Professional Documents
Culture Documents
Chemistry
C1.4
Name: .
Date: ..
consider and evaluate the social, economic and environmental impacts of the
uses of fuels
evaluate developments in the production and uses of better fuels, for example
ethanol and hydrogen
evaluate the benefits, drawbacks and risks of using plant materials to produce
fuels.
Key words
Crude oil
Compound
Mixture
Distillation
Hydrocarbons
Saturated
Alkanes
Covalent bond
Evaporating
Condense
Fractional distillation
Fractionating column
Particulates
Combustion
Soot
Biofuels
Chemicals
Elements
Sulfur
Carbon
Hydrogen
Compounds
Methane
Ethane
Propane
Butane
Carbon dioxide
Carbon monoxide
Sulfur dioxide
Nitrogen oxides
Ethanol
C1.4.1
Crude oil
c) Most of the compounds in crude oil consist of molecules made up of hydrogen and carbon
atoms only (hydrocarbons). Most of these are saturated hydrocarbons called alkanes, which
have the general formula CnH2n+2
a) Alkane molecules can be represented in the following forms:
n=1
n=2
n=3
n=4
C1.4.2
Hydrocarbons
b) The many hydrocarbons in crude oil may be separated into fractions, each of which
contains molecules with a similar number of carbon atoms, by evaporating the oil and
allowing it to condense at a number of different temperatures.
This process is fractional distillation.
Candidates should know and understand the main processes in continuous fractional
distillation in a fractionating column.
c) Some properties of hydrocarbons depend on the size of their molecules.
Fraction
Petroleum
gas
Naphtha
Petrol
Kerosene
(paraffin)
Diesel
Oil
Bitumen
Number
Carbon
atoms
1 to 4
5 to 9
5 to 10
10 to 16
14 - 20
20 - 50
50 or more
of
Use
Heating and cooking
Making other chemicals
Fuel for cars and light
aeroplanes
Fuel for jet or turbine
aeroplanes
Diesel fuel or heating
Lubricating oil
Making roads
C1.4.3
Hydrocarbons fuels
a) Most fuels, including coal, contain carbon and/or hydrogen and may also contain some
sulfur.
The gases released into the atmosphere when a fuel burns may include:
carbon dioxide
water (vapour)
carbon monoxide
sulfur dioxide and
oxides of nitrogen.
Solid particles (particulates - sometimes called soot) may also be released.
b) The combustion of hydrocarbon fuels releases energy. During combustion the carbon and
hydrogen in the fuels are oxidised.
c) Sulfur dioxide and oxides of nitrogen cause acid rain, carbon dioxide causes global
warming, and solid particles cause global dimming.
d) Sulfur can be removed from fuels before they are burned, for example in vehicles. Sulfur
dioxide can be removed from the waste gases after combustion, for example in power
stations.
e) Biofuels, including biodiesel and ethanol, are produced from plant material.
There are economic, ethical and environmental issues surrounding their use.
Q1. (a)
Complete each sentence by choosing the correct words from the box.
condensation
distillation
melting
evaporation
sublimation
(c) Complete this sentence by crossing out the word in each box that is wrong. The first
one has been done for you.
are, the
Q2.
the molecules
(a)
(i)
Describe and explain how the mixture of alkanes is separated by fractional distillation.
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(ii)
The table gives the name and formula for each of the first three alkanes.
CH4
Ethane
C2H6
Propane
C3H8
Butane
Formula
(b)
(c) The relative amounts of and the market demand for some hydrocarbons from the
fractional distillation of crude oil are shown in the graph.
(i)
Why is the market demand for the C5 C8 fraction higher than the market demand for
the C21 C24 fraction?
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(ii) Cracking is used to break down large hydrocarbon molecules into smaller
hydrocarbon molecules.
Complete the symbol equation by writing in the formula of the other hydrocarbon.
C20H42 C16H34 + 2 ..........................................
(1)
(iii)
Suggest three ways in which the oil industry could overcome this problem.
1 .........................................................................................................................
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2 .........................................................................................................................
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3 .......................................................................................................................
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Q3.
(a)
Crude oil is a natural resource from which useful fuels can be separated.
Crude oil is a mixture of hydrocarbons.
Many fuels come from crude oil. Some of these fuels are shown in the diagram.
Suggest two properties of these fuels that allow them to be separated from crude oil.
