S GIO DC-O TO

THI BNH

THI CHN HC SINH GII LP 12 NM HC 2014-2015

Mn: HO HC
Thi gian lm bi: 90 pht (khng k thi gian giao )
gm 04 trang; Th sinh lm bi vo Phiu tr li trc nghim

M : 157
Cho nguyn t khi ca cc nguyn t:
H =1; He=4; Be=9; C=12; N=14; O=16; Na=23; Mg=24; Al=27; S=32; Cl=35,5; K =39; Ca= 40; Cr= 52; Mn= 55; Fe = 56; Cu = 64; Zn = 65; Br=80; Ag=108;
Ba = 137; Au = 197; Sn = 119; Sr = 88; Cd=112; Hg=200; Pb=207; Ni=59; P=31.

Cu 1. Este X tc dng vi NaOH theo t l mol 1:2 thu c mt mui v mt ancol c s mol bng nhau v bng s mol X
phn ng. Cho 11,6g X phn ng va vi 2OO ml dung dch NaOH 1M thu c 6,2 gam ancol. Cng thc phn t ca X l
A. C4H4O4.
B. C3H6O2.
C. C4H8O2.
D. C5H6O4.
Cu 2. Cho O,15 mol aminoaxit X ch cha mt chc NH2 tc dng vi 2OOml dung dch HCl 1M thu c dung dch Y.
Dung dch Y phn ng va vi 5OOml dung dch KOH 1M thu c dung dch Z. Bit cc phn ng xy ra hon ton. C
cn cn thn dung dch Z thu c 46,25 gam cht rn khan. Khi lng tng ng vi O,15 mol X l:
A. 18,95g.
B. 2O,95g.
C. 21,95g.
D. 19,95g.
Cu 3. Hn hp X gm 2 cht hu c n chc, u c cha C,H,O, u c %O = 53,33%.
-m gam hn hp X tc dng vi dung dch AgNO3/NH3 d, tO thu c ti a 12,96 gam Ag.
-m gam hn hp X tc dng va vi 336ml H2 ktc (Ni, tO).
T l khi lng ca hai cht hu c trong m gam hn hp X l
A. 1:2.
B. 1:3.
C. 1:1.
D. 1: 4.
Cu 4. Chia m gam hn hp cc kim loi Al,Fe,Ba thnh 3 phn bng nhau. Phn 1: vo nc d, thu c O,896 lit H2 (ktc).
Phn 2 tc dng vi dung dch NaOH d thu c 1,568 lit H2 (ktc). Phn 3 tc dng vi dung dch HCl d thu c 2,24 lit
H2 (ktc). Gi tr ca m l
A. 8,26.
B. 12,39.
C. 24,78.
D. 4,13.
Cu 5. Nhit phn hon ton 54,8 gam hn hp Fe(NO3)2 v Cu(NO3)2 trong iu kin khng c khng kh thu c 24 gam
hn hp cht rn A v hn hp kh X. Sc X vo dung dch NaOH d n phn ng hon ton thu c dung dch Y. Khi
lng mui c trong dung dch Y l:
A. 3O,8 gam.
B. 34 gam.
C. 17 gam.
D. 49,4 gam.
Cu 6. Thm nc vo 1Oml axit axetic bng (axit 1OO%, D=1,O5 gam/cm3) n th tch 1,75 lt 25OC thu c dung dch
X c pH = 2,9. in li ca axit axetic l
A. 2,5%.
B. O,O9%.
C. O,126%.
D. 1,26%.
Cu 7. Ha tan hon ton m gam hn hp Cu v Mg vo 4OO ml dung dch HNO3 1M thu c dung dch A v 2,24 lt hn
hp kh NO v NO2 (ktc). Cho t t dung dch B gm NaOH O,1M v Ba(OH)2 O,2M vo dung dch A cho n khi thu c
