil 5Fe2+ + Mnoa" +8H+ -+ MnZ* + 4H ro + 51' c3+ 251 Using VBI account for thc geomctry and magnet i c propert y of [ A' i Cl a] 2* gi vcn at omi c numbcr of Ni = 28. Ans: Nickel is in +2 oxidation state. The orbitals oll Ni2+ ion are: n[r One s and t hrcc p orbi t al s ur. t yt ri a; r. a . , . r. 1 therefore the hybridisation is spr. Consequentll,, the compiex has a tctrahctiral geometry. ^ . . . ) r The conf i gur at r r r n of - Ai ' ' JI i ! ' r acccpl i r g electron pairs flom ligands bccorrcs: 1l t l 1I T t Four c- Pairs fiom 4 C/ - i ons 1' he compl ex i s pat amagnet i c due t o t he Presencc of2 unPaircd electrons i ' ZOf Ci n. t hc I UPAC namc of I Pt C' 12@n)2l Cl t ' Dr aw ci s and t r ans i somer s of 7Pt cl "( cn) 12+ i on and t hc dext r o and lacvo forms of the cis form' Ans: Di chl or i dobi s ( et hane *i , 2- di ami ne) piatinum (lV) chloride T ( . t - 1z* [ ct 12* I t , . r, I l ' ' xj f -i ' l l al i ' --. I I a' i " I l'"J\_,/ | I b,,J __l , Dextro Laevo ' ci s - 1. I c/ l ' - l r t i"r--i,:),, I | '.--U lt-, I LCI I trans 271 What is a crystal lattice? Draw the unit cell ofa body centred cubic lattice and calculate the packing efficiency in the BCC crystal l at t i ce. l 5l A ns : A rcgular tlucc di mcnsional arrangement of points in spacc is called a crystal latlice' BCC unit cell ln A DIiD b2 =c, 2 +a2 =2a2 a is the edge length b is thc lace diagonal I n AAFD E ) L1 ) ^1^2 t ' = t l ' ' l t ' - t t " I l Lt " = ) ( l c i s the body di agonal r : , . . c=Vj xa=4f r is the radius of thc sPhere 1r ut "F J3 An unit cell o1u gClC crystal lattice contains 2 spheres. -lbtal volume of the unit cell nil DrflI ' , ( qr ) ' l J: i Packing efliciencY Vol unt e occt rPi ed bY 2 sPheres . . , ^^ _ - x t wv Total volume of the unit cell z*( l n t \ = \ 3, / *1oo=68% [ +' ) ' tEl al Thc vapour pressure of pure A is 70 mm of Hg at 25 oC. It forms an ideal sol ut i on wi t h B i n rvhi ch t hc mol e fraction ofA is 0.8. If the total vapour prcssure of the mixturc is 84 mm of Hg at 25 oC, what wi l l be t he vaPour pr essur c of Pur e B at t he samc temPeraturc? b! What happens to the solubility of a gas in a liquid with increasc in pressure? Writc the narnc and statement of the law on which Your answer is based' [ 3+21 281 bl P A and P s are the partial vapour pressues ofA and B respectively. l) , and I' ,, arc vapour pressures ofpure A and pure B respectively. .r'1 and xg are the mole fractions of A and B respectively in the liquid mixturc. If the mole liaction of A is 0.8, then the mole fraction of B : 0.2. Vapourplessureof the mixture : P.,t + pB 64=xAp, +xBpB 84 = (0. 8) 70+ (0. 2) p", 84=56+0. 2 p' s o" = 28 = 140 nrm of i l e 0. 2 The solubility ofa gas in a liquid increpses wi l h i ncrcasc i n prcssure. I t i s based on thc Ilenry:5 Law which states that the solubility o1 a gas in a liquid is directly proportional to the pressure ofthe gas. Calculatc the standard cmf of the cell at298K in which thc ccll rcaction isl ^ ^, + . - 2+ Cu6r +2Ag- pn, - + Cu' - gq) +2Agr 1 Given the equilibrium constant of the r eact i on i s 3. 92x1015. What is limiting molar conductivity? State Kohlrausch' s law of indcpendcnt migration of ions. Illustratc the larv rvith a suitable cxample. [3 + 2] ^ n nsql E. u. , , rt = Y l og K. . . at 298K 0. 0591 1 l og -1. 92 x l 0' ' - - 046V Li mi t i ng r nol ar conduct i vi t y i s mol ar conduct i vi t y of t he sol ut i on when i t s c:oncentration is zero. Kohlraush law of indcpcndcnt migralion of ions states that t hc l i ni i t i ng mol ar conduct i vi t y of an 291 al Ans: a] bl Ans: a] Ps=x, qP, and Pn=xaP, , Fffiffi t l r ' t l t ul l l r r ' t t r l " r ' 1' r ' "! l ' i ' l l l t r ' i t r , l t r t , l t t . t l , , ' r r l r r l 1, r , ' , , , I r i , , , l c: t l i ot l t , l l l r t i l r , l r , ' l ' l ' l ; gr cxi r t l pl t ' , r l / t ' , . r r , , l t hc l i nr i t i ni l l l l t l l l t t , , ' t t ' l t t ' l r r r l ' "i and C/ - r cspccl i vr - 11' , l l t l t t l l t r l t t r r r l I r r ' mol ar conduct i vi t ) ' ol Nr r ( ' / t ' l ' r v' r r l ' " . 0 r 0 r 0 Lm=LNa. ' , r "r l 301 al The vcl oci t y const ant of a l l rsl rrrrl l r react i on was f ound t o bc I . . 2 x l 0 ' . r ' and 2. 4 x I 0-a s--l at 300K arrd at 3 I 0 K resp, ect i vel y. Cal cul at c t he acl i vl t i on ener g/ gi ven R =8. 314 JK- ' nol - ' bl Provc t hat t he hal f l i f c pcri od of a f i rst ordcr rcact i on i s i ndepcndcnt of t hc i ni t i al conccnt rat i on of t he react ant s. t 3+21 . k. [ . ^ ( t "- T, \ Ans: al l os- l = " l - I K1 z) u) ^\ / l r 2 / . 2. 4x10{ E, , r 3l 0- 100) l ^o - - : Yi - l ' "o' . t "' o' : l o3{Bl 14 t ' 3oo*I l o/ E^ l 0 l ^c1=- - - - - L- ' - c- 2. 303x8. 314 l oo. l l o 0. 3010 x 2. 303 x 8. 314 r 300 x 3 l 0 10 = 53,598 J . nrol -t = 5J..6 kJ ' mol -' I When t =t 172 I [ Rl =; [ R] 6 I For a first order reaction, . 2. 103 , l f i o l . i ( ] i , [ Rl , ) k = - l r), 1 -- i u! : _- | ' l Rl 1. 7 - l t at . 2. 303, ^ 2103, , , . , , = ::' l og I ( 0.J(, I 0) I t / 2 t l i 2 _ 0. 693 t t t z Ea bl f--oiet U'A 'fhis expression does not contain the term inI wf i"ft impfies thatthe half life period- of a first order reaction is independent of the initial concentration of the rcactants' 3l l al What i s pept i sat i on? Dcscr i be t hc preparation ofa positivcly charged AgI sol and a negatively chargetl AgI sol from lgN03 solution and KI solution' bl Expl ai n t hc t erms cl cct ri cat doubl c laYcr and zeta Potcntial' [3 + 2l Ans: a.l Peptisarion is a process of converting a f reshl y prepared preci pi t at t 1L". , i colloidal solution by shaking it wm tne dispenion medium in lhe presence ofa small *i*t oi* .f otolyte' The electoll'te used fol this process is called the peptizng aSell *t * ,lg,Vn.r solution is added to KI ,olution, ih" p.ecipitatedAgl adsorbs I- ions lrom the dispenion medium resulting in the fo.rnution oiu negatively charged colloidal Agl solution When KI solution is added to AgNo3 solution, positivcly charged Agl sol is fonned due to adsorption ofAg' ions from disPcrsion medium' bl Thc combination of two laycrs of opposite -' .ttg., around the colloidal particle is calli Helmhottz electrical double layer' The potential difference between the fixed tuy.i tta the difffrrsed layer of opposite c-harges is called as elechokinetic potential or zeta Potential' Mention the major product formed in the following reactions: Propene is trcated with diborane f ol l owcd bY oxi dat i on usi ng hydrogen Peroxidc in an alkaline mcdium. Ni t ri l es are hYdrol Ysed i n t he presence of an acid' i i i l Sodi um Phenat e i s heat ed iodomethane. Writc the structural ieprcsentation of S1' 12 mcchanism using the hydrolysis of methYl bromide as an examPle' [ 3+21 following: il Rcimcr Tiemann reaction iil Fifiig reaction Oxidstion of a comPound P gives a prgduct Q which reacts with PhenYl hydrrtine but does not answer thc silvcr mirror tcst. Name thc compounds P and Q' [ 3+21 331 al 321 al I cti o >>l l l \,2 Sr t i c\ l al deh{de iil bl - + ONr I cHrl "' ,," zY r:::+ I ll \-2 otl Ans: al il tu l- ?r" A srg"l /-\"^ L__ ,r arr.xrHl \rl J l ' henol l r t er me( l s. c Ans: al i ] Pr oPan- 1- o1 iil atniat or carboxYiic acid iii.l Anisole -a ,t-i\ onr hs ( / \ { \ ) r : N. x Di Phcrl ' l . , H HTI t t bl EoH.u>Be{Ho.:1-n : 7 LFI ' H n Wri te equrti ons E@ ,l*no{ -r,.u, I \i' ru@ 341 bl Pisasecorldaryalcohql Q is a ketone al Wr i t c cquat i ons f or each of t he followingr i | [ t osenmund r educt i on f or t he preparation of benzaldehyde, iil, Aldol conQcnsation taking ethanal as an .*u-lrl., iiil Decarboxylation. Q! Gire rcasons: i l Aryl hal i dcs are cxt r"emcl y l ess r cact i vc t owar ds nucl cophi l i c substitution. i i l An el ect ron rvi t hdrawi ng gr0up i ncr cascs t hc aci d st r engt h of phcriol. [3 + 2] Ans: a] i l f i l i Y"1, .. pdirrrsor Atdi'.>, l . l l ' ' + H' -----i I l l rr + rl L/ \,2 \/ ' ,Bmznylchloridc Benayldchtde iil : i . , ail- NaOH. 2CH3 -CIIO \ -\ CH1-C.H -L:H2-CHO Ethanril ' d, .r_"r[:xli,,*d -4=-Cn,-CH =CH -CHI - H. O ' - - ' ) ' " - Bul2-enal (Aldol condensation product) iiilR - COOH + NaOH + R - COONa + I-I2O Ccf r R- COONa+NaOH- *" R- H - * A llydrcruhn Sodalime + Na2CO1 bl I TheC-Xbondacquiresadoublebond character due to resonance involving a lone pair of electrons on X. i! EWG renden phenoxide ion more stable due to effective delocalisation ofnegativc charge. 35] al A kctone is treated with hydrazine to form a compound X. X is boiled with KOH in ethylcne glycol to form Y. What are X and Y? Name t he reduct i on. bl Arrange the following in the increasing ordcr oftheir acidic strength in aqueous rncdi um: Acet i c aci d, monochl oroacct i c aci d and pr opanoi c aci d. Gi ve onc rcason for the trend observetl. [ 3+21 Ans: a] X is a hydrazone. Y is a hydrocarbon. It is Wolff-Kishner reduction. : l ' KoH/ : -" = n tutt*'rl )c = ru-lru, ethvlene glycol ,,.- " _H.Ci ,/- heat \ ^, , , , , . / ' un1- t r2 i b] Pr opanoi c aci d < Acet i c aci d < Monochloro acetic acid. EWG increases the acidity of carboxylic acids by stabilising the conjugate base through delocalisation of negative charge by inductive or rcsonance effect. EDG decrease the acidity by destabilising the conjugate base. 361 al Ment i on t rvo di f f erences i n l he structures of amylose and amylopcctin. Write the llaworth' s structure of the monomer of starch. ( 9) Ci ". an examPl e f or each of t he following: i l a sul phur cont ai ni ng cr - ami no acid. iil a globular protcin. 