Professional Documents
Culture Documents
September 2002
Acknowledgments
Several Reclam ation em p loyees help ed
p r ep a r e t h is g u id e, a n d th eir con tr ib u tio n is
gr ea tly ap p re ciate d . The se p eo p le ar e Ku rt F.
von Fay, m aterials engineer , w ho set u p
fu n d in g an d s h ow e d g re at p a tie n ce ov er th e
w r i tin g i n t erv al; D . Th o m as (T o m ) Jo h n son,
m ater ials en gine er, for h is corr osion exp ertise
co n t r ib u t i on ; G r e g o r y J. M y e r s a n d R ich a r d A .
Pe p in , m a t e rials en g in eerin g tech n ician s, for
th eir initial rev iew in ferretin g ou t obv iou s
er r or s; an d Ro b er t Ro od , ed ito r , for h is
n u m e r o u s I d o n ' t u n d e r s ta n d co m m e n t s th a t
forced m e into w riting a clearer, m ore concise,
a n d u n d er st a n d a b le d ocu m en t.
A d e b t o f g r a tit u d e is ex p r e ss ed t o N A C E
Inter n ation al, Society of Pro tective Co ating s,
a n d U n iv er sit y of M iss ou r i-Ro lla, C oa tin g
In s t it u t e fo r p r o v id in g a l l t h e co u r s e s a n d
references that m ad e this guid e p ossible.
Preface
In r e c en t y e a r s , co a t in g t e ch n o lo g y h a s
ch an g ed d ra m at ically . Th e d riv in g for ce
b e h i n d t h e ch an g e h as b een reg u latio n s
affecting the en vironm ent an d p ersonn el
h e a l t h a n d s afety . F o r ex am p le, reg u lations
r e la t ed t o d u s t p a r t icle s fr o m a b r a siv e b la s tin g ,
vo latile org an ic com p ou n d (VOC ) em ission s,
a n d h a z a r d o u s m a t e r ia ls su ch a s le a d ,
ch r o m a t e, a n d o t h er h e av y m e t a ls h av e
chan ged .
Before the late 1980s, coating m aterials w ere
m or e t ole ra n t o f less th an op tim u m su rfa ce
p r ep a r a tio n con d itio n s b eca u se p a in t
form u lation contained high VOC s to allow the
m ater ial to w et or p en etr ate st eel su rfaces. The
m o s t su cce ssfu l w e r e r ed le ad p r im e r s a n d
v in y l r es in s ; h o w e v e r , r eg u la tio n s h a v e
d isco u r a g ed th e u se of t h es e m a te r ials . Pa in t
m an u factu rers reform u lated their coatings to
com p ly w ith ne w regu lation s. This has led to
th e d ev elo p m en t o f a w id e v ar iety of h igh -tech
co a tin g m a te r ials th a t a r e m u ch m or e s en sit iv e
t o su r fa ce p r e p a r a t io n a n d e n v i r o n m e n t a l
a p p lica t io n p r a ct ice s . T h e Fe d e r a l H ig h w a y
A d m in ist r a tio n h a s e st im a te d th a t u p to 80
p e r c en t o f all p rem atu r e co atin g failu res on
Contents
Page
Ch ap te r I In tro d u cti o n an d Back g ro u n d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1. St a n d a r d s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2. Coating References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3. T er m in o lo g y . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4. C o r ro s io n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5. Se r v ice Ex p o s u r e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1
1
1
1
1
5
5
5
7
7
C h ap te r III S p e ci f icati o n s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
9. Con stru ction Sp ecification Institu te . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10. R e clam atio n C o atin g S p ecificatio ns . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
11. Coating Tabu lations an d Categor ies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
12. M an u factu rer's Prod u ct Data an d Ap p lication She ets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
13. A d d e n d u m s a n d M o d ifica tio n s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
11
11
11
12
13
14
15
15
15
16
16
17
17
17
17
19
19
19
19
21
21
23
23
24
25
27
30
vii
Page
C h ap te r V I I En v i ro n m e n t al Co n d i ti o n s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
32. E n v ir o n m e n t a l Fa ct o r s A f fe ct in g C o a t in g s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
Cha pte r VI II A p p licatio n a n d C u rin g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
33. Ap p licatio n T em p eratu re an d H u m id ity R e stric tions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34. C o a t in g L a y er s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
35. M ixin g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
36. Ap p licatio n M eth o d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
37. A p p l ica t io n T ech n i q u e . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
38. D r y in g , Reco atin g , an d C u r in g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
35
35
35
36
36
39
39
41
41
42
42
45
C h ap te r X M a i n te n an c e C o ati n g s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
43. De f in itio n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
44. Pu rp ose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
45. R isk E v alu atio n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
46. In sp ectio n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
47. Toxic-Based Paints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
48. W ork er Pr otection from Toxic-Based Paints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
49. L e a d E x p o s u re L ev els b y Rem o v a l M e thod s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
50. C o r rectiv e A ctio n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
51. M a t e r ia l Se le ct io n F act o r s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
52. Sch ed u lin g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
47
47
47
47
47
49
50
50
51
52
52
53
53
54
54
54
55
57
59
59
59
61
61
62
63
67
Bi b li o grap h y . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
viii
Appendices
A
B
C
D
E
F
G
H
I
J
K
L
M
N
O
P
Q
R
S
T
U
V
W
X
Figures
Figure
1
Page
C o m p o n e n t s o f co a t in g s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Tables
T able
1
2
3
4
5
6
7
8
9
10
Page
N u m ber of spot m easu rem ents based on total coated sur face area . . . . . . . . . . . . . . . . . . .
Typ ical and m axim u m lead exposu re levels in m icrogra m s per cubic meter
b y rem o v al m eth o d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
G alv an izin g m eth o d s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Fo r m u l a tio n -r e la t ed fa ilu r e s fo r o r g a n ic co a t in g s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Fo r m u l a tio n -r e la t ed fa ilu r e s fo r in o r g a n i c co a t in g s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Ad hesion-related failu res . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Su bstrate-related failu res . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Ap p lication-related failures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Design-related failu res . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Failures related to exterior forces . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
44
51
53
60
61
62
63
64
66
67
ix
Chapter I
Introduction and Background
Pro tective or ind u strial coating s are th e
p r i m a r y m ean s em p lo y ed b y th e Bu reau of
R e cla m a t io n (Reclam atio n ) to co n tro l
co r r os ion . H y d r a u lic st r u ctu r es ar e t y p ically
co n s t ru c t ed w it h fe r r o u s m e t a ls a n d a r e
su b je ct t o co rro s io n . M an y Reclam atio n
s tr u c t u r e s a r e 50 y e a r s o ld , a n d s o m e a r e
a p p r o a ch i n g 100 y e a r s. T h e se st r u c tu r e s a r e
exp ected to continu e fun ction ing into th e
fo r e se e ab le fu t u r e . P r o te ct iv e co a t in g s
in flu en ce t h e life, sa fety , op er at in g efficien cy ,
ap p ear an ce, an d econo m y of th ese stru ctu res.
A coa tin g 's e ffect iv en es s d ep en d s o n se lect in g
coating m aterial that correctly m atches th e
in te n d ed se r v ice ex p o su r e fo r th e m eta lw or k .
In t h e p a s t, co a t in g m a t e r ia l s e le ct io n w a s
b a se d o n Fed eral, m ilitary , o r R eclam ation
form u lations; how ev er, nea rly all these
fo r m u l a tio n s h a v e b e en w it h d r a w n . T od a y ,
s e le ct io n i s b a s e d o n s e r v i ce e xp o s u r e t y p e a n d
th e r es u lts of a ccele r a te d p er for m a n ce t es tin g
of com m ercially av ailable p rod u cts.
So cie t y fo r P r o te ct iv e C o a tin g s
(form erly called Steel Stru ctures
P a in tin g C ou n cil) (SSPC ).
Bu r ia l
Im m e rs ion
A tm os p h er ic
N
N
In d o o r s
Ou tdoors
D i r ect su n l ig h t o r U V : s e v e r a l
co a tin g s, su ch as ep ox ies , w ill
d eteriorate by cha lking w hen
exp osed to su nlight.
Chapter II
Materials
C o a t i n g fo rm u latio n is g en erally b as ed on
organ ic, inorgan ic, p olym er, an d co-p olym er
ch em ist r y . It is n ot th e in te n tio n of t h is
chap ter to d iscu ss coating chem istry b u t,
r a th er , to p r ov id e a b a sic k n ow led g e o f coa tin g
com p onen ts and gen eric coating typ es
sp e c ifie d b y R eclam atio n .
6. Components of Coatings. A ll or g a n ic
co a tin g s co n sis t of t h r ee b a sic co m p o n en ts:
(1) so lv en t, (2) r es in , an d (3) p ig m en t. N ot all
coating s contain solven t and p igm ented
co m p on en ts . Th er e a r e s olv en t-fr ee (100
p ercent solids) coating s an d clear, p igm en tfree coating s, bu t n ot resin -free coat ings.
C oa tin g ch em ical fo r m u lat or s co m m on ly
gro u p solvent, resin, and p igm en t com p on en ts
in t o t w o g e n e r a l ca t eg o r ie s. T h e fir s t ca t eg o r y
co m b in es t h e so lv en t a n d th e r esin to g eth er .
Th e s olv en t p or tio n is ca lled th e v ola tile
veh icle, an d the r esin p ortion is called th e
n on volatile veh icle. The com bination of the
so lv en t a n d th e r es in , w h er e t h e r es in is
d is so lv e d in t h e s o lv e n t , is ca lle d t h e v e h i cle .
The secon d category is the p igm en t. Pigm en ts
are ad d itives th at im p art sp ecific pr op erties to
the coating an d are su bd ivided into tw o
So lv en t
(Volatile)
Re sin
(No nv olatile)
g e n e r a l ca t e g o r ie s : (1) co lo r a n d (2) in e r t a n d
r ein for ced . Figu r e 1 illu st r a te s t h e r ela tio n sh ip
of these com p on en ts.
W hen a coating is ap p lied , the solvent
ev a p or a te s d u r in g th e cu r in g p r oc es s, lea v in g
only the re s in a n d the p igm e nt c omp one n ts on
t h e s u b s t r a te . T h e r e m a i n in g r e s in a n d
p ig m en ts ar e s om et im es calle d th e co a tin g
s olid s , a nd the y form the p rote ctive film for
co rr osio n p r ote ctio n .
(a) So lvent. Or gan ic solven ts are form u lated
in t o co a t in g s t o p e r f or m t h r e e e ss e n t ia l
fun ction s: (1) dissolve the r esin com p on en t;
(2) co n t r o l e v a p o r a t i o n fo r film fo r m a t io n ; a n d
(3) re d u c e the c oa ting v is cos ity for e a s e of
a p p licat ion . Solv en ts w ill als o a ffect d r y film
a d h es ion an d d u r a b ility coa tin g p r op er tie s. In
g e n e r a l, r e sin s t h a t a r e le ss so lu b l e w i ll r e q u i re
either m ore solven ts or stron ger solven ts to
d issolve th e resin s.
T h e te r m s s o lv e n t s a n d t h in n e r s a r e
o ft e n u s e d i n t er ch a n g e a b ly , b u t t h e r e ar e
d ist in ctio n s w ith in an d b etw een th e tw o te r m s.
The term solvent can im p ly tw o d ifferen t
u sa g es : (1) th e s olv en t o r so lv en t b len d s in
the coating form u lation a t p red eterm ined
C olor
Pigm en ts
Ve h icle
In e rt a n d
Reinforced
P ig m e n t
C oa tin g
Figure 1.Com ponents of coatings.
C o a t in g s
M ineral sp irits
O ils an d alk y d s
Co al tar ep oxies,
alkyd s, chlorina ted
rubbers
Keton es (MEK,
M IBK)
Vinyls, ep oxies,
u rethan es
P h en olics , in or g a n ic
zin cs
W ater
A cry lics, s o m e
in or g an ic zin cs
So lv e n t s p r o d u ce v a p o r s t h a t a r e h e a v ie r t h a n
air and w ill collect in tank b ottom s or confined
a r ea s. Th e k et on es h a v e t h e lo w es t fla sh p oin t
of the or gan ic solven ts; how ever, any solven t
in t h e r i g h t co m b in a t io n w it h a ir ca n c r e a te a n
e x p l o siv e co m b in atio n .
Fed er a l, Stat e, co u n ty , city , an d loca l air
q u a l it y co n tro l d is tricts reg u late th e am ou nt of
v o la tile or g a n ic so lv en ts (VO C ) in co a tin g s. A s
the coating cures, VOC s evap orate into the
M e ch a n ism a n d t im e o f cu r in g
P e r fo r m a n c e in s e r v ice e xp o s u r e ty p e
P e r fo r m a n c e o n s u b s t r at e t y p e
C o m p a t ib ilit y w i t h o th e r co a t in g s
Flexibility an d tou gh n ess
Ext er ior w ea th er in g
A d he s ion
Materials
ach ieve t h e d esired film p ro p ert ies. Th e
fo llo w in g p r o p e r t ie s a r e acco r d e d b y
p igm ents, and a brief d escription is prov ided
fo r e ach .
Co lor. N a tu r a l ea r th p ig m en ts (k a olin
clay, m agn esiu m silicate, calciu m carbona te)
p rov id e color stab ility from u ltrav iolet (UV)
su nlight d eterioration. N atu ral earth p igm en ts
a r e m or e U V s ta b le t h a n sy n th et ic or g a n ic
p igm en ts.
Opacity. Titan ium oxide h ides th e
s u b s t r a t e o r p r e v i o u s c oa t in g c o lo r a n d
p r o t e ct s t h e b in d e r fr o m U V s u n l ig h t
d e te rio ra tio n .
Wet pa int. Silica an d talc co n tro l
v isco sit y , w et film lev elin g , an d se tt lin g b u t
p r o v i d e lit tle h id in g ( op a c it y ) p o w e r .
Weath er an d m oisture resistance.
A lu m in u m lea fs a n d m icac eo u s ir on ox id e
(M IO ) in cre as e b ar rie r t h ickn es s a n d for ce
m o is tu r e t o d e t o u r a r o u n d t h e se p l at e -lik e
ad d itive s.
Co rrosio n resistance. Pigm en ts ad d ed to
in h ib i tiv e (p rim er) co atin g s im p ed e co rr os ion
o f fe r r o u s s u b s trates . P as t fo rm u latio n s
in clu d ed ch r o m a te an d lea d p ig m en ts , b u t
t h e y a r e se ld o m u s ed to d ay b ecau s e o f
en vir on m en tal an d h ealth con cern s. The
fo llo w in g c h r o m a t e a n d le a d p ig m e n t s a r e
rar ely u sed in cu rre n t coating form u lations:
R ed le a d
W h i te le a d
Basic lead silico-chrom ate
Stron tium chrom ate
Zinc chrom ate
(g) Epoxy, Fusio n-Bo nde d. Fus ionbon d ed ep oxies (com m only called p ow d er
coating s) are com p lete coating s in p ow d er
form . The re a re tw o ap p lication m eth od s,
flu idized -bed an d electrostatic. In the
flu i d i z ed -b e d m e t h o d , t h e m e t a l it e m s a r e
p r eh e ate d to a fu s io n te m p e r atu r e a n d
im m er se d in th e p ow d er -ep ox y so lu tio n . In
the electrostatic meth od , the ep oxy p ow d er
p a r t icle s a r e ch a r g e d w it h h i g h v o l ta g e , a n d
t h e m e t a l it e m i s t h e n s p r a y e d . A ft e r s p r a y in g ,
the ite m is pla ce d in a n ove n to c ure a t a bo u t
350 to 650 d e gre e s Fa hre n he it (F). Fus ionb o n d e d e p o x ie s a r e s p e c ifie d fo r b u r ia l a n d
im m er sio n se r v ice e xp os u r es , bu t t h ey w ill
fa d e a n d c h a lk in d ir e ct su n lig h t a n d a r e
brittle. A n ew m aterial is fu sion-bon d ed
nylon. This ma te ria l is s up e rior to the fu s io nbon d ed ep oxy an d w ill be incorp orated into
Re clam a tio n 's sp ecifica tio n . Po w d er coa tin g s
cu r e b y fu sio n (h ea t).
(h) Ino rgan ic Zinc Prim ers. In or g a n ic
z in c s a r e p r im e r s t h a t in c o rp o r a t e a h ig h
loa d ing (p ou nd s pe r ga llon) of m e ta llic z in c for
p ig m e n t a t io n ( h e n c e, t h e t er m z in c -r ich ) a n d
a r e e ith er so lv en t o r w a te r b a se d . D ep en d in g
on th e s olv en t a n d r es in s u se d , th e co a tin g
m ay be a zinc-rich ep oxy o r u reth an e. Th ese
coating s are exclusively p rim ers because th ey
p rovid e galvan ic or cathod ic p rotection to steel
s ub s tra te. Inorg a nic z inc s a re sp e cifie d for
atm osp h eric and im m ersion serv ice exp osu res,
b u t t h ey can b e t op co a te d to ex te n d th eir
s e rvic e life . Su ita ble topc oa t m a te ria l s e le ct ion
is requ ired to p rev en t ou t-gassing from the
in or g a n ic zin c th a t p r od u ces sm a ll p in h ole s in
th e t op co a t. Re clam a tio n sp ecifie s in or g a n ic
zinc coatings only to fraying su rfaces or heated
tre ated m etalw or k (A STM A 325 or A STM
A 4 90). A p p lica t io n r e q u ir e s sp e cia l s k ills a n d
kn ow ledge. Inor gan ic zincs cure by either
re a c tion to w a te r (s olve n t re du c ible ) or
r ea ctio n to car b on d iox id e (w a te r r ed u cib le).
(i) Organic Zinc Prim ers. O rg an ic zin cs
a r e p r im er s t h a t in cor p or a te a h ig h loa d in g
(p ou nd s pe r ga llon) of m e ta llic z inc for
p igm en tation w ith a w ide v ariety of solven ts
a n d r esin s. D ep e n d in g on th e so lv en t a n d
Materials
re sin s u se d , th e co at in g m ay b e a zin c-rich
alkyd , d rying oil, ep oxy, or m oistu re-cu red
u r et h a n e. Th es e co a tin g s a r e e xclu siv ely
p r im er s b eca u se th ey p r ov id e g a lv a n ic
p rotection to steel substr ate or th ey ar e u sed to
rep air da m aged galvan ized coatings on steel
su b st r a t es. O rg an ic zin cs are sp ecified for
at m os p h er ic, bu ria l, an d im m er sio n se rv ice
exp osu res bu t are n orm ally top coated to
ex te n d th e s er v ice life of t h e co a tin g . Su ita b le
top coat m aterial selection is requ ired to
p r ev en t o u t-g a ss in g fr o m th e or g a n ic z in c.
O u t-gassing p rod u ces sm all p inh oles in th e
top coat. The w ay org an ic zincs cure d ep end s
on th e coating typ e.