lng kt ta ln nht. Th tch dung dch B ti thiu dng l:
A. 6OO ml.
B. 7OO ml.
C. 5OOml.
D. 83Oml.
Cu 8. Ha tan hn hp bt gm m gam Cu v 2,32 gam Fe3O4 vo dung dch H2SO4 (long, rt d), sau khi cc phn ng kt
thc ch thu c dung dch X. Dung dch X lm mt mu va 5O ml dung dch KMnO4 O,1M. Gi tr ca m l
A. O,62.
B. O,32.
C. 1,6.
D. O,48
Cu 9. Cho 22,4 lt (ktc) hn hp E gm x mol C2H4, z mol C2H2, y mol H2 (dE/He=3,6) qua bnh ng Ni nung nng, sau mt
thi gian phn ng thu c 15,68 lt hn hp kh G (ktc). Dn ton b kh G li chm vo bnh ng dung dch Brom d, khi
lng brom phn ng l 8Og. Gi tr x v y ln lt l
A. O,2 mol v O,3 mol.
B. O,2 mol v O,5 mol. C. O,3mol v O,4 mol.
D. O,3 mol v O,2 mol.
Cu 10. Cho bt Fe vo 2OOml dung dch NaNO3 v H2SO4, phn ng hon thu c dung dch A, 6,72 lt hn hp kh X
gm NO v H2 (c t l mol l 2:1) v 3 gam cht rn khng tan. Bit dung dch A khng cha mui amoni. C cn dung dch A
thu c khi lng mui khan l:
A. 12O,4 gam.
B. 75,O gam.
C. 126 gam.
D. 7O,4 gam.
Cu 11. Cho cc polime: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; poli(vinyl ancol); nha novolac; t visco, t
nitron, cao su buna-S. Trong , s polime c iu ch bng phn ng trng hp l
A. 7
B. 5
C. 6
D. 4
2n+1
R
l
nguyn
t
m
nguyn
t
c
phn
lp
electron
ngoi
cng
l
np
(n
l
s
th t ca lp electron). C cc nhn
Cu 12.
xt sau v R:
(I) Tng s ht mang in ca nguyn t R l 18.
(II) S electron lp ngoi cng ca nguyn t R l 5.
(III) Cng thc oxit cao nht to ra t R l R2O7.
(IV) Dung dch mui natri ca R tc dng vi dung dch AgNO3 to kt ta.
(V) Axit khng c oxi ca R l mt axit mnh..
S nhn xt ng l:
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A. 3
B. 1
C. 2
D. 4
Cu 13. in phn vi in cc tr dung dch cha O,4 mol AgNO3 vi cng dng in 4,32 A, trong thi gian t giy thu
c dung dch X (hiu sut qu trnh in phn l 1OO%). Cho 12,64 gam bt Fe vo X thy thot ra kh NO (sn phm kh
duy nht) v sau cc phn ng hon ton thu c 2O,4 gam cht rn. Gi tr ca t l
A. 8935,2 giy
B. 3574,O7 giy
C. 2685 giy
D. 5361,1giy
(1) KMnO4 + HCl c, nng
(2) SO2 + dung dch KMnO4; \
Cu 14. Cho phn ng sau:
3) H2SO4 c, nng + NaCl;
(4) Fe3O4 + HNO3 long, nng;
(5) Cl2 + dung dch NaOH;
(6) C6H5CH3 + Cl2 (bt Fe, tO); (7) CH3COOH v C2H5OH (H2SO4 c). S cp phn ng thuc loi phn ng oxi ha - kh l
