Page: 1

SAFETY DATA SHEET

Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
(!$D
PY)!0091
*ersion: 1+1
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
&s,-an. Regu-ator/ n0ormation Number 11800132213721
P+O+ )o3 2219 %e-e4,one 516179013333
7o-umbus8 O9 63215 #mergen:/ te-e4,one 118001&S9!&ND
;11800127612253<
Pro.u:t name PYRO!" PR#M$M S%&R%N' (!$D
Pro.u:t :o.e PY)!0091
Pro.u:t $se Des:ri4tion No .ata
2. HAZARDS IDENTIFICATION
Emergenc O!er!"e#
&44earan:e: -i=ui.
#>%R#M#!Y (!&MM&)!# !?$D &ND *&POR+ *&POR M&Y 7&$S#
(!&S9 (R#+ 7ON%#N%S $ND#R PR#SS$R#+ M&Y &((#7% %9# 7#N%R&!
N#R*O$S SYS%#M 7&$SN' D@@N#SS8 9#&D&79# OR N&$S#&+ 7&$S#S
#Y# RR%&%ON+ M&Y 7&$S# SAN &ND R#SPR&%ORY %R&7%
RR%&%ON+PRO!ON'#D OR R#P#&%#D 7ON%&7% M&Y DRY SAN &ND
7&$S# D#RM&%%S &ND )$RNS+
P$%en%"&' He&'%( E))ec%*
R$+%e* $) e,-$*+re
n,a-ation8 SBin absor4tion8 SBin :onta:t8 #/e 7onta:t
Ee c$n%&c%
Ma/ :ause mi-. e/e irritation+ S/m4toms in:-u.e stinging8 tearing8 an. re.ness+
S."n c$n%&c%
7an :ause sBin irritation+ Pro-onge. or re4eate. :onta:t ma/ .r/ t,e sBin+
S/m4toms ma/ in:-u.e re.ness8 burning8 an. .r/ing an. :ra:Bing o0 sBin8 burns an.
ot,er sBin .amage+ Passage o0 t,is materia- into t,e bo./ t,roug, t,e sBin is 4ossib-e8 but
it is un-iBe-/ t,at t,is Cou-. resu-t in ,arm0u- e00e:ts .uring sa0e ,an.-ing an. use+
Inge*%"$n
Page 1 / 10
Page: 2
SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
(!$D
PY)!0091
*ersion: 1+1
SCa--oCing sma-- amounts o0 t,is materia- .uring norma- ,an.-ing is not -iBe-/ to
:ause ,arm0u- e00e:ts+ SCa--oCing -arge amounts ma/ be ,arm0u-+ %,is materia- :an get
into t,e -ungs .uring sCa--oCing or vomiting+ %,is resu-ts in -ung in0-ammation an.
ot,er -ung inDur/+
In(&'&%"$n
)reat,ing aeroso- an./or mist is 4ossib-e C,en materia- is s4ra/e.+ &eroso- an.