(j) Polyu rethane . T ech n i ca lly ,
p o ly u r e t h an e is a s u b clas s o f u reth an e. A tw oco m p o n e n t p o ly u r e t h a n e is cr e a te d b y
ch e m ica lly c om b in i n g a p o ly is o y a n a t e a n d a
p o ly o l to p r o d u ce an is o cy an ate th at h as a tw om o d e cu r e m e ch a n ism o f so lv en t e va p o ra tio n
Chapter III
Specifications
Reclam ation constru ction jobs are ad vertised
t o co n t r a ct o r s t o p e r fo r m t h e r eq u i r e d w o r k ,
a n d con tr a cto r se lect ion is m a d e b y a b id
p r o c e ss. T h e m o s t co m m o n b id ty p es are low
p r ice , n eg o tia te d , fixe d co st , an d so le so u r ce .
O n ce Re cla m a tio n acce p ts a co n tr a cto r s b id , a
contra ct exists betw een Reclam ation an d the
contractor. The contract is often called a
sp ecification. The sp ecification can be d efined
a s a w r i tt e n , d etailed , tech n ical d es crip tion of
w o rk to be p er fo rm e d , d e scr ib in g th e
m a te r ia ls, q u a n tities, a n d m o d e of
co n str u ctio n .
Sp e cific a tio n s are d iv id ed in to m an y d ivis ions
t o d e s cr ib e t h e v a r io u s jo b r e q u i r e m e n t s a n d
m a y in clu d e ge n er al jo b d e scr ip t io n ,
su bm ittals, p re-existin g con d ition s,
e n v i r o n m e n t a l r e q u i r e m e n t s , a n d t e ch n ica l
a r ch ite ctu r a l, civil, e lect r ical, m ech a n ical,
co a tin g , an d ca th o d ic p r o te ctio n d isc ip lin es.
E a ch d iv i sio n i s s o m e t im e s ca lle d a t e ch n ica l
p a r ag ra p h o r se ctio n .
11
C os t p ro v is io n s fo r eith er lu m p s um or
bid item
A p p lica tio n eq u ip m e n t
R efe r e n ce s fo r in d u s t r ia l s ta n d a r d s
u se d in th e s p ecificatio n s ectio n
Re p a ir of d a m a g ed an d n on a ccep ta b le
co a t e d a r e a s
C olo r sch ed u le
" M a n u fa ctu r er s p r o d u ct d a ta an d
ap p lication sheets
" P u r ch a se or d e rs, e n su r in g th a t th e
contractor u sing ap p roved
m at er ials t o in clu d e b at ch
n u m b ers , q u an tity , an d co lor
Q u ality as su ra n ce
Ab rasives
M IO
C o a t in g s
12
Specifications
of e a ch ap p lied coa t, a n d to ta l d r y film
thickn ess (DFT) of the coating system
a r e id en tifie d in th e s eco n d colu m n .
Su r f a ce p r e p a r a t io n m e t h o d s a r e
id en tifie d b y let te r or alp h a n u m er ic
la b e l in t h e t h ir d co lu m n a n d a r e
d e fin ed in th e ex ecu tio n p art fo r
su r face p r ep aratio n .
In s t r u c t io n a l n o t es , if s p e c ifie d , a r e
located at either tab le front or en d .
G e n e r i c ch e m ica l co a t in g n a m e
(acrylic, alkyd , ep oxy, p olyur ethan e)
Re co m m en d ed d r y or w et film
th ickn ess
D r y , re co a t, cu r in g , an d fu ll cu r e t im e
p eriod s at tem p eratu re an d hu m idity
ran ges
Sh elf life
Sa fe ty pre c a u tions
Sh ip p in g d ata
13
14
Su b st r a te ty p es th a t a r e co m p a tib le
w ith th e co a tin g m a te r ia l (e .g .,
a lu m in u m , con cr et e, g a lv a n ize d , ste el,
cast iron , or existin g coated su rfaces)
Pot-life-tim e of m u lticom p on en t
c o a tin g m aterial at v ario u s
tem p eratu re an d hu m idity ran ges
Lo w e r a n d u p p e r te m p e r atu r e a n d
h u m id ity ra n ge re str ictio n s d u r in g
a p p lica tio n
M o st m a n u fa ctu r er s sta te th a t th e
coating is to be ap p lied only w hen the
su bs tr at e te m p er at u re is 5 d eg re es F,
m i n im u m , a bo v e th e d ew p o in t
D r y i n g , r e co a t , a n d cu r in g t i m e s a t
va riou s tem p eratu re an d hu m idity
ran ges
A p p l ica t io n m e t h o d : b r u s h , ro lle r ,
conv en tiona l airless sp ray , or airless
sp r a y . M a y in clu d e s p ecific
equ ipm en t at re com m en d ed p ressu res,
h os e d iam et er siz es , sp r a y g u n , n oz z le
tip siz es , etc.
Chapter IV
Inspector's Role
The coating insp ector ensu res th at: (1) the
w or k is a cco m p lish ed in a t im ely m a n n er in
a c co r d a n c e w ith th e s p ecificatio n s ; (2 ) w ork
a ctiv itie s a r e d oc u m en te d ; an d (3) w or k is
p erform ed safely. The coating insp ector at the
jobsite is eithe r th e contra cting officers or th e
field en gineers rep resentative.
The insp ector shou ld n ot ver bally cha ng e the
r eq u ir em en ts or r eq u ir e m or e r ig id
r e q u i r em e n t s o n t h e co n t r a ct o r th a n w e r e
or ig in a lly sp ecifie d . Th e in sp ect or sh ou ld
contact his su p erv isor for reso lution if the
s p e c ifica t io n s a r e in a d e q u a t e . C o n t r a c to r s m a y
r e q u e s t a v a r ia n t fr o m s p e c ifica t io n s t h a t m a y
o r m a y n o t b e s ig n ifican t. R eg ard les s o f
v a r ian t s ig n ifican ce, t h e in sp ect or sh ou ld
inform his sup ervisor of an y requ ested
c h a n g e s. If a co atin g ap p licato r is n o t
fo llo w in g t h e s p ecificatio n s , th e in s p ector
sh o u ld n o t co n fr o n t t h e ap p lica to r . In st ea d , h e
sho u ld a sk th e coating contra ctor su p erv isor to
d et er m in e w h y th e s p ecifica tio n s a r e n ot b ein g
fo llo w e d . In s o m e ca s e s, a d e v ia t io n m a y h a v e
b e e n a l lo w ed o r th e co atin g co n tracto r
su p e r v i so r m ay n eed to co rrect h is o w n
w or k er s p ra ctices .
E n s u r e a ll s p e c ifica t io n s u b m it t a l
requ irem ents are m et
E n s u r e w e a t h e r co n d it io n s a r e
c ond u c ive to bla sting op e ra tions
En su r e w or k is co n d u cte d in a s a fe
m an ner
15
E n s u r e a ll co a t in g m a t er ia ls a re
ap p roved
E n s u r e in t e r m e d ia t e co a t a n d t o p c o a t
a p p licat ion s a r e w ith in r eco a t t im e
interv al for tem p eratu re an d hu m idity
r an g es a n d th a t th e y m e e t th e
sp ecifica tio n s or th e m a n u fa ctu r er s
requ irem en ts
C h eck am b ie n t te m p e r atu r e a n d
h u m id ity d u rin g cu rin g p erio d
A p p rov ed . In d ica t es m a t e r ia l ca n b e
p u rchased and ap p lied .
Co nd it io na ll y a p p rov ed .Ind icates the
m at er ial se lectio n is a ccep ta b le a n d th e
m a t er ia l m a y b e p u r ch a se d ; h o w e v er , th e
su b m itt a l is in co m p let e o r is m iss in g
d oc um e nta tion. Re s ubm itta l of inc om p le te or
m iss in g d ocu m en ta tion is r eq u ir ed .
C on d itio n a l ap p r ov a l d oe s n ot im p ly
a c ce p ta nc e for m a te ria l a p p lic a tion.
N o t a p p rov ed .Ind icates the selected
m a t er ia l is n o t a p p r ov ed fo r a p p lica tio n .
E n s u r e t h a t d e fe ct iv e , d a m a g e d , a n d
d eficient areas are rep aired to m eet
sp ecification r equ irem en ts.
Fo r a m o r e co m p reh en s iv e lis t o f
resp on sibilities, see ap p en d ix C.
T h e m a n u fa ct u r e r s p r o d u ct d a t a ,
ap p lication , an d M aterial Safety Data
Sh eet (M SD S)
16
Inspector's R ole
Re fer en ce s ta n d a r d s a r e d iscu ss ed in
m or e d et a il for th e p er tin en t
in sp ectio n m eth o d in oth er ch a p te r s.
A p p e n d ix D lis ts r efe r e n ce st a n d a r d s
cited in this docu m ent
T h e t w o p a r t ie s a r e n o t u s i n g t h e s a m e
typ e of instru m en t sets:
" O n e in s t r u m e n t m a y b e
m a lfu n ctio n in g
" O n e in s tru m en t m ay b e o u t of
calib ratio n
T h e t w o p a r t ie s a r e u s in g t h e s a m e
typ e of instr u m en ts bu t:
" T h e y a r e ta k in g r e a d in g s a t
d iffe re n t lo ca tio n s
" O n e in s tru m en t m ay b e o u t of
calib ratio n
17
18
T h e m e t h o d o f d u s t co lle ct io n a n d
d isp osal of u sed abrasives
T h e p l a n fo r co a t in g i n a cce s sib le a r e a s
T h e N A C E / SSP C r e fe r e n ce st a n d a r d s
t h a t ar e sp e c ifie d , th e v is u a l s ta n d a r d s
to b e m et , an d th e a ccep ta n ce cr ite r ia
T h e co n t r a ct o r s w o r k i n g h o u r s
Th e m a te r ial s to r a g e a r ea , in clu d in g
tem p eratu re, ven tilation, and security
T h e ap p ro v ed s u rface p r ep aration
m eth od s, ab rasiv es, coatin g m ater ials,
ap p lication m ethod s, and curing tim es
Chapter V
Material Storage, Containers, and Shelf Life
C o a t in g m a t er ia ls a rr iv e o n t h e jo b s it e b e fo r e
a p p lica tio n b eg in s, a n d th ey r eq u ir e st o r a g e.
M a n u fa c tu r ers reco m m en d s p ecific p ro vis ions
fo r st o r a g e to p r ev en t co a tin g d ete r io r a tion .
C oa tin g m a te r ials m u st b e u se d w ith in a
sp ecified tim e from m an u factu re or sh ipm en t.
22. Storage. C o a t in g m a t er ia ls sh o u ld b e
s t or e d in a c o v e r ed , w e ll-v e n t i la t e d a r e a a w a y
fr o m sp a r k s, fla m es, a n d d ir ect su n lig h t.
M a n y co a t in g s r e q u ir e a lim it e d t e m p e r a tu r e
r a n g e f or p r o p e r s t o r a g e . C o ld s to r a g e m a y
r e q u ir e a co atin g to b e ex ces s iv ely th in n ed for
a p p lica t io n , r es u l tin g i n lo w s o lid s co n t e n t a n d
a le ss-t h a n -in ten d ed D F T . A t o r b elo w
freezing tem p eratu res, coating s (su ch as w ater
b a s e d m a t e r ia ls ) ca n d e g r a d e t o th e p o in t t h a t
t h e y a r e u n u s a b le . M a t e r ia ls in c o ld s to r a g e
s h o u l d b e m o v e d t o a h e a te d a r e a b e fo r e
a p p lica t io n . A t h i g h t e m p e r a t u r e s , a m a t e r ia l
su c h a s so lv en t-b as ed co atin g m ay g el o r
b e co m e fla m m a b le o r e xp lo s iv e . T h e st o r a g e
sit e sh o u l d b e m o n ito red u s in g a h ig h / low
t h e r m o m e t er .
C o a t in g m a t er ia ls sh o u ld b e st o r ed t o g et h e r b y
t h e sa m e b a tch o r lo t n u m b ers . T w o com p onen t coating system s shou ld be stored
c lo se t o g e th er b u t b e d is tin g u is h ab le fro m one
a n o t h e r . For sto rag e o f s ev eral m o n th s or
lo n g e r , co ntain ers s h o u ld b e in v erted o n a
m o n t h l y b a s is to a v o id e x ce s siv e s e tt lin g a n d
for ea se of fu tu r e m ixin g . Th e o ld es t co a tin g
m aterials sho u ld b e u sed first.
Solvents an d thinn ers shou ld be stored
se p a r a t e l y fro m co atin g m aterials. Sep ara tion
o f s o lv e n t s an d t h in n e r s is a sa fe t y co n c er n
because m an y of these m aterials hav e low er
flash p oint tem p era tu res th an m ost coating s,
a n d t h e y p o s e a p o t e n t ia l fir e h a z a r d .
C o n t r a c to r s w i ll o ft e n s to r e co a t in g m a t e r ia l a t
t h e jo b s it e in t r a ile r s. T ra ile r s w it h n o h e a t in g ,
co olin g , or v en tila tio n sy st em s a r e u n su ita b le
for storage b ecause they becom e cold in w inter
20
Chapter VI
Surface Preparation
The serv ice life of a coating d ep en d s on th e
d e g r e e o f s u r f a ce p r e p a r a t io n a c h ie v e d a s
m u ch a s it d e p e n d s o n m a t e r ia l s e le ct io n a n d
a p p licat ion . A ll coa tin g sy st em s w ill
even tu ally fail; how ever, pr em atu re failures
ar e o ften th e r es u lt o f in ad eq u at e s u rfa ce
p r e p a r a t i on . Ev e n s u r fa ce p r e p a r a t io n s t h a t
a ch i ev e a n a cce p t a b le m a r g i n o f cle a n lin e s s b u t
leave contam inan ts on th e su rface w ill tend to
lessen th e coating serv ice life. Thu s,
cle a n l in e s s o f t h e s u b s t r a te is a n e s se n t ia l a n d
integral com p onen t of a coating system .
C on d en sa tio n is o ccu r r in g
W at er is u se d in th e s u rfa ce
p r e p aratio n m eth o d
22
Surface Preparation
23
24
co n te n t. A b r a siv es w ith h ig h so lu b le s a lt
conten t shou ld n ot be u sed becau se the salts
ca n con ta m in a te th e s u b st r a te d u r in g b las tin g
op erations and , thu s, cause coating failu re.
M ine ra l a nd s la g a bra s ive s shou ld be te s te d for
the p resen ce of solub le salts by a con d u ctivity
m et er . Co n d u ctiv ity is th e io n ic p r op er ty of a
flu id o r s o lid t h a t p e r m it s t h e p a s s a g e o f a n
ele ctr ic cu r r en t. Solu b le s a lts d iss olv ed in
w ater can be m easu red by a cond u ctivity
m e t er . C on d u ctiv ity m e te rs m e a su r e th e
cond u ctance of all salts (ch lorid es, sulfates,
ferrou s, etc.) in d issolution bu t cann ot d etect a
sp ecific sa lt io n (e.g ., th e ch lo r id e io n ).
R ecla m a t io n s p e c ifie s th a t m in e r a l a n d s la g
a b r a siv es a r e to b e in acco r d a n ce w ith SSP C A B1, an d the stan d ard s cond u ctivity
r eq u ir em en t is n ot to ex cee d 1,000
m icr os iem en s. Th e ch lor id e-s p ecific io n in
a b r a siv es ca n b e te st ed u sin g a tit r a tion k it.
(See ap p en d ix H for te st p r oc ed u r es .) Tes tin g
fo r to xic m eta ls r eq u ir es la b or a to r y m eth od s.
C e r t ifica t io n o r a n a l y s is o f a b r a s iv e m a t e r ia l
co n t e n t is a v a ila b le fr o m t h e m a n u f a ct u r e r .
Althou gh w ater is not consid ered an a brasive,
it is us e d a s a s urfa ce pr e p a ra tion m e d iu m for
p r e v io u s l y co a t e d m e t a lw o r k . W a t e r m a y
contain a n excessive am ou nt o f solub le salts
that, if left as resid u e on th e p rep ared sur face,
can cause th e coating to blister. The w ater
u s e d in w a t er je t tin g o p e r a tio n s sh o u ld b e
tested for high chlorid e ion levels. (See
a p p en d ix I for p r oce d u r es.)
Surface Preparation
If th e n oz z le b las t p r es su r e is su sp ect , it is
r eco m m e n d ed t h at th e in sp e cto r r eq u e st th e
coating sup ervisor to check the p ressur e. (See
a p p en d ix J fo r th e p r o ce d u r e.)
D e g r e a sin g .
H a n d a n d p o w e r to o l cle a n in g .
A b r a s iv e (w e t o r d r y ) cle a n in g .
W a t e r je t tin g o r p r e s s u r e cle a n in g .
C h e m ica l s tr ip p in g .
25
26
lig h t s h a d o w s , s lig h t s tr e a k s, o r m in o r s tr e a k s
ca u se d b y r u st , m ill sca le, o r p r ev iou sly
a p p lied coa tin g s. A t le a st 95 p er cen t o f ea ch 9in ch -sq u a r e a r ea sh a ll be fre e o f all v isib le
r es id u e, a n d th e r em a in d er of t h e a r ea sh a ll
h av e on ly th e ab ov e-m en tion ed stain ing . The
vis ua l sta nd a rd is de te rm ine d by c om p a rison
to SSPC -VIS 1 referen ce p h otog rap h s.
(j) NAC E 1/SSPC-SP 5: W hite M etal Blast
Clea ning. W h it e m e t al b la s t cle a n in g e m p l o y s
abr asive blasting to rem ove all grea se, oil, d irt,
d u s t, m ill s ca le, ru s t, c oa tings , oxid e , c orro sion
b y p r o d u c t s, a n d o t h e r fo r e ig n m a t te r th a t a r e
v isib le w ith ou t m a g n ificat ion . Th e r es u ltin g
b la s te d s u r fa ce is g en e r a lly a u n ifo r m g r a y w hite color. Variation in color cau sed by steel
typ e, origina l su rface cond ition, steel
thickne s s , w e ld m e ta l, m ill or fa brica tion
m ark s, h eat tr eatm en t, heat-affected zon es,
blasting abr asives, or d ifferen ces in blast
p a tt er n is a ccep ta b le. Th e v isu a l st a n d a r d is
d ete r m in ed b y co m p a r iso n to SSP C -VIS 1
referen ce p h otog rap h s.