13 + 2l ril Amylose Amylopectin I iil Iiis a linear polymer It does not contain ct, l*6 glyoosidic linkages lt is a branched polymer It contains cr, 1-6 glycosidic linkages The monomer of starch i s u* D - glucopyranose, the Haworth's structure of which is given below: CHPH ll' \l YY N/ ou\qH 4/on t-{ H OI-{ Explain with an example, thc formation of il an addition polymer. iil a condcnsation polYmer. Namc the monomers of Buna - S. Give an example of a thermoplastic. [ 3+21 Addition po$grers are formed bY repeat ed addi t , i on of monomer molecules possessing double bond or triple bonds. eg: Polythene is an addition polymer formed by polymerisation of ethene. n CH7=Q11r -+ -(CHz-CH)n Condensation polymers are formed by repeated condensation between t wo di f f erent bi -f unct i onal or trifunctional monomeric units. eg: Nylon - 6, 6 is a condensation polymer formed from hexamethylene diamine and adipic acid n H2N(CH)6NH2+ n HOOC(CH)aCOOH' + [w a g a 11 u N HCo(c H ) 4 cof ,, +nH2O Thc f ormat i on of a condensat i on polymer will be accompanied by the elimination of small molecules such as water, alcohol, HCI etc. Buta - 1, 3 - diene and stYrene Polythene. Ans:' a] ! bl al bl bl 1l What is the unit of the rate constant for a first order rcaction? Ans: S-r (or) min-r (ot) Hr' _)l Give an cxample of a nchvork polymcr. Ans: Bakelite (or) Melamine - formaldehyde resins (og any suitablc example. -31_,' Dcfine a fucl ccll. Ans : A fuel cell is a galvanic cell in which the chemical energy is converted directly into electricalenerry. iJl__,/ What is the dispcrsion phasc in a gel? Ans: Li qui d ''il Write the IUpAC name of: i,. lcr(N\\ (t{2o\lCb, Ans: Triammine triaquachromium (III) chloride lll Calculate the number of particles per unit cell of fcc? Ans: Number of atoms per unit cell of a fcc = fa {ut .orn.rr) x 1 {contLibution)] + 6 (at face centr.e; x I lcontribution ) 2 - a What is thc osmotic prcssurc of a S' /o (wl v) solution of canc sugar rt 288 k (mol, mass of canc sugar = 342 gmol -' , R= 0. 082 l i t at m k- r mol r ) . n/. R1 n I l . l \ . {) 01, 1. ' . . ) l l l J 1, 1 r t ) | 6l Why i s Hcl i um uscd i n f i l l i nyg ; r t r . r ht pr r r r r r l balloons [or weathcr study ? Ans: Hel i um used i nai r. shi ps and r. vci rt l t t . r l rrl h, l r, , becausc l{elium is non-inflanururblc lrrrl lig,lrt 1' ,r,. 7l What is the gcncral clcctronic con ligrr r:r ( io rr of thc 3/ scrics? Ans: [ Ar] 3dt -l o 4rl -2 8l Name t he most sui t abt c oxi di si ng rcagont for the convcrsion of a primary alcohol to an aldchydc. Ans: PCC (or) pyridinechlorochronrate 9l Givc an example of a non-narcotic drug. Ans: Aspirin (or) paracetamol l0l Which vitamin deficiency causes pernicious anaemia? Ans: Vitamin - B1r r2l n=3. 452 at m [f unit not mentioned, deduct I Mark] l 3l Wri t c t hc symbol i c represent at i on and ccl l rcact i on f or t hc Dani el cel l . Ansi Zn / Zrri,,r1 // (' ui,,,,1 / ( )tr znl -, zn2+ + 2e- (oxi dat i on) C' t )2' +2e + Cr (l {educri on) (oR) Zn + Crt 2+ r) Zn2t + ( )r (Ccl l rcacl . i on) l 4l ' l Cxpl : r i n t hc cxt r act i on of Ni hy Monr l ' s p r0ccss. Ans: Ni t : kcl i s l r r : r r t cr l i r r ; r sl t r ' ; r r r r ol r . o l of t r r i r r r , , r v{) l l l l t l c ( r ) i l t l ) l ( . r , r r i r ' l r . l ! t . t r t r t t r r l r ol t Vl A/ r r , l r ' , r l l l I "r ) ^ , l vr , , , t , l Ans: EI Thc carbonyl is subjccted to highcr tempemture so that it is decomposed giving thc purc metal' [w,rco),] 4so-4' 1ok ' Ni +4co l5l Writc thc modificd A' rrhenius ratc cquation and cxplain thc tcrtns involvcd in it' Ans: , ( = PZ1-E' | RT K -+ rate corlstallt P + steric factor (or) probability factor Z -+ collision frequt:ncy ofreactants E" -, Ilnergy of Activation ' l' -+ Absolutc tcmperaturo (any 1wo tcrms) (-t61) n' lcntion any hvo uscs of phcnol' Ans: Uses of phenol il As an antiseptic and disinfectani' iil In the ntanufacturc oftsakelitc i i i ] I n t he manuf act ur e of dyes l i ke phenolplithalein, picric acid etc' iv] In the manufacture of dettol' v] As a preservative for ink. ,.. vri] In the manufacture of products such as a salicYlic acid, a rnethf salicYlate etc. I 7l I l on' do you preparc benzal dchyde by I Gattcrman-Koch reaction? Ans: When ben,&ne is trcated with carbon and hydrogen chl ori de i n t he presenoe anhvdrous aluminium chloride (or) cuproug chloride, it gives benzaldclryde. r. \ t o. l l C/ a' ^-r"' ' n I r-r t ---=+t ( ) | !-] ui' y AIC/r \:2 OR Scl I exPl anat orY cquat i on. ( f ey f " r , r ' hat r vay i s sucr ol asc a super i or sweetening agent than asPartamc? Ans: It is stable at cooking temperatue and 650 times as sweet as cane sugar. It does not provide additional calories in food' 191 Describe the extraction of Alurninium from purifibd Alumina. Ans: Purified AJ2O3 mixed with Na1 41F6 (or) CaF2t o l owcr t hc mel t i ng poi nt of t he electiolye and to increase the conductivity of the elecirolye. The fused rralrix is elecholysed aird A/is formed at the cathodc' At cathode ', Al3+ 3e- -+ Alpl At anode : C1"1+O2" -+Co19+2e- C1.r1 + 2O2- -+ Ca' t,g + 4e' 201 Expt ai n t hc l aborat ory rnct hod f or t hc preParation of dinitrogcn' Ans: in the laboratory, dinitrogen is prepared by treating an aqueolls solution of 'V//aCl with sodium nitrite. NHaCI@q1+ NaNo4onl-+ N2(s) +2HQg1 + NaCl@q1 $Em @ Smallamounsof NO & t/NO1 arealsoformed' These impuities can be remoyed by passingrhe gas t hrough aqueous I / 2SOa cont ai ni ng K2Cr2O1 . 211 Explain rvhy transition mctals and thcir compounds shorv paranlagnetic bchaviour and also calcutate the rnagnctic moment of a di val cnt i on i n aqueous sol ut i on i f i t s at orni c numbcr i s 26' Ans: Pat' amagnetism ariscs duc to thc presence of unpaired elcctrons' v=1,,04 t . . , ^i 4. 90 i t ={a( a+/ }=! l c= 221 I Iow docs acidificd potassium pcrmanganate rcact with il iron (11) ion iil Oxalate ion i r: ,.";;q 1125 . , ! : l Wri t e i oni c cqual i ons f or t hc rcact i on. tAh,v ft. * 5Fe21 + MnOo- +8lla -+ N4n2' +4Ht o+ 5Fel + Fe2+ ion(grecn) is.onu.rt.d to Fc3' (yellow) iil Oxalic acid (or) oxalate ion is oxidised to coz 5C, . O42- +2MnOa- +l 6H+ -+2i t 4n2+ +8f l rO +10CO1 iiil HrS is oxidised to sulphur. 5, 52- +\ MnOa- +16I I ' F ->2i , t n2+ +8I1"O + 55 .1, ( 231 ) Mcnti<tnthcconditions rcquircd to maximisc thcyicld of NH3 and rvritc thc florv chart for its manufacture, Ans: N' 1gy r-3F1' 1r; F: 2N1l j (s) Thc optimum conditions for thc production of Nl13 arc: i I A nressrrrn nf 100 aLm iil A temperature of 700k iii] Catalysts such as iron oxidc with a small anount of K2O xtd Al2Q. (Nr+H' :fl l l J Li qui i l NH, 241 Writc any three postulates of Werner' s thcory of co-ordination compounds. Ans: i] In co-ordination compounds, the central metal atom (or) ion possesses two types of va.lencies. One is primary and the othcr one is secondary. i! Ile primary valency is variable and ionisablc whereas thc secondary valcncy is fixcd ln.l . non-ionisablc: ., iiij The primaw valency refers to the oxidation statb ofthe ccntral metal atom and is satisfied ' by negative ions whereas the secondary . valency is equal to the coordination number and are satisfied by neutral molecules (or) ncgative ions. ivl The primary valency is non-directional . whcreas secondary valency is direclional anC has characterisljc sp{ial arrangements. It also gives specific geometry to the complex compounds. 251 On t hc basi s of t hc val cncc boud t heory, explain why JCot ,l' ,v; )c JJ* fbrms an inner orbital complcx, . - L. Ans; [ CO( Nl l 3) 6] ' ' olbital of COl+ ioi 4P ./l spr hybri cl orbi tal s . - l + ICO (n"t{3)61 MW 'r-r L_l 4,r n-il ,/2qr3 hybriclised olbitals of.Oi+ Si x pai rs ol el ect rons f rorn si x , , \ ' / J3 mol ecul es. , Si ncc. t he i nner d oLbi t al ( 3f l i s used i n hybridiz-aiion, the complex forms a-n inner or.bilal complok. 261 Expl hi n why & has a smal l er cnt hal pl , of dissociation compared ta that of Cl2? Ans: The smaller bond dissociation enthalpy of ,!. can bc attributed to the smaller atomic size of fluorine. WEtr In a molecule the inter-nuclear distance between two fluorine atoms is small and the distance between a pair ofelechons is smaller' 27) al Calculate the packing efficiency in a body centered cubic crystal (bcc)' bl What type of stoichiornctric defect is shown by ZnS? 14+r l al Packing eflioiency in a bcc crystal G ln bcc Volumc occuPied bY 2 sPhercs tn Dij= =-.--- ' ' ' f ot al vol ume of uni t cel l Ib calculatc the volume of the I n AEFD, b2 =o2 +, r 2 =2cr 2 C2 =oz +b2 o2 +2o2 ( ' . ' b2 =2a2) c = J3a ! u1 c = 4r' = VJa r--Tl l . ' . a = -=l I vl l 1 -' - volurne of the cube = a- unit ccll l PIr = 68%l ( a' ) ' \ Jr l A^ z\ - Tr . pp= 3 , x100 ( q \ ' l - n' I \ vr , / ' Volume of i sphere = 4r 3 Thisresults in relatively large elerton to electon repulsion among the lone pairs of electons in the Fr molecule. ( onr' l ...Volumeof2spho.t l2*; ) Frenkel defect. State HenrYts law and mention two important aPPlications. Givc hvo diffcrcnces bctwcen an idcal and non-idcal solution. [3 + 2] Hcnry' s Law: St at ement : At a gi vcn temperature the solubility of a gas in a liquid is directly proportional to the partial prcssure ofthe gas above the solution' (or) Suggcst any thrce methods ofprcventing l . . dt ' , - . , , , , , q^; DI , the rusting ofiron. Calculatc the equilibrium constant of thc rcactlon Cu19+2Ag- . . : Crrf o, +2A961 Gi ven E[ ", =0. 46t r [ 3+21 Mcthods of prcventing corrosion: il By painting i i l l l y mct al l i c coat i ngs (Gal vani zi ng, finning) By making alloys Cathodic protection wkt, - o 0. 