MOCK TEST PAPER 1 PHYSICS SECTION

CODE
MOCK
TEST
PAPER-I
Time: 3:00 Hours
A.
B.
C.
1.
2.
3.
4.
5.
Max. Marks: 240
VERY IMPORTANT
The question paper consists of 3 section (Section-1 contains Physics, Section-2 contains Chemistry and Section-3
contains Mathematics ). Please fill the OMR answer Sheet accordingly and carefully.
Each Section contains (15 questions in Part-A, 1 questions in Part-B and 4 questions in Part-D).
Please ensure that the Question Paper you have received contains ALL THE QUESTIONS in each Section
and PAGES. If you found some mistake like missing questions or pages then contact immediately to the
Invigilator.
INSTRUCTIONS
PART-A
Q.1 to Q.7 are single correct type questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct. For each question, you will be awarded 3 marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble are darkened. In all other cases, minus one (1)
mark will be awarded.
Q.8 to Q.10 are Paragraph type. Based upon the paragraph 3 single correct type questions have to be answered. Each
of these questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. For each question you will be
awarded 3 marks, if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble are
darkened. In all other cases, minus one (1) mark will be awarded.
Q.11 to Q.15 are multiple correct type questions.Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct. For each question, you will be awarded 5 marks if you have darkened only the
bubble corresponding to the correct answer and zero mark if no bubble are darkened. No negative marks will be awarded
in this section.
PART-B
Q.1 is Matrix Match type question. Each question has Three statements (A, B, C) given in Column-I and
Four statements (P, Q, R, S) given in Column-II. Any given statement in Column-I can have correct matching with one or
more statement(s) given in Column-II. For example, if for a given question, statement B matches with the statement given in
Q and R, then for the particular question, against statement B darken the bubbles corresponding to Q and R in the OMR.
For each row, you will be awarded 3 marks in which you have darkened the bubble(s) corresponding to the correct
answer and additional 1 Bonus marks will be awarded if all the answers are correct.
Thus Q.1 carries a maximum of 10 marks.
PART-D
Q.1 to Q.4 are Integer Type questions. The answer to each question is a upto 4 digit ranging from
0 to 9999. The correct digit below the question number in the OMR is to be bubbled.
For each question, you will be awarded 5 marks if you darken the bubble corresponding to the correct answer and
zero mark if no bubble is darkened.
For example, if for a given question, your answer is 7 or 77 or 777 or 7777, then for the particular question, against
question number you must fill as 0007 or 0077, 0777 & 7777 respectively in the OMR. No negative marks will be
awarded in this section.
6.
7.
Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
8.
The answers of the questions must be marked by shading the circle against the question by dark Black Ball point Pen only.
USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.5, Ti = 48,
Ba = 137, U = 238, Co= 59, B =11, F = 19, He = 4, Ne = 20, Ar = 40 , Mo = 96
[Take : ln 2 = 0.69, ln 3 = 1.09, e = 1.6 1019, me= 9.1 1031 kg ]
Take 0 = 8.85 1012 , g = 10 m/s2 unless otherwise stated
PHYSICS
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.7 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1
Asolid cylinder is rolling with slipping on perfectly rough partAB as shown. It has angular momentum L
about A. Find its angular momentum about Awhen it reaches the top of the part BC which is perfectly
smooth.
C
30
A
(A) zero
(B) L
(C)
L
2
(D)
L
3
Q.2
The escape velocityof a body on a planet is Ve, if we assume the planet to be isolated from other bodies.
The escape velocity if we assume that there are others planets too in the surroundings will be
(A) > Ve
(B) < Ve
(C) = Ve
(D) Data insufficient
Q.3
In a series LCR, ac circuit, the voltage across each of R, L and C is 100 V, and the current is 5A. If
resistance is shorted by means of a conducting wire, the current in circuit will become
(A) zero
(B) 10 A
(C) 20 A
(D) (infinite)
Q.4
1 mole of an ideal gas is taken through the process AB as shown. The maximum temperature of the gas
during AB is 500 K. If work done by Gas is W then (n 2.7 = 1)
P
A
B
V
(A) W < 5000 J

(C) 6000 J < W < 7000 J
2.7V
(B) 5000 J < W < 6000 J

(D) W > 7000 J
Q.5
Initially the radioactivity of a sample is three times that of another.After a half life of one of them, the
combined activity becomes one-third of the initial combined activity. Ratio of their half lives is closer to
(A) log10 1.5
(B) log2 3.6
(C) lone 3.6
(D) loge 1.8
Q.6
In a X-ray tube, the operating voltage V is slightly changes by V. Then if min is the original cut off
wavelength, the spread between k and min changes by :
(A) min
V
V
Mock Test-1 [Paper-I]
(B) min
V
V
(C) min
V
V2
(D) min2
V
V
Page # 2
Q.7
PHYSICS
A body moves with speed 20 m/sec for 10 sec and then with 30 m/sec for some distance. The average
speed may be
(A) 8 m/sec
(B) 15 m/sec
(C) 25 m/sec
(D) all of these are possible
[PARAGRAPH TYPE]
Q.8
Q.9
Q.10
Paragraph for question nos. 8 to 10

A convex lens, a concave mirror and a convex mirror have same
B
A
magnitude of focal length are available. In the figure shown,
these are denoted as optical element E, the real object O and
image (real or virtual) is denoted as I. Three points A, B and C
O
I
are on a straight line as shown.AC is less than three times the
E
O
focal length of optical element. Two trials are conducted giving
results as shown. Position B is the same for both trials.
In trial-I, E can be :
(A) only a convex lens
(B) only a concave mirror
(C) only a convex mirror
(D) convex lens or a concave mirror
In trial-II, E is :
(A) convex lens
(C) convex mirror
E Trial-I
I
Trial-II
(B) concave mirror

(D) both concave mirror and convex mirror are possible
In the case of trial-I, consider the correct element then BC (ie - image distance) can be
(A)
AC
2
(B) =
AC
2
(C)
AC
2
(D) all the three are possible
[MULTIPLE CORRECT CHOICE TYPE]