(k) NACE 5/SSPC-SP12: Surface Preparation
and C leaning of Steel and Other Hard Metals
by High- and Ultra-Pressure Water Jetting Prior
to R ecoating. H igh- or ultra-high w ater jet
b las tin g em p loy s w a te r b las tin g to r em ov e a ll
gr ease, oil, dirt, d u st, m ill scale, ru st coating s,
oxid es, corrosion b yp rod u cts, and other
fore ign m a tte r tha t a re vis ible w ithou t
m a g n ificat ion . Rem ov e n on v isib le s olu b le
s a lt s t o a llo w a b le lim it s t h a t r e q u i r e p h y s i ca l
testing to ver ify. The stand ard d efine s the
fo llow in g fo u r d iffe r en t w a ter p r essu r es:
(1) lo w -p r e s su r e w a t e r cle a n i n g a t le s s t h a t
5,000 p s i; (2) h i g h -p r e s su r e w a t e r cle a n i n g a t
5,000 to 10,000 psi; (3) high -pressu re w ater
jet tin g at 10,000 to 25,000 p si; an d (4) u ltr a h ig h p r e s su r e w a t e r je t tin g a t g r e a t e r th a n
25,000 psi. The d egree of cleanliness is d ivid ed
in t o t w o ca t e g o r ie s : v i sib le co n t a m in a n t s a n d
no nv isible con tam inan ts. Visible contam inan ts
are su bd ivid ed into fou r classifications,
d esignated W J-1 thr ou gh W J-4 (WJ-1 is the
clean est) on the b asis of allow able visible ru st,
coating s, m ill scale, and foreign m atter
v er ified w ith ou t m a g n ificat ion . N on v isib le
contam inants are su bd ivid ed into three
clas sifica tio n s, d es ig n a te d SC-1, SC -2, an d SC-3
Surface Preparation
(SC-1 is th e cle a n es t) o n th e b a sis of a llow a b le
so lu b l e c h lo rid e io n s , iro n -s o lu b le s alts , or
su lfat e io n s. Th e v isib le a n d n on v isib le
a llo w a b le co n t a m i n a n t le v e ls a re sp e c ifie d b y
the d esignation W J-x/ SC-x; x ind icates the
s p e c ifie d d e fin i tio n n u m b e r . T h e v is u a l
stan d ard w ill be d eterm ined by com p arison to
SSPC -VIS 4/ N A CE 7 referen ce p h otog rap h s.
Re clam a tio n sp ecifie s W J-2/ SC -2 for all
im m ersion serv ice exp osu res.
W a te r jet tin g can n ot p r od u ce a su r face p r ofile
w ithou t the ad d ition of abrasives into the jet
flo w a n d , t h erefo re, is n o t s p ecified fo r
su rfaces w ithou t a sur face p rofile, e.g., new
co n st r u ctio n st ee l. Recla m a tio n sp ecifie s t h is
stand ard only for pr eviou sly coated sur faces
that h ave an existing sur face p rofile.
2.
Fr om th e s p ecifica tio n s, d et er m in e
the s pe c ifie d s urfa ce pr e p a ra tion
s ta nd a rd . The s urfa ce pr e p a ra tion
sta n d a r d w ill b e on e of t h e fo llow in g :
N A C E 1/ SSP C -SP 5, N A C E 2/ SSP C SP10, N A C E 3/ SSPC -SP6, or N A C E
4/ SSPC -SP7.
3.
Fr o m t a b le 1 in t h e v is u a l s ta n d a r d ,
s e le ct the s pe c ifie d s urfa ce pr e p a rat ion
stan d ard an d the initial cond ition to
ob ta in th e co r r ect p h ot og r a p h ic
d e sig n atio n .
4.
27
SP 3/ P W D : P ow e r w i re br u sh .
(R ecla m a t io n d o e s n o t p e r m it r o ta r y
p ow e r w ire bru s hing be c a us e the t ool
h as th e ten d en cy to bu rn ish or p olish
t h e m e t a l s u r f a ce , t h u s r e m o v i n g a n y
exis tin g su r fa ce p r ofile .)
2.
28
Be fo r e h a n d - o r p o w e r -t o ol cle a n in g ,
m a tch th e ex is tin g s u rface co n d ition
tha t m ost closely rep resen ts the
a p p earan ce w ith th e in itial co nd ition
sh ow n in on e o f th e p h ot og r a p h ic
stan d ard s. Initial cond ition s (or ru st
g r a d es ) A , B, C , an d D are fo r
u n c o a te d s u r f a ce s ; co n d it io n s E , F , a n d
G a re for p rev iou sly p ainte d su rfaces.
In i tial co n d itio n s are d efin ed in s e c tion
4 .1 o f th e s tan d ard . V ario u s area s of
th e s u rfa ce t o b e clea n ed m ay m at ch
o n e o r m o re in itial co n d itio n
p h otog rap h s.
From the sp ecification s, d eterm ine th e
sp e cified s u rface p r ep aratio n
st an d ard . T h e s u rface p r ep aration
Fr o m t a b le 1 in t h e v is u a l s ta n d a r d ,
s e le ct the s pe c ifie d s urfa ce pr e p a rat ion
stan d ard an d the initial cond ition to
ob ta in th e co r r ect p h ot og r a p h ic
d e sig n atio n .
5.
Surface Preparation
sp ecifie d d eg r ee of cle a n in g is W J-2.
St ep 2 : Select p o w er to o l d es ig na tion
SP1 1 b ecau s e a n eed le g u n p o w e r tool
w as u sed to p rep are the su rface.
Step 3: From table 1, the finished
su r fa ce p h oto gr ap h t h at co rr esp o n d s
to ru st g ra d e C a n d su rfa ce
p r e p aratio n S SP C -SP 1 1, an d th e tool
u se d is C SP11.
Step 4: Ev alu at e t h e fin ish ed su rfa ce
aga inst p ho togr ap h C SP11 to
d e te r m i n e if t h e su r f ace m e e ts SSP C SP11 clean lin ess req u irem en ts.
3.
Th e gu id e sh o w s p h oto gr ap h s of th e
follow ing fou r d egr ees for flash
ru sting : (1) no ru sting , (2) light,
(3) m ed ium , and (4) heav y. These
d e g re es o f fla sh r u stin g ar e th e
d eg r ee s o f ru st in g allo w ed to r em a in
on th e su r fa ce after w a te r jet clea n in g .
T h e d e g r e es o f fla s h r u s t in g a r e
d en oted in th e g u id e b y th e fo llow in g :
(1) n o le t te r d e s ig n a t io n fo r n o r u s t in g ,
(2) L fo r lig h t , (3) M f o r m e d iu m , a n d
(4) H fo r h e a v y . Fo r e xa m p l e , if lig h t
flash ru sting is allow ed by th e
sp ecificat ion s, a p os sib le su rfa ce
p r e p a r a t io n w o u l d b e N A C E 5/ SSP C SP12 W J-2/ SC-3 L, w he re L is the
a llo w a b le a m o u n t o f fla s h r u s t in g , a n d
it is d e n o t e d i n t h e g u i d e p h o t o g r a p h s
as W J-2 L.
4.
Fr o m t a b le 1 in t h e v is u a l s ta n d a r d ,
select the d egree of cleaning, den oted
by W J-1, -2, -3, or -4, corresp on d ing to
the in itial con d ition to obtain the
c orre ct ph otogra p hic d e s igna tion.
5.
6.
2.
29
30
m a t e r ia l r e q u i r e s a d e e p e r p r o file , t r a d i t io n a l
a b r a siv e b la st cle a n in g m u st b e em p lo y ed .
Th e fo llow in g se ctio n s p r ov id e a lte r n a tiv e
cleaning m ethod s w ith an abbr eviated
d e scr ip t io n .
(a) Sponge A brasive B lasting. This m e tho d
follow s th e tra d ition al abr asive b last m eth od s,
e xce p t t h a t th e a b r a siv e p a r t icle s a r e
en cap su lated in a sp on ge m ater ial. Th e
sp ong e m aterial p reven ts abrasive pa rticles
from brea king u p an d d iffusing on im p act,
t h u s r e d u cin g t h e a m o u n t o f d u s t . Sp o n g e
bla sting c re a te s a bou t 10 to 20 p e rc ent of
t h e d u s t t h a t w o u ld b e cr e a te d b y
n on en cap su lated ab ra sive m ater ials. Th e
m etho d d oes create a su rface pro file, an d the
su r fa ce cle a n lin ess ca n b e co m p a r ed to SSP C VIS 1.
(b) So da B icarb onate B lasting. This m e th od
p rop els larg e crystals of sod a bicarbon ate
(b a k in g so d a ) b y p r es su r ize d air or w a te r . It is
u s ed m o stly as a str ip p e r fo r cle an in g
co n ta m in a n ts an d for th in coa tin g s. Th er e is
n o s u r face clea n lin es s s ta n d a r d for th is
m ethod ; how ever, cleanliness can be sp ecified
to m eet th e req u irem en ts of a consen su s
su r face p r ep a r a tio n (e.g ., N A C E 3/ SSPC -SP6).
(c) Ice Blasting. Th is m et h od p ro p els ice
p ar ticles b y p re ssu riz ed air . O n im p act , th e ice
exerts a shee r force across the su bstrate
su r face , re m ov in g con ta m in a n ts an d th in
coating s. If d ry ice is u sed , it sho u ld n ot be
u s e d in c onfine d s pa c e s be ca u s e of c a rbon
d ioxid e b u ild u p . Th er e is n o s u rfa ce
cleanliness stand ard for this m ethod ; how ever,
clean line ss can be sp ecified to m eet the
re q u ire m en ts o f a co n se n su s su rfa ce
p r ep a r a tio n (e.g ., N A C E 3/ SSPC -SP6).
(d) Chem ical Strip pers. C h e m ica l s tr ip p e r s
c a n be cla s s ifie d into tw o ge ne ric c omp os ition
typ e s : (1) bond bre a ke rs a nd (2) c a us tic . Bond
b r ea k er st r ip p er s w or k b y b r ea k in g th e p a in t's
m o le cu la r b on d s b etw e en p a in t la ye rs a n d
b e t w e e n t h e p a i n t a n d t h e s u b s t r a te s o t h a t
p a in t w ill cr in k le u p an d b e ea sily r em ov ed .
Bond break er strip p ers can contain tolu ene,
m e t h yle n e ch lo rid e , o r m e th y l e th y l k eto n e
th a t r em ov es p a in ts in a r ela tiv ely sh or t t im e
Surface Preparation
b u t m a y b e co n sid er ed h a z a r d o u s t o w o r k er s.
Le ss h a z a r d ou s b on d b r ea k er s co n ta in N m ethyl-pryr rolid one (N M P) or d ibasic ester
(DBE) com p ou n d s, bu t th ese rem ov e p aint less
q u ick ly . Bo n d b r e ak e r s tr ip p e rs w ill r em o v e
a ll co a tin g s e xcep t o il-b a se d , in o r g a n ic, a n d
m e t allic co a t in g s . C a u s t ic s tr ip p e r s w o r k b y
s o ft e n in g t h e e n t i r e p a in t s y s te m r a t h e r t h a n
b r e a k in g m o le cu l a r b o n d s . C a u s t ic s tr ip p e r s
ca n con ta in so d iu m , calciu m , an d m a g n es iu m
hy d roxid e. Cau stic strip p ers are r estricted to
oil-based p aints bu t w ill not w ork on oil-based
p a in ts th a t a r e p ig m en te d w ith alu m in u m
flak es . Th is is b eca u se h y d r og en g a s is
g en er a te d w h en cau st ic com p ou n d s co m e in
contact w ith alum inu m , thu s p rev en ting th e
ca u st ic st r ip p er fro m p en et r a tin g th e p a in t
system .
31
Chapter VII
Environmental Conditions
Cold w eath er, high h u m idity, w ater, fog, frost,
m i st, r ain , ice , a n d sn o w a re so m e of th e
en viron m en tal factors d etrim en tal to the
p e r f or m a n c e o f co a t in g s . C o a tin g s s h o u l d b e
a p p lie d u n d e r o p t im u m e n v i r o n m e n t a l
co n d itio n s, b u t t h e w ea th er can ab r u p tly
ch a n g e. Th e p r ev a ilin g en v ir on m en ta l ru le-o fth u m b is t h a t e v a p o r a tio n sh o u ld b e occu r r in g .
C o m m o n s e n se , t h e m a n u f a ct u r e r s
instru ction s, an d ind u stry p ractices ap p ear to
be the m ost com m only follow ed gu idelines
r eg a r d in g en v ir on m en ta l con d itio n s d u r in g
co a tin g ap p lica tio n an d th e cu r in g p er io d .
F a ilu r e t o co n f o r m w it h e n v i r o n m e n t a l
r e st r ic tio n s res u lts in a v ariety o f ap p lica tion
failu res.
34
Chapter VIII
Application and Curing
C o a t i n g a p p licatio n is next in imp ortan ce after
su rface p rep ara tion, an d accou n ts for m ost
failu re s. A coa tin g is n ot a fin ish ed p ro d u ct
u ntil it ha s been su ccessfu lly ap p lied to the
st ee l su b st r a te an d cu r ed . Co a tin g
p e r fo r m a n c e is a ffe ct e d d u r in g a p p lica t io n a n d
cu r in g b y t e m p e r a t u r e , r e la t iv e h u m id it y , a n d
d e w p o in t . (Se e ch a p t e r VII, E n v ir o n m e n t a l
C o n d it io n s . ) M i x in g , n u m b e r o f co a t s a n d
th ickn ess, and ap p lication tech n iqu e w ill also
affect coating p erform an ce. N ot obser ving the
env ironm ental restrictions or im p rop er
ap p lication tech n iqu es can resu lt in d efects,
p rem atu re failure, or red u ced serv ice life.
A ir an d su b st r a te te m p er a tu r es sh a ll
b e a b ov e 50 d eg r ee s F d u r in g
a p p lica tio n an d c u rin g an d w ith in th e
m a n u fa ct u r e r s u p p e r t e m p e r a tu r e
lim it.
Su r faces sh all b e a m in im u m o f
5 d eg r ee s F a b ov e t h e d ew p oin t
te m p er a tu r e a t t h e t im e o f coa tin g
a p p lica tio n .
35
Sh a k i n g .
Bo x in g ( r e q u i r es p o u r in g t h e m a t e r ia l
from the original ship p ing container
in to an em p ty con ta in er an d r ep ea tin g
th e p rocess sev era l tim es). It is m ost
often u sed for sing le-com p on en t,
m oistu re-cur ed m ater ials.
36
37
38
Equipm ent. Th e eq u ip m e n t u s ed in th e
electrostatic sp ray m etho d is sim ilar to
conven tiona l, airless, and air-assisted spr ayer
e q u i p m e n t , e xce p t t h a t an e le ct r o st a tic, h i g h voltage su p p ly is requ ired.
Working principle. A t o m iz e d c o at in g s
a r e a p p lied to th e s u b st r a te b y con v en tio n a l,
air less , or air -as sist ed sp ra y eq u ip m en t, w h ich
is con n ected to an electr ost a tic p ow er so u r ce .
The coating m aterial is p ositively charged ,
an d the su bstrate is neg atively charg ed
(conv entional electrical theor y). Sp rayed ,
p ositively charged , atom ized coating p articles
are attracted to n egatively charg ed sub strate.
Ad van tages. T h e e le ct r o st a t ic s p r a y
m e thod is ca p a ble of a p p lying c oa tings to od d
sh a p es a n d a ro u n d co rn e rs, a n d o ve rsp r a y a n d
r e b o u n d m a t er ia l in c o n fin e d s p a ce s a r e
rea ttracted to th e su bstr ate. This m eth od h as a
h igh tr an sfer efficiency r ate an d p rod u ces a
u n ifo rm f in ish .
Disa dva ntag es. Th e w in d m a y ca rr y th e
co a tin g m a te r ial a w a y , th e m et h od allo w s o n ly
on e thin coat, the cov erag e an d p rod u ction rate
a r e less th a n w ith th e oth er sp r a y m eth od s, a
co n d u ctiv e co a tin g for m u lat ion is u su a lly
r e q u i r ed , t h e m e t h o d is u n s u it a b le fo r la r g e
stru ctu res, an d th is m eth od p resen ts a
p o t e n t ia l e le ct r ica l s h o ck h a z a r d .
Use s. Th is m et h od is su ite d to sm a ll
a r e a s b e h i n d co r n e r s , r e ce s se d a r e a s, ir r e g u l a r
a r e a s, o r a r ea s th a t ca n n o t b e co a t ed b y
conv en tional-typ e ap p lication equ ipm en t.
(i) Plural Comp onent S pray. T h is sp r a y
ap p lication m etho d is the m ost com p lex of the
spray equipm ent group an d should be used by
a p p lica t o rs w h o a r e t r a in e d a n d ce r tifie d b y
the c oa ting m a nu fa c tu re r. This a pp lic a tion
m e t h o d i s co m m o n ly u s e d t o ap p ly t w o o r
39
40
t e m p e r a t u r e a n d h u m id it y . W h e n t h e r e co a t
w in d ow h a s b ee n ex cee d ed , th e co a tin g
su rfa ce m ay re q u ire fu rt h er su rfa ce
p r e p a r a tio n fo r w h i ch m o s t m a n u fa ct u r e r s
recom m end abrad ing the su rface or solvent
a p p lica t io n o r b o th . R eco a t w in d o w s v a r y
w idely, from a few m inu tes to a m on th o r
lon g er , d ep en d in g on th e t y p e o f coa tin g
m a te r ial. If te m p er a tu r e a n d h u m id ity ar e n ot
sho w n o r are ou tsid e the listed valu es on the
m a n u fact u r er s in st r u ctio n s, th e co a tin g
m a n u fa ctu r er sh ou ld b e co n su lted .
Reclam ation sp ecification s sp ecify the
m a nu fa c tu re rs re com m e nd e d re coa t w ind ow
becau se recoat w ind ow s var y gr eatly w ith
m a te r ia l ty p e.
(c) Cu ring. This is the ne c e ss a ry tim e pe ri od
at a referen ced tem p eratu re an d hu m idity
com bination to allow the coating to com p lete
t h e ch e m ica l r e a ct io n a n d t o a ch i e v e st r u c t u r a l
integrity so th at it w ill be read y for th e
in t e n d e d s e r v ice e xp o s u r e . E xce ss iv e m o is tu r e
a n d lo w o r h i g h h u m id it y o r te m p e r a t u r e ca n
stop or r etar d th e cu ring p rocess. Mo st
m a n u fact u r er s in st r u ctio n sh ee ts p r ov id e
inform ation for cu re tim e an d cur e tim e to
im m e rsio n .
C u r r en tly , th er e is n o a ll-en co m p a ss in g
m e t h o d t o d e t e r m in e i f a co a t in g h a s
com p letely cu red .
Chapter IX
Field Inspection and Testing
Field in sp ection an d testing is necessary to
en su r e co a tin g p er for m a n ce a n d to v er ify
s p e c ifica t io n a c ce p t a n c e . Fie ld in s p e ct io n a n d
te st in g ar e p er for m ed in th e fo llow in g coa tin g
areas: (1) su rface prep aration , (2) w et p aint,
(3) h a r d e n e d p a in t , a n d (4) d e st r u c tiv e t es tin g .
D i al s u r fa ce p r o file g a u g e
41
42
DF T gauges. T h e ty p e s o f D F T g a u g e s a r e
d eterm ined by th e specific m agn etic prop erties
(Se e ap p e n d ix P fo r ca lib r a t io n a n d p r o c ed u r e
fo r e ach g a u g e ty p e a n d a D F T p r o c ed u r e
ex a m p le.).
1.