059 , f , r "11 =- l Of l k, . o.ou= o Jln,"n o 2 *' l og ft"=15.6 r-----.----:;1 l i . . =3. 92x l o' ' I A first ordcr rcaction takcs 40 minutcs Ior 30Todccomposition. Calculatc /i. Definc threshold energr. 14 + 1l lRlo = 100' t = 40min l Rl =100- 30=70 bl bl 281 al Aps: a] bl i i i l ivl bl Ans: a] The partial presswe of the gas in vapour- phase is proportional to the mole fraction of the gas in the solution. Application d To incrcase thc solubility of CO2 in soda water and other soil drinks, the containers are sealed under high Pressure' Io avoid bends, scuba divers are provided with tanks filled with air diluted with Helium. bl ldcal solution Non-idcal solution K= ? tn2 =? Forafi rstorderreacti on. . . 2. 303. f n. l ^ - _t osl i I / - LRI 2.303 , 100 =- t og- 40 ' -" 70 301 al 6 Ans: a] Obey Raoult's law at all tcmperature and concentrations. The A. . . B interactions are of thc same order asA. . , AandB ... B interactions. AV. . =0 mlxtog A H,o., = o Do not obeY law at all temperature and concentrations. The A. . . B interactions are not of the same order as A. . . A and B . . . B interactions. AV. *0 fttxln8 AH . . + 0 nrilfig 321 al How do you convert chloro benzene to biphenyl? Name the reaction. bl Explain Finkelstein's reaction with an example. [ 3+21 Ans: a] When chl orobenzene i s heated wi th sodium in dry ethcr two aryl group join together forming biphenyl. Er6 Et!ilt ffiIm bl 0.()() l t l l 2 * - , . 0.691 8. 906? x l 0 r E=-uiqll The mi ni mum encrgy t hat t l rc rcl cl i rrl l mol ecul es musl posscs i n ordcr t o l i rrrrr products is called threshold cncrgy. Dcscri bc somc f cal urcs of cnt al vsi s hv zcol i t cs. Givc rcasons: Finety divided substances are morc ef f cct i vcl y absorhent t han thcir crystalline form. [3 + 2J Zeolites are good sbape-selective catalysts because of t hei r honeycomb - l i kc structures. They are microporous aluminosilicates with 3-D network of silicates in which some Si atoms are replaced by A/ atoms giving an A/ - O - Si framcwork. The reaction taking place in zcolites depend upon the size and shape of the reactatt and product molecules, as well as upon the pores and cavities ofthe zeolites. The extenl of adsorption increases with t he i ncrease of surf ace area of t he adsorbent. Thus finely divided substances having large surface areas make good adsorbents. 3l l al bl Ans: a] bl Fittig reactron Fittigreaction O*@"*',@@*'"u'' b] Finkelsteinreaction: When alkyl chlorides (or) bromides are bi phenyl trcated with Nal in dry acetone' halo.gen cxchange t akes pl acc f or nr i ng al Kyt i odi de. R- x + Nu[ -o"t nnu > R- I + Nax C\-Ct+Nal-!YYL+CH' - I +NaCI 331 al Writc the mcchanism of acid catalysed dchYdrat i on of al cohol ' bl llorv is anisolc prcparcd from pheno!? [ 3+21 Ans: a] Mechani sm of removal of wat sr f rom al cohol (aci d cat al Ysed) I st eP: H+ t, C II 3C I{ 20 H JL c I-t 3cH z - oH 2 t sl + CHi - CH1- OHz+ CI I 3- CHz + IlrO II steP: + cu. +Zu, -+cHz=CLI z+H+ ONa *oot-, ----'@ * H,o OLI bt l ol + l-l,l.f/ al bl Ans: al Monochloro acetic acitl is a stronger the u.iJ tnun u..ti. acid' due to the - I effect' where Chl ori ne acts as the el cctron ^Olu ,,.-,-/O -CH] f ol t l - cH. - - ) l CJ+Nr t \--, - \.,- Anisole Exptain why monochloroacotic acid is a strongcr acid than acctic acid' What i s cr oss al dol condcnsat i on? I )uri ng cross al dol condcnsat i on' si nce both the reactants contain cl I{-atoms;' hol many product s wi l l bc f ormed i n a nrixfurc? cl Name t hc reagent uscd i n Cl cmmenson i reduction. [ 2+2+11 rvithdrawing goup. An electon withdnwing er oun i n. r . a. es t he st abi l i t Y ol t he Jarboxvlate anion and hence increases the acidic strenglh of carboxylic acid' 1{l 9. , bl When aldol condensation is carried out between trvo different aldehydes and / or ket ones i t i s cal l ed cr oss al dol condensation. If both the compbunds contain cr - H - atoms, it gives amixture of four Products' c] The reagent used in Clemmcnson's reaction is Zn - Hgi Conc. l - l C/ ' 'i a| Give a reason: Although the aminc group is an O and P dirccting group, anilinc on nitnation givcs a substantial arnount of M-nitruanilinc. bl Dcscribc thc carbylaminc rcaction' c] r{.rrangc the follorving in thc incrcasing Ans: a] orqler of iheir basic strength C6l i s NI I 1, CH3NHt ' NHt ' 12+2+11 Wl:en ariline is treated withconc' /INO1 and conc. ll ;O4, aniline is protonatedto form au anilinium ion which is ileta directing. Tlierefore in addition to th ort hc i nd Para deri vat i ves' mdt a derivativcs are also formcd' bl Vhen primary amlne ls mi xt ure of chl orof brm KOll, isocYanide having heated with a and al cohol i c an intolerable cl '11,.,'' bl smell is formed. R - N I'l ) + C Li(' 4 + 3 KO H -+ R- NC +3KCl +3H2O ( 611 5NI 1) . NH1. ( : H3NH) Wr i t c t hc I l awor t h st r uct ur c f or sucrose. Mcnt i on t he bi ol ogi cal i mport ancc of RNA. [ 2 + 3l trmsq @$w ffrq a] I Iaworth structue for sucrose F fl'oq Y rif::: ! - ! r ' bl Def i ne t hcrmopl ast i cs and t hcrnro- sefting polymers. [3 + 2l bl The Biological impoflance of RNA: There arc tlree typcs of i{NA in a ccll which play an important role in protcin syrthesis. They are: n-RNA + Carries message liom DNA lor a specifi c protein synthesis. r.RNA -+ Provides the site for protein synthesis /-RNA -+transferAmiiro acids to thc site of protein synthesis. Write a note on the vulcanisaticn of rubber. Dl Ans: al VulcalisationofRubber Nat ural rubber i s sof t and st i cky. I t s properties can be improved and modified by the process of Vulcanisation. Vul cani sat i on i s a process of heat i ng nat ural rubber wi t h S-porvder: at a t emperat ure bet ween 373k and 415k. Sul phur r eacl s wi t h t he pol ymer mol ecul es f or mi ng a cr oss - l i nked network which gives meshanical stre nglh to rubber. bJ ' l ' hermopi ast i cs are l i near (or) si i ght l y br anchcd pol ymer s whi ch can bc r epeat edl y sof t ened on heat i ng anci hardcned on cooling. Thermosctting plastics are closs linkecl and heavi l y branched pol Ymcrs. On heating, they mould" become harcl, in-l,rsible and therefore they cannot be recycled. i t i Vapoiir Pressure. Ans: Raouliis Larv states that the relative lowering of - -- uupouipr.ssure is equal to the mole ftaction of Zl Narnclhe organicproductformcdrvhen phcnol is trcaied with excessof bromine water' Ans: 2. 4. 6 - TribromoPhenol Silicon and Germanium are rcfincd try State Law of Relative Lowering of Zonerefining Write the IUPAC name of Acetophcnone' Phenylethanone the hydrides ofgrouP 15 elements? BiH3. The SRP valucs of Al and Ag arc - 1' 66V and +0.80V rcspcctivcly. Which of thcsc is a more Powerful reducing agent? Aluminium What will happen to the half life pcriod of a first ordcr rcaction if the ternpcrature is increased? l'he half life period of a first order reaction decreases, if the tempcrature is increascd' What type of magnetic behavior is shown bv thc ScJ+ ion? A BCC unit cell has 8 comers. / l \ . . | 8 ": I - I atom is prcsent in the unit cell. An \ U/ atom at the centre ofthe body ofthe unit ccll is not sharcd with any othcr unitcell. This particle as a whole belongs to lhe unit cell. . . lbtal numberof particlcs per unit cell = 2, Give rcasons for cach of thc firllorving: il Bcnzaldchydc undcrgoes Cannizzaro' s rcaction. Benzal dehyde undergoes Canni zzaro' s reaction because it has no a hydrogcn -- atoms. wl trtt:: ti . , ( , \ 1", l t \ l l ..0 "' 1t ' t ' ' t I t 1 i s t l l c sl i l l l ( l i l l ( l r ' l r ' t I t r " l ' 1 "' l ' r ' r ' R i s the utl i vcrsal grts cot tsl i rt tl T i s thc absol ute tcnl Pcrattl rc n i s the chargc <l rt thc nl ctal i ttrr. [M] i s the concentrati orr ol ' thc rnt{l l [M' *] i s the conccntrati on o1' thc tl tcl al i otr l 7l What ar e anal gcsi cs? Gi vc r r n cxampl t r . Ans: Anal gesi cs arc pai n ki l l eru' cg:Aspi ri n. lSl [Iow is phenol converted into salicylic acitl? Writc thc structural sequcnce. Ans: Phenol i s convert ed t o sal i cyl i c by Kol c' s reactiotr as shown bclow: o,u oNa oi' cooll /) N"oH, . 1' +!aa\ \ _2 V ' , ' r1 \ , , ' l , hcnol Sal i cyl i c r ci d soo! ul n Phenate :g@djaccnt uriit cclls.' lhr:rt' fore. o"1, l"' n1' t o' un' , t i ' , ' i . t *t t y u. l ongs t o a part i cul ar uni t ccl l ' tsl 8l Ans: Ans: el Ans: 4l Ans: ( i i l , i t cct ophenonc docs not r cact r vi t h - - sodi umbi sul phi t esol ut i on. Ans: Acctophenone does not rcact with sodium bi sul phi t e sol ut i on bccause of st eari c hindra.nce . 16l Writc the Ncrnst cquation and indicatc the terms involved. _0 RT . t Ml 6ns: L, y*t u) = L: ( u*nt ) - - t n l M, +l (li\ wn^, are homolYPtic comPlexes? .+.' -os: Complexes in which a metal is bound to only one kind ofdonor group are called homolyptic comPlexes. ( ot\ lvt ion it the strongest reducing agent among ''.-:'/ i', Writi the IUPAC names of each of the folloriinB il tcp(NII3)ol [Cr(cW)6] Ansl Hekaamminecobalt(lII) He-lacYanidochro mate (lll) " and iil Nd3[Co(ox)3l Sodium trioxalatocobattate (lII) Ans: The ,scj"ion shows diamagnetism' 101 Namt a vitamin, the deficicncy of which gives rise to scunY. Ans: The deficieney of \4tamin' C gives rise to scurly. For example [Co(NH3)5(NO2fCI2 and [Co(AIH3)5(ONO)]C/2 show this type of isomerism. ln [Co(NH3 )5 (NO2 ]C/2 the nitite ligand is bound through nitrogen whereas in [-o(NH3)5(ONO]C/2 the nitritc ligand is bound through oxYgen. I Hcuo cH.cH:oH a t'o. an,adotra, Et l l anol l9l Write the postulates of Werner' s theory of coordination compounds' Ans: i] ln coordination compounds, metals show hvo tlpes oflinkages (valences) - plimary and secondary. i i l Thc pr i mar y val ences ar e nor mal l y i:il:*' . and are satisfied bY negative iii] -l hc secondary valcnces are tron-ionisablc 1' hey arc satisfied b)' neutral molecules or negative ions. i v] The i ohs/ groups bound by sccondal y linkages to the metai havc charactet'istic spatial arrangements corlesponding to different coordination numbers. 