Q.11 to Q.15 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct.
Q.11
Q.12
Consider a conductor with a cavity as shown. There is a the charge +Q

placed outside and a negative charge q inside the cavity to the left of
the centre of cavity. Now choose the correct statement (S)
(A) Force acting on q must be towards left.
(B) Force acting on +Q will be towards left
(C) Force on + Q will change if q is displaced slightly from its position.
(D) Force on q will change if +Q is displaced slightly from its position.
ABCD is a regular tetrahedron made of six conductors, and is moving
in a region of uniform magnetic field as shown. Now choose the correct
option (S) :
(A) VA < VD
(B) VB = VC
(C) VD > VB
(D) VA > VD
here VA , VB , VC and VD represents potentials at these points.
A
V
D
Page # 3
Q.13
PHYSICS
A force F starts acting on a plank of mass M on which a small block of mass m is kept, then
(All surfaces are smooth)
m
F
(A) The acceleration of m w.r.t. plank is
F
m
(B) The acceleration of m w.r.t ground is
F
m
(C) time taken by m to seperate from M is
2m
F
(D) time taken by m to seperate from M is
2M
F
Q.14
Which of the following will have different time period if taken to the moon ?
(A)Atorsional pendulum
(B)Aphysical pendulum
(C)Aspring-mass system placed vertically
(D) An hourglass clock, which is essentially a vessel filled with liquid emptying through a hole in the
bottom.
Q.15
Agirl stops singing a pure note. She is surprised to hear an echo of higher frequency, i.e. a higher musical
pitch then :
(A) There could be some warm air between the girl and the reflecting surface.
(B) There could be two identical fixed reflecting surfaces, at seperation of
from the girl.

2
(C) The girl could be moving towards a fixed reflector

(D) The reflector could be moving towards the girl.
Page # 4
PHYSICS
PART-B
[MATRIX TYPE]
Q.1 has three statements (A,B,C) given in Column-I and four statements (P,Q,R,S) given in Column-II.Any
given statement in Column-I can have correct matching with one or more statement(s) given in Column-II.
Q.1
Consider a rectangular vessel containing ideal liquid which is

released on an inclined plane which may be rough/smooth.
AB is horizontal,AD is parallel to inclined andAC is the free
surface of liquid.
B
C
D
P
E
F
(A)
(B)
(C)
Column - I
PQ is smooth
PQ is rough ( > tan )
PQ is rough ( < tan )
(P)
(Q)
(R)
(S)
Column - I
Liquid surface is parallel toAB
Liquid surface is parallel toAD
Pressure at E and E are equal
Pressure at E and F are unequal.
PART-D
[INTEGER TYPE]
Q.1 to Q.4 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits) [5 Marks]
Q.1
Q.2
An unknown cell balances 300cm of wire in a potentiometer circuit, but the balance length reduces to
280 cm when a resistance of 28 is added in parallel with the cell.Astandard cell of emf 1.1 V balances
220 cm on the same potentiometer. Find the balance length (in cm) when 48 resistance is connected
across the unknown cell.

A very long straight conducting wire, lying along the z-axis, carries a current of 2A. The integral B.d is
computed along the stright line PQ, where P has the coordinates (2 cm, 0, 0) and Q has the coordinates
( 2cm, 2cm, 0). The integral can be expressed as N 107 in SI units. Find N ?
Q.3
Two identical capacitors with charges Q0 each are connected as shown. Initial seperation between
plates is d0. Now left plate of upper capacitor and right plate of lower capacitor is moved towards left
with speed V in the direction shown. The current in the circuit then can be written as N
Q0 V
. Find N.
d0
+Q
v 0 Q0
+Q0 Q0
v
Q.4
Aparticle starts atAwith initial speed v0 = 10 m/sec. It moves along a circular path under the action of
a variable force which is always directed towards B.Aand B are end poits of a diameter. Find its speed
(in m/sec) when it reaches P.
P
10m/sec
60
B
Page # 5
CHEMISTRY
PART-A
Q.1
A liquid system consists of two immiscible liquids water and n-butyl chloride distills at one atmosphere
pressure. If vapour pressure of water at that temperature is 570 mm of Hg, then the ratio of masses of
water and n-butyl chloride distilled is :
(A) 3 : 1
(B) 0.58 : 1
(C) 1 : 1
(D) 1 : 3
Q.2
The incorrect option among the following is :

Cl
Cl
Cl
>
(A)
(Dipole moment order)
Cl
Cl Cl
(B) (CH3)2 C = C = C (CH3)2 maximum number of 7 atoms are lie in the same plane
(C) CO < CO+ < CO2 (Bond length order)
(D) NH3 > N2H4 (Basic strength)
CH3
Q.3
Zn Hg
H
( i ) CH 3MgBr
O AlCl
(B) HF
(D) (E)
3 (A)
(C)
HCl
(ii ) H O
Se or S
(F)
The compounds (C) and (F) are respectively.

COOH
(A)
H3 C
(C) H3C
,
O
,
O
(B)
H3 C
H3 C
,
H3C
CH3
(D)
H3C
OH
H3C
,
H3C
OH
H3C
H3C
OH
CH3
Page # 6
Q.4
CHEMISTRY
From the graph given below, select the option which correctly matches the orbitals for which the radial
probabilitydistribution is given:
B
A
C
4r (r)
2
(r)
(A) A - 3p, B - 3d, C - 3s

(C) A - 4p, B - 3d, C - 5f
(B) A - 3s, B - 3d, C - 4p

(D) A - 3p, B - 4d, C - 4p
Q.5
During the process of electrorefining of copper, which of the following option is incorrect :
(A) Some metals Ag andAu present as impurity settle as anode mud.
(B) Dil. CuSO4 is used as a electrolyte
(C) Concentration of dil. CuSO4 should be remain same during the process
(D) The impurity of Cu2O is removed.
Q.6
The compound which does not give foul smell when heated with CHCl3 and KOH, is
NH2
(A)
(B) CH3NH2
CH3
O
||
(C) Me C NH 2
(D) NH2 CH2 CH2 OH
CO CO2
FeO
CCO2
500
Q.7
C
CO
Mg O
1000
500
1000
1500
1900 2000
Temperature(C)
Using the Ellingham diagram, show the temperature at which MgO can be reduced to metal by carbon.
(A) below 1500C
(B) below 1120C
(C) above 1900C
(D) below 1600C
Page # 7
CHEMISTRY
[PARAGRAPH TYPE]
On order to analyse phase equilibria involvingonlysolids, thermodynamic data are required for calculation
of equilibrium constant. From the given data, answer the questions that follow.
H combustion of graphite = 394 kJ/mole
Sm graphite = 5.8 J/K mole
H combustion of diamond = 396 kJ/mole