P u l l o f f g au g e s .In g en er a l, p u lloff
g a u g es u se a p er m a n en t m a g n et in
co n t a ct w it h t h e co a t e d s u r f a ce a n d a
calib ra te d sca le to m ea su re th e fo rce
requ ired to p u ll the m agn et from the
co a te d su r fa ce . Th e sca le is n o n lin ea r .
Th e fo llow in g ar e t w o t y p es of p u lloff
gau ges an d their ap p roxim ate
thickn ess range:
C o n s tan t p re s s u re p ro b e g a u g e s.
The g en eral w ork ing p rinciple of the
constan t p ressu re p rob e gau ge is that a
p r o be exe rts a co n sta n t p r essu r e o n th e
co a t ed s u r fa ce , a n d e le ct r o n ic cir cu i t ry
c o nv erts a referen ce sig n a l in to a
c o a tin g th ick n es s th at is d is p lay e d on
a n an a lo g o r d ig ita l scr ee n .
2.
3.
M ea su re th e h ar d en ed coa te d su rfa ce
w it h t h e ca lib r a t e d D F T in s t r u m e n t a t
the n u m ber o f sp ot m easu rem en ts
in d ica t e d i n t a b le 1. D i sr e g a r d
in c o n s is t en t h i g h o r lo w r e a d i n g s t h a t
ca n n ot b e r ep ea te d . Th e fo llow in g
are th e n u m ber of gau ge r ead ings,
sp ot m easu rem ents, and avera ging p er
100- s q u a r e - fo o t a r ea :
a.
D ete rm i n e th e 5 sp o t m e a su r em e n t
locations requ ired p er 100-squ arefo o t a r ea .
b . Ta ke 3 ga u ge re a d ings p e r s pot
m e a su r em e n t a n d a v er ag e th e
3 re a d ings . This is a tota l of
15 g a u g e r ea d in g s, m in im u m
(3 ga u ge re a d ings x 5 s pot
m ea su r em en t lo ca tio n s p er 100sq u a r e-fo ot ar ea ).
43
Three (3) 100-square-foot areas for the first 1,000 square feet within the
total area; plus
One (1) 100-square-foot area for each additional 1,000 square feet of
coated areas or fraction thereof
c.
A v erag e th e 5 in d iv id u al s p o t
m ea su r em en ts to ob ta in a s in g le
avera ged valu e for the 100-squ arefo o t a r ea .
4.
5.
D et er m in e m in im u m an d m a xim u m
t h ick n e s s a cce p t a n c e cr it e r ia .
6.
A n y n u m b e r o f in d iv id u a l g a u g e
r e a d i n g s m a y b e le s s t h a n
90 p ercent of the sp ecified
th ickn ess.
b . N o s in g le av erag ed s p o t
m eas u rem en t in 10 0-s q u are-foot
area m ay b e les s th an 90 p er c ent of
th e sp ecifie d th ick n ess ..
W he re av erag e sp ot m easu rem en ts
are less than 90 p ercent of the
s p e c ifie d t h ick n e s s , a d d it io n a l
m easu rem en ts m ay b e taken to
red efine the n oncon form ing area
7.
A n y n u m b e r o f in d iv id u a l g a u g e
read ings m ay exceed 150 percent
of the sp ecified th ickn ess.
b . N o s in g le av erag ed s p o t
m easu rem en t in a 100-squ are-foot
44
Te st in g is n ot r eq u ir ed on con d u ctiv e
co a tin g s p ig m en te d w ith alu m in u m ,
g r a p h ite , zin c, or ot h er ele ctr ically
cond u ctive p igm en ts.
45
Chapter X
Maintenance Coatings
Reclam ation infrastru ctures m ay still be coated
w it h t h e o r ig in a l m a t e r ia ls fr o m t h e in i tia l
in st a llat ion or th ey m a y h a v e r ece iv ed fu ll,
p artial, or sp ot coating rep air in th e
in te r v en in g y ea r s. O b v iou sly , an y coa tin g
m a t e r ia l h a s a fin i te s er v i ce life , a n d
m a in t e n a n c e co a t in g s h a v e b e co m e a n
im p ortan t com p on en t in m aintaining the
stru ctu ral integ rity of h igh-cap ital-cost
infrastr u ctu res.
46. Inspection. To d e te rm in e th e co r re ct iv e
a c tion re qu ire d , s truc ture s id e ntifie d for
m a in t e n a n c e co a t in g s w o r k sh o u ld b e
in s p e ct e d b e f or e b e g in n in g w o r k . P r e lim in a r y
w o rk sh o u ld in clu d e ga th e rin g ba ck g ro u n d
in for m a tio n on th e s tr u ctu r e, in clu d in g
location , original installation d ate, d im en sions,
d r a w in g s, s u b st r a te ty p e, an d co a tin g h ist o r y .
The coating history sh ou ld includ e the
follow ing inform a tion, if know n:
Se r v ice e xp o s u r e
P r e v e n t s ig n i fica n t lo s s o f m e t a l
Pr ev en t s ig n ifican t d eg r ad atio n of
co a t in g m a t e r ia l
A g e o f co atin g
D FT
Id en tify b y co lo r co d e
O b se r v e a n d d oc u m en t t h e fo llow in g
coating cond ition s:
D e fe ct s: b lis te r in g , ch a l k in g ,
c ra cking, e ros ion, de la m ina tion,
p inh ole s , p e e ling, un d e rc utting, or
oth er d efects
A p p e a r a n c e: co a t in g o r t o p co a t
lo ss , ab r a sio n st r ea k s, r u st st a in in g ,
fading color, w eathering , or oth er
ab n or m al a p p ea ra n ce
F or m o s t R ecla m a t io n s t r u c t u r e s , t h e g e n e r a l
o v e r v i e w a n d d etailed v isu al s u rv ey m ethod s
a r e su f fic ien t to id en tify co atin g an d co r rosion
d eterior ation tren d s.
Genera l overview survey. Th is qu a lit at iv e
s u r v e y ca n b e a cco m p l is h e d i n a fe w h o u r s
a n d is a d e qu ate to ascertain s ev ere co rro s ion
cond ition s an d d egra d ed coating s. On ly the
m a jo r fe a tu r e s o f t h e st r u c tu r e o r fa cilit y a r e
inspected .
1.
2.
3.
T h e g en e r a l co n d it io n o f co a t in g ;
ch eck fo r d efects o r d eterio r a tion
A n y ev id e n ce of r u stin g
E st im a t e t h e a m o u n t o f r u s t b y
u sing SSPC -VIS 2. (See ap p en d ix U
fo r p r oce d u r es.)
48
2. By ob se r v a tio n , d oc u m en t t h e fo llow in g
ru st cond ition s:
Maintenance Coatings
su rvey incorpor ates the observ ations recorded
in th e D et a iled Visu a l Su r v ey w ith q u a n tit a tiv e
m easu rem ents. This surv ey evalu ates w heth er
a n e x ist in g co atin g can b e s p o t rep aired or
ov er co a te d or if fu ll re m ov a l an d r eco a tin g is
requ ired . For a h igher level of confid en ce, the
su rvey shou ld be cond u cted by a certified
N A CE or SSPC coating sp ecialist.
1. O b se r v e a n d d oc u m en t t h e fo llow in g
coating cond ition s:
D e fe ct s: b lis te r in g , ch a l k in g ,
crack in g , ero s io n , d elam in atio n,
p in h o les , p eelin g , u n d ercu tting, or
oth er d efects
A p p e a r a n c e: co a t in g o r t o p co a t
lo s s, a b r a sio n s tr e a k s, r u s t st a in i n g ,
fading color, w eathering , or oth er
abn orm al app earan ce.
2. O b se r v e a n d d oc u m en t t h e fo llow in g
ru st cond ition s:
M e t a l lo s s: m in i m a l o r s ig n i fica n t
D et er m in e D FT (SSPC -P A 2)
D ete rm i n e th e p re se n ce an d
co n cen tr a tio n of s olu b le s a lts , if
p r ese n t
D ete rm i n e th e ty p e an d
concentration of toxic m etal-based
p a in t, if p r ese n t
D et er m in e t h e d ep th an d fre q u en cy
of corro sion p its
U se a To ok e g au g e to d e te rm i n e th e
n u m b e r o f co a t in g s
A p p ly te st p a tch es to d et er m in e if
the c oa ting is com p a tible for
ov er co a tin g (A STM D 5064)
49
50
W e a r w o r k clo t h in g d u r in g r e m o v a l
o p e r a t io n s a n d h a v e c lo t h in g i n d u s t r ia l
w a s h e d b y c on t r a ct o r or o w n e r .
W a s h h a nd s a nd fa c e be fore e a ting or
smoking.
F or co m p r e h e n s iv e r e q u i r e m e n t s fo r p e r s o n a l
s a fe t y , s e e t h e fo llo w in g C o d e o f F ed e r a l
Re g u lat ion s (C FR):
29 C FR 1910.1018, A r se n ic
29 C FR 1910.1027, C a d m iu m
Maintenance Coatings
of airbo rn e p articles bu t w ill not elim inate
t h e m . T a b le 2 p ro v id es O SH A res u lts for
t y p i ca l a n d m a x im u m le a d e x p o s u r e le v e ls b y
r e m o v a l m e th o d .
Maximum
exposure
17,300
59,000
Blast cleaning in
containment system
25,700
59,000
Welding, cutting, or
burning
600
28,000
45
167
735
20,600
Chemical stripping
11
476
500
2,100
Removal method
51
52
Fe rrous (s te el or iron)
C o n c r et e o r m a s on r y
O l d c o at in g s
W ood
C av ita tio n .
C h em ical co n ta ct
52. Scheduling. A c ce ss ib le st r u c tu r e s a r e
r e la t iv e ly e a s y to s ch e d u le fo r in s p e ct io n a n d
m a in te n an ce co atin g w o r k. H o w e ve r, m a n y
R e cla m a tion s tru c tu re s s uc h a s inte rior of
tu rb ines, p u m p u n its, p en stocks, d raft tu bes,
d ischarge lines, and other interior w ater
be a ring s ur fa c es a re diffic ult to a cc es s w ith ou t
a s ch e d u l e d o u t a g e a n d m a n y a r e a s ca n n o t b e
d ew atered in excess of 5 years. Therefore,
p lanned or u np lanned ou tages shou ld be tak en
a d v a n t a g e o f fo r e it h e r in s p e c tio n o r co a t in g s
w ork.
In s ch e d u l in g a p la n n e d o u t a g e to p e r fo r m
m a in te n a n ce co a tin g w or k , th e r ev en u e lo ss in
e le ct r icit y o r w a t er d e liv e r y n e e d s t o b e
a cco u n te d for sin ce r ev en u e lo ss w ill like ly
b e co m e a sig n i fica n t fa ct o r .
Chapter XI
Galvanizing
Ga l v a n i z in g is th e ap p licatio n o f zin c o n to a
st ee l su r face . Zin c is a n od ic to st ee l (i.e., zin c
w ill sa cr i fice its elf to p ro tect steel fro m
c o r r o sio n ) . Reclam atio n s p ecifies n u m erou s
st eel m eta lw o r k ite m s t o b e g a lv a n iz ed .
M etalw ork item s m ay ran ge from sm all item s
s u c h , a s b o lt s a n d n u t s , t o la r g e it e m s , s u c h a s
gates. The follow ing are reason s to coat over
g a lv a n izin g : (1) to for m a b a r r ier coa tin g in
bu rial or im m ersion serv ice exp osu res b ecau se
the z inc w ill be rap idly con su m ed ; (2) to
rep air da m aged areas; and (3) to im p rove
Process
Specifications
Thickness
Typical application
Electrogalvanizing
Electrolysis
ASTM A 591
Up to 0.14 mil
Zinc
plating
Electrolysis
ASTM B 633
Mechanical
plating
Peening
ASTM B 695
Continuous
galvanizing
Hot-dip
ASTM A 653
Up to 4.0 mil
Hot-dip
galvanizing
Hot-dip
ASTM A 123
ASTM A 153
Thermal
Spraying
Hot zinc
spray
AWS C2.2
Zinc-rich
painting
Brush, roller,
airless, or
conventional
spray
Varies with
owner's or
manufacturers
specifications
53
a n d s eco n d p h a s e r e a ct io n s m a y co n t in u e fo r 1
to 2 y ea r s a fte r th e g a lv a n ize d m a n u fact u r in g
p r o ce s s is fin i sh e d , d e p e n d in g o n t h e lo ca l
en viro n m en t. Zinc carbon ate (third p h ase
r e a ct io n ) is a d e n s e , in s o lu b le m a t e r ia l t h a t
fo r m s th e p r o t e ct iv e la y e r . T h e fin a l
g a lv a n i z ed s u r fa ce is a d u ll m a t te g r a y .
Z in c ox id e is for m ed ab ou t 24 t o 48
h o u r s aft e r t h e g a lv a n i z in g p r o ce ss b y
the r eaction of zinc w ith oxyge n in the
a ir .
Z in c h y d r oxid e is fo rm e d b y th e
r e a c tio n o f th e zin c w ith m o is tu r e from
r a i n , d ew , o r h ig h co n d en s atio n .
Z in c ca rb on a te is fo rm e d b y th e
r ea ctio n of z in c ox id e a n d zin c
h y d ro x id e w ith carb o n d io x id e from
fr e e flo w in g a ir .
54
Galvanizing
follow ing are th e m ost com m on p osttreatm ent
m e t h o d s a n d t h e ir e ffe ct s o n p a in t in g :
Apply a coating of oil to form a barrier
from mo isture. Pain ts w ill not a d h ere to oils,
a n d a p p ly in g o il w ill r e su l t in a d h e s io n fa ilu r e
if the oil is not rem oved .
T o ch e c k fo r th e p res en ce o f o il, p erfo rm a
w a te r b ea d te st . Pla ce a d r op of w a te r on th e
su rface. If the w ater b ead s, it ind icates the
p r es en ce o f oil.
Quen ching (coo ling in a water bath).
W a t e r m a y co n tain g r eas e an d o ils th at floa t on
the w ater su rface and contam inate th e
g a lv a n ize d su r face , re su ltin g in coa tin g
a d h e si o n failu re if th e g reas e an d o il are not
rem oved .
Chrom ate q uenching . Typ ically, pa ints
w ill not ad her e to galvanized sur faces treated
b y th is m et h od . Ch r om a te q u en ch in g is b ein g
d isco n tin u e d b eca u se of h u m a n sa fe ty an d
en viro n m en tal concern s.
Pho sphate q uen ching . A d h e sio n of p a in t
is im p r o v e d b y th is m eth o d .
Ther e is no easy field test to d eterm ine th e
ty p e of q u en ch tr ea tm en t t h a t w a s u se d , if a n y .
The m ost reliable m etho d is to contact the
g a l v a n i z in g s h o p .
(c) Depo sited C ontam inan ts. Dep osited
co n t a m in a n t s a r e fo r e ig n s u b s t a n ce s th a t
accu m u late on th e ga lvan ized su rface. The
m ost com m on con tam inants are d irt, grease ,
o il, a n d s o lu b le s a lt s . C h l o r id e s a lt s a r e
aggr essively d estru ctive to galvan ized
m et a lw or k . For p r ot ect ion ag a in st ch lor id e
co n t a m i n a t io n , g a lv a n i z ed it e m s s h o u l d b e
p r o t e ct e d b y co n tain ers d u rin g tran s p o rt or
storage.
fo r m a t io n o f r ea ct iv e z in c o xid e a n d
zin c hy d ro xid e com p ou n d s. The
chem ical reaction m ay con tinu e for 1 to
2 years, d ep end ing on local w eather
co n d it io n s a n d m e t alw o r k g e om e t ry .
Weath ered galva nized m etalw ork.
T h e s u r fa ce h a s co m p le t ed ch e m ica l
co n v er sio n fro m zin c ox id e a n d zin c
h y d r o x id e co m p o u n d s to n o n r ea ct iv e
zinc carbon ate.
(a) Newly Ga lvanized Metalw ork. Z in c is st ill
r e a ct iv e o n n e w ly g a lv a n i z e d m e t a lw o r k , a n d
se v er a l con ta m in a n ts m a y ex ist , su ch as oil
co a tin g or p os tt r ea tm en t a p p lied at th e p oin t
o f g a lv a n i z in g . Ea ch s p e cific co n t a m in a n t m a y
re qu ire a s pe c ia liz e d s urfa ce pr e p a ra tion
m et h od . Th e fo llow in g ste p s a re su rfa ce
p r ep a r a tio n m et h od s fo r r em ov a l of s p ecific
conta m inan ts:
Rem ova l of white sto rage stain (w hite ru st),
if prese nt. A p p ly a 1- t o 2-p er cen t a m m on ia
solution by b ru sh or sp ray . For severe w hite
st or a g e s ta in , ap p ly 1 p a r t a cet ic or citr ic acid
to 25 p arts of w ater. Thorou gh ly rinse th e area
w h e r e th e s o lu t i on w a s ap p lie d w it h w a r m
p o t a b le w a t er a n d a llo w t h e a r ea t o a ir d r y .
Rem ova l of dirt, grease, an d oil.So lv en t
cleaning in accord an ce with SSPC-SP1. W aterb a s e d e m u ls ifie r s a n d a l k a lin e c le a n e r s h a v e
b ee n sh ow n to w or k b es t. En su r e t h a t a lk a lin e
clea n er s h a v e a p H of le ss th a n 12 b eca u se zin c
w ill d issolve in h ighly a lkalin e solu tions.
A p p l y cle a n in g s o lu t i on s b y d i p p in g ,
sp r a y in g , or b r u sh in g w ith so ft b r ist le b r u sh es.
D ip p i n g a n d sp r a yin g w o r ks b est w h e n th e
cleaning solu tion is at abou t 140 to 185 d egrees
F. Thor ou gh ly rinse the a rea w he re th e
solven t w as ap p lied w ith h ot p otable w ater
a n d a llo w t h e a r ea t o a ir d r y .
s u r fa ce p r e p a r a t io n o f g a lv a n i z ed m e t alw o r k
b efo re p ain tin g d e p en d s on w h e t h er th e
m etalw ork is new ly galvan ized or w eathered :
55
56
Galvanizing
Th e b las t n oz z le s h ou ld b e h eld at a r ela tiv ely
low ang le to rem ove th e reactive zinc oxid es
a n d zin c h y d r ox id es . H old in g th e b las t n oz z le
p er p en d icu lar to th e s u r face can q u ick ly
rem ove sou nd zinc m etal. Op tim al am bient
cond ition s for sw eep blasting are 70 d egr ees F
an d 50 p ercent or less relative hu m idity. After
sw ee p b las tin g , coa t t h e s u r face w ith in
24 h ou rs.