201 Descr i be t hc shapc and st r uct ur e of t t rc [ Co(NH: )e l ' *i on usi ng t he Vat cnce bond thcory' Predict its magnctic property. In the given ion [Co (,N,rfj)6] " Cobalt is in +3 oxidation state' The presence of ArH3 molecules as a ligand, causes tlie pairing up ofthe unpaired electrorls i n t he 3d subshel l . Thi s r esul t s i n t he availability of two orbitals of the 3d subshell to get hybridised along with 4s and 4p orb:.tals leading to the I' ormation 6 ecluivalent c/-.s7-' hybrid orbitals. Ihe orbitals of Col* ion are represcnted as FilTTI]-rl t-] t-r -f-l l r l l l l r l r l r l Ll i l l l 3db 4so ' 4P" 6if') exprai., tinkage isomerism with an example' anit ft it ti?. of isomerisrn arises in a coordination compound containing ambidentate ligands' Thelsomers will differ in the donor atom ot the ligand that is bound to the central metal atom or ion. @ Uow is methanol converted into ethanol? Ans: cH. oH. ' c' ' ra, r, a, Mg/ d' f et l t e! cg' vgc/ Methanol 141 Calculate the number of particles present in each unit ccll of a BCC crystal lattice' Ans: Each atom at a corner is shared between 8 d2.r7rl hybri d orbi tal s mw M 3d6 The configuration of Co3+ after accepting clcctron pairs from ligands becomes: i I TI il Ti r i l t l (r pirirs of electrtrns l'rorn (i Nl l, nrolccules 'fhc gcometry ofthe complex is octahedral due to tlz sp3 hybridisation' The conplex is tlianagnctic due to the absence of unpaired electrons' the reactions taking Place are: C + CO2 -> 2CO FeO + CO -+ Fe + CO2 Li mest one - decomposes t o CaO whi ch femoves silicate impurity as slag' Gl Draw a neat l abcl l cd di agram of t hc Bl ast \J furnacc and cxplain thc reactions involvco i n t hc cxt r act i on of cast i r on f r om hacmat i t c' Ans: In the blast furnace, thc reduction of iron oxides takes place in differcnt temperature- ,ung.s' t'tnr air is blown from the bottom of t he f ur nacc' Coke i s bur nt t o gt ve a i"tp..**. upto 2200K in the lorver portion itseif, Thc CO and heat formed moves to the uPf . , Purt of t he f urnace where t he t.tp"ruturc is lower' The iron oxides are reduced in stePs to FeO' At 500 - 800K (lower temperature range).the following reactions.take Place: 3Fe203 + CO -+ 2FqOa + CO2 FqOa + 4CO -+3Fe + 4CO' t Fe2(\ + CO -+ 2FeO + CO2 At 900 - 1500K (highcr temperature range) .. i,/t e"l$.'1-- With thc hclp of a flow charl' outline thc ,u.iou, stcps which are involved in the rnaouf uct or. of sul phuri c aci d by t he Contact Proccss. - F1 [ - - - l - - i - _i Ans: Air$ ll H H H ll-lt-J1 l-] ?' i l ?T 6 7 tT-ol ey. Ftow cha( $l2szq) ll SulPhur bumer 2l Dust PreciPitator 3] Washi ng and cool i ng tower (water i s sPraYed) 4l sl ol 7) 8l Drying tower (Conc' ti 2SOa is sprayed) Arseni c pui i f i es (Cont ai ns gcl at i nous hydrated Fe201) Preheater Cataly' tic convert (contains V2O5) Absorption tower (packed with quartzand conc. I!150a is sPraYcd) The conversion of SO2 to SQ by reaction with oxygen in the presence ofa catalyst (Vzo). Thc absorption of SOi in H2SOa to give oleum (I/2S2O7). The manufachtre ofsulphuric acid by the contact process involves the following thtee steps: il The bumingof sulphur or sulphide orcs in air to generate SO2. iiil The SO2 produced is purifred by removing dust and other impurities such as arsenlc- compounds. The key step is the catalytic oxidation of SO2 with 02 to give SO3 in the presence of Z2O5 (oatalYst). I ' O 2,S(/2(.{) + O:rs r ----]g 2SOl{s) - _t LH = -196. 6 W nt ol ' The reaction is exothermic' reversible and the forward reaction leads to a decrease in uoturn.' Therefore, low temperature and hioh or.rrur. ute the favourable conditions for u fiuiitrt vl.ld' But the tcmperatwe should not b. u.ry low otherwise the rate of reaction will become slow' m Enil ln practice, the plant is operated at a pressue or @r ,iri, ;Z bar and a:temperature of 720 k.'Ihe SO2 gas "i:;. lfrom the catalytic converter is absorbed in concentrated H2SOa to produce oleum. ' ,so, -+ I{2soa -+ H2s2o7 'fhe dilution of oleum with water gives H2SOa of the desired concentration. Z3l How is potassium dichromatc preparcd from purified chromite ore? Ans: Purified chromite ore is fused with sodium carbonate in free air. The reaction occurs as follows: 4FeCrOa +8Na2CO3 +702 -+ SNa2CrOa -2Fe2O3 +8C02 The yellow solution of sodium chromate is filtered and acidified with sulphuric to givc a sol ut i on f r om whi ch or ange sodi um di chromat c Na2Cr2O7 . 2H2O can be crystallised. Na2CrOa +2H+ -+ Na2A2O7 +2Na+ + H2O Potassium dichromate is prepared by treating a solution of sodium dichromate with KCl. Na2CryOy +2KCl -+ K2Cr2O7 +2NaCl Orange cryst al s of pot assi um di chromat c crystallise out. 241 Name the mctal of thc X"l r' ow transition . scries that il does npt displace hydrogen from dilute acids Copper iil forms colourless ions in its +2 oxidation state 271 al Catculate the packing efficiency in a simple cubic crystal lattice. In a simple cubic crystal lattice, the atoms are located only at the comers. Let the edge length of the unit cell be i a' and the radius ofthe sphere be r. Ans: hrw iiil Can exhibit +7 oxidation state Ans: Manganese 251 Complete thc following equations: il 3clz + 6NaOH (hot and conc.) -+ iil XeF6 +3H2O -+ iiil .lO2 +Cl2-+ Ans: il 3Cl2 + 6Na0H -+ 5NaCl +NaCl O3+3H2O iil XeF6 +3H20 -+ XeO3 + 6HF iiil .SO2 + CI2 -+ SO1C|2 261 Dcscribe cach ofthe following: il Passivity,of alurninium , ii] Brown ring test Ans: i ] When a pi ece of al umi ni um i s put i rrt o conc. HNO3, an insoluble and inactive film of the oxide of the metal is fornrcd over t he surf ace of t he nret al whi ch prevsnts further action by conc. HN()3 on t he rnet al . Thi s i s t ermed as t hc passivity of aluminrum. iil The familiar brouh ring test for nitratcs depends on the ability of Fe2* to reducc nitrates to NO, u'hich reacts with Fe2n ta form a brown coloured complex. The test is usually carried out by adding dilute ferrous sulphate solution to an aqueous solution containing nihate ion and then carefully adding concentrated H 2SO a along the si.les ofthe test tube. A brown ring is formed at the junction of the two liquids. . . a =2r A urit cell of a simple cubi c crystal l atti ce contains I sphere. ." Packing efficiency \ r l s: - !\ul"g99u.all'-'!Eryi]!q Tot al vol unt e o1' t hc unt l ccl l cYl = -3--*, 100 = 52. 4% (2, )r l ut ' ) ci u. an cxanrpl c of mctal dcfi ci cncy "t - ' t . ' d. f . . t . ZtJ I el l' tO is nrostll' forrnd ivith a coniposition o1' I c6 q5 0' ' an' l is an cxatnl-' le of a metal ri ri l r rrr, ' t r. i d: t ci cncr' def cct ' l hc nrol al cl cvat i r' rn const ant of rvrt t r * 0. S2"/ kg. l f a sol ut i on of 3' ?5 g of a non-r' ol at i l c sol ut c i n 50 g of rvat cr has a hoi l i ng poi nt of 100' 95 ' C' rvhat wi l l t hc nrol ar mrss of t hc sol ut e bc? Af ' , = / - I o= 100 95 - 100 = 0 95 . , _ 100. 0x r\ ' , > f f z AI,, r l4t 1000x0. 52y3. 75_ar n< - - +l . vJ 0. 95 x 50 Ans: ( n- l l Dcscr i be any t \ Yo appl i cat i ons of ' ' --' I l cnryt s Law. The two applications of l{enry's law are as follorvs: il 'fo increase the solubility of C02 in '' ,on a.int, and soda water' the bottle is sealed under high Presswe' Scuba di vers must cope rvi t h hi gh .on..noution of dissolved gases while br eat hi ng ai r al hi gh Pr essur e undcr wat cr . I ncr cased Pr essur e ln.r"ur., tt. tolubility of atmospheric p,ur., in the blood' When the divers Iomc towards the zurlace' the pressurc errduatty decreases This rcleascs the l i . r uf u. A gases and l cads t o t he iorrn*.n oit ubbles of nitrogen in the f rl ooa. l f t i * bl ocks capi l l ari cs and l r"o, ". u medi cal condi t i on cal l ed ' benar". ' l b avoi d bends' t he ai r i s diluted with helium' al zel With thc hclp of a:schgnatic diagram'' dOscribc thc working of a hydrogcn; oxygcn fuct cell. Hydrogen and oxYgen are bubbl ed t hrough carbon el ect rodes i nt o concentrated NaOl{ solution' Catalysts l i ke f i ncl Y di vi ded Pt or Pd are lntcgrating this equation. wc get l n l Rl = - kt + L.. [1i s constant of i nl coral i onl when i =0. [ Rl =[ R] 0 IrR]s is the initiai concentration of the reactant substituting in equation (l), we get / r [ X] o = ( - t x 0) + 1= / substituting in equaticn (1), we get / n[ Rl =- kr 1n[ t ?] s Reananging this equation: kt =l n[ R] o - l nt Rl k1 = 1n lRlo t Rl tt =! 1' ,l R)o / [ R] r = !7, lft]o / [ R] . 2.303 , [/?l n k=- l n- - / [ R] bl Afirst ordcrreaction takes 100 seconds to be 50% completc. Calculate thc ratc constant and the time rcquired for thc rcaction to be7 SYo comPletc. Ans: incorporated into the electrodes foi' incrcasing thc rate ol electrode reactions which are given below Cathode: O. t rr, + 2l I 2O{l ) + 4e- -+ 4OH- (ag) Anode: 2H21r1 + 4OH- Ud i 4H7O(l) + 4e- The overall reaction being: 2II r1g + O21r1' + 2 H 2O(l) bl St at e Far adaY' s Fi r st Law of ElcctrolYsis' Ans: Faraday's First Law ofElectroiysis states that the amount of chemical reactlon which occurs at any clectrode during eleclrolysis is proportional to the quantrty of el ect ri ci t Y Passed t hrough t he elcctrolYte' 301 al Derivc an intcgratcd ratc equation for thc velocity constant of a first ordcr neaction' Ans: Considcr a first order reaction: R- - t P dl Rl Rat c =- - : = Kl ^l Ans: t =9! 