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b,*
a
b
Department of Chemical Engineering, Faculty of Engineering, Prince of Songkla University, Hat Yai, Thailand 90110
Department of Biological and Agricultural Engineering, Texas A&M University, College Station, TX 77843-2117, USA
Received 4 May 2001; accepted 2 July 2001
Abstract
A fundamental 2-D model was developed to predict the heat and mass transfer that occur during the frying and cooling process
of tortilla chips. Semi-empirical correlations were included to account for structural changes, such as shrinkage and expansion due
to pung. All water present in the tortilla chip was considered bound and led to shrinkage when removed. The parameters that were
studied included water saturation, Sw , oil saturation, So , temperature, T, and pressure, P. Liquid ow results from convective ow
due to the gradient in total gas pressure and capillary ow due to the gradient of capillary force. Gas movement results from
convective ow due to the total gas pressure gradient and Knudsen diusion due to the concentration gradient. The only transport
phenomenon during cooling is oil absorption, which is assumed to be a function of the capillary pressure. 2002 Elsevier Science
Ltd. All rights reserved.
1. Introduction
It is understood that fried products absorb oil during
frying and as they cool which contributes to a high fat
and high calorie product. Oil content in fried foods has
been related to initial moisture content (Gamble, Rice,
& Selman, 1987; Moreira, Palau, Sweat, & Sun, 1995b),
pre-frying treatment (Gamble et al., 1987; Moreira,
Castell-Perez, & Barrufet, 1999), structural changes
during baking (Lee, 1991; McDonough, Gomez, Waniska, & Rooney, 1993; Rock-Dudley, 1993), and cooling
time (Sun & Moreira, 1994). Moreira, Palau, and Sun
(1995a) showed that bulk density decreases, and porosity and oil uptake increase with frying time during
frying of tortilla chips.
Still, changes taking place during frying are dicult
to model since there are a number of inter-related factors that have to be taken into account. It is important
to identify the structural changes during the dierent
stages of the process to better understand the quality
changes that occur during frying. The porosity of the
product formed during frying plays an important role in
*
0260-8774/02/$ - see front matter 2002 Elsevier Science Ltd. All rights reserved.
PII: S 0 2 6 0 - 8 7 7 4 ( 0 1 ) 0 0 1 3 4 - 0
Nomenclature
apparent diusivity coecient due to capillary force (kg/m s)
C
molar density of gas mixture kmol=m3
c
mass concentration kg=m3 total volume
Cp
specic heat (J/kg K)
Deff;g
eective gas diusivity in moist materials
m2 =s
d
diameter of tortilla chip (m)
Exfactor expansion factor (dimensionless)
h
heat transfer coecient on open boundary
W=m2 K
hmv
vapor transfer coecient on open boundary
(m/s)
K1 K32 coecients in dierential equations
k
thermal conductivity (W/m K)
ki
intrinsic permeability m2
kgr
gas relative permeability (dimensionless)
kwr
water relative permeability (dimensionless)
kor
oil relative permeability (dimensionless)
k10
constant in Eq. (38) (kg mol/kJ)
k20
constant in Eq. (38) (dimensionless)
M
molecular weight (kg/kmol)
m
mass of component (kg)
*
n
total ux kg=m2 s
P
total pressure (Pa)
p
partial pressure (Pa)
pc
capillary pressure (Pa)
ps
saturated pressure of pure water (Pa)
R
universal gas constant (J/kmol K)
Ra
air gas constant (J/kg K)
Rv
vapor gas constant (J/kg K)
am
S
Sg
So
Sw
Sfactor
T
t
V
W
w
x
Greek symbols
dT
coecient of Soret eect due to capillary
force (kg/m s K)
/
total porosity (dimensionless)
k
latent heat of vaporization (J/kg)
l
dynamic viscosity (Pa s)
q
intrinsic density (kg/m3 )
qCp eff eective heat capacity of the moist materials
J=m3
Subscripts
a
air
amb
ambient
c
capillary
g
gas
o
oil
s
solid matrix
w
water
v
vapor
e
eective
Si 1:
i1
P
;
RT
co qo /So :
cv
6
7
ki kgr
C2
qa
rP Ma Mv Deff;g rxa ;
lg
qg
10
ki kgr
C2
rP Ma Mv Deff;g rxv :
lg
qg
11
nv qv
12
13
14
15
16
17
ki kwr
rP am rSw dT rT ;
lw
ki kor
*
no qo
rP amo rSo dTo rT :
lo
*
nw qw
oSw
oT
rK1 rSw rK3 rT rK4 rP :
K7
ot
ot
18
oSo
rK10 rSo rK11 rT rK12 rP :
ot
19
K21
The liquid ux of water and oil based on the total crosssectional area can be derived as:
20
Fig. 2. Schematic of the 2-D model of the tortilla chip (gure not drawn to scale).
21
*
na
0;
23
24
25
26
So So1 ;
27
P Pamb ;
28
29
34
dt
do
35
where
Sfactor
ki kor opc
;
lo oSo
wt
wo
37
30
Exfactor
31
32
P Pamb ;
36
where
~
no qo
Sw < 0:20;
33
The input parameters are vital in yielding an accurate
predictive model. For dierent products, the input parameters will vary, thus reliable experiments must be
conducted. For food products, relatively little data, such
as the permeability of liquids and gases, the sorption
isotherms, and the capillary pressure curve, are available.
