Applications of Matrices and Determinants: Adjoint, inverse properties, computation of inverses, solution of system of linear equations bymatrix inversion method. Rank of a matrix elementary transformation on a matrix, Cramers rule, non-homogeneous equations, homogeneous linear system and rank method.
Complex Numbers: Complex number system - conjugate, properties, ordered pair representation. Modulus Properties, geometrical representation, polar form, principal value, conjugate, sum, difference, product, quotient, vector interpretation, solutions of polynomial equations, De Moivres theorem and its applications. Roots of a complex number n th roots, cube roots, fourth roots.
Analytical Geometry of two dimensions: Definition of a conic general equation of a conic, classification with respect to the general equation of a conic, classification of conics with respect to eccentricity. Equations of conic sections (parabola, ellipse and hyperbola) in standard forms and general forms- Directrix, Focus and Latus rectum - parametric form of conics and chords. Tangents and normals cartesian form and parametric form- equation of chord of contact of tangents from a point (x 1 ,y 1 ) to all the above said curves. Asymptotes, Rectangular hyperbola Standard equation of a rectangular hyperbola.
Vector Algebra: Scalar Product angle between two vectors, properties of scalar product and applications of dot products. Vector product right handed and left handed systems, properties of vector product and applications of cross product - Product of three vectors Scalar triple product, properties of scalar triple product, vector triple Product.
Differential Calculus: Derivative as a rate measurer - rate of change, velocity, acceleration, related rates, derivative as a measure of slope, tangent, normal and angle between curves, maxima and minima. Mean value theorem - Rolles Theorem, Lagrange Mean Value Theorem, Taylors and Maclaurins series, L Hospitals Rule, stationary points, increasing, decreasing, maxima, minima, concavity, convexity and points of inflexion.
Integral Calculus and its Applications: Simple definite integrals fundamental theorems of calculus, properties of definite integrals. Reduction formulae reduction formulae for sinnx dx and cosnx dx , Bernoullis formula. Area of bounded regions, length of the curve. 2
Differential Equations: Differential equations - formation of differential equations, order and degree, solving differential equations (1 st order), variables separable, homogeneous and linear equations. Second order linear differential equations - second order linear differential equations with constant co-efficients, finding the particular integral if f (x) = e mx , sinmx, cosmx, x, x 2 .
Probability Distributions: Probability Axioms Addition law - Conditional probability Multiplicative law - Bayes Theorem - Random variable - probability density function, distribution function, mathematical expectation, variance Theoretical distributions - discrete distributions, Binomial, Poisson distributions- Continuous distributions, Normal distribution.
Groups: Binary operations, semigroups, monoids, groups, order of a group, order of an element, properties of groups.
3
PHYSICS - KEE 2014
Electrostatics: Frictional electricity Charges and their conservation Coulombs law Forces between two point electric charges Superposition principle Electric field Electric field due to a point charge Electric field lines Electric dipole Electric field intensity due to a dipole (on its axial line and on the equatorial line) Behaviour of dipole in a uniform electric field Application of electric dipole in microwave oven Electric potential Potential difference Electric Potential due to a point charge and due to a dipole Equipotential surfaces Electrical potential energy of a system of two point charges Electric flux Gausss theorem Field due to infinitely long straight wire Field due to uniformly charged infinitely plane sheet Field due to two parallel sheets Field due to uniformly charged thin spherical shell (inside and outside) Electrostatic induction Capacitor and capacitance Dielectric and electric polarization Parallel plate capacitor with and without dielectric medium Applications of a capacitor Energy stored in a capacitor Capacitors in series and in parallel Action of points Lightning arrester Van de Graaff generator
Current Electricity: Electric current Flow of charges in a metallic conductor Drift velocity and mobility Their relation with electric current Ohms law Electrical resistance V-I chraracteristics Electrical resistivity and conductivity Classification of materials in terms of conductivity Superconductivity Elementary ideas Carbon resistors Colour code for carbon resistors Combination of resistors Series and parallel Temperature dependence of resistance Internal resistance of a cell Potential difference and emf of a cell Kirchoffs law Illustration by simple circuits Wheatstones bridge and its applications for temperature coefficient of resistance measurement Meterbridge Special case of Wheatstone bridge Potentiometer Principle Comparing the emf of two cells Electric power Chemical effect of current Electro chemical cells Primary (Voltaic, Lechlanche, and Daniel cells) Secondary Rechargeable cell Lead acid accumulator
Effects of Electric Current: Heating effect Joules law Experimental verification Thermoelectric effects Seeback effect Peltier effect Thomson effect Thermocouple, thermo emf, neutral and inversion temperature Thermopile Magnetic effect of electric current Concept of magnetic field Oersteds experiment Biot- Savart law Magnetic field due to an infinitely long current carrying straight wire and circular coil Tangent galvanometer Construction and working Bar magnet as an equivalent solenoid Magnetic field lines Amperes circuital law and its application to solenoid 4 Force on a moving charge in uniform magnetic field and electric field Cyclotron Force on current carrying conductor in a uniform magnetic field Forces between two parallel current carrying conductors Definition of ampere Torque experienced by a current loop in a uniform magnetic field Moving coil galvanometer Conversion to ammeter and voltmeter Current loop as a magnetic dipole and its magnetic dipole moment Magnetic dipole moment of a revolving electron