Sm diamond = 2.4 J/K mole
Density of graphite = 2.3 g/ml
Density of diamond = 3.5 gm/ml
Both densities can be assumed to be independent of temperature and pressure. Using the data given and
assuming that heat capacities of the two allotropic forms are approximately same, answer the questions
that follow.
Q.8
The value of G 300 for the reaction C(graphite)

C(diamond) is equal to :
(A) 2 kJ
(B) 104 kJ
(C) 1022 kJ
(D) 3.02 kJ
Q.9
The pressure at which graphite and diamond will be at equilibrium at a temperature of 300 K.
(A) 1 bar pressure
(B) 104 Pa
(C) 106 Pa
(D) 1.7 109 Pa
Q.10
At what temperature can the equilibrium be attained between graphite and diamond at 1 bar pressure.
(A) 500 K
(B) 200 K
(C) 2000 K
(D) At no temperature
Q.11
Which of the following options correctly represent concentration of an aqueous solution of NH3 having
Molarity = 4M and density = 2.068 gm/ml?
(A) Molality of ammonia in solution = 2
(B) Mole fraction of ammonia =
(C) % w/w of NH3 = 4%
(D) % w/v = 6.8%
4
115.11
Q.12
In which of the followingpairs, both the complexes have not the same geometrybut different hybridisation
(A) K2[NiCl4] , K2[Ni(CN)4]
(B) Na3[CoF6], [Co(NH3)6]Cl3
(C) Ni(CO)4 , K2[Ni(CN)4]
(D) [Cu(NH3)4]SO4, [Ni(NH3)6]Cl2
Q.13
Which of the following is/are correct?

(A) CH3 CH = CH CHO undergoes aldol condensation.
O
(B)
yields
as major product when treated with KOH
O
O
(C) Ph CH = CH CHO does not undergo aldol condensation.
(D) When an aldehyde and a ketone undergo cross-aldol condensation, it is the -H of ketone which is
involved in carbanion formation producing major product.
Page # 8
CHEMISTRY
Q.14
Q.15
Which of the following is / are not possible?

(A) NOF3
(B) NF5
(C) OF4
(D) SnCl3
Which of the following would produce iodoform when heated with I2 and NaOH?
(A) Ph CH 2 C CH 3
||
O
(B) CH2 = CH CHO
O
O
||
||
(D) Ph C CH 2 C Ph
(C) CH3 CH CH2 CH CH3
OH
OH
PART-B
[MATRIX TYPE]
Q.1
(A)
Column I (Reaction)
Column II (Major product)
CH2 = C = CH2 H
3O
(P) CH3COCH3
CH2 OH
(B)
CH OH
CH2 OH
(C)
COOH
+
COOH
2
Hg
CH3 C CH
( H 3O )
240C
(Q) CH2 = CH CH2 OH

(R) CO2 is evolved
(S) enol is produced during the reaction which
tautomerises into final product.
PART-D
[INTEGER TYPE]
Q.1 to Q.4 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits)
Q.1
A B2 is a salt of strong base A(OH)2 and weak acid, 'HB'. The saturated solution of AB2 contains 0.6
moles in 2L solution. If pOH of the solution is 5.6 and 90% dissociation of the salt takes place then what
is pKa of weak acid. [Given : log (0.54) = 0.27]
Q.2
s p mixing is not possible in among the following :

C2 , B2 , NO, CO, NO+ , C22+, O22+, O2+, N2 , N2+, N2
[If your answer is 1 so write 0001.]
Q.3
How many moles of HCHO would be used by NH3 to prepare one mole of a compound which is used
in the treatment of urinary infection.Assume 100% efficiency of the reaction.
Q.4
Which of the following will obey Sidewick's E.A.N. rule (or E.A.N. rule) ?
(i) K4[Fe(CN)6]
(ii) K3[Fe(CN)6]
(iii) Ni(CO)4
(iv) Fe(CO)5
(v) [Zn(NH3)4]SO4
(vi) [Cd(NH3)4]SO4 (vii) [Cr(en)3]Cl3
(viii) [Cr(H2O)6]Cl3
(ix) [Mn2(CO)10]
(x) [V(CO)6]
(xi) [Fe(CO)2(NO)2]
[If your answer is 4 so write 0004.]
Page # 9
MATHEMATICS
PART-A
Q.1
Suppose f : R R be a continuous function such that f(3x) = f(x) x R and f(2) = 5, then value
5
of
sgn f (x ) dx is equal to
2
(A) 0
Q.2
(B) 1
(C) 3
(D) 3
Suppose g is the inverse function of a differentiable function f and G(x) =

1
then G'(3) is equal to
125
(A) 1
(B) 2
4
. If f(5) = 3 and
g 2 (x )
f '(5) =
Q.3
(B) (1, 3)
(C) (2, 3)
(D) ( , 0) (2, )

Let v1 , v2 and v 3 are three unit vectors in a plane such that they are equally inclined to each other and

if k1 = v1 v 2 . v 2 v 3 , k2 = v 2 v 3 . v 3 v1 and k3 = v 3 v1 . v1 v 2 then the value of
(k1 + k2 k3) is equal to
(A)
Q.5
(D) 8
If loga (x2 2x) > loga (2x 3), where the point (a, 2) lies between the lines x 2y + 3 = 0 and
x 2y + 4 = 0 then the set of values of x is equal to
3
(A) ,
2
Q.4
(C) 4
3
4
(B)
3
4
(C)
6
4
(D)
9
4
A bag contains three red, six blue and four green dice. 2 dice are selected at random, then the probability
that one dice is blue and other is red given that they are of different colour
(A)
1
4
(B)
2
3
(C)
1
3
(D)
1
2
Q.6
A shopkeeper sells three varities of perfumes and he has large number of bottles of the same size of each
variety in his stock. There are five places in a row in his showcase. The number of different ways of
displaying the three varities of perfumes in the show case are
(A) 240
(B) 210
(C) 150
(D) 90
Q.7
The distance between the directrices of the ellipse (4x 8)2 + 16y2 = x 3 y 10
(A) 12
(B) 16
(C) 18
(D) 20
is
Page # 10
MATHEMATICS
[PARAGRAPH TYPE]
Paragraph for Question no. 8 to 10
Consider the parabola x2 = 4y and circle x2 + (y 5)2 = r2 (r > 0). Given that the circle touches the
parabola at the points P and Q. Let R be the point of intersection of tangents to parabola at P and
Q and S be the centre of circle.
Q.8
Which of the following statement(s) is/are TRUE?