A. 5.
B. 6.
C. 4.
D. 7.
Cu 15. Ha tan hn hp Na2CO3, KHCO3, Ba(HCO3)2 (trong s mol Na2CO3 v KHCO3 bng nhau) vo nc lc thu
c dung dch X v m gam kt ta Y. Chia ton b dung dch X thnh hai phn bng nhau. Phn 1 phn ng va vi dung
dch cha O,O8 mol NaOH. Nh t t dung dch HCl vo phn 2 n khi lng kh thot ra l ln nht th tn ht O,12 mol
HCl. Gi tr m l
A. 1,97O gam.
B. 3,94O gam.
C. 4,925 gam.
D. 7,88O gam.
Cu 16. Nung hn hp rnFeCO3, FeS2 trong bnh kn cha va khng kh(oxi chim 2O% th tch cn li l nit) sau phn
ng hon ton a bnh v nhit ban u, c cht rn duy nht Fe2O3 v hn hp kh;p sut trong bnh sau phn ng bng
67/7O ln so vi p sut trc phn ng.Phn trm ca FeS2 l
A. 16,2%
B. 83.44%
C. 83,8%
D. 15,6%
Cu 17. Cho 31,65g hn hp rn R , RO phn ng va vi m (g) dung dch HCl 14,6% thu c1 mui v 6,72 lit kh H2
(ktc).Bit nng phn trm ca mui trong dung dch l 23,9%. Phn trm khi lng ca R trong hn hp ban u l
A. 38,39%
B. 24,3%
C. 61,61%
D. 75,7%
Cu 18. Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 4OO ml dung dch cha hn hp gm H2SO4 O,5M v NaNO3
O,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch
NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l
A. 24O.
B. 4OO.
C. 12O.
D. 36O.
Cu 19. Cho V lt dung dch Ba(OH)2 O,O1 M vo 1OO ml dung dch Al2(SO4)3 O,1 M, sau khi phn ng hon ton thu c
4,275 gam kt ta. Gi tr ca V l
A. 2,5.
B. O,8.
C. 1,75.
D. 1,5.
Cu 20. Trong cng nghip, khi in phn dung dch NaCl c mng ngn thu c hn hp gm NaOH v NaCl khu vc
catot. tch c NaCl khi NaOH ngi ta s dng phng php
A. kt tinh phn on
B. chit
C. lc, tch
D. chng ct
Khi
bn
m
ure
cho
cy
ngi
ta
khng
bn
cng
vi
Cu 21.
A. NH4NO3
B. phn kali
C. Vi
D. phn ln
Cu 22. Pht biu no sau y khng ng?
A. nh hng ca vng benzen n nhm -OH lm phenol phn ng vi dung dch brom.
B. nh hng qua li gia vng benzen v nhm -OH lm cho phenol khng c phn ng tch nhm OH.
C. nh hng ca vng benzene lm anilin c tnh baz yu hn benzyl amin.
D. nh hng ca vng benzene lm anilin khng lm i mu qu tm m.
Cu 23. Cht hu c X mch h tc dng vi AgNO3 trong NH3, un nng thu c Ag. Hiro ha hon ton X c 2,3imetylbutan-1-ol. X c s cng thc cu to l
A. 3.
B. 4.
C. 5
D. 6.
Vitamin
(Retinol)
l
mt
vitamin
khng
tan
trong
nc
m
ha
tan
trong
du
(cht bo). Cng thc ca vitamin A
A
Cu 24.
CH3

