REVlSlON DATE: 16/12/2009

SAFETY DATA SHEET

LOW BAKE STOVlNG ENAMEL PAlNT LCF
1 lDENTlFlCATlON OF THE SUBSTANCE/PREPARATlON AND OF THE COMPANY/UNDERTAKlNG
PRODUCT NAME LOW BAKE STOVlNG ENAMEL PAlNT LCF
PRODUCT NO. LB LCF
R J STOKES & CO LTD SUPPLlER
BLACKWELL ROAD
HUTHWAlTE
NOTTlNGHAMSHlRE
NG17 2RL
Tel: 01623 510585
Fax: 01623 556481
2 HAZARDS lDENTlFlCATlON
Flammable. Harmful by inhalation and in contact with skin. lrritating to eyes and skin.
CLASSlFlCATlON (1999/45) Xn;R20/21. Xi;R36/38. R10.
ENVlRONMENT
The product is not expected to be hazardous to the environment.
PHYSlCAL AND CHEMlCAL HAZARDS
The product is flammable, and heating may generate vapours which may form explosive vapour/air mixtures.
HUMAN HEALTH
ln high concentrations, vapours and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. Harmful by inhalation
and in contact with skin. The product is irritating to eyes and skin.
3 COMPOSlTlON/lNFORMATlON ON lNGREDlENTS
EC No. Name Classification (67/548) CAS-No. Content
200-751-6 BUTANOL-norm R10 Xn;R22 Xi;R37/38,R41 R67 71-36-3 5-10%
202-849-4 ETHYLBENZENE F;R11 Xn;R20 100-41-4 1-5%
200-001-8 FORMALDEHYDE ...% Carc. Cat. 3;R40 T;R23/24/25 C;R34 R43 50-00-0 < 1%
201-148-0 lSO-BUTANOL R10 Xi;R37/38,R41 R67 78-83-1 1-5%
202-049-5 NAPHTHALENE Carc. Cat. 3;R40 Xn;R22 N;R50/53 91-20-3 < 1%
265-198-5 SOLVENT NAPHTHA (PETROLEUM), HEAVY
AROM.; KEROSlNE - UNSPEClFlED
Xn;R65 64742-94-5 10-30%
215-535-7 XYLENE R10 Xn;R20/21 Xi;R38 1330-20-7 10-30%
The Full Text for all R-Phrases are Displayed in Section 16
COMPOSlTlON COMMENTS
The Data Shown is in accordance with the latest EC Directives.
4 FlRST-AlD MEASURES
GENERAL lNFORMATlON
General first aid, rest, warmth and fresh air. Do not give victim anything to drink if he is unconscious. Get medical attention if any discomfort
continues.
lNHALATlON
Place unconscious person on the side in the recovery position and ensure breathing lf respiratory problems, artificial respiration/oxygen. Get
medical attention if any discomfort continues.
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REVlSlON DATE: 16/12/2009
LOW BAKE STOVlNG ENAMEL PAlNT LCF
lNGESTlON
lmmediately rinse mouth and drink plenty of water or milk. Keep person under observation. Do not induce vomiting. lf vomiting occurs, keep
head low. Transport immediately to hospital and bring along these instructions.
SKlN CONTACT
lmmediately remove contaminated clothing. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked
through and flush skin with water.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get
medical attention promptly if symptoms occur after washing.
5 FlRE-FlGHTlNG MEASURES
EXTlNGUlSHlNG MEDlA
Fire can be extinguished using: Water spray, fog or mist. Foam, carbon dioxide or dry powder. Dry chemicals, sand, dolomite etc.
SPEClAL FlRE FlGHTlNG PROCEDURES
Use pressurised air mask if product is involved in a fire. Cool containers exposed to flames with water until well after the fire is out.
UNUSUAL FlRE & EXPLOSlON HAZARDS
Fire causes formation of toxic gases.
PROTECTlVE MEASURES lN FlRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACClDENTAL RELEASE MEASURES
PERSONAL PRECAUTlONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVlRONMENTAL PRECAUTlONS
Avoid discharge into drains, water courses or onto the ground.
SPlLL CLEAN UP METHODS
Keep combustibles away from spilled material. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb
in vermiculite, dry sand or earth and place into containers. Wash thoroughly after dealing with a spillage.
7 HANDLlNG AND STORAGE
USAGE PRECAUTlONS
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved
respirator if air contamination is above accepted level.
STORAGE PRECAUTlONS
Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and
well-ventilated place. Keep in original container. Avoid contact with oxidising agents.
STORAGE CLASS
Flammable liquid storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTlON
Std STEL - 15 min TWA - 8 hrs
Name
Notes
WEL 50 ppm(Sk) 154
mg/m3(Sk)
BUTANOL-norm
100 ppm(Sk) 441
mg/m3(Sk)
WEL 125 ppm(Sk) 552
mg/m3(Sk)
ETHYLBENZENE
50 ppm 154 mg/m3 WEL 75 ppm 231 mg/m3 lSO-BUTANOL
50 ppm(Sk) 220
mg/m3(Sk)
WEL 100 ppm(Sk) 441
mg/m3(Sk)
XYLENE
WEL = Workplace Exposure Limit.
lNGREDlENT COMMENTS
WEL = Workplace Exposure Limits
PROTECTlVE EQUlPMENT
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REVlSlON DATE: 16/12/2009
LOW BAKE STOVlNG ENAMEL PAlNT LCF
PROCESS CONDlTlONS
Provide eyewash station.