7
(A) Centroid of PQR is 0, .
9
(B) Distance between chord PQ and directrix of the parabola is
4
.
3
40
.
3 3
(D) The common tangents to the circle and parabola intersect at (0, 3).
(C) Area of PQR is
Q.9
The equation of the circle which passes through the vertex of the parabola x2 = 4y and touches it at the
point M ( 4, 4) , is
(A) x2 + y2 10x 18y = 0
(B) x2 + y2 8x 16y = 0
(C) x2 + y2 + 8x = 0
(D) x2 + y2 8y = 0
Q.10
Tangents drawn from the point A(1, 1) to the circle x2 + y2 4x + 6y 1 = 0 touch the circle at the
x 2 y2
2 1
points B and C. If the circumcircle of the ABC cuts the auxiliarycircle of hyperbola
4
b
orthogonally, then b2 is equal to
(A) 1
(B) 2
(C) 3
(D) 5
Q.11
Q.12
Let f(x) = ax2 + bx + c where a, b, c R and a 0. If c2 + 4ac 2bc < 0, then which of the
following is/are correct ?
(A) f(x) = 0 has equal roots
(B) f(x) = 0 has imaginary roots
(C) f(x) = 0 has real and distinct roots
(D) one root of f(x) = 0 lies in ( 2, 0)
Consider f(x) =
cos 1 cos (sin x ) x

sin 3 x
(B) f(x) has removable discontinuity at x =
(A) Lim f ( x ) does not exist

x0
(C) jump of discontinuity at x = is
, then
1
.
3
(D) f(x) is discontinuous at all x = n, n I
Page # 11
MATHEMATICS
Q.13
In ABC, a = 4, b = c = 2 2 . A point P moves within the triangle such that the square of its distance
from BC is half the rectangle contained by its distances from the other two sides. If the locus of P is a
conic, then
(A) locus of P is parabola
(B) locus of P is ellipse with eccentricity
(C) locus of P is hyperbola with eccentricity

Q.14
3
2
2
3
2
(D) centre of conic is 0,
Consider a ABC whose circumcircle is | z | = r in the argand plane with A, B, C be represented by

complex numbers a, b, c respectively. The foot of altitudes from A, B, C meet the opposite side at D, E
and F and the altitudes when produced meet the circle | z | = r at L, M and N respectively then which of
following is/are correct ?
(a 2 b 2 b 2c 2 c 2 a 2 )
3abc
(B) the mirror image of orthocentre of ABC with respect to BC lies on | z | = r.
bc
(C) the mirror image of orthocentre of ABC with respect to BC is
.
a
(D) none of these
(A) centroid of LMN is
Q.15
Tangents are drawn from P( 2, 0) to y2 = 8x, radius of circle (s) that would touch these tangents and the
corresponding chord of contact can be equal to
(A) 4
(B) 4 2 1
(C) 4 2
(D) 4 2 4
PART-B
[MATRIX TYPE]
Q.1 has three statements (A, B, C) given in Column-I and four statements (P, Q, R, S) given in Column-II.
Any given statement in Column-I can have correct matching with one or more statement(s) given in Column-II.
Q.1
Column-I
(A)
Column-2
If , , are roots of x3 x + 2 = 0, then the value of
(A)
1
2
(B)
1
4
(C)
(S)
( ) ( ) + ( ) ( ) + ( ) ( ) is
(B)
In ABC, if incentre I is the mid point of median

through Athen the value of sin
(C)
C
is
2
If z1, z2 C then the maximum value of

is equal to
z1z2 z1z 2
z1z 2
Page # 12
MATHEMATICS
PART-D
[INTEGER TYPE]
Q.1
Let G(x) be a non-negative continuous function on R such that G(x) + G x = 5,

3
1200
then calculate the value of integral
G (x ) dx .
0
2k
tan x
Lim
x 0
2013
k 1
2013
Q.2
Find the sum of an infinite geometric series whose first term is

3
e tan x e x
and whose common ratio is the value of Lim
.
x 0 2 ln (1 x 3 sin 2 x )
[Note : where {k} denotes fractional part of k.]
Q.3
Q.4
If V1 i 2j 3k and V2 ai bj ck where a, b, c {1, 0, 1, 2, 3} then find the number of non
zero vectors V2 which are normal to V1 .
2x
Let A = 5 , B = 2a b
2
3x
5c , C = 5x 1 4x 2
2