mist ma/ 4resent a greater risB o0 inDur/ be:ause more materia- ma/ be 4resent in t,e air
t,an 0rom va4or a-one+ )reat,ing sma-- amounts o0 t,is materia- .uring norma- ,an.-ing
is not -iBe-/ to :ause ,arm0u- e00e:ts+ )reat,ing -arge amounts ma/ be ,arm0u-+
S/m4toms are not e34e:te. at air :on:entrations be-oC t,e re:ommen.e. e34osure
-imits8 i0 a44-i:ab-e ;see Se:tion 8+<+
Aggr&!&%e/ Me/"c&' C$n/"%"$n
Pree3isting .isor.ers o0 t,e 0o--oCing organs ;or organ s/stems< ma/ be
aggravate. b/ e34osure to t,is materia-:8 sBin8 -ung ;0or e3am4-e8 ast,ma1-iBe
:on.itions<8 :entra- nervous s/stem8 ma-e re4ro.u:tive s/stem8 n.ivi.ua-s Cit,
4ree3isting ,eart .isor.ers ma/be more sus:e4tib-e to arr,/t,mias ;irregu-ar ,eartbeats<
i0 e34ose. to ,ig, :on:entrations o0 t,is materia-+
Sm-%$m*
Signs an. s/m4toms o0 e34osure to t,is materia- t,roug, breat,ing8 sCa--oCing8
an./or 4assage o0 t,e materia- t,roug, t,e sBin ma/ in:-u.e:8 stoma:, or intestina- u4set
;nausea8 vomiting8 .iarr,ea<8 irritation ;nose8 t,roat8 airCa/s<8 :entra- nervous s/stem
.e4ression ;.iEEiness8 .roCsiness8 CeaBness8 0atigue8 nausea8 ,ea.a:,e8
un:ons:iousness<8 -oss o0 a44etite8 -oss o0 :oor.ination8 irregu-ar ,eartbeat8 nar:osis
;.aEe. or s-uggis, 0ee-ing<
T&rge% Org&n*
Pro-onge. an. re4eate. e34osure to n1,e3ane ma/ :ause 4eri4,era- neuro4at,/ b/
.amaging 4eri4,era- nerve tissue ;t,at o0 t,e arms an. -egs< an. resu-t in mus:u-ar
CeaBness an. -oss o0 sensation+8 Overe34osure to t,is materia- ;or its :om4onents< ,as
been suggeste. as a :ause o0 t,e 0o--oCing e00e:ts in -aborator/ anima-s:8 mi-.8 reversib-e
-iver e00e:ts8 mi-.8 reversib-e Bi.ne/ e00e:ts8 nasa- .amage8 testis .amage8 -ung .amage8
Overe34osure to t,is materia- ;or its :om4onents< ,as been suggeste. as a :ause o0 t,e
0o--oCing e00e:ts in ,umans:8 visua- im4airment8 :entra- nervous s/stem e00e:ts
C&rc"n$gen"c"%
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Page: 3
SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
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PY)!0091
*ersion: 1+1
%,is materia- is not -iste. as a :ar:inogen b/ t,e nternationa- &gen:/ 0or
Resear:, on 7an:er ;&R7<8 t,e Nationa- %o3i:o-og/ Program ;N%P<8 or t,e
O::u4ationa- Sa0et/ an. 9ea-t, &.ministration ;OS9&<+
Re-r$/+c%"!e (&0&r/
%,is materia- ;or a :om4onent< ,as been s,oCn to :ause ,arm to t,e 0etus in
-aborator/ anima- stu.ies+ 9arm to t,e 0etus o::urs on-/ at e34osure -eve-s t,at ,arm t,e
4regnant anima-+ %,e re-evan:e o0 t,ese 0in.ings to ,umans is un:ertain+
1. COMPOSITION/INFORMATION ON INGREDIENTS
C$m-$nen%* CAS2N$. C$ncen%r&%"$n
n19#P%&N# 16218212 FG501H70I
#%9Y! #%9#R 5012917 FG201H30I
3. FIRST AID MEASURES
Ee*
0 s/m4toms .eve-o48 move in.ivi.ua- aCa/ 0rom e34osure an. into 0res, air+
(-us, e/es gent-/ Cit, Cater C,i-e ,o-.ing e/e-i.s a4art+ 0 s/m4toms 4ersist or t,ere is
an/ visua- .i00i:u-t/8 seeB me.i:a- attention+
S."n
Remove :ontaminate. :-ot,ing+ (-us, e34ose. area Cit, -arge amounts o0 Cater+
0 sBin is .amage.8 seeB imme.iate me.i:a- attention+ 0 sBin is not .amage. an.