(b) W eath ered Galvanized Metalw ork. Fu lly
w e a t h e r e d g alv an izin g w ith an o u td o o r
ex p os u r e o f b et w ee n 1 an d 2 y ea r s s h ou ld
h a v e c o m p le t ely c on v e r t e d t h e z in c o xid e a n d
z in c h y d r ox id e co m p ou n d s t o fo r m a s ta b le
(n on r ea ctiv e) p r ot ect iv e la y er of z in c
car b on at e. Th e m os t co m m on su rfa ce
p r e p a r a t i on m e t h o d is w a t e r p o w e r w a s h in g a t
a p ressu re of abou t 1,450 psi to rem ove d irt,
g r e a se , a n d o il. H ig h e r p r e s s u r e s s h o u l d b e
a v o i d e d t o red u ce th e risk o f rem o v in g s ou nd
zinc. Sw eep blasting is ano ther m ethod u sed ,
often u sed after w ater p ow er w ash ing to
p r o m o t e a d h e sio n o f t h e p r im e r .
Aged or weathered galvanized
me talwork. O l d , a g e d g a l v a n i zin g t h a t h a s
b ee n in se r v ice fo r se v er a l y ea r s a n d is
sho w ing ev iden ce of d eterioration p resen ts
a d d it io n a l p r o b l em s a n d r e q u i r e s r e m e d ia l
su r f a ce p r ep aratio n m eth o d s d ifferen t fr om
those ap p rop riate for n ew ly galvan ized
m e t alw o r k .
De t e r io r a t ed areas m ay s h o w a red d is h -brow n
st a in . Th i s co lo r s tain m ay b e m is tak en for
co r ro sio n o f t h e s te el b a se m e t al. Ju s t a b ov e
t h e in t e r fa ce b e tw e e n t h e s te e l b a s e m e t a l a n d
th e z in c th a t w a s a p p lied d u r in g th e h ot d ip
g a lv a n izin g p r oc es s, a zin c-iro n allo y lay er is
fo r m e d . Th e z in c -ir o n a llo y la y e r m a y b e
co r r o d in g r a t h e r t h a n t h e s te e l b a s e m e t a l, a n d
be bleed ing thr ou gh the m ore p u re zinc above,
r e su l t in g i n th e red d is h -b ro w n s tain . Z inc -iron
a lloy is b r ow n ish , an d st ee l cor r os ion is
red d ish. It is difficu lt to visu ally d istin gu ish
t h e d i ffe r e n ce b e tw e e n th e t w o m e t als b y
co lo r .
A m a g n e t ic o r e le ct r o n ic D F T g a u g e c an b e
u sed to d eterm ine if the steel base m etal or the
58. Coatings. N u m e r o u s c oa t in g m a t e r ia ls
ca n b e a p p lied ov er g a lv a n izin g ; ho w ev er , it is
b es t t o e n su r e t h a t t h e m a te r ial s ele cte d is
com p atible w ith zinc. The selection d ep end s
n ot on ly on com p a tib ility b u t a lso , in cer ta in
cas es , on ch em ical tr ea tm en ts, su rfa ce
p r ep a r a tio n , an d se r v ice e xp os u r e. C on su lt
th e co a tin g m a n u fact u r er or th e s p ecific
p rod u ct da ta shee ts for com p atibility w ith
sp ecific ch em ical tr ea tm en ts a n d su rfa ce
p r ep a r a tion m eth od s .
(a) Coating Se lection . T h e fo llo w in g c o at in g s
a r e su i t ab le to o v e r co a t g a lv a n i z in g u n d e r
57
Bu r i a l o r im m e r sio n s e rv ice e xp o s u r e
A t m o s p h e r ic s er v ice e xp o s u r e
" Ep oxy
" A cr y lic or w a te r -b or n e a cr y lic
" M o istu r e cu r ed u r eth a n e
" Acrylic latex
" Z i n c-r ich e p o x y fo r d a m a g e d a r e a s
" W aterborn e latex
" Z in c-r ich m o istu r e cu r ed u r eth a n e
" Z in c-r ich ae r os ol s p r a y for r ep a ir in g
d am aged areas of bare galvan ized
su rfaces
" E p o x y p r i m e r w it h U V - r es is t an t
a lip h a t ic u r e t h a n e t o p c o a t
58
fo r d a m a g e d a r e a s
Do n ot u se oil-ba sed or a lkyd coating s u n less
the y a re s p e cific a lly formu la te d for
g a lv a n iz in g . Z in c is an alk a lin e m eta l.
M oisture w ill eventu ally p erm eate th rou gh the
coating film . The zinc and bind ers in oil-based
or a lkyd c oa tings re a c t in th e pr e s e nc e of
a lk a lin ity an d m ois tu r e t o fo r m a m et a llic
so a p . Th is p r oce ss is calle d sa p on ifica tion .
C a s e h i st o r ie s s h o w t h a t oil-b a s ed a n d a lk y d
co a t in g s t h a t a r e ad h e r in g w e ll w ill r e q u i re
a b o u t 6 m o n t h s t o 1 y e a r a ft e r a p p lica t io n i n a n
ou td oo r en v ir on m en t t o b eg in to fail.
Chapter XII
Coating Failures
Coatings fail for m an y reason s. These failu res
c a n b e r e la t ed to m aterial s electio n ,
form u lation, ad hesion, substrate typ e,
a p p lic a tio n , stru ctu re d es ig n , o r ex terio r
for ces . Th es e r ela te d failu re ty p es m ay act
ind ep en d en tly of each oth er or in concert w ith
each oth er. The read er is strong ly u rged to
p u r ch a se on e o f th e p h ot og r a p h ic coa tin g
fa ilu r e b o o k s lis ted in ap p en d ix B.
Se lectio n o f a p ain t fo r th e w ro n g
s e r v ice e xp o s u r e . Fo r e xa m p le , if a n
a t m o s p h eric co atin g is sp ecified for
im m e r sio n s e rv ice e xp o s u r e , fa ilu r e
w ill occu r in a r ela tiv ely sh or t t im e
p er io d .
Se lectio n o f a p ain t b as ed s o lely on
co st s. N o t a ll p a in ts ar e eq u a l. A
m a n u factu rer m ay p ro d u ce s o m e
excellent p rod u cts but o ther p aints
fr o m th e s am e m an u factu rer m ay not
p e r f or m w e ll. A s a r u l e-o f-t h u m b ,
w h at y o u p ay fo r is n o rm ally w h a t you
get, and this, in gen eral, ap p lies to
p aint m ater ials.
Se le ct io n o f a p a in t b a s e d s o le ly o n a n
u n s u b sta n tia te d o p in io n . A p e rso n
w it h lim it e d k n o w le d g e o f in d u s t r ia l
co a tin g s ca n se lect th e w r on g or p oo r ly
p er for m in g m a te r ials , re su ltin g in
p r em a tu r e fa ilu r e.
59
Cause
Remedy
CHECKING - Surface
phenomena with uneven, small,
noncontinuous fissures in
coating that do not penetrate to
the substrate.
DISCOLORATION - Yellowing,
graying, or darkening of
coating.
MICROORGANISMS - Blotchy
brown or black spots on coating
surface causing poor, dirty
appearance with softening or
slimy feel.
60
Coating Failures
Table 5.Formulation-related failures for inorganic zinc coatings
(modified from SSPC, Good Painting Practice, volume 1, third edition, 1997)
Failure description
Cause
Remedy
61
Cause
Remedy
UNDERCUTTING - Corrosion
byproducts from the substrate
build up under the coating and
will break the coating at edges
or pinholes. The corrosion
progresses under the coating.
62
r an g in g fr om f ailu r e to u n d e rsta n d th e
co n se q u en ces of im p r op er ly p r ep a r in g
su rfaces to im p rop erly ap p lying coating s to
ru s hing the job. Ta ble 8 p rovid e s a de s c rip t ion
of ap p lication failu res, the cau se of the failur es,
an d the rem ed y for the failures
Coating Failures
Table 7.Substrate-related failures
(modified from SSPC, Good Painting Practice, volume 1, third edition, 1997)
Failure description
Cause
Remedy
GALVANIZED or METALLIC
ZINC - White zinc corrosion byproduct developing under or
breaking through the coating.
63
Cause
Remedy
IMPROPER ENVIRONMENTAL
CONDITIONS - Blistering and/or
poor adhesion caused by damp,
humid conditions. Powdery
coating where drying occurred too
rapidly (overspray). Soft, uncured
coating.
64
Coating Failures
Table 8.Application-related failures
(modified from SSPC, Good Painting Practice, volume 1, third edition, 1997)
Failure description
Cause
Remedy
65
Cause
Remedy
Cause
Impossible to apply coating in
crevice between angles and
plates.
Remedy
Design: Use T bar or pipe in
construction.
Precoat: Coat angles and plates
before construction assembly.
Stopgap measure: Fill crevice with
resinous chalking and topcoat with
compatible material.
SMALL DISCONTINUOUS
AREAS - Corrosion is developing
on edges of bolt heads, bolt
threads, nuts, washers, rivets,
and other small edged or
cornered surfaces.
66
Coating Failures
Table 9.Design-related failures
(modified from SSPC, Good Painting Practice, volume 1, third edition, 1997)
Failure description
Cause
Remedy
w a t e r th a t co n t a in s a b r a s iv e m a t e r ia l s u c h a s
s a n d p a r t icle s . In t h i s s e ct io n , or d in a r y
a tm osp h er ic e xp osu r es a r e n ot con sid er ed .
Table 10 prov ides a d escription of failu res
related to exterior forces, the cau se of the
failures, and the rem ed y for the failures
Cause
Remedy
CHEMICAL - Dissolution of
coating; undercutting or underfilm
corrosion.
67
Cause
Remedy
68
Bibliography
69
70
Appendix A
Organizational Sources for Standards and References
A m erican Society of Testing an d M ater ials (A STM)
1916 Race Street
P h ilad elp h ia P A 19103
Te lep h on e: (610) 832-9500
Fa x: (610) 832-9555
W e b s it e A d d r e ss : w w w .a s tm .o r g
N A CE In ter n ation al (N A CE)
P O Box 218340
H ou st on TX 77218
Te lep h on e: (218) 228-6223
Fa x: (281) 228-6329
W e b s it e A d d r e ss : w w w .n a c e.o r g
Socie ty fo r P r o te ctiv e C o a tin g s (SSP C )
40 24 th Str eet, 6 th F lo o r
P itt sb u r g h P A 15222
Te lep h on e: (412) 281-2331 ext 16
Fa x: (412) 281-992
W e b s it e A d d r e ss : w w w .s sp c .o r g
Bu r e a u o f R eclam atio n
G u id e Sp e cifica tio n s
W eb site A d d re ss: h tt p :/ / in tr a.u sb r.g ov / g u id es p ecs
A-1
Appendix B
Reading Sources
Goo d Painting Pra ctice, Steel Stru ctur es Painting M an u al, Volum e 1, Third Ed ition , 1993. (The four th
ed itio n is d u e in 2003.)
Sys te m s a n d Sp ecifica tio n s, Ste el Str u ctu r es P a in tin g M a n u a l, Vo lu m e 2, Eig h th Ed itio n , 2000.
Coating an d Lining Insp ection M an u al, Bechtel Corp oration, 1983, exclusively d istributed by Steel
Str u ctu r es P a in tin g C ou n cil (SSPC ), A u g u st 1991, SSPC P u b licat ion N o. 91-12.
Th e In sp ectio n of C o a tin g s a n d Lin in g s, A H a n d b ook of Bas ic P r a ctice fo r In sp ector s, O w n er s, a n d
Sp ecifie r s, SSPC P u b licat ion N o. 91-12, Fir st Ed itio n , 1997.
Corr osion P reven tion b y Protective Co atings, by C ha rles G. Mu ng er, Pu blished by N AC E
In te r n a tio n a l, Firs t Ed itio n , 1984.
P a in tin g : N ew C on st r u ctio n an d M a in te n a n ce, U .S. Ar m y C or p s o f En g in ee r s, M a n u a l N o. E M 1110-23400, A p r il 30, 1995.
FH W A Field M an u al for Bridg e Paint Inspection, U.S. Dep artm ent of Transp ortation, Feder al
H ig h w a y A d m in ist r a tio n (FH W A ), FH W A Brid g e C oa tin g s Te ch n olo g y Te a m , O cto b er 1997.
Steel Penstock Co ating a nd Linin g Reh abilitation, A H yd rop ow er Techn ology Rou nd u p Rep ort,
Vo lu m e 3, Te ch n ical R ep or t TR -113584-V3, A u g u st 2000.
Av a i la b le fro m E lectric P o w er R es earch Ins titute (EPR I), 3412 H illvie w A v e nu e , Pa lo A lto C A
94304; t ele p h o n e: (650) 855-2000; C u stom er Se r v ice: (800) 313-3774; W eb sit e A d d r ess:
w w w .e p ri.co m
Vis u a l C om p a r iso n M a n u a l, A p p licat ion an d C oa tin g s D efe cts , Bren d a n Fitz im on s, Ro b in so n Irw in
Te ch n ical Su p p or t Lt d ., En g lan d 1997-1998, (SSP C P u b licat ion N o. 00-8)
B-1
Appendix C
Inspection Checklist
G D eliv er ed m a te r ials
G A p p r o v e d m a t er ia ls , r e co r d b a t ch n u m b e r s
G Sto r ed p r op er ly
G Con tainers secu red
G Shelf life not exceeded
G A b r a s i v e m a t e r ia l
G C om p lies w ith SSPC -A B1, Cla ss A , Ty p e I o r II
G Con tam inan ts
G C h eck for p r es en ce o f oil, A STM D 4940
G C h eck for ch lor id e io n , if su sp ect ed w ith C h lor *Rid A te st k it
G Re ta in sa m p le
G A ir co m p r e sso r e qu ip m e n t
G Com p ressed air lines
G C h eck for oil a n d w a te r con ta m in a n ts , A STM D 4285
G Bla s t n o z z le p r e s su r e
G C h e c k p r e s s u r e a t b la s t n o z z le w it h h y p o d e r m ic n e e d l e g a u g e
G Su r f a ce p r ep aratio n
G D o n o t p r o ce e d w it h s u r f a ce p r e p a r a t io n i f t h e s u b s t r a te s u r fa ce t em p e r a t u r e is le s s t h a n
5 d eg r ee s F a b ov e t h e d ew p oin t
G D e t er m in e t h e r u s t g r a d e b y o n e o f t h e fo llo w in g p r io r t o cle a n in g :
G SSPC -VIS 1, for ab r a siv e b las t cle a n in g
G SSPC -VIS 3, for h a n d an d p ow er to ol cle a n in g
G SSPC -VIS 4(I), for w a te r jet tin g
G Ch eck for chlorid e ion con tam inant in w ash w ater or w ater u sed in w ater jetting , if su sp ected
G U se C h lor *Rid W te st k it
G P r ep a r a tio n co m p lie s w ith sp ecifica tion m eth od (i.e., N A C E N o. 2/ SSP C -SP 10, N A C E
N o . 3/ SSP C -SP 6, etc.)
C-1
G Su r face p r ofile
G D et er m in e s u r face p r ofile b y N A C E RP 0287
G E n v i r on m en tal co n d itio n s
G A m b ie n t (a ir ) t em p e r a t u r e
G Su b s t r a te su r f a ce te m p e r a t u r e
G Relative h u m idity
G D ew p o in t
G W in d v elo city , if ap p licab le
G C o a t i n g ap p licatio n
G C o atin g m aterial co mp lies w ith s p e cific a tions
G M ixed in acco rd an ce w ith m an u fa c tu re rs ins tru c tions
G Typ e of ap p lication m ethod u sed
G Ensu re strip e coats are ap p lied before overall ap p lication p roceeds
G T e m p eratu re an d h u m id ity res tric tions
G A ir and su bstrate tem p eratu res are 50 d egrees F or g reater or com p lies w ith the
m a n u f actu r er s in str u ctio n s
G Su r face s a r e a m in im u m of 5 d eg r ee s F a b ov e d ew p oin t
G R elativ e h u m id ity w ith in m anu fa c tu re rs ins tru c tions
G Su rfa ces fre e o f m ois tu re , fro st, a n d ice
G C u r in g
G C o a t ed it e m s a r e n o t m o v e d o r a llo w e d f o ot tr a ffic b e fo r e d r y
G C o m p lies w ith m an u factu rers ins tru c tions for te m p e ra ture a n d hu m id ity d u ring c uring p er iod
G Po st a pp licatio n in s p ectio n
G D r y film t h ick n e s s b y SSP C -P A 2
G H olid a y te st in g b y N A C E RP 0188
C-2
Appendix D
Reference Standards Cited in Guide
American Society for Testing and Materials (ASTM)
ASTM A 123
ASTM A 153
ASTM A 591
ASTM A 653
Steel Sheet Zinc-Coated (Galvanized or Zinc-Iron Alloy-Coated (Galvanized) by the HotDip Method
ASTM B 633
ASTM B 695
ASTM D 3359
ASTM D 4138
ASTM D 4285
ASTM D 4414
ASTM D 4417
ASTM D 4541
ASTM D 4940
ASTM D 5064
ASTM D 5162
ASTM E 337
ASTM E 832
Recommended Practices for Metallizing with Aluminum and Zinc for Protection of Iron
and Steel
D-1
NACE RP 0287
Field Measurement of Surface Profile of Abrasive Blast Cleaned Steel Surfaces Using
a Replica Tape
SSPC-AB1
SSPC-PA2
SSPC-SP1
Solvent Cleaning
SSPC-SP2
SSPC-SP3
SSPC-SP8
Pickling
SSPC-SP15
SSPC-SP11
NACE No. 1/
SSPC-SP5
NACE No. 2/
SSPC-SP10
NACE No. 3/
SSPC- SP6
NACE No. 4/
SSPC-SP7
NACE No.5/
SSPC-SP-12
Surface Preparation and Cleaning by High- and Ultrahigh-Pressure Water Jetting Prior
to Coating
NACE No. 8/
SSPC-SP-14
SSPC-VIS 1
SSPC-VIS 2
SSPC-VIS 3
NACE No. 7/
SSPC-VIS 4
Guide and Visual Reference Photographs for Steel Cleaned by Water Jetting
NACE-VIS 9/
SSPC-VIS 5
Guide and Reference Photographs for Steel Surfaces Prepared by Wet Abrasive Blast
Cleaning
D-2
Appendix E
Inspection Equipment
In s p e ctio n G au g e s , Ins tru m e n ts, an d Ki ts:
Blast n oz z le a n a ly z er g a u g e (o p tio n a l)
C a lib r a te d sh im s
D r y film t h ick n e s s g a u g e
P u ll-off
Fix ed o r co n s t an t p r e s su r e p r o b e
L ow v o lt a g e
H ig h v o l ta g e
M icr o m e t er a n d r e p l ica t a p e
N oz z le o r ifice g a u g e (o p tio n a l)
P it g a u g e (o p tio n a l)
P r es su r e n ee d le g a u g e (o p tio n a l)
Th er m om et er w ith m a g n et ic b a ck in g
W e t film t h ick n e s s g a u g e
In s p e c ti o n T o o l s :
Fla s h lig h t
1 t o 1-1/ 2 in c h w id e st iff p u t ty k n i fe w it h s h a r p e n e d e d g e
Kn ife
Latex gloves
Plastic booties
M agn et
E-1
Appendix F
Example of Inspection Daily Check Sheet
1 of 2
Date:
Feature:
Report By:
Contract No:
Paint Contractor:
SPECIFICATIONS
Material Manufacturer
Product Name
DFT Range
Primer:
Intermediate:
Topcoat:
Reading Time:
WEATHER
SURFACE PREPARATION
Abrasives:
Manufacturer: ______________
Cleanliness:
______ CFM
2 of 2
Product Name
Batch Number
Gal
Color
Thinner
Product
Gal/Oz %
Environmental Control: Heaters ___ yes / ___ no; Dehumidification ___ yes / ___ no, Unit Size _________
Material Mixing: Power Mixing Time _____ minutes; Induction Time ___ yes / ___ no, _____ minutes
Stripe Coats Applied: ___ yes / ___ no;
Application Method: ___ Brush; ___ Roller; ___ Airless; ___ Conventional; ___ Plural; ___ Electrostatic
Applied Within Recoat Window: Primer __ yes /__ no; Intermediate __ yes /__ no; Topcoat __ yes /__ no
Wet Film Thickness (WFT): Primer ______ mils; Intermediate ______ mils; Topcoat ______ mils
Comments:
TESTING OF HARDENED COATING
Dry Film Thickness (DFT) by SSPC-SP PA2:
Area Inspected: ___ less than 300 ft2; ___ less than 1,000 ft2; ___ equal to or greater than 1,000 ft2
Number of 5 Spot Measurement Groups Taken Within Above Inspected Area: _____ at _____ 100 ft2 areas
Average of 5 Spot Measurement Groups _______ mils; Conform to Specifications ___yes /___no
Discontinuity (Holiday) Testing by NACE RP 0188
Tester Used:
F-2
Appendix G
Procedure for Detecting Moisture and Oil in Compressed Air
(ASTM D 4285)
A . Pu rp o s e
Th is t es t d et ect s t h e p r es en ce o f m ois tu r e a n d oil co n ta m in a n ts in com p r es se d air for ab r a siv e
blasting , air blast cleaning, and coating ap p lication o p erations. The contam inants are d etected
v is u a lly .
