IN HA HC

S pin :
(-) Zn(r) Zn
2+
(aq) (C) Cu
2+
(aq) (C) Cu(r) (+)
(C) nng dung dich mui Cu
2+
va Zn
2+
Qui c :
- !ch "h#ng $ng ch% ranh gii gi&a 2 'ha : 'ha r(n ()im *+!i) va 'ha *,ng
(dd)
- -ai v!ch "h#ng $ng ch% ranh gii gi&a 2 'ha *,ng *i.n h. vi nhau /0ng
m" c1u ni
Cng th Nerst: 2 3 2
4
+
5 6
5 6
*g
478 9 4
kh
oxh
n
: ;' d<ng cng "h$c =>r?" ch+ "@ng *+!i i. n cAc c< "hB :
aC Di. n cAc )im *+!i: (i. n cAc *+!i E)
F
n+
+ n> F
2 3 2
4
+
5 *g6
478 9 4
+ n
M
n
/C Di. n cAc *+!i 2:
GH : i. n cAc ca*+m>n :
-g2C*2 + 2> 2-g + 2C*
-

-aI -g2
2+
+ 2> 2-g
2 3 2
4
+
5 *g6
2
478 9 4
2
2
+
Hg

H+ -g2C*2 *a mui J" "an n.n "r+ng dung dich cK cLn /0ng :
-g2C*2 -g2
2+
+ 2C*
-

Ga cK "Jch ? "an : G("an) 3 6-g2
2+
56C*
-
5
2
6-g2
2+
5 3
2
("an)
5 6

Cl
T
GhaI va+ 'hMng "rNnh "r.n "a cK : 2(ca*) 3 2
4
+
2
("an)
5 6
*g
2
478 9 4

Cl
T
N G("an) *a m" h0ng ? n.n B "huL n "i. n "a viO" : 2(ca*) 3 2
4
+
2 2
*g
2
478 9 4
Cl Hg
T
-
2
5 *g6
2
478 9 4

Cl
DP " 2
4
(ca*) 3 2
4
+
2 2
*g
2
478 9 4
Cl Hg
T
(*a m" h0ng ? Q nhi. " RSc inh)
Ga cK : 2(ca*) 3 2
4
(ca*) - 49478*g6C*
-
5
L I "hO cTa i. n cAc ca*+m>n ch% 'h< "huc va+ nng C*
-
"r+ng dung dichU V )c "hN
2
4
(ca*) 3 + 492WX v
cC Di. n cAc +Ri hKa )hY : Zm "hanh )im *+!i "rM haI gra'hi" nh[ng "r+ng dung
dich ch$a ng "h\i d!ng +Ri hKa va d!ng )hY cTa cP ' +Ri hKa )hY
GH : i. n cAc ]>
^+
9 ]>
2+
_" `n
a+
9 `n
2+
_"
_hbn $ng i. n cAc : ]>
^+
+ E> ]>
2+
c `n
a+
+ 2> `n
2+
2 3 2
4
+ 49478*g
5 6
5 6
2
^
+
+
Fe
Fe
GH : i vi i. n cAc : Fnda
-
9 -
+
9 Fn
2+
_"
_hbn $ng i. n cAc : Fnda
-
+ X-
+
+ 7> Fn
2+
+ a-2d
2 3 2
4
+
5 6
5 56 6
*g
7
478 9 4
2
X
a
+
+
Mn
H MnO
dC Di. n cAc )hJ: Zm m" "hanh )im *+!i "rM haI gra'hi" Kng vai "re vL " dfn
i. n ng "h\i *a vL " mang cSc 'hLn "Y )hJ gc nh[ng "r+ng dung dich ch$a i+n "Mng
$ng va gc /h+ hea /0ng )hJ "Mng $ngU
GH : Di. n cAc hidr+ :
-^d
+
+ > i -2 + -2d
GhO cTa i. n cAc : 2 3 2
4
+ 49478*g
2
5 6
^
H
P
O H
+
vN 2
4
3 4 va "hng "h\ng _ 3 E a"m
n.n '" cK d!ng :
2 3 49478*g6-^d5
+

Ga cK : '- 3 - *g6-^d5
+
n.n 2 3 - 49478'-
d29 d-
-
_"
_hbn $ng i. n cAc : d2 + 2-2d + a> ad-
-

2 3 2
4
+
a
5 6
*g
a
478 9 4
2

OH
P
O
Ga cK :

+ OH O H O E a C 2
4
2 2
3 + 49a4E v n.n :
2 3 49a4E +
a
5 6
*g
a
478 9 4
2

OH
P
O
nOu "a gi& ch+ _d2 3 E a"m "hN :
2 3 49a4E - 49478*g6d-
-
5
Mi quan h gia G
0
p , E
0
pin va hng s cn bng cua phan ng : K
Ga cK : Z
4
3 - n]2
4
mP " )hSc "hN Z
4
3 - jG*nk *nk 3 pin E
RT
nE
4
GhaI ] 3 8W744 C c j 3 X9^Ea l c G 3 28X k ri chuIBn ?ang *g "a cK : *gk 3
478 9 4
4
pin
nE

k 3
478 9 4
4
E4
nE
(n *a ? >*>c"r+n "ra+ mi "r+ng 'hbn $ng +Ri hKa )hY)