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(c)
When a fuel burns, it combines with oxygen in the air and produces carbon dioxide
and water. When there is not enough oxygen, the fuel burns and also produces carbon
monoxide and carbon particles.
Draw a straight line from each substance that links it to a possible environmental
problem. One has been done for you.
Q4.
Use words from the box to complete the sentences about cracking.
alkanes
alkenes
catalyst
fuel
gas
could be reused
could be recycled by melting and making into new plastic products
could be burned to release energy
Use the information above and your knowledge and understanding to give the positive and
negative environmental impacts of using these methods to reduce the amount of plastic
bags sent to landfill.
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Q 5. The table gives some information about a family of molecules in crude oil.
NUMBER OF CARBON ATOMS
IN MOLECULE
MASS OF MOLECULE
(atomic units)
16
30
58
(a)
Show information from the table in the most appropriate way on the grid.
(b)
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(c)
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(d)
(ii)
Q6.
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Name
Formula
Boiling point in C
methane
CH4
16
160
ethane
C2H6
30
90
44
40
propane
(a)
......................
butane
C4H10
58
pentane
C5H12
72
36
hexane
C6H14
86
68
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(b) (i)
What happens to the boiling points of the alkanes as the relative formula
mass increases?
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Draw a graph. Plot the points and draw a best fit line.
(iii)
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(iv)
Show clearly on the graph how you found the boiling point of butane.
(c)
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C9H18
C11H24
C24H50
Q7.
(a)
oil?
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(2)
(b)
Table 1 gives some information about some of the useful substances obtained from
crude oil.
Table 1
Number of
carbon atoms
Viscosity (cP)
Refinery gas
14
< 30
0.009
Petrol
410
50
0.5
Naptha
611
130
0.9
Kerosene
1016
200
2.5
Diesel fuel
1620
260
6.2
Lubricating oil
2040
310
22.7
Substance
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(c)
The relative amounts of substances obtained from crude oil are given in Table 2.
Table 2
Substance
Relative % demand
Petrol
10
20
Kerosene
15
23
Diesel
20
25
Fuel oil
45
12
Q8.
Fuel scientists develop and blend fuels for use in motor vehicles.
volatile
easy to ignite
produces a large amount of energy when it burns
produces the minimum amount of pollution.
Information about some of the hydrocarbons that are found in petrol is given in the table.
Name
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Chemical formula
Melting point in C
Boiling point in C
Butane
C4H10
138
Pentane
C5H12
130
36
Hexane
C6H14
95
69
(a)
(i)
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(ii)
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(ii)
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(e)
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Q9.
Useful fuels can be produced from crude oil. Crude oil is a mixture of
hydrocarbons.
(a)
Tick (
Hydrocarbon
Boiling point in C
methane, CH4
162
butane, C4H10
pentane, C5H12
+36
decane, C10H22
+175
Tick (
(b)
The diagram shows an apparatus to investigate the two substances produced when natural
gas burns completely in air.
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(i)
(ii)
(c)
Some crude oil contains sulfur. Petrol and diesel fuels are produced from crude oil.
The sulfur must be removed from these fuels before they are burned.
Explain why.
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Q10.
(a)
C6H14
C6H12
2C2H4
This type of reaction is carried out because there is a greater demand for the products than
for the original hydrocarbon.
Suggest two reasons for this.
1 .................................................................................................................................
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(b)
(ii)
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Q11.
(i)
(a)
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(ii) Give a chemical test which would show the difference between an alkene and an
alkane.
Test ..................................................................................................................
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(b)
(i)
Complete the following to show how the ethene molecules bond to form part of a
polymer.
(ii)
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(iii)
Explain one important problem caused by the everyday use of this polymer.
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Q12.
One reason the oil industry is important is that it uses crude oil to produce many
of the plastic materials we use in everyday life.
(a) The first stage in the formation of a plastic material is called cracking. Butane (C4H10),
a hydrocarbon in crude oil, can be cracked to produce two different hydrocarbons, ethane
(C2H6) and ethene (C2H4)
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(i)
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(ii)
Complete the equation for the cracking of butane using displayed formulae.
(iii) Complete the balanced chemical equation far the complete combustion of ethane in
oxygen.
............C2H6(g) + ............(g) ............(g) + ............(l)
(3)
(b)
Describe how ethene (C2H4) forms poly(ethene). You do not need to give the reaction
conditions or the names of catalysts.
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