s/m4toms 4ersist8 seeB me.i:a- attention+ !aun.er :-ot,ing be0ore reuse+
Inge*%"$n
SeeB me.i:a- attention+ 0 in.ivi.ua- is .roCs/ or un:ons:ious8 .o not give
an/t,ing b/ mout,J 4-a:e in.ivi.ua- on t,e -e0t si.e Cit, t,e ,ea. .oCn+ 7onta:t a
4,/si:ian8 me.i:a- 0a:i-it/8 or 4oison :ontro- :enter 0or a.vi:e about C,et,er to in.u:e
vomiting+ 0 4ossib-e8 .o not -eave in.ivi.ua- unatten.e.+
In(&'&%"$n
0 s/m4toms .eve-o48 move in.ivi.ua- aCa/ 0rom e34osure an. into 0res, air+ 0
s/m4toms 4ersist8 seeB me.i:a- attention+ 0 breat,ing is .i00i:u-t8 a.minister o3/gen+
Aee4 4erson Carm an. =uietJ seeB imme.iate me.i:a- attention+
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Page: 6
SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
(!$D
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*ersion: 1+1
N$%e* %$ -(*"c"&n
H&0&r/*4 n,a-ation o0 ,ig, :on:entrations o0 t,is materia-8 as :ou-. o::ur in
en:-ose. s4a:es or .uring .e-iberate abuse8 ma/ be asso:iate. Cit, :ar.ia: arr,/t,mias+
S/m4at,omimeti: .rugs ma/ initiate :ar.ia: arr,/t,mias in 4ersons e34ose. to t,is
materia-+ %,is materia- is an as4iration ,aEar.+ Potentia- .anger 0rom as4iration must be
Ceig,e. against 4ossib-e ora- to3i:it/ ;See Se:tion 2 1 SCa--oCing< C,en .e:i.ing
C,et,er to in.u:e vomiting+
Tre&%men%4 No in0ormation avai-ab-e+
5. FIRE2FIGHTING MEASURES
S+"%&6'e e,%"ng+"*("ng me/"&
Kater mist8 7arbon .io3i.e ;7O2<8 Dr/ :,emi:a-
H&0&r/$+* c$m6+*%"$n -r$/+c%*
Ma/ 0orm:
Prec&+%"$n* )$r )"re2)"g(%"ng
Materia- is vo-ati-e an. rea.i-/ gives o00 va4ors C,i:, ma/ trave- a-ong t,e
groun. or be move. b/ venti-ation an. ignite. b/ 4i-ot -ig,ts8 0-ames8 s4arBs8 ,eaters8
smoBing8 e-e:tri: motors8 stati: .is:,arge or ot,er ignition sour:es at -o:ations near t,e
materia- ,an.-ing 4oint+ Never use Ce-.ing or :utting tor:, on or near .rum ;even em4t/<
be:ause 4ro.u:t ;even Dust resi.ue< :an ignite e34-osive-/+Kear 0u-- 0ire0ig,ting turn1out
gear ;0u-- )unBer gear<8 an. res4irator/ 4rote:tion ;S7)&<+
7. ACCIDENTA8 RE8EASE MEASURES
Per*$n&' -rec&+%"$n*
(or 4ersona- 4rote:tion see se:tion 8+ Persons not Cearing 4rote:tive e=ui4ment
s,ou-. be e3:-u.e. 0rom area o0 s4i-- unti- :-ean1u4 ,as been :om4-ete.+
En!"r$nmen%&' -rec&+%"$n*
Prevent run1o00 to seCers8 streams or ot,er bo.ies o0 Cater+ 0 run1o00 o::urs8
noti0/ 4ro4er aut,orities as re=uire.8 t,at a s4i-- ,as o::urre.+
Me%($/* )$r c'e&n"ng +-
&bsorb -i=ui. on vermi:u-ite8 0-oor absorbent or ot,er absorbent materia-+
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Page: 2
SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
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PY)!0091
*ersion: 1+1
9. HAND8ING AND STORAGE
H&n/'"ng
7ontainers o0 t,is materia- ma/ be ,aEar.ous C,en em4tie.+ Sin:e em4tie.