B . Eq u i p m e n t
W h ite ab so r b en t m a te r ial, filte r p a p er , blo tt er p ap er , or clot h w ith a r ig id b a ck in g .
C . Pro ce d u re
1. A llow th e air com p ressor to rea ch op era ting cond ition s.
2. Sh u t o ff th e ab ras iv e flo w .
3. P la ce t h e a b so r b e n t m a t e r ia l w it h in 2 4 in c h e s o f t h e d is ch a r g e - p o in t -ce n t e r e d a i r st r e a m a n d
d ow n strea m from th e in-lin e oil and m oistu re sep ara tors.
4. Allow air to flow for 1 m inu te.
5. Vis u a lly ch eck ab so r b en t m a te r ial fo r th e p r es en ce o f m ois tu r e o r oil.
A ny observ ed contam inan ts on th e cloth or in th e air flow w ill requ ire corre ctive action. Tests
sh o u ld b e p er fo r m ed at t h e b eg in n in g of th e sh ift or after th e air co m p r ess or h a s b een sh u t o ff.
Te st in g is r eco m m en d ev er y 4 h ou r s d u r in g b las tin g op er a tio n s o r m or e fr eq u en tly if h u m id ity is
h ig h .
G-1
Appendix H
Procedure for Detecting Chlorides and Soluble Salts in
Abrasives by Conductivity Method
A . P u rp o s e
T o d e t ect an d d eterm in e th e lev el o f s olu ble s a lts in a br a s ive s to pre v e nt s ub s tra te d e te riora tion
an d sub sequ ent coating failu re.
B.
C o n d u cti v i ty M e t h o d
1. Eq u ip m e n t
a . Electron ic cond u ctivity m eter
2. P r o ce d u r e
a . Ca libr ate th e cond u ctivity m eter a ccord ing to th e m an u factur ers instru ction s.
b . P la ce e q u a l v o lu m e s of a b r a s iv e m a t e r ia l a n d d is t ille d o r d e -io n i z ed w a t e r in a g l a ss a n d
st ir for 1 m in u te . Let st a n d for 8 m in u te s a n d st ir ag a in for 1 m in u te . A llow th e a b r a siv e
m aterial to settle.
c. In se r t t h e co n d u ctiv ity m et er p r ob e in th e w a te r w ith ou t co n ta ctin g ab r a siv e m a te r ial.
d . A llo w th e co n d u ctiv ity m eter to sta b iliz e in accor d a n ce w ith th e m a n u fa ctu r er s
instru ction s.
e. Re a d an d r eco r d th e d ir ect r ea d in g in m icr osie m en s.
C . C h l o ri d e -S p e c if i c Io n M e th o d
1. Pu rp ose
To d eterm ine th e concentr ation of chlorides in a bra sive m aterials and p rev en t su bstrate
contam ination a nd sub sequ ent coating failu re.
2. Eq u ip m e n t
C H LO R*TEST A , Ch lor id e Io n Te st Fo r A b r a siv es tit r a tio n k it
H-1
3. P r o ce d u r e
a . O v e r fill t h e s m a l l co n t a in e r w it h a b r a s iv e b la s t m a t e r ia l a n d le v e l-o ff w it h t h e m e t a l
snap p er inclu d ed w ith th e kit or w ith a straigh t ed ge.
b . Re m ov e t h e lid fro m th e C H LO R*EXTRA C T so lu tio n con ta in er an d p ou r th e le v ele d -off
b last ab ras iv e m aterial in to the s olution.
c. R ep lace th e lid o f th e CH L O R*EXTRA C T solu tion c onta ine r a nd vigorous ly s ha ke for 2
m in u t e s. A l lo w t h e a b r a s iv e m a t e r ia l t o se t tle fo r a b o u t 5 m i n u t e s b e fo r e p r o c e ed in g . C le a r
solu tion sh ou ld be v isible abou t a inch from the top sur face.
d . H o ld th e titratio n tu b e alo n g t h e m id d le . D o n ot ha n d le or touc h the n a rrow e nd s be for e or
after snap p ing th em off. H an d ling of the titration tu be n arr ow end s can conta m inate th e
solution w ith bod ily p ersp iration , i.e., salts, an d affect the resu lts. Sna p off both end s of the
titr a tio n tu b e an d h o ld th e tu b e in th e so lu tion w ith th e b lu e ar r ow h ea d p oin tin g u p . D o
not insert the titration tu be into the ab rasive m aterial because th is m ay p lug th e tub e.
e. A llow th e t itr a tio n tu b e t o r em a in in th e e xt r a cte d so lu tio n u n til t h e s olu tio n h a s w ick ed -u p
to th e t op of t h e co tt on w ick et . Satu r a tio n of t h e w ick et is co m p let e w h en th e co tt on tip
ch a n g e s t o a n a m b e r co lo r .
f.
H-2
Im m ed iately after th e cotton tip ha s chan ged to an am ber color, rem ove the titration tu be
fro m th e tes t s leev e an d read the c hloride le ve l a t the inte rfa ce of the p ink-w hite color
ch a n g e. W h ite in d icat es th e p r es en ce o f ch lor id e. If n o co lor ch a n g e o ccu r s (r em a in s a ll
p ink ), th e chlor id e leve l is be low th e th resh old d etection lim it of the titration kit. The
chlorid e concentration level is read d irectly from the titration tu be in m icrogra m s per
s q u a r e ce n t im e t er o r p p m .
Appendix I
Procedures for Detecting Chloride Ion in Water
A . P u rp o s e
T o d e t erm in e th e co n cen tratio n o f chlorid e ions in w a te r us e d w ith w a te r je tting b la s t cle a ning or
for w ater evalu ation to p reven t sub strate contam ination a nd sub sequ ent coating failu re.
B.
Eq u i p m e n t
C H LO R*TEST W , Ch lor id e Io n Te st Fo r W a te r / Liq u id s t itr a tio n k it
C. Pro ce d u re
1. Rem ove d rop p er assem bly cap from bottle.
2. U se the d rop p er assem bly in th e bottle to tr an sfer th e w at er to b e t es te d . A d d ab ou t a in ch
of wa ter to the bottle.
3. H o ld th e titratio n tu b e alo n g th e m id d le . D o n ot ha n d le or touc h the n a rrow e nd s be fore or
after snap p ing th em off. H an d ling of the titration tu be n arr ow end s can conta m inate th e
solution w ith bod ily p ersp iration (i.e.), salts, an d affect the resu lts. Sna p off both end s of the
t it r a tio n t u b e a n d h o ld t h e tu b e i n t h e so lu t i on w it h t h e b lu e a r r o w h e a d p o i n t in g u p .
4. A llow the titration tu be to rem ain in th e extracted solution u ntil the solution ha s w icked -up to
t h e t o p o f co t to n w ick e t . Sa t u r a t io n o f th e w ick e t is co m p le t e w h e n t h e c o t to n t ip ch a n g e s to a n
a m b e r co lo r .
5. Im m ed iately after th e co tto n tip ha s c ha ng e d to a n a m be r c olor, re m ove the titra tion tu be from
th e te st sle ev e an d r ea d th e ch lo r id e lev el a t t h e in te r fa ce of th e p in k -w h ite co lo r ch a n g e.
W hite ind icates the p resen ce of chloride. If no color cha ng e occu rs (rem ains all p ink), the
ch lor id e le v el is b elo w th e t h r es h old d et ect ion lim it o f th e t itr a tio n k it. Th e ch lor id e
concentration level is read d irectly from the titration tu be in m icrogra m s per squ are centimeter
or p pm .
I-1
Appendix J
Procedures for Determining Blast Cleaning Air Pressure
A . P u rp o s e
T o m e a su r e t h e b la s t h o s e air p r e s su r e f or a ss es sin g a b r a s iv e b la s t cle a n in g e fficie n cy .
B.
Eq u i p m e n t
H yp od erm ic need le p ressur e gau ge, 0 to 120 p ou nd s per squ are inch (psi) or m ore.
C. Pro ce d u re
1. Blast clean ing e qu ipm en t is to be op era tiona l at the tim e of testing. If m ore th an on e blast h ose
is to be u sed , ope rate all blast h oses.
2. In se r t h y p od er m ic n ee d le p r es su r e g a u g e in to th e in te r ior of t h e b las t h os e im m ed iat ely in
front of the b last nozzle an d slan t the n eed le at a 45 deg ree an gle so that it is p ointed in the
d irection th e abrasives are flow ing to m inim ize need le clogging and d am age.
3. Re a d th e b las t cle a n in g air p r es su r e d ir ect ly fro m th e d ial g a u g e. N or m a l b las t p r es su r e is
b et w ee n 90 an d 100 p si.
4. Pr essu re r ead ings sh ou ld be ta ken p eriod ically or w h en blast clean ing e fficiency d ecreases.
N O TE:
1. U se th is t es t m et h od on ly for ab r a siv e b las t h os es . D o n ot u se th is m et h od on coa tin g
ap p lication h oses.
2. T h e r e is n o cu r r e n t s ta n d a r d r e fe r e n ce t o d e t e r m i n e b la s t p r e s su r e ; A S TM D 4 264 w a s
w ith d r a w n .
J-1
Appendix K
Determination of Environmental Factors
E n v i r o n m en tal facto rs are d eterm in ed b y va r iou s ins tru m e nts , a nd s om e ins tru m e nts ca n p e rform
m u ltiple fu nctions. Electron ic and d igital instrum ents are becom ing increasing ly m ore accu rate,
fas te r , m or e a ffor d a b le, a n d acc ep ta b le. Th e in st r u m en ts ar e n ot d et a iled b elo w b eca u se of w id e
va riation am on g instru m en t typ es an d becau se of the va riation in the w ay instru m en ts are u sed . Bu t,
a s w it h a n y in s tru m en t, alw ay s fo llo w the m a nu fa c tu re rs ins tru c tions . The follow ing s e c tions
d e scr ib e th e in s t r u m e n t a n d t h e p r o ce d u r e s t o b e u s e d t o d e t er m in e e a ch e n v i r o n m e n t a l fa ct o r :
A . A m b i e n t Te m p e ratu re b y T h e rm o m e te r
1. D e s cr ip t i on o f t h e P r oce d u r e
a . D e t er m in i n g t h e am b ie n t te m p e r a t u r e b y a s in g l e d ir e ct r ea d in g w it h a t h e rm o m e t er .
2. Eq u ip m e n t
a . A t h e r m o m e t er o r th e d r y b u l b th e r m o m e t er o f a p s y ch r o m e t er .
3. P r o ce d u r e
a . A m b ien t t em p er a tu r e s h ou ld b e t a k en n ea r th e s u r face to b e co a te d . Loca te all
th er m om et er s a n d in st r u m en ts w h er e t h ey ar e n ot su b ject to d ir ect su n lig h t, w in d ,
constru ction lighting, heating or ven tilation d u cts, and w her e they ar e not su bject to other
cond ition s th at w ou ld affect tru e tem p era tu re r ead ings.
b . L et te m p e r a t u r e e q u i p m e n t st a b iliz e fo r 1 t o 2 m in u t e s if it w a s b r o u g h t fr o m a p l a ce w h e r e
th e t em p er a tu r e w a s d iffer en t fr om th e a r ea w h er e t h e e q u ip m en t w ill be u se d (e.g ., an air
co n d itio n ed or h ea te d r oo m or n ex t t o s om eo n e's b od y ).
c. A ll instru m en ts are d irect read . For electron ic instru m en ts, follow instru ction s an d en su re
th at th e co rrect m o d e is b ein g u s e d a n d the re a d ing is on the d e s ire d s ca le, d e gre e s F or
Celsiu s.
B.
K-1
3. P r o ce d u r e
a . P lace th e d ial th erm o m eter o n the s te e l s ubs tra te a nd a llow the te m p e ra ture to s ta biliz e for
ab ou t 2 to 3 m inu tes.
C. Re lati v e H u m id ity an d D e w Po in t (A S TM E 337)
1. De s crip tio n
a . D eter m inin g r elative h u m id ity an d d ew p oin t to a scerta in if eva p or ation w ill occu r. The
su bstrate su rface is to be at least 5 d egrees F abo ve th e d ew p oint.
2. Eq u ip m e n t
a . Psy chr om eter, either slin g or batt ery , and p sych rom etric table an d char ts.
b . Ele ctr on ic or d ig ita l m et er (p r ov id es d ir ect r ea d in g s).
3. Proced u re for Psychrom eter
a . Th e w ick o f a w et b u lb p sy ch ro m et er (cott on so ck ) sh ou ld b e r ela tiv ely clea n . Dir ty w icks
need to be cleaned or rep laced .
b . Sa t u r a t e t h e w i ck o n t h e w e t b u l b , b u t k e e p t h e d r y b u lb t h e r m o m e t er d r y .
c. W hirl (sling typ e) or op erate fan (battery typ e) un til the th erm om eters stabilize, abou t 20 to
30 second s, and note th e tem p eratu re.
d . R ep e a t s te p s 2 a n d 3 w it h o u t r e -w e t tin g t h e w ick u n t il t w o o r m o r e w e t b u l b r ea d in g s a r e
equ al to the low est temp eratu re obtained .
e. Record th e d ry (air) an d w et bu lb tem p era tu res.
f.
Th e relativ e h u m id ity is d eter m ine d from the inte rse ct of the d ry a n d w e t bulb re a d ings on
p sychro m etric tables or char ts. Psychr om etric tables and charts n orm ally ar e inclu d ed w ith
the in stru m en t.
4. D ew P oin t
a . U sing th e p sych rom etric tables:
(1) D eterm in e th e atm o s p h eric (ba rom e tric ) p re s s ure for your ge ogr a p hica l loc a tion from
U .S. De p a r tm en t o f C om m er ce o r U .S. W ea th er Bu r ea u ta b les . Th e a v er a g e b a r om et r ic
p r es su r e a t s ea lev el is ab ou t 30 in ch es of m er cu r y , an d it w ill av er a g e le ss th a n 30
inche s at h ighe r eleva tions.
K-2
(2) D et er m in e t h e d iffer en ce b et w ee n th e d r y an d w et b u lb te m p er a tu r es . Th e w et b u lb
tem p eratu re is alw ays less than the d ry b u lb. The d ifference is com m on ly called the
d ep r ess io n of th e w et b u lb .
(3) Fr om th e t a b les , loca te y ou r g eo g r a p h ic at m os p h er ic p r es su r e (lo ca te d in ta b le h ea d er ),
d r y b u lb t e m p e r a t u r e (r o w h e a d e r ), a n d d e p r e s s io n o f w e t b u lb (co lu m n h e a d e r ) a n d
d eterm ine the corresp ond ing d ew p oint value. Dew p oint is given in d egrees
Fah ren h eit or Ce lsiu s.
D . Wind
1. De s crip tio n
a . Deter m ining w he n th e w ind velocity can cau se in d ry sp ray , over sp ray , or d am age to
n e a r b y e q u ip m e n t , m e t alw o r k , o r p r o p e r ty .
2. Eq u ip m e n t
a . Ro ta tin g v a n e a n em om et er s, d ir ect d ial, o r ele ctr on ic (d ig ita l)
3. P r o ce d u r e
a . P la ce or h o ld th e in st r u m en t in th e d ir ectio n of th e w in d an d r ea d th e w in d (a ir ) v elo cit y .
D ig ital an em o m eters m ay req u ire holding d ow n a s w itch or bu tton for a fixe d p e riod of
tim e to d eterm ine th e av era ge a ir velocity. Follow th e m an u factur ers instru ction s.
K-3
Appendix L
Procedures for Detecting Chloride Salts on Prepared or Existing Surfaces
A . P u rp o s e
T o d e t ect ch lo rid e io n s an d th eir co n c e ntra tion le ve l on p re p a re d s urfa ce s or e xis ting s u rfa ce s for
p recoating evalu ation to p reven t sub strate contam ination a nd sub sequ ent coating failu re.
B.
Eq u i p m e n t
C H LO R*TEST t itr a tio n k it
C. Pro ce d u re
1.
T e st a sp o t w h e r e t h e s u r f a ce is r e la t iv e ly s m o o t h . D o n o t p ick ir r e g u l a r s u r fa ce s su ch a s
corrosion p its and w eld sp atter, and d o no t p ick areas betw een d ep ressed and raised su rfaces
becau se these su rfaces m ay allow the solu tion to leak ou t.
2.
Pou r the en tire contents from the solution bottle into th e test sleeve.
3.
P e a l o ff t h e b lu e b a ck in g f r o m t h e a d h e s iv e s t r ip o n t h e o p e n e n d o f t h e t es t s le e v e a n d
d is ca r d t h e b a ck in g . Re m o v e a ir fr o m t h e t es t s le e v e b y s q u e e z in g b e t w e e n fin g e r s a n d
thu m b. Do n ot sp ill any o f the solution. If solution is lost, d iscard the test sleeve an d the
rem aining solution a nd bega n w ith a n ew kit.
4.
5.