and D = 1 be four given matrices, where a, b, c and x R.
4

Given that tr(AB) = tr(DC) x R where tr(A) denotes trace of matrix A , then if
2i
V1 ai bj ck , V2 10j 30k and V3 k then find the value of V1 V2 V3
5
[Note : [k ] denotes greatest integer less than or equal to k.]
Page # 13
MATHEMATICS
ROUGH WORK
Page # 14
CODE
MOCK
TEST
PAPER-II
Time: 3:00 Hours
A.
B.
C.
1.
Max. Marks: 249
VERY IMPORTANT
The question paper consists of 3 section (Section-1 contains Physics, Section-2 contains Chemistry and Section-3
contains Mathematics). Please fill the OMR answer Sheet accordingly and carefully.
Each Section contains (15 questions in Part-A, 1 questions in Part-B and 4 questions in Part-D).
Please ensure that the Question Paper you have received contains ALL THE QUESTIONS in each Section
and PAGES. If you found some mistake like missing questions or pages then contact immediately to the
Invigilator.
INSTRUCTIONS
PART-A
Q.1 to Q.7 are single correct type questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct. For Q.1 to Q.4, you will be awarded 3 marks and for Q.5 to Q.7, you will be awarded
4 marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble are
2.
Q.8 to Q.10 are Paragraph type. Based upon the paragraph 3 single correct type questions have to be answered. Each
of these questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. For each question you will be
awarded 3 marks, if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble are
3.
Q.11 to Q.15 are multiple correct type questions.Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct. For each question, you will be awarded 5 marks if you have darkened only the
bubble corresponding to the correct answer and zero mark if no bubble are darkened. No negative marks will be awarded
in this section.
4.
5.
PART-B
Q.1 is Matrix Match type question. Each question has Three statements (A, B, C) given in Column-I and
Four statements (P, Q, R, S) given in Column-II. Any given statement in Column-I can have correct matching with one or
more statement(s) given in Column-II. For example, if for a given question, statement B matches with the statement given in
Q and R, then for the particular question, against statement B darken the bubbles corresponding to Q and R in the OMR.
For each row, you will be awarded 3 marks in which you have darkened the bubble(s) corresponding to the correct
answer and additional 1 Bonus marks will be awarded if all the answers are correct.
Thus Q.1 carries a maximum of 10 marks.
PART-D
Q.1 to Q.4 are Integer Type questions. The answer to each question is a upto 4 digit ranging from
0 to 9999. The correct digit below the question number in the OMR is to be bubbled.
For each question, you will be awarded 5 marks if you darken the bubble corresponding to the correct answer and
zero mark if no bubble is darkened.
For example, if for a given question, your answer is 7 or 77 or 777 or 7777, then for the particular question, against
question number you must fill as 0007 or 0077, 0777 & 7777 respectively in the OMR. No negative marks will be
awarded in this section.
6.
7.
Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
8.
The answers of the questions must be marked by shading the circle against the question by dark Black Ball point Pen only.
USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.5, Ti = 48,
Ba = 137, U = 238, Co= 59, B =11, F = 19, He = 4, Ne = 20, Ar = 40 , Mo = 96
[Take : ln 2 = 0.69, ln 3 = 1.09, e = 1.6 1019, me= 9.1 1031 kg ]
Take 0 = 8.85 1012 , g = 10 m/s2 unless otherwise stated
PHYSICS
PART-A
Q.1
[3 Marks]
A square loop is placed in an external uniform field as shown in (a). The torque acting is . Now imagine
a branch is removed but still same current in rest of the branches. The new torque about c in (b) will be
B
(a)
(A) zero
(B)
3
4
(b)
(C)
(D)
Q.2
Two electric bulbs with rated powers P1 and P2 at same rated voltage are connected in series across a
source. One of them gives less than rated power. The other one will give
(A) less than the rated power
(B) more than the rated power
(C) equal to the rated power
(D) can be any of the above
Q.3
The mutual inductance of two co-axial coils of small radii at large distance x between them is proportional
to
(A)
Q.4
1
x
(B)
1
x2
(C)
1
x3
(D)
In Young's double slit experiment for d = 0.001 cm, D = 1 m interference pattern is obtained for radiations
of wavelengths 5000A and 5800A. Which of the following is nearest to 3rd maxima for wavelength
5000A
(A) 2nd maxima for 5800A
(B) 3rd minima for 5800A
rd
(C) 3 maxima for 5800A
(D) 3rd minima for 5000
Q.5
1
x4
[4 Marks]
In a standing wave, the phase difference at any time t, between two particles of the medium seperated by
a distance x
(A) depends on x and t
(B) depends on x but independent of t
(C) depends on t but independent of x
(D) independent of both x and t
Mock Test-1 [Paper-II]
Page # 16
Q.6
PHYSICS
Two layers of insulators are kept as shown. Hot surface is maintained at 1000C.ABC is an imaginary
straight line in which D and E are mid points of AB and BC. If l1 < l2 and at steady state temperatures
at D and E are 875C and 600C then
AD B
Hot
surface
k1
l1
(A) k1 > k2
Q.7
k2
cold
surface
l2
(B) k1 = k2
(C) k1 = 1.3 k2
(D) k1 < 1.2 k2
The accuracy of a cesium clock is 1 part in 1011. What can be the maximum difference between two
such clocks operating for about 3200 years (1011 sec.).
(A) practically no difference
(B) 1 sec
(C) 4 sec.
(D) 2 sec.
[PARAGRAPH TYPE]
Consider a cylindrical vessel of radius R and length L. If one molecule is present in it then the motion of
that one molecule can be described by radial and Axial velocities as shown. Now consider N identical
molecules. Each molecule has a mass m.Apply assumptions of KTG, law of equipartition of energy and
answer the following question (K is boltzmann's constant and T is absolute temperature)
vr
va
Q.8
Which of the following is correct expression for rms speed of radial components of the gas sample
(A)
Q.9
(B)
2KT
m
(C)
KT
2m
(D)
3KT
m
Which of the following is correct expression for rms speed of axial componet of gas smaple
(A)
Q.10
KT
m
KT
m
(B)
2KT
m
(C)
KT
2m
(D)
3KT
m
Which of the following expression can be used to give the pressure ?

(A)
mN( v rms a ) 2
2R 2 L
(B)
mN( v rmsa ) 2
r 2 L
(C)
mN( v rms a ) 2
4R 2 L
(D)
2mN ( v rms a )2
R 2 L
Page # 17
PHYSICS
Q.11
A capacitor of capacitance C is connected to two voltmeters A and B. A is an ideal voltmeter having

infinite resistance, while B has resistance R. The capacitor is uncharged and then the switch S is closed
at t = 0, (Assume that battery is ideal)
A
B
(A) readings of B and A will be and zero at t = 0