:ontainers retain 4ro.u:t resi.ues ;va4or8 -i=ui.8 an./or so-i.<8 a-- ,aEar. 4re:autions
given in t,e .ata s,eet must be observe.+ &voi. 4ro-onge. or 0re=uent-/ re4eate. sBin
:onta:t Cit, t,is materia-+ SBin :onta:t :an be minimiEe. b/ Cearing im4ervious
4rote:tive g-oves+ &s Cit, a-- 4ro.u:ts o0 t,is nature8 goo. 4ersona- ,/giene is essentia-+
9an.s an. ot,er e34ose. areas s,ou-. be Cas,e. t,oroug,-/ Cit, soa4 an. Cater a0ter
:onta:t8 es4e:ia--/ be0ore eating an./or smoBing+ Regu-ar -aun.ering o0 :ontaminate.
:-ot,ing is essentia- to re.u:e in.ire:t sBin :onta:t Cit, t,is materia-+ Stati: ignition
,aEar. :an resu-t 0rom ,an.-ing an. use+ #-e:tri:a--/ bon. an. groun. a-- :ontainers8
4ersonne- an. e=ui4ment be0ore trans0er or use o0 materia-+ S4e:ia- 4re:autions ma/ be
ne:essar/ to .issi4ate stati: e-e:tri:it/ 0or non1:on.u:tive :ontainers+ $se 4ro4er bon.ing
an. groun.ing .uring 4ro.u:t trans0er as .es:ribe. in Nationa- (ire Prote:tion
&sso:iation .o:ument N(P& 77+
S%$r&ge
Do not store near e3treme ,eat8 o4en 0-ame8 or sour:es o0 ignition+
:. E;POSURE CONTRO8S / PERSONA8 PROTECTION
E,-$*+re G+"/e'"ne*
n2HEPTANE 1322:225
&7'9 time Ceig,te. average 600 44m
&7'9 S,ort term e34osure -imit 200 44m
NOS9 Re:ommen.e. e34osure -imit
;R#!<:
82 44m
NOS9 Re:ommen.e. e34osure -imit
;R#!<:
320 mg/m3
NOS9 7ei-ing !imit *a-ue an. %ime
Perio. ;i0 s4e:i0ie.<:
660 44m
NOS9 7ei-ing !imit *a-ue an. %ime
Perio. ;i0 s4e:i0ie.<:
18800 mg/m3
OS9& @1 Permissib-e e34osure -imit 200 44m
OS9& @1 Permissib-e e34osure -imit 28000 mg/m3
OS9& @1& time Ceig,te. average 600 44m
OS9& @1& time Ceig,te. average 18500 mg/m3
OS9& @1& S,ort term e34osure -imit 200 44m
Page 2 / 10
Page: 5
SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
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PY)!0091
*ersion: 1+1
OS9& @1& S,ort term e34osure -imit 28000 mg/m3
$S 7& O#! %ime Keig,te. &verage ;%K&<
Permissib-e #34osure !imit ;P#!<:
600 44m
$S 7& O#! %ime Keig,te. &verage ;%K&<
Permissib-e #34osure !imit ;P#!<:
18500 mg/m3
$S 7& O#! S,ort term e34osure -imit 200 44m
$S 7& O#! S,ort term e34osure -imit 28000 mg/m3
&7'9 time Ceig,te. average 600 44m
&7'9 S,ort term e34osure -imit 200 44m
ETHY8 ETHER 7<22=29
&7'9 time Ceig,te. average 600 44m
&7'9 S,ort term e34osure -imit 200 44m
OS9& @1 Permissib-e e34osure -imit 600 44m
OS9& @1 Permissib-e e34osure -imit 18200 mg/m3
Gener&' &/!"ce
%,ese re:ommen.ations 4rovi.e genera- gui.an:e 0or ,an.-ing t,is 4ro.u:t+
Persona- 4rote:tive e=ui4ment s,ou-. be se-e:te. 0or in.ivi.ua- a44-i:ations an. s,ou-.