2- 0' 693 -o. oo693s-l ttrz 100 seconds 321 a] Mentionthemajorproductformedinthe following reactions: i l A hal oal kane i s heat cd wi t h an alcoholic solution of silver acetate. Ans: I l st cr iil Acid chloridc is lrcatcd rvith dialkyl cadmi um. Ans: Kct onc i i i i i At : ct onc i s oxi rl i zcd usi ng sodi um hypoi odi l r: . Ans: Iocloforrrt l-trprriri. "iliiii,r' i] 'n,r.t-"rlt;. iii] They cannot be easily coagulated 11, , ", , l l ' r l r l l r r l I h' i r t l i ot r l : l t t l l l t t r r t l t l l r r r t r r I i I ' r I ' *r " l 1' opl r i l i r t t t l l , r t , l ' t r r r l l r "1' 1"' l ' t ' col l oi t l s. If the <lispersion medi urn i s separaicd frorn the dispersed phase, the sol can be reconstituted by si mpl y rernixing with the di spersi on n-redium. 'fhey are called reversible sol s. ' lhey can be easily coagulated. Ans: bl Mention any four cha:"acteristics of enzyme catalYsis' i l Most hi ghl Y ef l i ci en: iil Highly sPecific nature, iiil HighlY active under oPtimum ternperattlle. iv] Highly active under optimum PH. bJ Ilorv clo aldehydes react with monohy- dric alcohols in the presence of rIryHC/? Ans: When aldehydes react with monohydric aicohols in the presence of dry HCl, Acetai is firrmed R' oH/Hct,, f ,n4 o' on - , t . , \ ' \ l D t l J l . _ 1( - ( r f i l s. - f ' ( , , r yl . U Hern i aceta I , OR' R CH + I.t,o \Ofi , Acctal ffiBffi 1. 1' opl r ol r i r r t t l l t t t t l i l l t c: , t ' , , r 1 , . t t , r t r l : t l i vcl v l r ", : , . l , r l r l ' i ) nr c pr c. , ; , i t , , t , ' , 1 t hel ' do t l r t l t i vc back t l rt : col k' i t l rrl sol by si mpl c addi t i on ol ' t ht di spcrsi on mcdi t rrn. ' fhey are irre' versiblc sol s. 331 at .Wri te, gguati ons following: l l il Swarts rcduction Ans: H. , C- Br + AgF 4 H3C- F +AgBr i i l StcPhen rcducti on Ans: ltcl;jrll/4, R-('H=NH rt'o, R-CH) i i i l Etard' s rcacti on f or each of t hc ,'1t'('1J Ans: V Tol uenc ^ r' H(t )t ' rOH(' / )' c.t ).(/, ( \Y -:;-- > Il 'i /r ( .\r \t/. Chrottttum comPl ex ,/\>/( Ho H, t ) - l l - l - -+\y'2 BenzaldehYde bl Complcte the following cquations: \ ROII + SOCI2 -+ lil RCHO + NH2OH -) Ans: \ \ ROH + SOC| --' R-Cl + SO2+ HCI : : r R NH. OH r r l ' ' \ a =o - - - ) l l /- ROH u)c(tur-totl , , j N: 6=ygl - l +H, O Oxi nte riot) 'r Ans: De scr i be Gabi i el i s Pht hal i mi de svnthcsis. Gabr i el ' s synt hesi s i s used f or t he or.o.tu,i"" of I " amints' Phthalimide on i r. -"t ""t wi t h et hanol i c KOH f orms ;;;;i"'" salt of Phthalimide which on [."1"* *frft attcyt traiae followed by ;i l ;ffi . hYdroi Ysi s Produces the corresPonding Primary amtne' Phthalimide !il;Illl q? :;'"'*Gl,)'' uo xb 0 tl [i Y' -n-o V\;, 0 N - Al kYl Pht hal i rni de U I al A.niline cannot be prepared by Gabriel ptttnaiimiOe synthesis because aryl ' n"iiJ"r,r" noi,.,ndetgo nucleophilic substitution with the anion formed by phthalimide. Describc the synthesis of each of thc f ol l owi ng st ar t i ng f r om benzenc diazonium chloridc' il Benzcne -' Bnnr.n" can be sYnthesised bY the reduction of benzerc diazonium chloride using aqueous hlpophos-phorous acid' ArNr+ cl- + H1Po2 + H2o -+ Benzrne diazonium chloride Ar H +H3PO7+HCl Benzene iil lodobenzene Iodobenzene can be sYnthesised bY it*ting U.*tne diazonium chloride solutionwithKl' Ans: bl Gi ve r casons f or each of t hc following: i l Ani l i nc rl ocs not undcrgo Fri cdcl - Craft' s rcaction' Ani l i ne cl oes not undergo Fri edel - Crafl' s rcaclion due to salt formation with l/Cir, a Lewis acid' ( i i ) h- r ont ut i c ami nes cannot bc - J, . . Por. , l bY t hc Gabri cl Pht ha' limide sYnthesis method' Ans: EEffi , ArNlCt-+ KI =+ - .Arl + KCI + N2 l oooDenzne iii] pHydroxyazobcnzenc Para - Hydroxyazobenzene is synthe- sised by coupling benzene diazonium chloride with phenol in an alkaline medium. a+^oH (r zI"=NCt I It< \>oi l -1 vwJ /:\ ,/-\ ( / FN- N. . ( \ >( ) r / - ct . Ho \__, L? p-Hydroxyazobenzene (Orange dye) bl How i s Bcnzami dc conver t ed i nt o Aniline? Benzami de i s convert cd t o Ani l i nc by Floftnann's bromamide rcaction givor below: 0 tl CeHs -C- NHy+ Br2+4NI OH -+ Benzamide CeHs- NH2+Na2+NI 2CO3 Ani l i ne +2NaBr +2H2O cl Name an amino acid hormone, Epinephrine or Thyroxine is an arnino acitl hormone. l What are thermosctting plastics? Namc t he monomers of Buna-N; and wri t c its partial structure. Thermoset t i ng pl ast i cs are l i ncar or slightly branched polyrners capablc o1' repeat edl y sof t eni ng on heat i ng and hardeni ng on cool i ng. These pol yrners possess intermolecular forces of attraction intermediate to elastomers and fibres. The monomers of Buna - N are l, 3 - Butadiene ano Acrylonitrite. The partial structure of Buna - N can be represented as follows: [ ' i l I cu, *cu =cH -(' Ht -cH. -(:lH I r - l Lt , What i s saponi f i cat i ou? Wr i t e t he equation, Soaps containing sodium salts are formed by heating a fat (i.e. a glyceryl ester of fatty acid) with aqueous NaOFI solution. This process of producing soarp is called saponification and is represented bi' the following equations: o cH2- o- ( ' - cnHJs o i i l c H - o- c- cnH35+3NaoH hl l o l l l c H2- o- c- cnH3s Fat 3C11l135COONa Sodium stearate cH2oil I + CHOU I cH2oI{ glycerol Ans: Ans: bl ( Xl) "l Dcscribc thc formation of a nuclcosidc and nuclcotide. Ans: A nucleoside is formed when a nitrogen base is attached to the I' posilion of a pentose sugar. A nucleotide is formed whbn a nucl eosi de i s l i nked t o a phosphorie acid molecule at 5' position of a sugar moiety. b] What is a Zwitterion? Write its general strucfure. Ans: A zwitterion is a doubly charged ion that carries both positive and negative charges at di f f erent poi nt s on i t . i t s general strucfure can be represented as: R- CH- COO' n*, ,o0,. gases have weak dispersion forces''due ^"' io *nt.i *", also have low melting and boiling U' Define Vant Hoff s factor' Ahs: Vantl{ofs factor Total no. of moles of particles after , association/dissoclatlon N"-f;"1.*f Particles before association/d issociation 2HI:+ Hz + I, Mention the method by which Nickel can be punfled. tli.tit.*t" p*lfied ttrough the Vapour phase refinfirg / Mond Process' Nobi l grr., bave very l ow mcl ti ng boililg PoinS, whY? Ans: The presence of rmpaired electrols in an el,lent is responsible for is paramagnetic properhes' 6l points. What is the condition for an element to show paramagnetic ProPcrties? What are Enantiomcrs? Enantiomcrs are non-superitnposable minor images. Whi ch t YPe of at dchYde undcr goes Cannizaro's rcaction? 2l What is a Primary cell? Ans: A cell in which a chemical reaction occurs only ' ^""' on". ana trterefore cannot be reused' 1l Wri t e t he chemi cal f ormul ar f or t hc rat c equation or Ratc larv' 7l Ans: 4l f" /"1\ / {l l , - ") 9l Whl' can't vitamin C hc stored in our body? Ans: Wamir, C is waier soluble and therefore cannot be stored in cur bodY' 101' What are' franquilbcrs? fr-* f*nquitir* are C."trg5 which give a soothing e{h Ans: Aldch;'des rvhich do uot contain o-hydrogen' undergo Canni int ro's rcadton' formind. form a regular tetrahedron' State and explain Kohlrauschts law of IndePendent Migration of Ions Ans: Kohlrausch's larv oflndependt} *"T:::*i# #; ffiil ;;lar coniuctivitY .l* :ITTY: sul l csur4l urLruv^*----- ssedasthezumof ati nfi ni tedi l uti oncanbeexpre- . . ..-,^^^) and ,8, Atrs: ' ' sandtetrahedral )What are interstitial defect voids? i l Intersti ti al defects are a type of ^' .ryr,uifogtupt'ic defects wherein atoms are ilila"J from their normal Positions to ;.";;"* 'itt i" tht ttltt"l 1v1tT::5:: thereis no atomor two ormofe atoms shaflng Oil*tt""t *tn that number ofaioms is larger than the number of lasice sites' iil A void which is swounded by form spheres "' i;;;;;J;''etranedral void' because wlren ,f',...ti* "f tftese spheres are joirred' thus r2l *llffiffi t io ioauiouur ions (cations and anions) 1, 0 =1, 0, +l "o_ frdfar .ona*tioity at a dilution = limiting molar conductivity of cation+ ailon 131 Write thc Ncrnst equation with an oxidation,- rcduction rcaction for thc ccll vu,., lr"tufi,, llcui;, lcu - . . n 0. 059 , Ans: L,..,, =tt..rr - ^ tog / i Mo' -l L"J t*"1 141 ldentiff thc reactionorderfromthefollowing rat c const ant s. : i l K=2. 3x10r Lmol - r s- r i i l K =3 x l 0{ S-l Ans: ! Second order iiJ l:irstorder - ---) l 5l Why i s Crr' rcduci ng and Mnr' oxi di si ng whcn both hrvc a di configuration? Ans: Cr2' is rcducing in nature as its configuration chiurgcs fi'orn d4 to dr. The changc liom Mn2t to Mnr' results in the hall hlled - d5 configuration which has extra stabilify. 161 Explain Williamson' s ether synthesis with an exampl e. Ans: When a hal oal kane i s heat ed wi t h sodi um Explain the method of bleaching Alumina from Bauxite. Powdered ore is concentrated by digesting it with NaOFI at 473-323 K and 35-46 bar pressure. Al2Or + 2NaOH,".,, 1-31-1,O,,, -+ 2Na[,{l(OFI),.] Sodiurr aluminate Sodium a.luminate is neutralised by passing CO, gas and hydrated AlrO, is precipitated. 