ENGlNEERlNG MEASURES
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. All
handling to take place in well-ventilated area.
RESPlRATORY EQUlPMENT
Wear mask supplied with: Gas cartridge suitable for organic substances.
HAND PROTECTlON
Use protective gloves made of: Neoprene. Nitrile. Rubber (natural, latex).
EYE PROTECTlON
Wear splash-proof eye goggles to prevent any possibility of eye contact.
OTHER PROTECTlON
Wear appropriate clothing to prevent any possibility of skin contact.
HYGlENE MEASURES
DO NOT SMOKE lN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove
any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke.
9 PHYSlCAL AND CHEMlCAL PROPERTlES
APPEARANCE Viscous liquid
RELATlVE DENSlTY 0.95 to 1.30 FLASH POlNT (C) 23 to 55C
VOLATlLE ORGANlC COMPOUND
(VOC)
460 to 500 grams per Litre
10 STABlLlTY AND REACTlVlTY
STABlLlTY
No particular stability concerns.
CONDlTlONS TO AVOlD
Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.
HAZARDOUS DECOMPOSlTlON PRODUCTS
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
11 TOXlCOLOGlCAL lNFORMATlON
GENERAL lNFORMATlON
Prolonged and repeated contact with solvents over a long period may lead to permanent health problems.
lNHALATlON
ln high concentrations, vapours may irritate throat and respiratory system and cause coughing. Harmful by inhalation.
lNGESTlON
Gastrointestinal symptoms, including upset stomach. Pneumonia may be the result if vomited material containing solvents reaches the
lungs.
SKlN CONTACT
Acts as a defatting agent on skin. May cause cracking of skin, and eczema. lrritating to skin. Harmful in contact with skin.
EYE CONTACT
lrritating and may cause redness and pain.
ROUTE OF ENTRY
lngestion. Skin absorption. lnhalation.
12 ECOLOGlCAL lNFORMATlON
ECOTOXlClTY
The product is not expected to be hazardous to the environment.
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REVlSlON DATE: 16/12/2009
LOW BAKE STOVlNG ENAMEL PAlNT LCF
13 DlSPOSAL CONSlDERATlONS
GENERAL lNFORMATlON
Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.
DlSPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements. Make sure containers are empty before discarding (explosion
risk). Absorb in vermiculite or dry sand and dispose of at a licenced hazardous waste collection point.
14 TRANSPORT lNFORMATlON
PROPER SHlPPlNG NAME PAlNT
1263 UN NO. ROAD Class 3: Flammable liquids. ADR CLASS
lll ADR PACK GROUP (E) TUNNEL RESTRlCTlON CODE
15 REGULATORY lNFORMATlON
LABELLlNG
Harmful
CONTAlNS XYLENE
RlSK PHRASES
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R36/38 lrritating to eyes and skin.
SAFETY PHRASES
S24/25 Avoid contact with skin and eyes.
S26 ln case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S36/37 Wear suitable protective clothing and gloves.
S51 Use only in well-ventilated areas.
S60 This material and its container must be disposed of as hazardous waste.
P14 Contains FORMALDEHYDE ...%. May produce an allergic reaction.
EU DlRECTlVES
Dangerous Preparations Directive 1999/45/EC.
STATUTORY lNSTRUMENTS
The Chemicals (Hazard lnformation and Packaging for Supply) Regulations 2009 (S.l 2009 No. 716).
APPROVED CODE OF PRACTlCE
Classification and Labelling of Substances and Preparations Dangerous for Supply.
NATlONAL REGULATlONS
The Chemicals (Hazard lnformation and Packaging for Supply) Regulations 2002. No. 1689. Workplace Exposure Limits 2005 (EH40) The
Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2007 (CDG 2007)
16 OTHER lNFORMATlON
REVlSlON COMMENTS
Replaces MSDS from the old system.
REVlSlON DATE 16/12/2009
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REVlSlON DATE: 16/12/2009
LOW BAKE STOVlNG ENAMEL PAlNT LCF
REV. NO./REPL. SDS
GENERATED
1
RlSK PHRASES lN FULL
Flammable. R10
Highly flammable. R11
Harmful by inhalation. R20
Harmful by inhalation and in contact with skin. R20/21
Harmful if swallowed. R22
Toxic by inhalation, in contact with skin and if swallowed. R23/24/25
Causes burns. R34
lrritating to respiratory system. R37
lrritating to respiratory system and skin. R37/38
lrritating to skin. R38
Limited evidence of a carcinogenic effect. R40
Risk of serious damage to eyes. R41
May cause sensitisation by skin contact. R43
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R50/53
Harmful: may cause lung damage if swallowed. R65
Vapours may cause drowsiness and dizziness. R67
DlSCLAlMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty
guarantee or representation is made to its accuracy, reliability or completeness. lt is the user's responsibility to satisfy himself as to the suitability of such
information for his own particular use.
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