(B) during time interval (0 t < ) reading of B andAare changing
(C) reading of A and B will be equal at t = RC ln 2
(D) none of these
Q.12
Hydrogen atoms absorbs radiation of wavelength 0 and consequently emit radiations of 6 different
wavelengths of which two wavelengths are greater than 0.
(A) The final excited state of the atoms is n = 4
(B) The initial state of the atoms may be n = 2
(C) The initial state of the atoms may be n = 3
(D) There are three transitions belonging to Lyman series.
Q.13
An sustained interference pattern is formed on the screen, when light from two different monochromatic
sources are allowed to interfere. Then, it is true that,
(A) frequencies of light from the two sources are equal to each other
(B) the sources are coherent
(C) the sources should be located in the same medium
(D) the path difference should either be an even or, an odd multiple of , where is the wavelength of
2
light
Q.14
Athin rigid uniform ciruclar disc rolls without slipping on a horizontal rigid surface (or the ground).At a
certain instant, its position with respect to ground frame is as shown in the figure.
Y'
B
A
Y
O' C
D
Ground frame
X'
X
(A) sector ABC has greater kinetic energy than sector ADC with respect to ground frame
(B) sector BO'C has greater kinetic energy than sector CO'D with respect to ground frame
(C) sector BO'C has the same kinetic energy as sectorAO'B with respect to ground frame
(D) all the sectorsAO'B, BO'C, CO'D andAO'D have same kinetic energy with respect to the centre of
mass frame
Page # 18
Q.15
PHYSICS
A target object is placed at the bottom of a tank of depth 20 m, and filled with a liquid of density500 gm/
cc.Another object of density 100 gm/cc is dropped onto it, from a height of 45 m from the upper surface
of the liquid. (take g = 10 m/s2) (Neglect viscous force)
45m
(A) The second object collides with the target

(B) The seocnd object does not collide with the target
(C) The least separation between object and target is 11.25 m.
(D) The retardation of the object in the liquid is 40 m/s2.
PART-B
[MATRIX TYPE]
Q.1
ColumnAlists different type of methods to use different physical quantites while column B lists name for
instrument that are used in these methods.
Column - I
Column - II
(A)
Determination of g using simple pendulum
(P)
Vernier calipers
(B)
Determination ofYoung's modulus of steel

by Searle' method.
(Q)
Stop clock
(C)
Focal length of a concave mirror using

u v method
(R)
Screw gauge.
(S)
Optical Bench
PART-D
[INTEGER TYPE]
Q.1
Radiation from hydrogen gas excited to first excited state is used for illuminating certain metallic plate.
When the radiation from some unknown hydrogen like gas excited to the same level is used to expose
the same plate, it is found that the de-Broglie wavelength of the fastest photoelectron has decreased
2.3 times. It is given that the energy corresponding to the longest wavelength of the Lyman series of the
unknown gas is 3 times the ionization energy of hydrogen gas (13.6 eV). Find the work function of
metallic plate in eV. (Take (2.3)2 = 5.25).
Page # 19
Q.2
PHYSICS
Two identical smooth balls are projected from points O andAon the horizontal ground with same speed
of projection. The angle of projection in each case in 30 (see figure). The distance between O andAis
100 m. The balls collide in mid air and return to their respective points of projection. If the coefficient of
restitution is 0.7, find the speed of projection of either ball (in m/s) correct to nearest integer.
(Take g = 10 ms2 and
3 = 1.7)
y
u
30
u
30
Q.3
A double slit of separation 1.5 mm is illuminated by white light (between 4000 8000 ). On a screen
120 cm away colored interference is formed. If a pinhole is made on this screen at a distance 3.0 mm
from the central white fringe, some wavelengths will be absent in the transmitted light. How manynumber
of wavelengths will be absent at pin hole.
Q.4
A body of mass m = 4 kg starts moving with velocity v0 in a straight line is such a way that on the body
work is being done at the rate which is proportional to the square of velocity as given by P = v2 where
=
0.693
. Find the time elapsed in seconds before velocity of body is doubled.
2
Page # 20
CHEMISTRY
PART-A
Q.1
[3 Marks]
For two reactions :A B and C D; activation energies are 20Kcal and 30 Kcal respectively. Which
of the following options must be true regarding rate constants K TI and K TII where K TI and K TII are rate
constant for the first and second reactions at temperature T kelvin respectively.
(A)
Q.2
Q.3
K 300
I
K 300
II
K 300
II
K 310
K 310
I
II
(C) 300
300
KI
K II
[Co(dien)Cl3]
Which of the following is correct option for above complex?
(i) fac and mer geometrical isomers
(ii) Optical active geometrical isomers
(iii) Octahedral complex
(iv) Low spin complex
(A) TFTT
(B) FFTT
(C) TTTT
K 450
K 450
I
II
(D) 500
500
KI
K II
(D) FTTT
The correct order of relative rate of acidic hydrolysis of the following compounds is :
O
(I)
(A) I > IV > II > III

(C) I > III > IV > II
Q.4
(B)
K 350
I
O
(II)
O
O
O
(III)
O
F
O
(IV)
O
NH2
(B) IV > III > II > I

(D) I > II > III > IV
[Pt(NC)2(NO2)2] has many total isomers are possible for the complex?
(A) 19
(B) 4
(C) 8
(D) 16
[4 Marks]
Q.5
Identify the statements which is incorrect w.r.t. surface phenomenon.

(A)Asol, prepared by adding excessAgNO3 solution in KI solution when subjected to electro-phoresis
will show coagulation near cathode.
(B) The conductivity of a soap solution decreases steeply at CMC.
(C) Tyndall effect will be more prominent in gold solution as compared to rubber solution.
(D) Extent of physisorption increases with increase in temperature initial and then decreases with
temperature.
Q.6
Which is/are correct option regarding PF5?

(i) All the bond lengths of PF5 are seems to be equal.
(ii) It shows berry pseudo rotation.
(iii) Structure of PF5 is trigonal bi pyramidal and square pyramidal during pseudo rotations.
(iv)All bond angles are not equal
(A) TTTT
(B) TTTF
(C) FTTT
(D) FTTF
Page # 21
CHEMISTRY
O
Q.7
N
2H4 'X' (the most stable product)
EtOH
'X' is :
NH
N
(A)
(B)
NH
N
(C)
NH
(D)
NH
[PARAGRAPH TYPE]
Q.8
Q.9
Q.10

Salt (A) reacts with NaOH gives gas (B) and compound (C), compound (C) on reaction with Zn in the
solution gives gas (B), salt (A) on decomposition gives two neutral oxide (D) and (E), (D) on reaction
with P4 gives dehydrating agent (F).
What is covalency of central atom 'F'?
(A) 5
(B) 4
(C) 3
(D) 2
Hybridisation of salt 'A' is:
(A) sp3
(B) sp2
(C) both (A) & (B)
The oxidation state of central atom in compound 'D' is :

(A) 1+
(B) 2
(C) 1
(D) None
(D) 2+

Q.11
Which of the following statements is/are incorrect regarding defects in solid?