Electromagnetic Induction and Alternating Current: Electromagnetic induction Faradays law Induced emf and current Lenzs law Self induction Mutual induction Self inductance of a long solenoid Mutual inductance of two long solenoids Methods of inducing emf (1) By changing magnetic induction (2) By changing area enclosed by the coil and (3) By changing the orientation of the coil (quantitative treatment) AC generator Commercial generator (Single phase, three phase) Eddy current Applications Transformer Long distance transmission Alternating current Measurement of AC AC circuit with resistance AC circuit with inductor AC circuit with capacitor LCR series circuit Resonance and Q-factor: power in AC circuits
Electromagnetic Waves and Wave Optics: Electromagnetic waves and their characteristics Electromagnetic spectrum, Radio, microwaves, Infra red, visible, ultra violet X rays, gamma rays Propagation of electromagnetic waves Emission and Absorption spectrum Line, Band and continuous spectra Fluorescence and phosphorescence Theories of light Corpuscular Wave Electromagnetic and Quantum theories Scattering of light Rayleighs scattering Tyndal scattering Raman Effect Raman spectrum Blue colour of the sky and reddish appearance of the sun at sunrise and sunset Wave front and Huygenss principle Reflection, Total internal reflection and refraction of plane wave at a plane surface using wave fronts. Interference Youngs double slit experiment and expression for fringe width Coherent source - Interference of light Formation of colours in thin films Analytical treatment Newtons rings Diffraction Differences between interference and diffraction of light Diffraction grating Polarization of light waves Polarization by reflection Brewsters law Double refraction Nicol prism Uses of plane polarised light and polaroids Rotatory polarization Polarimeter
Atomic Physics: Atomic structure Discovery of the electron Specific charge (Thomsons method) and charge of the electron (Millikans oil drop method) alpha scattering Rutherfords atom model Bohrs model Energy quantization Energy and wave number expression Hydrogen spectrum energy level diagrams Sodium and mercury spectra - Excitation and ionization potentials Sommerfelds atom model X rays Production, properties, detection, absorption, diffraction of X-rays Laues experiment Braggs law Bragg s X-ray spectrometer X-ray spectra Continuous and characteristic Xray spectrum Mosleys law and atomic number 5 Masers and Lasers Spontaneous and stimulated emission Normal population and population inversion Ruby laser He-Ne laser properties and applications of laser light holography
Dual Nature of Radiation and Matter Relativity: Photoelectric effect Light waves and photons Einsteins photoelectric equation Laws of photoelectric emission Particle nature of energy Photoelectric equation Work function Photo cells and their application Matter waves Wave mechanical concept of the atom Wave nature of particles de Broglie relation de Broglie wave length of an electron Electron microscope Concept of space, mass, time Frame of references Special theory of relativity Relativity of length, time and mass with velocity (E = mc 2 ) NUCLEAR PHYSICS Nuclear properties Nuclear Radii, masses, binding energy, density, charge Isotopes, isobars and isotones Nuclear mass defect Binding energy Stability of nuclei-Bain bridge mass spectrometer Nature of nuclear forces Neutron Discovery Properties Artificial transmutation Particle accelerator Radioactivity Alpha, beta and gamma radiations and their properties, -decay, -decay and - decay Radioactive decay law Half life Mean life Artificial radioactivity Radio isotopes Effects and uses Geiger-Muller counter Radio carbon dating Biological radiation hazards Nuclear fission Chain reaction Atom bomb Nuclear reactor Nuclear fusion Hydrogen bomb Cosmic rays Elementary particles
Semiconductor Devices and their Applications: Semiconductor theory Energy band in solids Difference between metals, insulators and semiconductors based on band theory Semiconductor doping Intrinsic and Extrinsic semi conductors Formation of P-N Junction Barrier potential and depletion layer P-N Junction diode Forward and reverse bias characteristics Diode as a rectifier Zener diode Zener diode as a voltage regulator LED Junction transistors Characteristics Transistor as a switch Transistor as an amplifier Transistor biasing RC, LC coupled and direct coupling in amplifier Feedback amplifier Positive and negative feedback Advantages of negative feedback amplifier Oscillator Condition for oscillations LC circuit Colpitt oscillator Logic gates NOT, OR, AND, EXOR using discrete components NAND and NOR gates as universal gates Integrated Circuits Laws and theorems of Booleans algebra Operational amplifier Parameters Pin-out configuration Basic applications Inverting amplifier Non-inverting amplifier Summing and difference amplifiers Measuring Instruments Cathode Ray oscilloscope Principle Functional units Uses Multimeter construction and uses
Communication Systems: Modes of propagation, ground wave Sky wave propagation 6 Amplitude modulation, merits and demerits Applications Frequency modulation Advantages and applications Phase modulation Antennas and directivity Radio transmission and reception AM and FM Super heterodyne receiver T.V. transmission and reception Scanning and synchronizing Vidicon (camera tube) and picture tube Block diagram of a monochrome TV transmitter and receiver circuits Radar Principle Applications Digital communication Data transmission and reception Principles of fax, modem, satellite communication Wire, cable and Fibre-optical communication
7
CHEMISTRY - KEE 2014
Atomic Structure: Bohrs atomic model limitations Sommerfelds theory of atomic structure; Electronic configuration and Quantum numbers; Shapes of s, p, d, f orbitals Paulis exclusion principle - Hunds Rule of maximum multiplicity Aufbau principle of filling up of electrons in orbitals. Hydrogen spectrum Lyman, Balmer, Paschen, Brakett and Pfund series; deBroglies theory; Heisenbergs uncertainty principle wave nature of electron Schrodinger wave equation and its significance Eigen values and Eigen functions. Hybridization of atomic orbitals to form molecular orbitals.