H orizon tal and ver tical - Lift the closed end of the test sleeve u p , allow ing th e solution to
flow tow ard s the test surface.
b.
L-1
A fter m assag ing th e solu tion for 2 m inu tes, rem ov e th e test sleeve a n d solu tion from th e test
su r face . To r em ov e t h e t es t s lee v e a n d r et a in th e s olu tio n fro m th e t es t s u r face , th e fo llow in g
p roced u res ar e recom m en d ed for th e va riou s test su rface p osition s:
a.
Vertical and over he ad - Low er th e test sleeve, allow ing th e solution to flow tow ard the
closed end of the test sleeve.
b.
H orizontal - W ith th e test sleeve laying flat, squ eeze the solution tow ard s the closed end
of t h e t es t s lee v e. Th en , p in ch off a n d lift u p th e t es t s lee v e n ea r th e t es t s u r face , allo w in g
the solution to flow tow ard s the closed end of the test sleeve.
7.
8.
9.
10. Im m ed iately after th e cotton tip ha s chan ged to an am ber color, rem ove the titration tu be
fr o m th e te st sle ev e an d r ea d th e ch lo r id e lev el a t t h e in te r fa ce of th e p in k -w h ite co lo r ch a n g e.
W hite ind icates the p resen ce of chloride. If no color cha ng e occu rs (rem ains all p ink), the
ch lor id e le v el is b elo w th e t h r es h old d et ect ion lim it o f th e t itr a tio n k it. Th e ch lor id e
co n c en t r a t io n le v e l is r ea d d ir e ct ly fr o m t h e tit r a tio n t u b e in m icr o g r a m s p e r sq u a r e
ce n t im e t er o r p p m .
11. Af ter co m p letin g th e test, clean the te s t su rfa ce (s ub s tra te) w ith a c e tone or a lcohol to re mov e
all ad hesive strip resid u e.
N OT E : T h e p r es en ce o f s o m e s alt io ns a n d c erta in p H ra ng e s ca n a d ve rs e ly a ffe ct the a bove
chlorid e test resu lts in th e follow ing w ay s:
L-2
The p resence of brom ide, iod ide, or cyan ide ions can yield a high er concentration level
than the actua l chloride ions extracted from the test surface.
p H v a l u e s o f le s s t h a n 3 .5 a n d h i g h e r t h a n 1 1 ca n y i e ld a h i g h e r co n c e n t r a tio n l ev e l t h a n
the actua l chloride ions extracted from the test surface.
Appendix M
Determining Surface Profile of Blast-Cleaned Steel Using Replica Tape
(NACE RP0287 or ASTM D 4417, Method C)
A . D e s cri p ti o n
To d eterm ine the an chor p attern d ep th of abrasive blasted sur faces by u se of a sp ring m icrom eter
an d rep lica im p ression tap e.
B.
Eq u i p m e n t
1.
2.
C. Pro ce d u re
1.
M easu rem en ts are to be ta ken on a sm ooth , flat or cu rv ed p late that is free of su rface dirt,
d u s t, an d ab ras iv e p articles th at w ill d is tort res ults . A n a c cu ra te profile ca nn ot be m a d e on
p itted or p artially coated are as.
2.
Select the corr ect rep lica tap e ran ge for th e sp ecified p rofile dep th
a.
0 to 2 m ils, u se coarse
b.
4.
5.
Before ap p lying the film to th e blasted sur face, the th ickn ess of the film m u st be sub tracted
from the final read ing. Su btra ction of the film thickness can be accom p lished by o ne of the
follow ing m eth od s:
M-1
a.
M eas u re th e rep lica tap e w ith the s p ring m ic rome te r a t the rou nd c utou t portion
o p p o s it e t h e 0.4 in c h s q u a r e w h it e p l a st ic film a n d s u b t r a ct th e r e p l ica film t h ick n e s s b y
on e th e follow ing m eth od s:
(1) Su b t r a ct th e t h ick n e s s fr o m t h e fin a l r e a d i n g .
(2) T u r n t h e d ia l in d ica t o r a r m o n t h e sp r i n g m icr o m e t er co u n t e r clo ck w is e fr o m z e r o
the m easu red rep lica film thickn ess (e.g., for a m easu red 2.2 mils film thickn ess, set
th e d ial in d icat or ar m at 7.8). Th is m et h od com p en sa te s fo r th e r ep lica film
t h ick n e s s a n d p r o v i d e s a d i r ect r ea d in g .
b.
6.
Ap p ly the film to the blasted su rface. The ad hesive backing w ill hold th e film in p lace.
7.
W ith a rou nd ed tool (a bar p lastic sw izzle stick has b een foun d to w ork w ell), ru b ov er th e
rou nd cutou t p ortion o f the rep lica tap e w ith m od erate p ressu re. The circu lar area of the
r ep lica ta p e w ill b eco m e d a r k er or g r a y ish , in d ica tin g th e b la st ed p r ofile h a s b een r ep lica te d .
Ensu re the en tire circular area h as u niform ly da rken ed .
8.
Rem ove the r ep lica tap e an d p lace it betw een the a nv ils of the sp ring m icrom eter (w ith
cir cu la r a r e a ce n t e r e d b e t w e e n t h e a n v i ls ). G e n t ly r e le a s e t h e t r ig g e r o f t h e m icr o m e t er a n d
t a k e r ea d in g . D e p e n d in g o n t h e g a u g e s e t tin g , eit h e r z e r o o r th e m e a s u r e d r e p l ica t a p e
t h ick n e s s, e n s u r e o r ig in a l r e p l ica t ap e t h i ck n e s s is su b t r a ct e d fr o m r e a d i n g .
9.
T h r e e r ea d in g s s h o u ld t a k e n in o n e lo ca t io n w it h in a b o u t 3 in c h e s o f e a ch o t h e r a n d
a v e r a g ed . L oca t io n r e a d i n g s (t h r e e a v e r a g ed r e a d i n g s) s h o u l d b e t a k en o n e v e r y 100 s q u a r e
feet of sur face, or p ortion thereof, to establish consistency of the p rofile.
M-2
Appendix N
Procedures for Measuring Wet Film Thickness (ASTM D 4414)
A . P u rp o s e
To d eterm ine th e w et coating th ickn ess bein g ap p lied an d to estim ate th e d ry film th ickn ess.
B.
Eq u i p m e n t
A n o t ch g au g e is a rectan g u lar o r s qu a re -s ha p e d p la te . Ea ch e d ge ha s tw o ou te r proje ctions of
eq u al h eig h t. Betw ee n th e o u te r p ro ject ion s is a se rie s o f gr ad u at ed n ot ch es m ar k ed in m ils. Each
e d g e o f t h e n o t ch g a u g e is ca lib r a t e d f o r a sp e cific m il t h ick n e s s r a n g e . T y p i ca l n o t ch g a u g e
m a te r ials ar e a lu m in u m , p las tic, p olis h ed st ee l, an d st a in les s s te el.
N O TE: Th e p lastic gau ge s ar e d isp osa ble an d ar e int en d ed for a lim ited n u m be r o f read ing s. The
alum inu m and p lastic gaug es w ill wear d ow n an d becom e ina ccu rate w ith extend ed u se.
C. Pro ce d u re
1.
If p ossible, test a flat area . For cur ved su rfaces, test along th e longitu d inal axis, no t the
c urv ed ax is . T est s mo o th areas tha t a re fre e from s urfa ce irre gu la ritie s su c h a s se a m s or
w eld s.
2.
Select the m il th ickn ess ran ge a long th e ed ge o f the g au ge for th e an ticipa ted film th ickn ess.
3.
4.
Firm ly p ress the g au ge into th e w et coating , ho ldin g th e gau ge p erp en d icu lar to the su bstrate
w it h t h e tw o e q u a l o u t e r p r o je ct io n s r es tin g o n t h e s u b s t r at e . D o n o t tilt o r s cr a p e t h e g a u g e
t h r o u g h t h e w e t co a t in g .
5.
Rem ove the g au ge from the w et coating an d no te the sh ortest coated step betw een the
notches. The w et film thickn ess lies betw een th is valve an d the ad jacent u ncoated step.
6.
N-1
Appendix O
Wet Film Thickness Formulas and Example Calculations
A . D e s cri p ti o n
D eter m inin g th e w et film th ickne ss (W FT) to a chiev e a d esired d ry film th ickne ss (DFT)
B.
Fo rm u las
N ote:
P e r ce n t o f s o lid s b y v o lu m e is ex p r e s se d i n d e cim a l fo r m .
Exam p le: The d esired DFT is 8 m ils. The coa ting m ater ial conta ins 83 per cent solid s by
vo lu m e. Dete rm ine t h e W FT to ach ieve a n 8-m il DFT.
N ote:
T h e p e r ce n t o f s o lid s a n d t h i n n e r s ad d e d b y v o l u m e is ex p r e s se d i n d e cim a l fo r m .
O-1
Appendix P
Procedures for Dry Film Thickness Gauges (SSPC-PA2) and Example
I.
P u rp o s e
D e t er m in i n g t h e th i ck n e s s o f a h a r d e n e d c o a tin g .
II. Eq u i p m e n t
The n on d estru ctive gau ges d escribed in SSPS-PA 2 are gr ou p ed into tw o ge n era l categ ories:
Typ e I, m agn etic pu ll off gau ge.
Typ e II, fixed p rob e or con stan t p ressu re p rob e ga u ges.
III. T y p e I, M a g n e ti c P u l lo f f G au g e
A. De scr i p tio n
Typ e I, m agn etic p u ll off gau ges, com m on ly referred to as ba na na gau ges, m easu re th e
co a t in g t h i ck n e s s o f a n o n - m a g n e t ic co a t in g o v e r a f er r o u s m e t a l s u b s t r a t e. T h e g a u g e h a s a n
exp osed m agn et attached to a sp ring . The am ou nt o f tension ap p lied on the sp ring to lift the
m agn et from the coated su rface is d irectly pr op ortiona l to the d istan ce of the m agn et from the
ferrou s surface.
B. C a l ib r a t io n
1.
U se n on m ag n etic, stan d ard calibr ated shim s, com m on ly chro m e. Plastic and m ylar sh im s are
n o t a cce p t a b l e fo r ca lib r a t in g p u ll o ff g a u g e s b e ca u s e p l as t ic o r m y la r is n o n a d h e r e n t a n d
m a y ca u s e t h e m a g n e t w it h in t h e g a u g e t o lift p r e m a t u r e ly .
2.
Select a shim that w ill be in th e ran ge of the expected d ry film th ickn ess to be m easu red .
3.
Place the shim on the p rep ared su bstrate o r an y clean bar e steel an d p lace the g au ge on the
sh im .
4.
5.
6.
If th e rea d ing d oes n ot ag ree w ith th e sh im th ickn ess, ch eck th e m ag n et for clean lin ess.
7.
8.
The gau ge is to calibr ated before u se, du ring u se, and after u se to v erify accur acy of rea d ings.
C . P r o ce d u r e
1.
E n s u r e t h e m a g n e t is cle a n .
2.
3.
4.
a.
b.
Soft or tacky coatings m ay inh ibit the lifting of the m agn et.
R ea d t h e co a t in g t h i ck n e s s o n t h e d i a l t h a t a lig n s w it h t h e m a r k e d lin e o n t h e g a u g e a n d
r e co r d t h e r e a d i n g .
C.
P-2
C a l ib r a tio n
1.
2.
Select a shim that w ill be in th e expected ran ge of the d ry film th ickn ess to be m easu red .
3.
Place the shim on the p rep ared su bstrate o r an y clean bar e steel an d p lace the g au ge on the
sh im .
4.
P la ce th e g a u g e fir m ly a g a in s t th e s h im a n d o b t ain a r e a d i n g .
5.
If the r ead ing d oes n ot agr ee w ith the sh im thickness, ad ju st the g au ge in accord an ce w ith the
m an u factur ers instru ction s. A d ju stm en t is nor m ally cond u cted by p ressing key s to ad ju st
u p w ard or d ow nw ard u ntil the gau ge rea d ing an d the sh im thickness ar e in agr eem en t.
P r o ce d u r e
1.
E n s u r e t h e p r o b e i s cle a n .
2.
3.
4.
Exam p l e :
Sp ecifica tio n s r eq u ir e t h e u p st r ea m face of a r a d ial g a te b e co a te d . Th e g a te h a s t h e d im en sio n s o f 26
feet in h eigh t alon g th e ra d ius cu rv atu re a n d is 10 feet in w id th . The coating tabu lation sp ecifies 2
c o a ts o f e p ox y at 8 m ils p er co at an d 1 topc oa t of p olyu re tha n e a t 3 m ils for 19-m il D FT, m inim u m , for
the total system .
Step 1: Det erm ine th e n u m ber of sp ot m easu rem en ts req u ired on an are a ba sis.
Su rface area of stru cture: 26 feet x 10 feet = 260 squ are feet
Su rfa ce a re a is less th an 300 sq u ar e fe et ; th er efo re , 5 sp ot m ea su re m en ts a re re q u ire d in ea ch
of t w o 100 s q u ar e fe et ar ea s (t ot a l of 30 in d iv id u a l g a u g e r ea d in g s).
Ste p 2: Th e D FT in st r u m en t is calib r a te d w ith a 20-m il sh im .
Ste p 3: An im a g in a r y lin e is d r a w n h or izo n ta lly acr os s t h e g a te at th e m id ele v a tio n , effect iv ely
d ivid ing the g ate into equ al low er an d u p p er areas. Five spot m easu rem ents are ran d om ly taken
in each area, consisting of thr ee ind ivid u al gau ge read ings w ithin a 1.5-inch-diam eter circle p er
sp ot m easu rem en t. Th e follow ing a re th e resu lts:
18.2
20.6
21.0
16.7
26.4
18.6
19.1
21.8
17.1
29.8
17.8
20.4
20.8
16.8
29.0
Average
18.2
20.0
21.2
16.9
28.4
22.6
20.4
18.6
19.5
29.3
22.1
21.7
18.3
19.9
31.0
21.9
21.3
19.4
19.2
30.4
Average
22.2
21.1
18.8
19.5
30.2
P-3
P-4
Appendix Q
Procedures for Discontinuity (Holiday) Testing (NACE RP 0188)
I.
P u rp o s e
To locate p inh oles an d oth er d efects in h ard en ed coating u sing low or h igh v oltage in stru m en ts.
II. U s i n g a Lo w V o l t ag e In s t ru m e n t f o r C o ati n g T h i ck n e s s e s o f 2 0 M i l s a n d Le s s
A . De sc r ip tio n
A l o w v o ltag e, n o rm ally b etw een 5 and 90 volts D C , ba ttery p ow e re d d e vice w ith a w e t s pong e
electric p rob e is d rag ged across the coated su rface to locate d iscon tinu ities (p inh oles) in the
coating film . Shou ld d iscontinu ities be encou ntered , an electric curren t w ill flow to the steel
su b st r a te . Th is p r oc es s w ill clos e a n ele ctr ical cir cu it w ith in th e in st r u m en t a n d se t o ff an au d ib le
o r v is u a l a la r m .
B.
Eq u ip m e n t
1.
C.
Electrom agn etic-sensitive or a solid state electronic relay circu it tha t, w he n d iscon tinu ity
is d et ect ed , clos es th e cir cu it a n d p r od u ces an au d ib le o r v isu a l ala r m . Ge n er a lly , th is
instrum ent can b e field ad ju sted .
b.
A n ele ctr on ic re lax at ion os cillato r cir cu it m ea su re s th e d ro p in ele ctr ical r es ista n ce
betw een th e coating and the steel sub strate and p rod u ces an a u d ible alarm w hen
d iscontinu ity is detected. Genera lly, this instru m ent typ e canno t be field ad ju sted .
P r o ce d u r e
1.
2.
3.
4.
Attach th e electrical grou nd (neg ative) w ire from the instru m ent to the steel su bstrate.
5.
Q-1
N ote:
a.
A l ow -s u d s in g w e t tin g a g e n t s u ch a s th a t u s e d i n p h o t og r a p h ic d e v e lo p m e n t ca n b e
ad d ed to th e p otab le w ater at a r atio of fluid ou n ce to 1 gallon of w ater to increa se
s en s it iv it y .
b.
The u se of d etergen t w etting solu tions is not p erm itted because a bu bble m ay form over
a d efect, rend ering it un d etectable.
6.
7.
8.
T h e sp o n g e sh o u ld b e k e p t sa t u r a t ed , b u t n o t d r ip p in g w e t , w h i le m o v i n g o v e r th e co a t in g .
9.
10. If w etting solu tions are u sed , the solu tions m u st be com p letely rinsed off before ap p lying the
r e p a ir co a t in g .
III. Usi n g Hig h V o ltag e I n s tru m en t fo r C oating T hic kne s s of G re ate r T han 20 M ils
A . De sc r ip tio n
A h ig h -v olt a g e d ev ice, n or m a lly in ex ces s o f 800 v olt s D C , w ith w et sp on g e e lect r ic p r ob e is
p a ss ed ov er th e co a te d su r face to loca te d isco n tin u itie s (p in h ole s) in th e co a tin g film . Sho u ld
d iscon tinu ities be en cou nter ed , the electric dev ice w ill sp ark thr ou gh the a ir gap at the
d isco n tin u ity an d p r od u ce a n au d ib le o r v isu a l ala r m . A g en er a l ru le-o f-th u m b for d et er m in in g
the r equ ired voltage is 100 to 125 volts p er m il; ho w ever , it is best to consu lt the m an u factu rer to
p r e v e n t d a m a g in g t h e co a t in g .
B.
Eq u ip m e n t
1.
2.
Q-2
b.
D i re ct cu r r e n t d is ch a r g e s co n t in u o u s v o lt a g e
b.
c.
C.
P r o ce d u r e
1.
2.
If m oisture is p resen t on the coated su rface, d ry th e su rface before testing b ecau se m oisture
w ill in d icate inv alid d iscon tinu ities.
3.
4.
5.
Attach th e electrical grou nd (neg ative) w ire from instrum ent to the steel su bstrate.
6.
7.
8.
Using a sing le p ass, m ove th e p robe ov er the coated sur face at a rate of abou t 1 foot p er
se co n d .
9.
W he n a d iscon tinu ity is d etected, m ark the sp ot for rep air. Use a grea seless m ark er th at be
ea sily clea n ed off.
Q-3
Appendix R
Procedure for Mechanical (Pulloff) Adhesion Testing
(ASTM D 4541; Annex A2)
A . P u rp o s e
To d eterm ine the ad hesive strength betw een a fu lly cur ed coating and the su bstrate.
B.
D e s cri p ti o n
Th e a d h es ion te st er m ech a n ically m ea su r es th e r ela tiv e s tr en g th of a d h es ion b et w ee n a co a tin g
a n d th e s u b st r a te or b et w ee n coa tin g lay er s. A n alu m in u m p u ll off s tu b (d olly ) is a d h es iv ely
b on d ed to th e co a tin g an d allo w ed to cu r e. A p u llin g for ce o n th e b on d ed d olly is co n tin u ou sly
in cr ea se d u n til th e d o lly d eta ch es o r a sp ecific fo r ce is a ch iev ed .