(A) AgBr(s) crystals show both schottky and frenkel defects.
(B) Impurity defect by dopingArsenic in Silicon yields 'P' type semiconductor.
(C) Doping in crystal introduces dislocation defects.
(D) Metal deficient defect can occur with extra anions present in the interstitial voids.
Page # 22
CHEMISTRY
Q.12
Whiich of the following alkene gives same ozonolysis product?
O
CHO
CHO
CHO
Q.13
(A)
(B)
(C)
(D)
Which option(s) is/are correct for SF4?

(A) l.p-b.p & b.p-b.p repulsion
(B) It has see-saw structure
(C) d z 2 orbital is participation in hybridization.
(D) d x 2 y 2 orbital is taking part in hybridization.
Q.14
Consider the reaction given below:
*
CH3 CHDCONH2 + PhCO N H2 Br
2OH
?
The products obtained are :
*
(A) CH3CHDNH2
(B) CH3CHD N H2
(C) PhNH2
Q.15
Which option(s) is/are correct?

(A) K4[Fe(CN)6] has 10 total isomers.
(C) K4[Fe(CN)6] has 7 linkage isomers.
*
(D) Ph N H2
(B) K3[Fe(CN)6] has 10 total isomers.

(D) K3[Fe(CN)6] has 7 linkage isomers.
Page # 23
CHEMISTRY
PART-B
[MATRIX TYPE]
Q.1
(A)
Column-I
Ratio of critical temperature to that
of Boyle's temperature
(P)
Column-II
Dependent on type of gas
(B)
Slope of PV vs V graph at Boyle's

temperature for low to moderate pressure
(Q)
(C)
Slope of compressibility factor(Z) vs

pressure(P) at high pressure and
normal temperature
(R)
is a constant value for any gas
(S)
PART-D
[INTEGER TYPE]
Q.1
How many millimoles of NH3 must be added to one litre of 0.016 M Ag+ solution to just prevent
precipitation ofAgBr when [Br] in the solution is 106 M.
[Given Ksp of AgBr = 1013 M2 and K in stability of Ag(NH3)2+ = 108 M2]
Q.2
(a)
Doubling the concentration of substrate doubles the rate of SN2 reaction.
(b)
Addition of mixture of ethanol and H2O in reaction mixture increases rate of SN1 mechanism.
(c)
Increasing the number of R groups on the C bonded to the leaving group increases the tendency
.
of SN2 reaction.
(d)
Increasing the concentration of nucelophile increase the rate of SN1 reaction.
Write 1 in OMR sheet if the statement is correct and 2 if it is incorrect. For example it all are
correct write 1111 as Answer in OMR sheet.
Q.3
Fe2(SO4)3 where reacts with excess of KCN first give ppt than excess of KCN will give complex (A).
What is primary valency., secondary valency, E.A.N. respectively.
Q.4
Consider the reaction given below :

NH2
NH2
1eq.HNO 2 ;0 5C
?
mild acidic condistion
Find the total number of degree of unsaturation in the main product formed.
Page # 24
MATHEMATICS
PART-A
Q.1
Tangents drawn from every point on the line y x + 2 = 0 to parabola y2 = 4x such that chords of contact
pass through the fixed point, the co-ordinate of this point is
(A) (2, 2)
(B) ( 2, 2)
(C) (2, 2)
(D) ( 2, 2)
Q.2
Radical centre of the circles drawn on the sides of triangle formed by lines 3x 4y + 6 = 0,
x y + 2 = 0 and 4x + 3y 17 = 0 as diameter is
(A) (0, 0)
(B) ( 2, 3)
(C) ( 2, 3)
(D) (2, 3)
Q.3
The product of the series

(1 + cot 7) (1 + cot 9) (1 + cot 11)...(1 + cot 45) (1 cot 52) (1 cot 54)...(1 cot 88) is
(A) 2 21
(B) 220
(C) 219
(D) 218
Q.4
1
The function f is defined for all non-zero real numbers such that 2f(x) + 3f = 5x,
x
then equation f(x) = f( x) is satisfied by
(A) no real numbers
(B) exactly one real number
(C) exactly two real numbers
(D) all non-zero real numbers
Q.5
Let f : [0, ) R be a continuous and strictly increasing function such that

x
f 4 (x) =
f 3 ( t ) dt x > 0. The area enclosed by y = f(x), the x-axis and the ordinates at x = 1 and
x = 4 is
(A)
Q.6
Q.7
17
48
(B)
65
48
(C)
257
48
(D)
235
48
A variable line x cos + y cot = a where a is constant meets the x-axis and y-axis at A and B
respectively. The locus of a point R which divide the line segmentAB externally 3 : 5 is given by
(A) 100 x2 36y2 = 225a2
(B) 100 x2 36y2 = 225a2
2
2
2
(C) 36 x 100 y = 225a
(D) 36 x2 100 y2 = 225a2
n
1
x cos x
,
Let f(x) =
m
tan
x
0
,
x0 .
x0
If f(x) is continuous but non-derivable at x = 0 then

(A) n m
(B) m < n m + 1
(C) n < 2m
(D) n < 2m + 1
Page # 25
MATHEMATICS
[PARAGRAPH TYPE]
[
x
]
,
0
{
x
}
7
7
2 .
For all x , , let f(x) =
1
2 2
x ,
{x} 1
2
[Note : [x] denotes greatest integer less than or equal to x and {x} denotes fractional part of x.]
Q.8
Lim f ( x ) is equal to
x
3
2
(A) 1
Q.9
(B)
Number of solution(s) of the equation f(x) =

(A) 2
Q.10
3
2
(B) 3
(C) 0
(D) does not exist
5
is equal to
2
(C) 4
(D)infinite
If L is the number of points of discontinuity and M is the number of points of non-differentiability

of the function f(x), then (L + M) is equal to
(A) 18
(B) 20
(C) 21
(D) 22

Q.11 Let v1, v 2 , v3 be three vectors such that v 2 v3 15 and v1 1 , v 2 1 , v3 4 .
If v 2 2 v3 = kv1 then k can be

(A) 4
(B) 2
(C) 2
(D) 4
Q.12
If P(, 2) falls inside the angle made by the lines y =

(A)
Q.13
1
3
(B)
1
2
(C)
x
, x > 0 and y = 3x, x > 0 then can be
2
3
4
(D)
5
3
1
x 3 ( x 1)
The function f(x) =

(A) has vertical tangent at x = 0.
(B) area enclosed by curve with x-axis from x = 1 to x = 1 is
3
.
2
(C) is concave up in (0, ).