2Na[ Al (0t l )o] , "0, n CO, , r, t Al ro, . xf [ , o . r 2Nal l coi r*rr Sodiunr silicate remains in the solution and hydrated alumina is filtcred and heatcd to give back purc Al , Or. Ans: , al koxi de, an ct hcr i s l i r t t t t r ' t l I l t i r ; t t t r ' l l r ' r ' l r ' tenned as Mlliamson' s ctltcr syrtlltc:iir; CHr - CH2 - Br 1' CI I , (i l I , ( )Nrr , Bromoet hane Sodi um ct hox i t l e CI J. - CI {r - O' ^CI I ? ( ' l l , l N; r l }r et hoxy et hanc cFl r - c=N+cFI r - Mg- Br dr t {r r cr + 1 rr' / r, o , 1, I dent i f yAand B. . [ 9S{ - - . }' t t "" AI CH. - C- _ : _Crt zo Bl c' l {, c- \ A, ,.4, l Vhat i s chcmot hcrapy? Wri t e t hc namc of t hc mcdi ci nc uscd f or t hc t r eat mcnt of pncumonia. The use of chemicals for theraper,rtic effcrct is cailed chemotherapy. 'Chloroamphinecol' is used for the treatrnent of pneumonia l Vr i t e t he r eact i ons i nvol ved i n t he manufacture of Sulphuric acid by Contact process. Ans: 2SO, , u, t O, , *, -*Y&-+ 2SOr, r, Al -l = -196. 6 K. l mol SOr +FI , S04+H, S, O, Oleum Oleum on dilution gives sulphuric acid H, S, O, +l . i , O+2[ l ^SO, Dcscribe thc prcparafion ofozonised oxy[cn. Namc t he oxi di zcd product obt ai ncd when ozone rcacts with lead sulPhide. I Whenasl ou' dr yst r eamol oxl gcni spassct l through a silent electricai discharge, the conversion ofoxygen to ozone (1 07o) occrns. r7l l 8l ' 0,,, 2l l @E 30, -+ 20, A! l ' 1rs r), : +142 KJ i nol -' iil PbS(.) r 40, irr -+ PbSOo,*, + 4O"' 711 Exphi n t hc l argc scal c prcparat i on of Ni t ri c aci d bY Osnval d' s Proccss' Ans: St cP-l : l-hc catalytic oxiclation of NI' l' by atrlospheric oxygoll. 4Nl I r("r | 50, , , , -#i $#-4No, r' +6l l : orrr StcP-2: Nitric oxidc thus fontred combines with oxygen gi vi ng NO' ' I NO( ") r o, , , , *f NOr ( "' St cp-3: Nitrogen dioxidc so fornrcd' dissoh/cs in \' \/ater t o gi vc I I NO-l l NO, l l , O, , , + 2l l NO, ' u' ' No' Ar l' hc Nt' lthus fomrcd is rccyclcd artd thc aqucous i ^; , . ; ; h". nn. . nt ' nt t d bv di st i l l at i on upt o ;;;d;;' r' rrt. Frtrtltcr conccntt ation to 980/o can i.,.i;""ii ot ochvdration with conc l I' Son' LJI Ans: Exnl ai n t hc pr cpar at i on of Pot asst um pcrm: rnganat n f rom MnOr' I'o*riurn p..runganate is prepared i, tTrl"i:: ;ffi ;; ;il;^,\11 t'Yl lti:ll*"T: :ffi ;L ;;;iit" rulo,' tt'i' p'"9'::,' :': 1A1 L. l ffi iln t rtnO^ *ttitn'aitptoportionatesin u n ulra ot u.iai. soiutionto give perrnmBdale ,tnn, t 4KOI-I r' o, + 2K,Mno 4+ 2I:l'1o^ i*"o; -r 4FI' + 2Mno,,- + Mno, r'2l,'o Wr i t e any t hr ee si nr i l ar i t i es bet ween Lanthanoids and Actinoids- 2'll What is packing efficiency in a crystal? Draw ' ' | ,r,. ""i1 .til tr t bcc structure and calculate ii. pu.ftitg tfncicncy in a bcc lattice' Ans: Packing efficiency is the percentage oftotal qpace hlled bY the Particles' In a bcc unit cell, there are two spheres per untt Gi, , ' ) Ans: il Both Lanthanoids and Actinoids show a Promincnt oxidation state of+3' iil Both arc elcctropositive and act as strong reducing agents' iiil Bo$ of them show a steady decrcase in their ionic radii along the senes' i | Expl ai n hydrat c i somcri sm wi t h an cxamPl c. iil Writc thc IUPAC name of Kr[CO(NO' )ol Ans: il -lwo or more conrpounds having the same ^""' " ,nof ..ular formula but diffcring in thenumber of*at""'''olttulcs present as ligands is called hYdratc isoncrism' t r. g. : I Cr (l l . O)n] Cl , and I Cr (l l , O), C] l l Cl ' ' l l 20 iil Potassium hcxallitrito-N -Cobaltale (lll) 261 Di scusst henat urcof bondi ngand magnct i c react i on of ' l -ct racyaoni ckcl at e (I I ) i on' l i l i pmi f ' "" thc basi s of thc val ance bond theory. t ' ct racvanoni . kcl al c (l l ) i on f Ni l CN)ol 2 i s ;;il;;;;; in natuie Nicker is in the +2 n*iaotiin ,rut und ha^s an clecfonic configuratron as follows: 3d 43 4P- Nr.3ds runTttrTlTl n f-n In the process of forming the complex' elecuons arepail**;. uutonira ott'ituts are involved dsp' 4P iNi(cN)4], Mtlltlhll ffil;Iil n The molecule is squarc planar due to dsp2 iyiriOirution -d is diamagnetic as there are no rurpaired electrons' indsf hYbridisatton' 3d cel l . Let ' G' be t he dge lcngth ofthe iurit cel l and ' r' be t he radius ofa sPhere' Volume of a sPhere - ! nr ' 3 IVI Five Marks arswers E?rE El:lll ffi m Vol umeoftwospheres = z"!i l =!rci t 3 Packing elficiency Volurne of spheres x 100 Volume of cube 8. - l tr" =j . xt 00 o+l ^ t : ' J! J 8x22x r' 3,13 - XI UU 3x64xr ' x7 = 68% 281 al 45 g of cthylene glycol (CrHoO,) is mixcd with 600 g of water. Calculatc: il the frcczing point dcprcssion and iil thc freezing point ofthc solution bl St at c l l cnry' s l aws and gi vc any hvo applications of thc larv. Ans: al Molality ofthe solution w,r.t cilrylene glycol _ moles of ethylene glycol nass of water in kg Moles ofethylene glycol = 01 =0. 73 mol bl 600 r Mass of water in kg = -:^ ^--- = 0.6 kg - 1000s - .'. Molalityofethyleneglycol = 911 = 1. 2 moVkg | freezingpointdepression = 1. 86 K Kgmol -r x 1. 2 mol / kg : 2. 2 K ii] &eezing pointofthe solution - 273. 1s - 2. 2 = 270. 95 K Llenry's law states that the solubility of a gas iu a liquid is directly proportional to the partial pressure ofthe gas prcsent above the surface ofthe liquid or solution. Calculate thc emf of the cell in which thc f ol l owi ng rcact i on t akcs pl acc, Al so represent the cell. Mg,,,+ 2Ag*(0.000I N{) -+ Mg' ?*(0.I30 M) + 2Ag(., Ans: a] hl I == 5 A t =20 nr i nul es=20x60= 1200 secs TheEquivalentmassofNi = At lnass rs 7 = 29-35 E m=ZI t = xl xr 96487 ?c) ' 15 = : : : - _- : x5x1200 1. 925 g 96487 301 @xpl ai n t hc i nf l ucnce of a cat al yst i n t l re rat c of a rcact i on. bl The ratc constant of a first order rcaction i s 1. 5 x 10. 3 S- r . What i s i t s hal f l i f c pr:riod? I Ans: al A catalystalters the rate ofa rcaction. A catalyst participates in a chemical reaction by forming temporary bonds rn'ith the reaclanls resulting in an intennediatc complex r.r' hich deoomposes to yield products. A catalyst also provides an altcrnate pathr'i'ry bl reducing the activation enclgy bcnvcctt tlt. reactants and products and hence lorvcling thP n^l enl i rl enerw ha:Ti ef. ur w Pvr er r r r 4! v"! ' bJ I - 0.693 0.693 hi t : K l . 5xl 0' Half life period t ,z = 0 462 x 10r S 311 al Di st i ngui sh bet wcen Lyophobi c and Lyophilic colloids' bl What is foarn? A sbl ut i on of Ni (NO. ), i s el cct rol yscd bchvcci f pl at i num cl cct rodcs usi ng a currcnt of 5Af or20 mi nut cs. Whi rt nrass of Ni i s dcposi t ed at t he cat hodc? [ G i vcn at omi c mass of Ni = 58. 71 0. 0591 , Mg' - L. "r = bc"r l og f uo, T L' ' b I 0. 0591 , - - [ 0. 130] = j . l o- - l oP. - z ' -" Io.ooor]' - 0. 05e 1 , bccr r =J l 0- - l og cl Ans: al I)cscribc thc Brcdig' s arc mcthod for thc prcparation of go9' "lott-t"' flphiliccolloids Io-p]robic colloids lr t llxhibitdcfinite a{IinitY betuaen the dispcrsed Phase & dispersedmedium No or litde affimty j lrreversible iUnstable Rcvcrsibie i l S1ablr l ce Bath \/l Fivc Marhs answers Water containing a small amount of alkali is ;i;;i" ;."";iner keiit :":r:1fl::: Electric arc Deionised rvater + tfaces of alkali b I lroarn is a subslancc that is formed by trappng "' ;t;;k"" t' f gas in the tbmr of bubble s in a iiquid or soli-d, usualiy by agitation Lurn. Rn.t."ol. ut" is struck bctween the two .t..t oO.t ,nuO. up of gold' Asmall amount "iit...t.r uupotittt due to the high i.*o.roo".t oftire arc' Thc vapours ofthe ;;;i.;;"t. into water to give a metal r"i*i*. irt" alkali stabilises in a metal solution. 321 al tixpiain S"rmcchanism with an cxamplc' t i f xpt ai n t hc act i on of al c' AgCN on hal oal l <ancs wi t h an cquat i on' . ' Ans: al l{ydrolysis of teniary buryl bromtdc,wttn "" " *' oq, t . ou' sodi um hydroxi dc gi vcs t -but yt alcohol. clH. Cl-l' l l H. c - l - s' r ' OH- + H' ( - C- oH ' Pt l au at l 331 a] Explain thc conversion of propenc to ' - 2-ProPanolwithancquation' hl Namc the major [roctuct formed whcn acctone is hcatcd with l'iAlHo' Explain Rcimcr-Ticmann reaction' Bv acid catalYscd hYdraion' il;;;;;.1' *th water.in the Presenbe of an acidto give 2-ProPanot' cl],- cH = cHr + H:O -i; cH' - cH -cH' z-p,?1"""r lsopropyl alcohol ^tnJ""iit i"t"a with chloroform and NaoH ."r"ti"". i"ai"* ialt ofsalicylaldehyde is "U,"i".J*ftrcft "n oxidation withHCl give salicYlaldebYde. oH PNU - j- a,'a,. + r'r"ott ..ATcHcl' 2Nr()H , l - l l - - + l . l l _2Na( ' l s) \-, _H.o ONa Pt' "rr^ ry'*ntctto o't' ' /Y" U Tut:t V Scditun Salt salicYlaldehl'cle of sal i c' ; l al dchl de 1dl al Howdoyouprcparccarbory-licacidfrom Jr I "' i.ignt.o" reagent? Writc thc reaction' n1 f Vnat i s t hc Hel l -Vol hard-Zel i nsky reaction? Givc an examPle' Ans: al Grignard's reagent whentreated with cmbon ^""' - ;;;;; (drv ice) forms salts of carboxylic cl al Mcchanism i,J,,i"ttru.midc undergoes heterolJtic lission to give the carbocation' H,C CH' \ / _sk) w> C- +Bf bl cl cl-lr I H, C- C- Br I CH, FlrC' clH, 6" r Ol'l ci i , Since this is slow step hence it is the rate dctcmrining steP. ( t n ? I ht nut l eophi l e 0H at t acks. t he ..i"l"t"t t" glut'itlrtiary uuryl alcohot CH, I t r sl > H, C*C- OH I C]H. I{aloalkcncs react with alcoholic AgCN to form alkYl isocl'anide q-{+AgCN,.r., $ R-N = C+AgX' acids, which on acidification with dil l lCl gives respective carboxylic acids. O tl R - M_{ - X + O - C = O ------} R-C-Olr4gX o l t / H. ( ) l l + t{--C *Ot-t ; tvtg(Ot.