OH
H3C

CH3

CH3

Phn trm khi lng ca hiro c trong vitamin A l:

CH3

A. 11,72%
B. 5,88 %
C. 1O,49%
D. 9,86 %
Cu 25. Trong s cc cht sau: (1) xiclopropan; (2) xiclobutan; (3) propen; (4) propin; (5) benzen; (6) toluen; (7) stiren,
(8)caosu buna-S,(9) caosu buna-N, (1O)thu tinh hu c. C bao nhiu cht c phn ng vi brom trong CCl4?
A. 4
B. 5
C. 6
D. 7
Cu 26. Khi cho kim loi Al tc dng vi HNO3, sau phn ng thu c sn phm kh Y duy nht, bit s phn t HNO3 khng b
kh gp 4 ln s phn t HNO3 b kh. Tng h s ca cc cht (l cc s nguyn ti gin) c trong phng trnh khi cn bng l
A. 77
B. 64
C. 9
D. 14
Cu 27. Cho 22Oml dung dch NaOH xM tc dng vi dung dch cha O,2 mol Zn(NO3)2, c m1 gam kt ta. Cho 28Oml
dung dch NaOH xM tc dng vi dung dch cha O,2 mol Zn(NO3)2, c m2 gam kt ta. Bit m2/m1 = 2/3. Gi tr ca x l
A. 1,2.
B. 1,875.
C. 1,375.
D. 1,225.
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Cu 28. Cho cc khng nh sau:

1.Trong phn t N2 cha 1 lin kt 3, iu kin thng N2 khng tc dng vi kim loi.
2.Nguyn t c cu hnh e phn lp ngoi cng l 4s1 phi nm th 19 trong bng HTTH.
3.Nguyn t c bn knh nh nht trong bng tun hon l hidro.
4. iu kin thng tt c cc kim loi u th rn
5.Cc cht:NaOH, CH4, NH3, NaCl, HCl, H2O, N2, CO2. S cht m phn t ch cha lin kt cng ha tr c cc l 4.
6.CO2 khng duy tr s chy nn c th dng CO2 dp tt tt c cc m chy.
7.Nc kh dng bo qun thc phm chnh l CO2.
S khng nh sai l
A. 3
B. 4
C. 1
D. 5
Cu 29. Cho 5,6 l st tc tc dng vi dung dch H2SO4 4M nhit thng. Tc phn ng khng thay i so vi ban
du khi
A. Dng dung dch H2SO4 5M.
B. Dng 5,6 gam st bt.
un
nng
dung
dch
trn.
C.
D. Tng th tch dung dch H2SO4 4M ln gp i.
Cu 30. Cho cc cp cht sau:
(a) H2S+dung dch Cu(NO3)2
(b) bt lu hunh+thu ngn
(c) H2SO4 c,nng+Ca3(PO4)2
(d) HBr +KI
(e) ZnS+dung dch HCl
(f) Cl2 + C
(g) Ca3(PO4)2 + H3PO4
(h) Si+dung dch NaOH
(i) AgCl+ dung dch HNO3
(j) H3PO4 + K3PO4
(q) SiO2+Mg
(k) Si+Mg
S cp cht xy ra phn ng (k c ) l
A. 1O
B. 9
C. 11
D. 8
Hn
hp
X
gm
hai
axit
cacboxylic
Y
v
Z.
t
chy
hon
ton
m
gam
X,
cho
ton b sn phm chy vo dung dch
Cu 31.
nc vi trong d, thu c 57 gam kt ta, v khi lng dung dch gim 21,66 gam so vi dung dch nc vi trong ban u.
Mt khc 2m gam X tham gia p trng bc ht th thu c 51,84 gam Ag. trung ho ht dung dch cha m gam X cn 27O
ml dung dch KOH 1M. Tn gi ca mt trong hai axit c trong X l
A. axit etanoic
B. axit butanoic
C. axit propanoic
D. axit acrylic
Cu 32. Mt dung dch c cha cc ion O,3 mol Mg2+; O,1 mol Al3+; O,12 mol Zn2+; x mok SO42- ;y mol NO3 ; z mol Cl .
em c cn dung dch, thu c hn hp cc mui rn khan c khi kng 71,27 gam. Khi lng ion nitrat ln hn khi
lng ion sunfat k 15,2 gam. Gi tr ca x, y, z ln lt k:
A. O,1; O,4; O,54
B. O,1; O,4; O,55
C. O,12; O,43; O,54
D. O,12; O,43; O,55
Cu 33. Mt oxit kim loi b kh hon ton cn 1,792 lit kh CO (ktc) thu c m gam kim loi R. Ha tan ht m gam R
bng dung dch HNO3 c nng thu c 4,O32 lit kh NO2 duy nht (ktc). CTPT ca oxit l
A. FeO.
B. CrO.
C. Cr2O3.
D. Fe3O4.
Cu 34. Thi hi nc qua than nng thu c hn hp kh A kh (H2, CO, CO2). Cho A qua Ca(OH)2 d thu c 1,4
gan kt ta cn li hn hp kh B kh (H2, CO). Mt lng kh B tc dng va ht vi 8,96g CuO . Thnh phn % theo th tch
ca CO2 trong A l:
A. 11,11%
B. 33,33%
C. 3O,12%.
D. 2O,OO%
Cu 35. A l dung dch CuSO4 v NaCl. in phn 5OO ml dung dch A vi in cc tr, mng ngn xp bng dng in
I=1OA. Sau 19 pht 18 giy ngng in phn c dung dch B c khi lng gim 6,78 gam so vi dung dch A. Cho kh H2S
t t vo dung dch B cho ti khi phn ng hon ton thu c kt ta v dung dch C c th tch 5OO ml, pH = 1,O. Nng
mol NaCl trong dung dch A l
A. O,15OM
B. O,122M
C. O,144M
D. O,125M
Cu 36. X phng ho hon ton 5OO kg mt loi cht bo cn m(kg) dung dch NaOH 16%, sau phn ng thu c 5O6,625
kg x phng v 17,25 kg glixerol. Gi tr ca m l
A. 149,2187 kg
B. 4OO kg
C. 156,25 kg
D. 14O,625 kg
Cu 37. t chy hon ton 12,5 gam mt hirocacbon X mch h (l cht kh iu kin thng), ri em ton b sn phm
chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 1O8,35 gam kt ta v phn dung dch gim
59,85 gam. S nguyn t hiro trong phn t X l
A. 2.
B. 4.
C. 8.
D. 6.
Cu 38. Hn hp X gm axit glutamic v lysin. Bit:
- Cho m gam X phn ng va vi V lit dung dch HCl 1M.
- Cho m gam X phn ng va vi V/2 lit dung dch NaOH 2M. Phn trm khi lng ca axit glutamic trong X l
A. 66,81%.
B. 5O,17%.
C. 35,O8%.
D. 33,48%.
Cu 39. Hn hp A gm 2 ancol n chc X,Y ng ng k tip nhau trong dy(MX<MY).chia A thnh 2 phn bng nhau:
P1:t chy hon ton thu c 5,6 lit kh CO2(ktc) v 6,3g nc.
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P2:un vi axit sunfuric c 14OOCto thnh 1,25g hn hp 3 ete c s mol l O,O15mol