:onsi.er 0a:tors C,i:, a00e:t e34osure 4otentia-8 su:, as ,an.-ing 4ra:ti:es8 :,emi:a-
:on:entrations an. venti-ation+ t is u-timate-/ t,e res4onsibi-it/ o0 t,e em4-o/er to
0o--oC regu-ator/ gui.e-ines estab-is,e. b/ -o:a- aut,orities+
E,-$*+re c$n%r$'*
Provi.e su00i:ient me:,ani:a- ;genera- an./or -o:a- e3,aust< venti-ation to
maintain e34osure be-oC %!*;s<+
Ee -r$%ec%"$n
7,emi:a- s4-as, gogg-es in :om4-ian:e Cit, OS9& regu-ations are a.vise.J
,oCever8 OS9& regu-ations a-so 4ermit ot,er t/4e sa0et/ g-asses+ 7onsu-t /our sa0et/
re4resentative+
S."n &n/ 6$/ -r$%ec%"$n
Kear resistant g-oves ;:onsu-t /our sa0et/ e=ui4ment su44-ier<+
%o 4revent re4eate. or 4ro-onge. sBin :onta:t8 Cear im4ervious :-ot,ing an. boots+
Re*-"r&%$r -r$%ec%"$n
0 CorB4-a:e e34osure -imit;s< o0 4ro.u:t or an/ :om4onent is e3:ee.e. ;see
e34osure gui.e-ines<8 a NOS91a44rove. air su44-ie. res4irator is a.vise. in absen:e o0
4ro4er environmenta- :ontro-+ OS9& regu-ations a-so 4ermit ot,er NOS9 res4irators
;negative 4ressure t/4e< un.er s4e:i0ie. :on.itions ;see /our in.ustria- ,/gienist<+
#ngineering or a.ministrative :ontro-s s,ou-. be im4-emente. to re.u:e e34osure+
Page 5 / 10
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SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
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*ersion: 1+1
=. PHYSICA8 AND CHEMICA8 PROPERTIES
P(*"c&' *%&%e -i=ui.
F$rm -i=ui.
C$'$+r No .ata
O/$+r No .ata
B$"'"ng -$"n%/6$"'"ngr&nge No .ata
-H No .ata
F'&*( -$"n% 169 L( / 162 L7
E!&-$r&%"$n r&%e No .ata
E,-'$*"$n '"m"%* No .ata
>&-$+r -re**+re No .ata
>&-$+r /en*"% No .ata
Den*"% 0+705 g/:m3
No .ata
S$'+6"'"% No .ata
P&r%"%"$n c$e))"c"en%4 n2
$c%&n$'/#&%er
No .ata
A+%$"gn"%"$n %em-er&%+re No .ata
1<. STABI8ITY AND REACTI>ITY
S%&6"'"%
Stab-e+
C$n/"%"$n* %$ &!$"/
&voi. ,eat8 o4en 0-ame8 an. 4ro-onge. storage at e-evate. tem4eratures+
Inc$m-&%"6'e -r$/+c%*
&voi. :onta:t Cit,:8 strong o3i.iEing agents
H&0&r/$+* /ec$m-$*"%"$n -r$/+c%*
Ma/ 0orm:8 :arbon .io3i.e an. :arbon mono3i.e8 various ,/.ro:arbons
H&0&r/$+* re&c%"$n*
Pro.u:t Ci-- not un.ergo ,aEar.ous 4o-/meriEation+
Page 7 / 10
Page: 8
SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
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*ersion: 1+1
T(erm&' /ec$m-$*"%"$n
No .ata
11. TO;ICO8OGICA8 INFORMATION
Ac+%e $r&' %$,"c"%
n19#P%&N# !D 20 Rat: F 128000 mg/Bg
#%9Y! #%9#R !D 20 Rat: 38230 1 38920 mg/Bg
Ac+%e "n(&'&%"$n %$,"c"%
n19#P%&N# !7 20 Rat: 103 g/m3 8 6 ,
#%9Y! #%9#R !7 20 Rat: 32000 44m8 6 ,
Ac+%e /erm&' %$,"c"%
n19#P%&N# !D 20 Rabbit: F 28000 mg/Bg
12. ECO8OGICA8 INFORMATION
A?+&%"c %$,"c"%
Ac+%e &n/ Pr$'$nge/ T$,"c"% %$ F"*(
No .ata
Ac+%e T$,"c"% %$ A?+&%"c In!er%e6r&%e*
No .ata
En!"r$nmen%&' )&%e &n/ -&%(#&*
No .ata
11. DISPOSA8 CONSIDERATIONS
@&*%e /"*-$*&' me%($/*
Page 8 / 10
Page: 9
SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
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*ersion: 1+1
Dis4ose o0 in a::or.an:e Cit, a-- a44-i:ab-e -o:a-8 state an. 0e.era- regu-ations+
(or assistan:e Cit, /our Caste management nee.s 1 in:-u.ing .is4osa-8 re:/:-ing an.