{)X bl Hell-Volhard-Zelinsky reaction WhenAliphatic carboxylic acids arc treated . ' r i t l ' / - l ^. I ) . : - ' L- l r eSCnCC Of r Cd phosphorous, the u-hydrogen atom ofthc acids is replaccd by a chlorine or bromine atom to form u-halocarlroxyclic acids. cr1, -cooH+ci , - i : l i i cl ct' I" - cooi t + I' l ct monochJoroacctrc acid 351 al I i xpl ai n Sandmcycr' s rcact i on *, i t h a sui t abl c cxanrpl c. l i | Wri t c t hc I UPAC name of Ani l i nt r. . -' : . - , cl rExpl ai n t hcconversi on oi ni t robcnzcnc t o -- ani l i nc rvi t h an cquat i on. Ans: a.l Sandmeycr's reaction: Whcn beniene dizuoniLun chloride is rcacted with cuprous chloride ald conc. IICI it gives conesponding halobenz-ene. chl orobenzene b] Berzamnine c.l Nihobenzcnc on reduction gives aniline. NI J. NO. S.,-ur*r-!t-l1ct d.'o,o a rr i l i ne i.3{]-] "l What is a Zwittcr ion? Gi.rc its structure. bl What i s t he di f f er cnce bet ween a nucleoside and a nuclcotide? cl lVritc thc Horvarth structure of sucrosc Ans: a] AZwi t t eri oni sadi pol ari oncarryi ngbot h positive and negative charges. The net charge is therefore zero. R- CI - l - COOH =- : l {- Cl J - COo l l NH, "NH, Nt r t l cosi t l C: 4, l t ' , 1 111111r r r 1 l ' \ t l r r . r n. r l r i r , . t l l ol ' al t i t sr t l r t ( ' - l r l t r "t l t r r r r , , l ' , r t 1' t t r l , ' , . . i i as a r t t r cl cosi r l c. Nucl cot i dc: Wl t ct t i t t t t r r l r ' o' , r r I r , , r r I , r r l , a phosphor i c aci t l i t t t t t cc[ r l i r h' l ' , l ' r r r r ' , 1 \ ' . t r l , a basc at t ached t o ( ) - I l r ut t l i t pl r , , ' , 1 r l r r r t t r , r , r , I r esi duc at l achcd t o ( l - 5r ; t t ont ol r r : ' t r 1, ; r r Sucrc.rc a] l )r: scri bc t hc f rec radi cal mcchani rt n f or pol ymcri sat i on of Et hcnc. hl How is Nylon 6, 6 rnanuf' actured ? Ans: a] Free radical mccharrism irivolves thc lollorving steps. ! Chain initiating step: 'ihis step involves titc addition ofa free radical formed bl, the peroxi de t o t he doubl e bond ol t he monomer generating ane'uv and ionger fiee raCical. oo i l l l c,,H. - c - (:) - () - c - c,,H. --| o rc,l l . t - o. IS!! :c u C, , t . {. + CH, = CH, + C"H, * Ct J. _ c. i l , iil Chain propagating step: This step involves the reaction ofthe free radical obtained from step I ivith another molecule of the monomer forming ar)other longer fre(3 radical. - c' H, - arH.+ cH- = Ct-r.+ c"H, - cLr, - cHl- cH. att, I ( H {( l l . ( l l i . ' l r r l l l iil Chain tcnninating step: This step involves the combination offree radicals in different ways from step 2 to form the pollT nerizcd products. bl iii':i \ - / ffiffi - CH, i C }T. -FCH, - CH} CH' ;'EH' - "' "ii..-t-"intlene diamineand adipic acid *O.tftigh pi."ure and at high temperatur c,H' +cu' - cHl" 'cH: - c'll' nH;N-(cHr)6 -NH,+ nHooc - icH')' -cooH-fffu [-nr.r-(cH,)" - NH - co - (cH:)o -co-]" + nHro f?,! fit:lll wffi li !.: ) tl What are isotonic solutions? Ans: Two solutions having the same osmotic pressure at a given temperature are called isotonic solutions. 2l State Hcnry' s larv. Ans: I{enry' s law "At constant temperature, the solubility ofagas in a liqLrid isdirectly proportional to the partial pressure ofthe gas present above the surface ofliquid or solulion." OR "The partial pressure ofthe gas in vapour phase (p) is proportional to the mole fraction of the gas (x) i n t hc sol ut i on I ) = K, , x. wherc K*, - I{enry's law collstant. ( 3,V Dcfine zero ordcr reaction. -- Ans: Zcro order reaction means "the rate ofa reaction is proportional to zrro power ofthe concentration ofreactants". OR "Rate of a reaction is independent of nrolar concentration of the reactants". (j11, ' stut. F.raday's 2nd law of clcctroll'sis. Ans: Faraday' s 2nd law ofelecholysis can be stated as, "'fhe amount ofdifferent substances liberated by the samc quantity of electicity passing tlrough electrolytic solution being proportional to their chemical equivalent weigh8 '. lll Explain Frenkel defect. Ans: The Frenkel defect is a type ofdefect shown by crystalline solids. It involves the displacement of an atom or ion (normally the cation) from its lattice position to an interstitial site, creating a vacancy at the origiaal site and an interstitial defect at [re new location. This defect is only possible ifthe cations are smaller in size when compared to the What is sorption? W}ren bothadsorption & absorption proccsses take place simultaneously, the phenomenon is called somtion. ' {) wnot i s t he rol e of l i me st one i n t hc extraction ofiron? Ans: Lime stone acts as flur. If reacts with qang.uc to give slag. 7l Hel i um i s used t o f i l l ai rshi ps and bal l ons why? Ans: Liglrt & non-inflammable. 8l NarncthcHeterocyclicnitrogentraseprcsen{ only in DNA but not in RNA. Ans: Thymine 9l Mention the niajor product in the follorving react i on C2H5B, -AgCN, u1. , no' , Ans: CrHr-NC or ethyl isocyanide 101 ' Atdehydes havc lower boiling points than alcohols of comparable molecular mass rvhl'? Ans: Absence of H-bonding in aldehydes. OR Aldehydes contain weak Van der-Waals force of atbaction whereas alcohols possess H-bonding. @ Ans: 121 N"ame the factors;influcncing clcctroll'tic ' crindrtctancc'cxcess Ans: - NatureofelectrbtYte Naturc of solveit & its viscositY Size ofParticle & its nature Concentration of electrolYte 'lemPerature 13] What is a Pseudo Give an examPle' unimolQcular reaction? (AnYhvo) 141 Ans: Pseudo urimolecularreaction is one inwhich the motecutarity of a reaction is Nvo 01 more but the order is equal to one' OR A highcr order reaction can be converted to a f,rrt-ora., ,.uttlon by taking a1l othel reactants excePt one in excess' Dg : HYdrolYsis ofester CHTCOOCl ll j +H' 6 *-{-r Ctl-{sCOO}l+CHrOll' [cH3cooc,H5]' u{,o]" What is Lanth#oid contraction? What is the common oxi dat i on st at c shor vn bY Lanthanoides. lanthanoici contraction is the decrease in thc size of the lanthanoids as we go affoss the period due to intcrierence ofthe 4f electrons' oxidation state of Lathanoides = + 3 Explain Kolbets reaction rvith an example' f ot U. ' , React i on: When sodi um sal t "fli.""t (sodium phenoxjde) is heated at . t -' ^, , r 140 desree C wrt hi carbon di o. xi de ffi il;; ;;;tsure or aboul 6-7 atrnospheres exptain the extraction of aluminium from purified bauxite by Hail-Ileroult process' and the p-roduct acidif,red' ortho hydroxy "il;il ;;iJlsaticvtic acial is formed as the mainproduct. ONa ONi r)H A -,"':i;ili-, d'*' e5O'Til"'- \Y/ rro'i \-/ Salicyclicacid Explain nitration of Anisolcwith an cquation' Whcn Anisole is treated witlr a nitrating mixrure .""i'* fi*. fr,Soo) and heatcd' nitration takes "i^.. *'tft,ft. fokation of Orrtro-nitro Anisolc and Para-nitro Anisole' ( 1t t , ( x l l Ul l ' .,{' ,nn" ' ""' "' n, 1fr' " 6 ' .r' r 'L:2 \:/ Y, t?] Cive equations for the rcactions of aldehydc rvittr hydroxylaminc and Sodium bisulfitc' Ans: With hydrorYlamine: O - nitro aniscle t *' ' 3, , t u, ' r" u, , + acetalduhYdc With scdinnr trisulPiritc: Nal{SO,-+Na' +FIS0-" P - nitro anisole ct t , ' ( . = N, {) H * l - 1. 0 H ethoxime t"' ). = orrriu., rtTiaS,l*, H rri' Wl,rt rr. t anquilizers? Give an example' : : / r ^^ -l : ais:fmnsquilizers are chernicals that are used to relieve '^-" t*tt^a a*gs thatactQncenral nervous system io help in reducinc qxr".ry.' il 0ffiffi;";i valium, barbitLuic acid etc) (AnyOne) ffi"p. is mixed with Na,AlFo or caF' which i*:*tr ,rr.'ii'.,ting point of the'mixtrue T*ll!: ;;;i"ir1;rtt 'nt" nit"l ti*ttot lt "lectolvsed' Steel or i:,*il "t ."rtt.o. and graptute as anode are used in the #ffi;;;ti tlt giapirit" tre'e l' 's"tui for reducing the metal. 1^l o +. t C + 4At +3C0, ' nr1vl J" nl i berat edat t heanodc' Dur-ing Elcctrolvsis, the ox1'ge *^"ir"*i,f, rft. .arbon anode to form CO and CO2' rftE EH$ ffi At Cathode: Al3+ + 3e -r Al(l) AtAnodc: CG) +02 + CO (g) +2e C(s)+ 202-+ C02 (g)+4e 201 .Mcnti on thrcc .anamol ous bchavi ours of ' r:i ' nuo*" Ans: il It forms only one oxacid as compared to other halogens lhat form a numberofoxacids. lonisation enthalpy, clectronegativity and electrode potential offlourine are much higher thal expected. I oni c and coval ent radi c, m. p and b. p, enthalpy ofbond dissociation and electron gain cnthalpy arc lowcr than expecled. 211 Dcscri bc t hc manuf act urc of ni t ri c aci d by Ostwald proccss. Ans: ltrec equations with explanation: 4N H3 +5o 2 -=j^!3li+ +N o+o H, o 2 NO + 02 Fi 2NO2 3NO2 + H2O -+ 2HNO, + NO St ep l : 4NH, (gas) + 50, (eas)1j{fi;+ 4No (eas) + 6l{2O (gas) I' his reaction takes place in the prcsence ofPt Rh as catalyst at a temperahre of500l( and at a pressure o[9 Bar. Step 2: 2 NO + Oz ir 2NO2 3NO, + Il2O -r 2l{NO, + NO In this step the nitric oxide Qrlo) that was crcated in the first stcp combines withNilrogen dioxidc u,hich is dilLrted u,ith watcr to formNitric acid. al Expl ai n t hc act i on of conc. I l , SO, on oxal i c aci d cryst al s wi f h an cquat i on. bl Wr i t c t hc st r uct ur c ol ' or t hr ; phosphor i c aci d Ans: Oxal i c aci d crl "stal s unde r:go ci ei rydrati ol wi th Conc I I . S0, t o l r t r t n Co, Co, and wat cr a) rr, c, o, l l l sQ- ct o r co, 1' 2t : , o ( ) tl r r , , z I t - , ) r J I i , , I ol t iil t r r ' "- | i l l j nl Exphi n l i nknge i sot t t cr l r l r r 1r l l l r *t t I r at r t l r l * - - ' U1 Wt r at i s t hc hci t r ok' pl i t ' t ' ot t t l t l r r ' ' Ans: a] Compourxl s havi rrl i tl rc r;:rr)l t r l l ( rl r' t I l l ' rr l { rr r t rr Ii I but di l f cr i ng i n t l t c r t t t t t l c ol ; l l l i l t l t t t r r t t l "l t l " l i sandt ot he"ccnt r al nr ct ; t l l t l t r t t t i l t i r r t t ; t t r ' ' ' r l l ' ' l l i i kage i somcr s and t l r c pl t ct t r : r r t , ' , ' , ' , , 1" 1' r l l r ' I linkagc isomerism. eg: [Co Q.ll.I,), NO,l' ?' any example. b] Complexes wherc more than onc kind ol' ligirrr,i:i are bonded to central metal atom. 241 Usi ng VBT, cxpl ai n t he gcomct r l ' r nd magnct i c pr opcr t y of I Co ( NI I r ) ol " complcx. Ans: [ CO(NI I , )Jt ' i s a di amagnet i c oct ahedral cotnplex, where the Co ion is in a+3 oxidation state and its electronic configuralion in the outermost orbital is 3d6. The hybridiz-ation is as lollows: cor+ ion lTllTfrlTfrl JO d2sor hvbridised or bi t al sof Cor ' l t Jl t Jl l Jl l l I I I I d'?spr hybrid |cnfNrl ) 1,. lTurlTI RIT-flr}rlTh-ll t vu\ r ! r 1116t l i l Six pairs of electrons lrom 6NI' 13 molccules' Thc. The geomet ry i s oot ahedral and i s diamagnetic dueto the absence. 