p, d and f Block Elements: p block elements Phosphorous compounds; PCl 3 , PCl 5 Oxides. Hydrogen halides, Inter- halogen compounds. Xenon fluorides. General Characteristics of dblock elements Electronic Configuration Oxidation states of first row transition elements and their colours; Lanthanides Introduction, Electronic configuration, general characteristics, oxidation state lanthanide contraction.
Coordination Chemistry and Solid State Chemistry Terminology in coordination chemistry IUPAC nomenclature of mononuclear coordination compounds Isomerism, Geometrical isomerism in 4-coordinate, 6-coordinate complexes. Werners theory of co-ordination, Valence Bond theory. Uses of coordination compounds. Bioinorganic compounds (Haemoglobin and chlorophyll). Lattice unit cell, systems, types of crystals, packing in solids; Ionic crystals Imperfections in solids point defects. X-Ray diffraction
Thermodynamics, Chemical Equilibrium and Chemical Kinetics First and second law of thermodynamics spontaneous and non spontaneous processes, entropy, Gibbs free energy Free energy change and chemical equilibrium significance of entropy. Law of mass action Le Chatliers principle, applications of chemical equilibrium. Rate expression, order and molecularity of reactions, zero order, first order and pseudo first order reaction half life period. Determination of rate constant and order of reaction. Temperature dependence of rate constant Arrhenius equation, activation energy
Electrochemistry Theory of electrical conductance; metallic and electrolytic conductance. Faradays laws theory of strong electrolytes Specific resistance, specific conductance, equivalent and molar conductance Variation of conductance with dilution Kohlraushs law Ionic product of water, pH and pOH buffer solutions use of pH values. Cells Electrodes and electrode potentials construction of cell and EMF values, Fuel cells, Corrosion and its prevention.
Alcohols and Ethers Nomenclature of alcohols Classification of alcohols - distinction between primary, seconadary, and tertiary alcohols General methods of preparation of primary alcohols, properties. Aromatic alcohols preparation and properties of phenols and benzyl alcohol. Ethers properties of aliphatic ethers Uses. Aromatic ethers Preparation of Anisole Uses.
Carbonyl Compounds Nomenclature of carbonyl compounds Comparison of aldehydes and ketones. General methods of preparation of aldehydes Properties Uses. Aromatic aldehydes Preparation of benzaldehyde Properties and Uses. Aromatic ketones preparation of acetophenone Properties Uses, preparation of benzophenone Properties. Name reactions; Clemmenson reduction, Wolff Kishner reduction, Cannizaro reaction, Claisen Schmidt reaction, Benzoin Condensation, aldol Condensation. Preparation and applications of Grignard reagents.
Carboxylic Acids and their derivatives Nomenclature Preparation of aliphatic monobarboxylic acids formic acid Properties Uses. Aromatic acids; Benzoic and Salicylic acid Properties Uses. Derivatives of carboxylic acids; acetyl chloride (CH 3 COCl) Preparation Properties Uses. Preparation of acetamide, Properties acetic anhydride preparation, Properties. Preparation of esters methyl acetate Properties.
Organic Nitrogen Compounds Aliphatic nitro compounds Preparation of aliphatic nitroalkanes Properties Uses. Aromatic nitro compounds Preparation Properties Uses. Distinction between aliphatic and aromatic nitro compounds. Amines; aliphatic amines General methods of preparation Properties Distinction between primary, secondary, and tertiary amines. Aromatic amines Synthesis of benzylamine Properties, Aniline Preparation Properties Uses. Distinction between aliphatic and aromatic amine. Aliphatic nitriles Preparation properties Uses. Diazonium salts Preparation of benzene diazonium chloride
Biomolecules Carbohydrates distinction between sugars and non sugars, structural formulae of glucose, fructose and sucrose, with their linkages, invert sugar definition, examples of oligo and polysaccharides, Amino acids classification with examples, Peptides properties of peptide bond.