Caste stream re.u:tion8 :onta:t &s,-an. DistributionMs #nvironmenta- Servi:es 'rou4 at
800153717922+

13. TRANSPORT INFORMATION
IMDG:
UN1993, FLAMMABLE LIQUID, N.O.S. (ETHYL ETHER, HEPTANE) 3, II
IATA_P:
UN1993, Flammabl l!"#!$, %.&.'. (ETHYL ETHER, HEPTANE) 3, II
IATA_C:
UN1993, Flammabl l!"#!$, %.&.'. (ETHYL ETHER, HEPTANE) 3, II
CFR_ROAD:
UN1993, Flammabl l!"#!$', %.&.'. (ETHYL ETHER, HEPTANE) 3, II
CFR_RAIL:
UN1993, Flammabl l!"#!$', %.&.'. (ETHYL ETHER, HEPTANE) 3, II
CFR_INWTR:
UN1993, Flammabl l!"#!$', %.&.'. (ETHYL ETHER, HEPTANE) 3, II
Dangerous goo.s .es:ri4tions ;i0 in.i:ate. above< ma/ not re0-e:t 4a:Bage siEe8 =uantit/8
en.1use or region1s4e:i0i: e3:e4tions t,at :an be a44-ie.+ 7onsu-t s,i44ing .o:uments 0or
.es:ri4tions t,at are s4e:i0i: to t,e s,i4ment+
15. REGU8ATORY INFORMATION
C&'")$rn"& Pr$-. 75
K&RNN'N %,is 4ro.u:t :ontains a :,emi:a- BnoCn in t,e State o0 7a-i0ornia to :ause
:an:er+
)#N@#N#
K&RNN'N %,is 4ro.u:t :ontains a :,emi:a- BnoCn in t,e State o0 7a-i0ornia to :ause
birt, .e0e:ts or ot,er re4ro.u:tive ,arm+
)#N@#N#
%O!$#N#
SARA H&0&r/ C'&**")"c&%"$n (ire 9aEar.
&:ute 9ea-t, 9aEar.
Page 9 / 10
Page: 10
SAFETY DATA SHEET
Revision Date: 01/28/2008
Print Date: 3/17/2010
MSDS Number: 000000022981
PYRO!" PR#M$M S%&R%N'
(!$D
PY)!0091
*ersion: 1+1
SARA 111 C$m-$nen%A*B
He&'%( F'&mm&6"'"% Re&c%"!"% O%(er
HMIS 1O 6 0
NFPA 1 6 0
17. OTHER INFORMATION
%,e in0ormation a::umu-ate. ,erein is be-ieve. to be a::urate but is not Carrante. to be
C,et,er originating Cit, t,e :om4an/ or not+ Re:i4ients are a.vise. to :on0irm in a.van:e
o0 nee. t,at t,e in0ormation is :urrent8 a44-i:ab-e8 an. suitab-e to t,eir :ir:umstan:es+ %,is
MSDS ,as been 4re4are. b/ &s,-an.Ms #nvironmenta- 9ea-t, an. Sa0et/ De4artment ;11
800132213721<+
Page 10 / 10