251 al ' t ransi t i on met al s and t hei r compounds arc good cat al Yst s, cxpl ai n. bl Gi ve t he out cr cl cct noni c conf i gurat i on ol ' Manganesc. (, \ t . No, 25) An. s: a] i )\ / ari abl e ori dat i ot l st i t t c ii) incomplctcly tilleti d-strbshcll bl 3di 4sl 261 al I l or v t l ocs Ki \ ' I r r ( ) , r eact u' i t h I l . S i n an aci di c mcdi unr ? Gi vc equat i on' b] l Vhat t r c i nt cr st i t i aI eompounds? i \ns: al Kntno, rtl acts rvi th l {,S i rr l ul aci di i mcti rurn as lo[lous: I n- n 45 4p I l s - r 2 l l ' + 52 !t] . tt"11,' - 16 H- _' 2Mn?' + 8H,o+ 5s Uiaotoo,to, of transition metal elements where 271 al Cnl cul at e t he percent age of maki ng effrciencY in a hcc unit ceil' b] A uretal crystallizes as fcc lattice with edge length 450 pm' trf the moltr mass of the nr.tal is 50g mol-r' find the densitv of thc rnct*1. Ans: el Pcrcentage packing fraction ofa BCC unit cell is 1;iven by: Total volume of ^! t!]to'"t (utott +@ VJtrrne of a unit cell Volume of all spheres:2 x f n f (No of atoms in BCC Per unit cell = 2) Volume of a unit cell = Considcr the A ABC' Ac2=AB2+Bc2 - . 3r +a2 rc.E =uJi (Face diagonal) Consider A ACD DCr =AD2+AC2, DC2 - ar , l Jr . ' ) or a' r ' ' a' ec=.67 =u' r; Btrt DC = 4r o, orut t a=$ Vrlume of arurit cell = ar small atoms iike Hydrogen' C' N'B occupy 'i,r"tt,ft*f tp*es in metal crystal of D-block elements. / +, \' 6413 =l - l =- - - - - \. J3 i 3J3 Substitutirg these values in equation (1) we have - s/ i r r 3- 1116=0. 6798 6413 8 r5 % packing efficiency :0 6798x 100 = 68%' u, ,r = i9 As it is an fcc cryst'al v, a, Nl L- a M = 50g rnol-' a = a50 Pm = 450 x 1O-rocm' 4x50 =; - - - - , ^r r * 6. 0221 10: j ( +so*t o- ' "; 4x50 _ 2oo =3.649gcm-3 54. 8 t Oa *t 0r x9, l 125000x6. 003 281 alDerivc an cxpression for first order ratc constant ofa reaction' blThe ratc of a rcaction increases 4 timcs when the temperarure changes from 300k to 320k Calculatc the activation energy (R=8. 314 J/ I Omol )' Ans:Expression for first order reaction' Consider a lust order reactton R+P If after a small interval of time d! d$) decomposes tirctl rate = K (i{)r _91! =61x1 OI /n (Ro) = I substituting the value ofl in above expression /n (R) = - kt + /n (Ro) P1 = 1n (Ro) (R) . . 2. 103. ( r i , , ) K=- t oo- j - t - ( R) u, rou Kr . ft [f,l ,l " Kr 2.301,R L TrTr .l Ea [;zo-;oo I l oqJ: - - - - - | - - | ' - - 2. i ol "8. l l 4l 320, l ool Fr ) n r 9. r 47 96000 - 0.6021x19.14' l "o = o.ooozos = 55. 41 KJ 291 al Calculatc std. frce energy change for lhc neact i on ZnrU+2Agror, , ?: 2, , 2' ' + ?, ' J1; 1r1 E" cell = 1.56V aild F = 96,500 C moi-r' ^. ( bl \ pi ve equat i ons f or t he cel l rcact i ons t aki ng -place at anode and cathotle in a button ce!l' cl What is the elbctrochemical series? Ans: al 4 G = -n l rl l o n: 2 = 2 x 96500 x1. 56 F=96500cot i l ar nb = -301080 JK-r E: ' = 1 56V celt = -301. 08 KJ blAt anode 2n,",+ 2olf ,"u. -+ ZnO(,)+[J,O(r)+ 2e Cathode I{gO,,,+HrO,,, + 2e -+ I' 1g,,,' l-2o1{.,u,,, Overall reaction 2r,,, + HgO,., -+ ZnO,.,'r lig,,, cl 'IheEle.ctrochemical series is a series of standard electrode potcntial of vlricus eientents an'atg:ed in an order (increasing or tlecreasing). Cal cul at e t hemol ar mass of t hesol ut e. (K- li'l'r;itdf ! ;;:= i;q:iiitd ;';r'l al Thc b. p. of bcnzcnc i s 353. 3k' Whcn 2g of , ,a' nrrn-volatile solute was dissolvcd in I 0(ig of l i enzene t he b' p. i ncreases t o 35' 1. 2k' [ l Wnot i r r non- i deal sol ut i on? Gi vc an example. k, . ' w" v 1000 Ans: rvr----* .al- aI b' r Yl ^, _2. si , 2' 1000 '''- --lil[i b] Solutions which do not obey Rault' s lau' 41 all conditions of temperature and concenlration rlc calied non-ideal solution. Eg: CTH, OH + CI {, COCH, etltaroi + water 3l I al Expl ai n t he mcchani sm of cn: n mc cat ah i i i . bl What is (i) peptisation (ii) cle ctrophorcsis? Ans: l-ock & Key mcchanisnr: a mechanism of En4'rne CatalYsis There are a uumber of cavities presc' nl. otl tltc sur{acs ofthe colloidal particles ofenzy.nes -l'hcsc ' cavities are ofa characteristic silalrc and posr;,:i;s act i ve groups I i ke -Nl l 2. -Cl ool l . Oh cl e I ' r' ' s' are acluallythe active active cenhes tlu lhc sr trlltcc of thc enzyme palticles' Thc molgcules Lrl l!":' r eacl al l t s i . e t he subst l al es t l t i i l hr l i ' r "i ccnnplementary shape that fit into these cavilic:;.jlrs1 like a key tits into a lock. Dur: to thc pt' esencc o1' active ggor:ps, an activaled complex is firrrr red. .\;d this decomposcs to yield the product.' . Step I - EnzYrne + Subsirate -r ES Enzlnne Substrate ctl tllPicx Step 2 - Product folmation ES -> EP llnzYle - Ploducl colllPltx Step 3 - Release ofproducl frort ettz-r'ure ccltllJrlc:::' - EP+F+P Enzyme Ptodttcl cor, rPlex [:r Jl t = =l l__l -E_l ymc product - t f - - l l r ' \ l I - t # n L-I T_-] hr z\ l t c l ' Li ' ( l r . l ru|ffi l nr \ r r l j \ . l l 1 l I : ' l s I n \ l ' ( - ' ' l h' l l l l c ' ei r r l Pl c' r bl i] 'Peptisation: The process ofconverting a freshly ' ' pr.purrd precipitate into colloidal form by the uaii,ion of a suitable electrolyte in small amounts. 321 a] Write the Snr mechanism for the conversion of bromomethane to ethanol' bl ExPl ai n Wurt z-Fi t t i g react i on crarnPle' c] What i s DDT? , Ans: al EqLral i on ( l l l l l l l I l i trl Wurtz-l' ' ittig Ilcaction: Wben an alkyl halide rcacls rvith S,,dir,n.' anil an ar1' l halide in the presencc ofdry cther, aikyl benzene is formed' ' A ctnc cg (' i l Rr. : r' t n, R, {9 ! ' ' ' l ' ' i rt ) r\ ' rnr cl Dichloro diphenyl trichloro ethane 33 | | al)I{ot is phcnol manufacturcd from Cumcne? b| Complctc the following roactions: i l R cl l 2oH cr o' - r CH. l Cu, i j ] cl r - ( ol 1 +k' ct l , Ans: al Cumene is heated rvith air at about 400 K' It ges oxidizrd to form cumene hydroperoxidc' Cumene Cumcnei-lYdroPeroxide Cumene Hydroperoxide on acidification with dil H,Soo g:ves Phenol and Acctone' CH. I an I - [ ifl Electrophoresis: The migration of colloidal part i cl es t owards t he opposi t el y charged ilectrode under the influence of the applied 341 electric current. bl D R-cH.oH co' >R-cHo + }I,o Primary alcohol AldehYde CI-I ,-, A-.u --l+* 69,-41'fl't H.O : l \ n- ( - \ ' r ' t i Tl K l l "t I cH cl l , ltrtionary Butyl alcohol But-2-ene al Ii,xplain thc following rcactions with an cxampl cl il Aldol condensation iil Gattcrmann - Koch rcaction t i Gin. .qu"tiun for the conversion of acctic acid toacctamidc Ans:a) i ) Al dol Condensati on: Al dehydes and Ketones containing at least one Llydrogen atgm in tt. pt"r.n.. Jf Oltutt NaoH as catalyst unJ.ti o.t sel f condensati on to form a S*-hYal o*Yuf athYat (al dol ) or B LIYdroxYketoneft etol)' i I , rri ' ?r' <rro-:' a-(l t' t' H (' rl {HO+' cH-ctl {-H LH!) rt lll I. oH l ) d ii) Gattcrman- Koch Reaction: Benzene is treated with Carbon monoxide and Hydrogen Chloride in the presence ofAnhydtous elcl, *hi"h giuts benzaldehYde' HCI/Alcl. ^(' no I Ol "co, o- . I OJ \ r / ' """r """" V Llenzrne BenzaldehYde bl cil,cooH + NH,--)cH3-cooNHp AmmoniurnAcetate cH3-CONH2+H2O Acetamide - c-{)- AceticAcid ffifiH ffi 351 t a1 t*Ot"' n aarbylaminc rcaction. bJHow do you convcr t Ni t r obenzenc t o Aniline? Givc cquation. cl Met hyl ami nc i s a st r ong base t han ammoni a. Gi vc rcason. Ans:al Carbylaminc Rcaction: When primary amines are trcated with Chloroform and alcoholic Pottasium llydroxide solution, foul smelling isocyanides (carbylamine) are formed. RN H, +C HC I 3+3 KOH +i ! l RNC+3 KC/ + 3H,o b] Convenion ofNitroberzene to Anilinc @-"_i*6;l:ill,, c I Mcthylamirre is a slrong base than ammonia due to r I effect of CI-I, group which increases availability of electrons on the nitrogen ley'a] write the Haworth slructure of Maltose. bl What is a peptide linkagc? How many peptide bonds are prcsent in a heptapeptidc? c] Name the vitamin responsible for coagulation ofblood Ans: a] lr4altose b] The t- .(,-trH") amide linkage present between NH, ErouP of an .c - amino acid & -COOH of another .c - amino acid is termed as a pcpl i t l e l r l r l , l r l ' t l l r ' t ' r r ' hcpt l r l x: pl i t l e cl Vi t ar ni r t K (:i l .ot1 CH. OH 6' ^r Whal ar c I l t cr r t r osct t t t t l ' p. l \ t t t ' t ' r ' r examplc. b] Explainwlcanizittion tri rttlrl x r' ' cl What are biodegiadablc poll' rrrcrs' i Ans: The pol ymers whi ch arc scl t l i sol i Ll : ; ; 11 l , rt t t t temperature and upon heating bccolttc ltitl ' l ; tr r' i i nsol ubl e masses are cal l ed t hcrnt oscl l rrrl ' pollmers. These can't be remortlclcd eg: bakelite or urea formaldehyde resin or lirv suitable example b] The process ofheating ofrubber with sulphur t o about 100-140' c t o make i t more cl ast i c & durable is called in rulcanisation Cross linkingofpllT nerchains takes place rtpon vulcanisation through zulphw atoms. CH. ^. . \ ^, , ^, , , _ CI ] _C=C}I _CI I . CH ( S i r -bH-c=cu-cH,-cFl- I CH, c] These are t he pol ymers whi ch undergo envircnmental degradation due to fte action of microorganisms.