Eq. (38) gives the sorption isotherm used in this
model. The equation is taken from Kawas (2000) who
tted experimental data for the frying of tortilla chips
with the Chung and Pfost (1967) model. The k1 and k2
values are 8:11 106 kg mol=kJ and 17.91, T is in
Kelvin, and W is moisture content (d.b.).
ln
pv
ps
k10
exp k20 W :
RT
Table 1
Heat capacity values used in this model
Parameter
Values (J/kg K)
Reference
2
Solid
Water
Cpw 4180 at 15 C
Oil
Cpo 2223
O2 (J/mol K)
Lewis (1987)
N2 (J/mol K)
Lewis (1987)
Air
Water vapor
Lewis (1987)
Lewis (1987)
38
Fig. 4. Model of thickness expansion due to pung. Upper slice of the tortilla chip, gure is not drawn to scale.
for T 6 100 C
The eective heat capacity, which includes the contribution of all the components in the tortilla chip, is given
in Eq. (40)
qCp eff qs Cps 1 / qw Cpw /Sw qo Cpo /So
40
Table 3
Thermal conductivity values used in this model
Parameter
Values (W/m K)
Reference
Water
Gas
Oil
kw 0:64
kg 0:026
ko 0:17
Table 2
Coecients for determining CpO2 , CpN2 , and Cpv (Lewis, 1987) from Table 1
Component
O2
N2
Water vapor
a
25.46
27.32
32.22
43
39
qg Cpg /1 Sw So :
42
c
2
1.5190 10
0.6226 10 2
0.1920 102
)0.7150 10
0.0950 105
1.0540 105
5
1.311 109
0
)3.594 109
3. Discussion
During the drying of food materials, water is removed from the system causing signicant shrinkage.
For tortilla chips, Kawas and Moreira (2000) observed
up to 9.6% shrinkage in the chip diameter for the control
sample and up to 7.6% and 11.6% shrinkage for the ne
and coarse masa particles, respectively. Also, they noticed signicant increase in the thickness of the chip due
to pung (gas pressure buildup). They recorded up to
100% increase in puness around the center of the chip
(taking into account gas bubble expansion) and about a
7% increase in the thickness of the chip (disregarding the
gas bubble expansion). This study includes these changes in the model in order to obtain a more accurate
prediction of the moisture and temperature prole.
Fennema (1985) presented an idea of water interaction within a food system that was useful in developing
the structure model. Fig. 5 illustrates three dierent
zones of water using a moisture sorption isotherm.
Water presented in zone I is the most strongly absorbed
and most immobile water in food and the enthalpy of
vaporization of this water is much greater than that of
pure water. This water forms a monolayer over the hydrophilic region of the solid material by either waterion
or waterdipole interaction. It is the most tenaciously
bound water and is thought of as constitutional
water. Water in zone II consists of zone I water and a
multilayer water that associates with neighboring molecules mainly by waterwater and watersolute hydrogen bonding. This bound water is called vicinal water.
The enthalpy of vaporization for the multilayer water is
slightly to moderately greater than that of pure water.
Water in zone III of the isotherm includes water in zones
Fig. 5. Generalized moisture sorption isotherm for the low-moisture range of food 20 C (Fennema, 1985).
Table 4
Percentage of shrinkage, thickness, and puness of the tortilla as a function of frying time for tortilla with 1.27 mm initial thickness fried at 190 C
(Kawas, 2000)
Time (s)
Shrinkage (%)
Thickness (%)
Puness (%)
Moisture (% w.b.)
0
5
10
20
30
40
60
0.0
7.8
8.0
8.0
8.1
8.3
9.4
0.0
0.0
0.0
0.0
0.0
7.0
7.0
0.0
0.0
0.0
70.0
90.0
100.0
100.0
42.0
28.0
22.0
10.0
5.5
3.8
3.8
4. Conclusions
The frying process, including cooling, of tortilla chips
was simulated based on the fundamental approach of
multiphase porous media. The parameters that were
studied included water saturation, Sw , oil saturation, So ,
temperature, T, and pressure, P. Liquid ow results from
convective ow due to the gradient in total gas pressure
and capillary ow due to the gradient of capillary force.
Gas movement results from convective ow due to the
total gas pressure gradient and Knudsen diusion due
to the concentration gradient. The only transport phenomenon during cooling is oil absorption, which is assumed to be a function of the capillary pressure.
;
Rv T oSw
Rv T
/1 Sw So o Pv
K7v
;
Rv
oT T
K1 K1v am ;
K3 K3v dT ;
kkwr
K4 K4v qw
;
lw
K5 K5v /qw ;
K7 K7v ;
K10 amo ;
K11 dTo ;
kkor
K12 qo
;
lo
K14 /qo ;
K1v
10
Ma Mv Deff;g
opv
P
;
RT P pv Ma pv Mv
oSw
Ma Mv Deff;g
opv
P
;
RT P pv Ma pv Mv
oT
P pv kkgr
Ma Mv Deff;g
pv ;
Ra T lg RT P pv Ma pv Mv
/ P pv 1 Sw So opv
;
Ra
T
T
oSw
/ P
PSw 1 Sw So o opv
2
;
Ra T 2
T
oT oT
T
/1 Sw So
;
Ra T
am k;
K17
K19
K20
K21
K23
K24
K25
K26 amo k;
K27 Keff dTo dT ;
kkwr
kkor
q
q k;
K28
lw w
lo o
K29 k/qw ;
K30 k/qo ;
K31 qCp eff :
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