Hiu sut phn ng to ete ca X,Y l:
A. 45% v 25%
B. 4O% v 4O%
C. 25% v 45%
D. 4O%v 2O%
Cu 40. Thu phn hon ton 1 mol pentapeptit A thu c 431g cc -aminoaxit(no ch cha 1 gc -COOH,-NH2). Khi
thu phn khng hon ton A thu c:Gly-Ala,Gly-gly; Gly-Ala-Val,Vla-gly-gly ; khng thu c Gly-gly-val vVal-Ala-Gly.
Trong phn t A cha s gc ca Gly l
A. 4
B. 2
C. 1
D. 3
Cu 41. Cho cc th nghim sau y:
(1) Nung hn hp NaNO2 v NH4Cl
(2) in phn dung dch CuSO4/c tr
(3) Dn kh NH3 qua CuO nung nng
(4) Nhit phn Fe(NO3)2
(5) Cho kh F2 tc dng vi H2O
(6) H2O2 tc dng vi KNO2
(7) Cho kh O3 tc dng vi dung dch KI
(8) in phn NaOH nng chy
(9) Dn hi nc qua than nng
(1O) Nhit phn KMnO4
S th nghim thu c kh oxi l
A. 7
B. 4
C. 6
D. 5
Cu 42. Cho cc phn ng:
Na2SO3 + H2SO4 Kh X;
FeS + HCl Kh Y
o
t
to
NaNO2 bo ha + NH4Clbo ha Kh Z;
KMnO4
Kh T
Cc kh tc dng c vi nc clo l:
A. X, Y, Z, T
B. X, Y
C. X, Y, Z
D. Y, Z
Tin
hnh
cc
th
nghim
sau:
Cu 43.
(a) Cho Mg vo dung dch Fe2(SO4)3 d;
(b) Dn kh CO (d) qua bt MgO nung nng;
(c) Dung dch AgNO3 vo dung dch Fe(NO3)2 d.
(d) Cho Na vo dung dch CuSO4;
(e) Nung hn hp Al-CuO;
(g) t Ag2S trong khng kh;
(h). in phn dung dch Cu(NO3)2/in cc tr.
(i) Dn kh NH3 qua bt CuO nung nng.
S th nghim khng to thnh kim loi l
A. 2.
B. 4.
C. 3
D. 5.
Cu 44. Oxi ha anehit X n chc bng O2 (xc tc thch hp) vi hiu sut phn ng l 75% thu c hn hp Y gm axit
cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 75 ml dung dch NaOH 1,OM ri c cn dung dch sau
phn ng thu c 5,1 gam cht rn khan. Nu cho hn hp Y tc dng hon ton vi dung dch AgNO3 trong NH3 d, un
nng th thu c khi lng Ag l:
A. 5,4 gam.
B. 1O,8 gam.
C. 27,O gam.
D. 21,6 gam.
Cu 45. t chy hon ton O,5 mol hn hp X gm 2 cht H2NR(COOH) x v CnH2n+1COOH, thu c 52,8 gam CO2 v
24,3 gam H2O. Mt khc, O,1 mol X phn ng va vi dung dch cha a mol HCl. Gi tr ca a l
A. O,O5.
B. O,1O.
C. O,O6.
D. O,125.
Cu 46. Chia V lt (ktc) hn hp kh gm axetilen v hidro thnh hai phn bng nhau. Phn 1: t chy hon ton c 9
gam nc. Dn phn 2 qua ng s ng bt Ni un nng, thu c hn hp kh X. Dn X ln lt qua dung dch d AgNO3
trong NH3 v dung dch d brom ng trong cc bnh A v B ni tip. bnh A thu c 12 gam kt ta. t chy hon ton
lng kh Y i ra t bnh B c 4,5 gam nc. Gi tr ca V v s mol brom phn ng ti a trong B l
A. 22,4 lit v O,1 mol.
B. 22,4 lit v O,2 mol.
C. 11,2 lt v O,2 mol.
D. 11,2 lit v 1,O1 mol.
Cu 47. Cht hu c X mch h c t khi hi so vi heli l 14 .t chy hon ton X trong oxi va ch thu c CO2,
H2O. Bit X phn ng c vi dung dch brom.S cng thc cu to c th c l
A. 5
B. 6
C. 4
D. 7
Cu 48. Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi H2 bng 23. Cho m gam X qua
ng s CuO d nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng
ng s gim 3,2g. Cho Y tc dng hon ton vi lng d dung dch AgNO3/NH3, to ra 48,6g Ag. Phn trm khi lng ca
propan-1-ol trong X l
A. 12,5%
B. 48,9%
C. 16,3%
D. 83,7%
Cu 49. t chy hon ton m (g) mt polime sinh ra t phn ng ng trng hp isopren v acrilonitrin bng lng khng
kh va thu c hn hp kh v hi trong cha 76,8 % nitr (khng kh cha 2O% oxi v th tch cn li l nitr)T l
mt xch isopren vi acrinitrin trong polime l(hiu sut cc phn ng u l 1OO%)
A. 2:3
B. 4:3
C. 1:2
D. 1:3
Cu 50. X l mt phi kim, hp cht kh vi hiro ca X l A; oxit cao nht ca X l B. Bit t khi hi ca A so vi B l
O,425. Cho 35,2 gam B vo 9OO ml dung dch NaOH 1M, tng khi lng cht tan c trong dung dch sau phn ng l
A. 69,4 gam
B. 6O,24
C. 63,28 gam
D. 62,48 gam
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