C. Eq u i p m e n t
Th ere ar e sev era l d ifferen t typ es of p u lloff ad h esion tester s. The ty p e II tester , cited in A STM D
4541, ann ex A.2, is the Elcom eter M od el 106. This mod el is the m ost com m only u sed . Elcom eter
M od el 106 is available in six scale ran ges. The scale m ost com m only u sed is 0 to 1,000 pou nd s per
sq u a r e in ch (p si), a n d it is d iscu ss ed b elo w . A st a n d a r d 3/ 4-in ch -d iam et er alu m in u m d olly is
u se d w ith th e E lcom et er M od el 106.
D . Pro ce d u re
1.
2.
3.
R-1
"
"
4.
C o n c a v e - o u t e r r a d i u s (e xa m p l e : p i p e e xt e rio r )
C o n v e x - in n e r r a d iu s (e xa m p l e : p i p e in t e r io r )
5.
W ipe clean an y gr it and rep eated ly solven t w ipe on the test sp ot.
6.
7.
8.
9.
R em o v e a n y e xce ss ep o x y a r o u n d t h e p e r ip h e r y o f t h e d o l ly w it h o u t d is tu r b i n g t h e d o l ly .
R-2
15. R e ad th e h ig h es t v alu e attain ed a t the bottom of the d ra g ind ic a tor in ps i. If the d olly d id not
p u ll fre e, r ep or t t h e r es u lt a s g r ea te r th a n th e m a xim u m cap a city of t h e in st r u m en t (i.e., 1,000
p si fo r th e E lcom et er M od el 106).
16. Alw ays reset the d rag ind icator to zero after testing. Failu re to reset w ill resu lt in a d istorted
o r p e r m a n e n t ly d a m a g e d h e l ica l s p r in g .
17. Repor t one or a com bination of the follow ing typ es of failu re:
A d h e siv e
"
"
C o h es iv e
"
F a ilu r e b e tw e e n t h e s u b s t r a te a n d t h e fir s t (p r im e ) co a t
Failur e betw een an y tw o coats
G lu e
"
"
C o h e s iv e fa ilu r e o f t h e a d h e s iv e g lu e ( g lu e r e m a in s o n t h e co a t in g a n d d o lly )
R-3
Appendix S
Procedure for Hydraulic Adhesion Testing (ASTM D 4541; Annex A3)
A . P u rp o s e
To d eterm ine the ad hesive strength betw een a fu lly cur ed coating and the su bstrate.
B.
D e s cri p ti o n
The ad hesion tester u ses a hyd rau lic system to m easu re the relative streng th of ad hesion betw een
a co a t in g a n d t h e su b s t r a te o r b et w e e n c o at in g l ay e r s. A u n i fo r m t en s ile lo a d i s a p p lie d t h r o u g h a
ho le in th e center of a p u ll stu b u sing a h yd rau lic piston a nd p in. An alum inu m p u ll off stu b
(dolly) is ad hesively bond ed to the coating and allow ed to cure. A p u lling force on th e bon d ed
d o lly is co n tin u o u sly in cr ea se d u n til th e d olly d eta ch es o r a sp ecific fo r ce is a ch iev ed .
Rep rod u cible resu lts are ach ieved becau se the ap p lied tensile load is consistent.
C. Eq u i p m e n t
The self-align ing ty p e III tester cited in A STM D 4541, ann ex A 3, is the H ate M ark VII. Testers ar e
a v a ila b le in th e fo llo w in g th r ee r a n g es: (1) 0 t o 1,500 p si, (2) 0 to 2,250 p si, a n d (3) 0 t o 3,000 p si.
D . Pro ce d u re
1.
2.
3.
"
"
C o n c a v e - o u t e r r a d i u s (e xa m p l e : p i p e e xt e rio r )
C o n v e x - in n e r r a d iu s (e xa m p l e : p i p e in t e r io r )
S-1
4.
5.
Ligh tly sand the test ar ea to achieve a n ev en , sm ooth su rface and w ipe clean. Rep eat th e
solven t w ipe.
6.
Insert the teflon p lug into th e load ing fixtur e u ntil the p lug tip p rotru d es from the su rface.
7.
A p p ly a thin coat of ad he sive ep oxy to th e bon d ing su rface of the fixtu re, taking care n ot to
g e t e p o x y o n t h e p lu g .
8.
9.
Rem ove the teflon p lug an d allow the a d he sive ep oxy to cu re in accord an ce w ith the
m an u factur ers instru ction s.
Repor t one or a com bination of the follow ing typ es of failu re:
A d h e siv e
"
"
C o h es iv e
"
S-2
F a ilu r e b e tw e e n t h e s u b s t r a te a n d t h e fir s t (p r im e ) co a t
Failur e betw een an y tw o coats
G lu e
"
"
C o h e s iv e fa ilu r e o f t h e a d h e s iv e g lu e ( g lu e r e m a in s o n t h e co a t in g a n d d o lly )
Appendix T
Procedure for Measuring Dry Film Thickness by Destructive Means
With Tooke Gauge (ASTM D 4138)
A . P u rp o s e
To d eterm ine the d ry film th ickn ess and the n u m ber of ind ivid u al coats of a coating system
B.
D e s cri p ti o n
Th e To ok e g au g e is u se d to cu t th ro u g h th e h ar d en ed coa tin g to th e s u b str at e. O n e s id e o f th e cu t
is m ad e at a specific ang le thro u gh the coating . A m icroscope w ith a g rad u ated (reticle) scale,
at ta ch ed to th e g au g e, is u se d to m ea su re th e e xp os ed coa tin g p er p en d icu lar to th e s p ecific cu t
a n g l e to d e t er m in e t h e d r y film t h ick n e s s . T h e n u m b e r o f a p p lie d co a t s a n d t h e in d iv i d u a l
t h i ck n es s es can als o b e d eterm in ed , p rovid e d tha t c oa ting la ye rs ca n be id e ntifie d by c olor
d iffer en ce o r b y a d ist in ctiv e lin e. Th is m et h od is co n sid er ed d es tr u ctiv e b eca u se th e cu t m a d e in
th e co a tin g is a n in te n tio n al d efe ct, u n les s r ep a ir ed . Th e T oo k e g a u g e is m os t o fte n u se d in
ev alu ation of coatin g failu res.
C. Eq u i p m e n t
A To ok e g a u g e, e ith er alu m in u m or p las tic b od y , w ith an illu m in a te d 50X m icr os co p e a n d r et icle
(calibrated ) scale. It includ es three cutting tips an d a m arker p en.
D . Pro ce d u re
1.
2.
3.
A fter selecting the p rop er cu tting tip, p lace the cu tting tip a nd tw o gu ide stu d s against th e
coa tin g su rfa ce, w ith th e cu tt in g tip ju st a b ov e t h e m ar k ed lin e. A lign th e fo re ar m to cu t
across (p erp end icu lar to) the m arked line. Draw the forearm straigh t back w ith su fficient
p r es su r e t o cu t co n tin u ou sly th r ou g h th e co a tin g in to th e s u b st r a te . M a in ta in th e t h r ee p oin t
surface co n tact (cu tter an d 2 g u id e s tud s ) to e ns ur e a s tra ight a n d ve rtic a l c ut. The le ngth of
cut into the su bstrate need s to extend slightly beyon d the m arked line.
T-1
4.
View th e cu t th ro u g h th e lig h ted 50X m ic rosc ope a nd foc us on the c oa ting on e ithe r s id e o f
th e e xp os ed su b st r a te . Focu s a n d alig n th e r et icle s ca le p er p en d icu lar to th e cu t. Th e co a tin g
on on e s id e o f th e cu t w ill be sm oo th er th a n on th e o p p os ite sid e o f th e cu t. If th e cu tt in g tip
w as correctly p osition ed , the sm ooth er sid e w ill be on th e left. Alw ays m easu re on the
sm oother sid e.
5.
6.
7.
T-2
Cutting tip
10X
0.1 mil
2X
0.5 mil
1X
1.0 mil
W he re th e p rim er is an inor gan ic zinc or galva nized zinc, it is d ifficult to d istingu ish the
zinc from the su bstrate. To d ifferen tiate betw een steel su bstrate and zinc, u se a 5 p ercent
solu tion o f copp er su lfate and d istilled w ater. The steel sub strate w ill tu rn a copp er
co lo r , a n d t h e z in c w i ll t u r n b l a ck .
Fo r d a r k - co lo r e d c oa t in g s , u s e a liq u i d e r a s e r w h i te -o u t in s t ea d o f t h e fe lt tip m a r k e r .
The th ickn ess of coating chips can be m easu red by v iew ing th e cross section of the
co a tin g ch ip th r o u g h th e To ok e g a u g e. (Ea ch d iv ision is e q u a l to 1 m il.)
Appendix U
Procedures for SSPC-VIS 2 (2000 Revision)
A . P u rp o s e
To ev alu ate th e am ou n t an d d istribu tion o f ru st on coated su rfaces.
B.
D e s cri p ti o n
T h i s a p p en d ix p ro v id e a s tan d ard m e thod of e va lua ting a nd qu a lifying the d e gre e of ru s t on
p ainted ferrou s (steel or iron ) su rfaces u sing p ictorial im ages (color an d black and w hite
p h otog rap h s) w ith a g iven ru st p ercen tag e an d d istribu tion. The r esu lts are rep orte d in a r u st
g r a d e s ca le fr om 10 (lea st r u st ed ) to 0 (m os t r u st ed ), an d r u st d ist r ib u tio n is n ot ed b y S (sp ot r u st ),
G (g en er a l ru st ), an d P (p in p oin t r u st ).
C. Pro ce d u re
1.
2.
D e t er m in e t h e r u s t d is tr ib u t i on a n d t h e p e r ce n t a g e o f r u s t b y th e fo llo w in g .
a.
Ch oose th e ru st d istribu tion (sp ot, gen era l, or p inp oint) for th e selected are a th at m ost
clo s e ly m a t ch e s t h e co r r e s p o n d in g c o lo r o r b la ck a n d w h i te p h o t o g r a p h .
b.
Select the p ercentag e of ru st for th e eva luated area th at m ost closely m atches th e
co r r e sp o n d in g p h o t o g r a p h . R u s t s ta in i n g o r d i r t w it h t h e a p p e a r a n ce o f r u s t is n o t t o b e
in c lu d e d . Ru s t u n d e r th e co a t in g a n d b r o k e n b lis te r s w it h a p p a r e n t r u s t a r e to b e
inclu d ed . N on bro ken blisters are to b e d efine d by th e follow ing an d inclu d ed in the
p ercentag e of ru st:
(1) Ru st filled b lister (de term ined by o p en ing b lister) is to be incorp orated in the
p ercentag e of ru st.
(2) Flu id filled b lister (de term ined by o p en ing b lister) is not to b e incorp orated in the
p e r c en t a g e of r u s t , b u t it is to b e r eco r d e d s ep a r a t e ly .
c.
3.
De term ine th e ru st gr ad e accord ing to table 1 of the stan d ard . For exam p le, th e ru st
d is t r ib u t io n a r e a w a s d e t e r m in e d t o b e s p o t , a n d t h e p e r c e n t a g e o f r u s t w a s g r e a te r t h a n
0.3 p er ce n t t o 1 p er ce n t; th er efo r e, th e r u st g r a d e is 6-S.
U-1
Appendix V
Procedure to Determine the Presence of Soluble Lead and Insoluble
Lead Chromate in Coatings
A . P u rp o s e
T o d e t e r m i n e w h e t h e r t h e co a t in g c o n t a in s le a d .
B.
D e s cri p ti o n
T h e p r e s en ce o f lead an d lead ch ro m a te pigm e nte d c oa tings c a n be d e te rm ine d by a c olor
ind icator u sing rea gen ts to sw ab ov er exp osed coating layers. The sw ab test w ill verify on ly the
p resen ce of lead an d chro m ate an d w ill not p rov id e qu an titative resu lts. The sw ab test m ay also
d etect the p resence of lead chrom ate.
C. Eq u i p m e n t
Le a d C h eck Sw a b s m a n u fact u r ed b y H y b r iv et Sys te m s, In c., PO Box 1210 Fr a m in g h a m ,
M a ss a ch u se tt s 01701; tele p h on e: 800-262-5323.
D . Proce d u re fo r D e tecti n g W ater S o lu b le Lead Pi g m e n ts (Le ad O xid e o r Lead Carbo n ate)
1.
C l ea n a n d r e m o v e a ll d u s t a n d d ir t fr o m t h e t es t a r e a .
2.
Cu t abou t a 1/ 4 inch n otch throu gh all coating layers and expose th e sub strate.
3.
Activate the sw ab by crush ing the g lass am p u les m arked A an d B on the sw ab tu be.
4.
5.
6.
Results
a.
b.
c.
V-1
7.
W ith th e u sed sw ab, squeeze a d rop onto r eagen t w ithin th e test circle.
b.
c.
If p ink o r re d d oes n ot ap p ear on th e circle, th e n ega tive test re su lt is inv alid, an d a rete st
is r e q u i r ed u s in g a n e w s w a b a n d t e st a r e a .
8.
9.
R ed b le e d i n g v e r s u s p in k - o r r ed -co lo r e d s w a b
V-2
"
Cru sh th e colorless solu tion in glass am p u le B on ly and squ eeze a d rop on to the
s w a b t ip . Sw a b t h e t e st a r e a . If r e d a p p e a r s , it in d ica t e s b le e d i n g i s o ccu r r in g a n d
the p resence of lead canno t be confirm ed .
"
Ta k e a cot to n tip d ip p ed in v in eg a r an d sw a b th e t es t a r ea . If re d ap p ea r s, it
in d ica t es b le e d i n g is o ccu r r i n g .
If the coating is bleed ing red an d lead is su sp ected bu t cann ot be con firm ed , the
m a n u fa ct u r e r r e co m m e n d s o n e o f t h e fo llo w in g m e t h o d s to co n f ir m t h e p r e s e n c e o f le a d :
"
"
U se a sod ium su lfid e solu tion su p p lied sep ara tely by th e m an u factur er a t a n ew test
area. If the test ar ea tu rn s black, lead is p resen t.
Appendix W
Procedure to Determine the Presence of Chromate in Coatings
A . P u rp o s e
To d eterm ine w heth er the coating contains chr om ate.
B.
D e s cri p ti o n
Th e p r es en ce o f ch r om a te p ig m en te d coa tin g s ca n b e d et er m in ed b y a co lor in d icat or u sin g
r e a g e n ts to s w ab o v er ex p o s ed co ating la ye rs . The s w a b te s t w ill ve rify only the p re s e nc e of
ch r o m a te an d w ill n o t p r o v id e q u a n tita tiv e r esu lts.
C. Eq u i p m e n t
C h r om a te C h eck Sw a b s m a n u fact u r ed b y H y b r iv et Sys te m s, In c., PO Box 1210 Fr a m in g h a m ,
M a ss a ch u se tt s 01701; te lep h on e: 800-262-5323.
D . Proce d u re fo r D e tecti n g W ater S o lu b le Lead Prim e n ts (l ead o r le ad carb o n ate)
1.
C l ea n a n d r e m o v e a ll d u s t a n d d ir t fr o m t e st a r e a .
2.
Cu t abou t a 1/ 4 inch n otch throu gh all coating layers and expose th e sub strate.
3.
Activate the sw ab by crush ing the g lass am p u les m arked A an d B on the sw ab tu be.
4.
5.
Ru b th e clear solu tion o n th e tip in th e exp osed coating n otch for 30 second s.
6.
Results
7.
a.
If the sw ab tip or th e test sur face tu rn s p ink or p u rp le, chrom ate is pre sent.
b.
b.
W -1
c.
8.
W -2
If p in k o r p u r p le d o e s n o t a p p e a r o n t h e cir cle , t h e n e g a t iv e t e st r e su lt is in v a l id a n d a
r e t es t is r e q u i r ed u s in g a n e w s w a b a n d t e st a r e a .
Appendix X
Determination of Toxic Metals in Hardened Paint
A . O b j e cti v e s
1.
Id en tify ty p e of toxic m etals tha t m ay be in th e p aint o n existin g infra stru ctu res.
2.
3.
The resu lts of the an alysis of the existing p aint are requ ired b efore the p aint can be rem oved
fo r :
B.
P r ed es ig n sp ecifica tio n d a ta g a th er in g
P r e m a i n t en a n c e w o r k
W o rk er p ro tectio n
Protection o f the en vironm ent
P ro p er d isp o sa l o f th e old p a in t
S am p l i n g
1.
2.
3.
4.
T a k e p a i n t sa m p l e in a b o u t a 2- t o 3-in c h s q u a r e
M ak e su re th e sam p le in clu d es th e p rim er (p rim er con tains m ost toxic m etals)
Sam p le in a t least thr ee locations to v erify resu lts
Place th e s am p les in s ep arate b a gs a nd la be l e a ch ba g for ide ntific a tion
5.
- to 1-inch w ood
chisel
T h e p r im a r y m e t als to t es t fo r :
2.
C o b a lt , a s so cia t ed w it h b lu e i sh a n d g r e en i sh c o lo r s
C a d m iu m , a s so cia t ed w it h s a fe t y co lo r s
C h r o m iu m , a s so cia t e d w it h le a d c h r o m a t e , z in c ch r o m a t e , a n d s a fe t y co lo r s le a d
L e ad
Z i n c (d e fin e d a s a to x ic m e t a l o n l y in t h e St a t e o f C a lifo r n i a )
T h e se co n d a r y m e t als to t es t fo r :
A r se n ic
Ba r iu m
Ber y lliu m
Sele n iu m
Silver
Va n a d iu m
X-1
3.
Requ est resu lts in p ercen t, by w eigh t of m etal, an d to at least th ree sign ifican t d igits.
4.
T y p ical tes t m eth o d s are EP A 6010B, EPA 7420 (le a d s pe c ific ), O SH A 125G m e ta l s ca n, IC P , or
p or ta b le XRF in st r u m en t fo r lea d on ly (re q u ir es cer tifie d op er a to r ).
D . Co s ts
A bou t $20 to $25 for ea ch m etal tested re d u ced cost for sev era l m etals.
E.
T e s t Lab o rato ri e s
Bu r ea u of R ecla m a tio n , Eco log ical R es ea r ch an d In v es tig a tio n (D -8220); con ta ct: C h r is
H old r en ; tele p h on e: (303) 445-2178
3.
X-2
E n v ir o n m e n t a l L ea d L ab o r a to r y A ccr e d i ta t io n P r o g r a m ( EL LA P )
N a t io n a l L ea d L ab o r a to r y A ccr e d i ta t io n P r o g r a m ( N L LA P )
W ebsite A d d ress: w w w .aiha .org (accr ed ite d lab or a to r ies ar e lis te d b y city an d Sta te in
table form at)
Mission Statements
The mission of the Department of the Interior is to protect and provide
access to our Nations natural and cultural heritage and honor our
trust responsibilities to tribes.