1
(D) is decreasing for x , .

4
Page # 26
Q.14
MATHEMATICS
Let r be a position vector of a variable point in cartesian xy-plane such that r ( 8i 10j r ) = 40
2
2
and M = max r 2i 3j , m = min r 2i 3j , then (M + m) is less than or equal to
(A) 9
(B) 18
(C) 27
12
Q.15
If the middle term of x sin x

x
(A)
(B)
is
(D) 28
6237
, then the value of sin1 (sin x) is/are
16
(C)
(D)
PART-B
[MATRIX TYPE]
Q.1 has three statements (A, B, C) given in Column-I and four statements (P, Q, R, S) given in Column-II.
Any given statement in Column-I can have correct matching with one or more statement(s) given in Column-II.
Q.1
Column-1
Column-II
(A)
(P)
(Q)
x } dx is equal to
(R)
Let f(x) = x + tan3x and g(x) = f1(x)
(S)
The sum of the coefficients in the expansion of

1
3
15x 15x
3
(B)
012
(17x 17x5 + 3)2013 is
If {x} represents fractional part of 'x'

9
then
{
0
(C)

then the value of 56 g ' 1 .
4
Page # 27
MATHEMATICS
PART-D
[INTEGER TYPE]
Q.1
x 3
Consider f(x) = sin1
, g(x) =
2x 5
Lim f ( x ) g ( x ) =
x0
ax 2 b
f ( x ) g( x ) = 0 and
x 2 5 . If xLim
, then find the value of (5a + 3b2).

4
Q.2
If c < 2 and the system of equations x + y 2z = 0, 2x + y cz and bx + 2by c z = 0

has non-trivial solution then if range of b is (m, n) then find value of 24(n m).
Q.3
If 16l2 + 9m2 = 24l m + 6l + 8m + 1 and the line mx + ly = 1 is tangent to circle S1 = 0,

then the equation of circle S2 = 0 which touches S1 = 0 at (0, 0) and passing through (3, 1) is given by
x2 + y2 ax by + c = 0 then find the value of (3a + 4b + 5c).
Q.4
In ABC, medians AD and BE are drawn. If DAB =

if area of ABC is
and ABE = then find the value of AD

6
3
32
sq. units.
3 3
Page # 28
ANSWER KEY
Mock Test-1
PAPER-1
PHYS IC S
PART-A
Q.1
D
Q.2
A
Q.6
B
Q.7
C
Q.11 AB
Q.12 BCD
PART-B
Q.1
(A) Q, R (B) P, S (C) S
PART-D
Q.1
0288
Q.2
0001
Q.3
Q.8
Q.13
D
B
D
Q.4
Q.9
Q.14
A
B
BD
Q.3
0001
Q.4
0040
Q.5
B
Q.10 C
Q.15 CD
C HE M IST RY
PART-A
Q.1
B
Q.6
C
Q.11 ABD
PART-B
Q.1
(A) P,S
PART-D
Q.1
0003
Q.2
Q.7
Q.12
C
C
ACD
(B) Q,R
Q.2
0002
Q.3
Q.8
Q.13
A
D
ABCD
Q.4
Q.9
Q.14
C
D
BC
Q.3
0006
Q.4
0007
Q.5
D
Q.10 D
Q.15 AC
(C) P,S
M AT HEM AT IC S
PART-A
Q.1
D
Q.6
C
Q.11 CD
Q.2
Q.7
Q.12
D
B
ACD
Q.3
Q.8
Q.13
C
B
BD
Q.4
Q.9
Q.14
B
B
ABC
Q.3
0006
Q.4
0024
Q.5
C
Q.10 D
Q.15 BD
PART-B
Q.1
(A) R , (B) Q , (C) S
PART-D
Q.1
3000
Q.2
HINTS & SOLUTIONS
0002
Page # 147
Mock Test-1
PAPER-2
PHYS IC S
PART-A
Q.1
C
Q.6
D
Q.11 A, B, C
Q.2
Q.7
Q.12
D
D
A, B, D
Q.3
Q.8
Q.13
C
B
A, B
Q.4
Q.9
Q.14
B
A
A, B, C, D
0038
Q.3
0004
Q.4
0008
Q.5
B
Q.10 B
Q.15 B, D
PART-B
Q.1
(A) P,Q (B) R (C) S]
PART-D
Q.1
0003
Q.2
C HE M IST RY
PART-A
Q.1
A
Q.6
A
Q.11 BCD
Q.15 ABCD
PART-B
Q.1
(A) Q,R
PART-D
Q.1
0072
Q.2
Q.7
Q.12
A
B
AB
(B) Q,R
Q.2
1122
Q.3
Q.8
Q.13
D
A
ABC
Q.4
Q.9
Q.14
A
C
AD
Q.3
3635
Q.4
0006
Q.5
Q.10
D
A
(C) PQ
M AT HEM AT IC S
PART-A
Q.1
B
Q.6
D
Q.11 AD
Q.2
Q.7
Q.12
D
B
CD
Q.3
Q.8
Q.13
B
D
ABCD
Q.4
Q.9
Q.14
C
A
BCD
0020
Q.3
0016
Q.4
0004
Q.5
C
Q.10 C
Q.15 BD
PART-B
Q.1
(A) S, (B) Q, (C) P
PART-D
Q.1
0004
Q.2
HINTS & SOLUTIONS
Page # 148
HINTS & SOLUTION
HINTS & SOLUTIONS
Page # 157
Mock Test-1
PAPER-1
PHYS IC S
PART-A
Q.1
[Hint. When it reaches at top part of BC only rotational velocity will be remaining. ]
Q.2
[Hint. Other planets will also exert attractive forces so Ve will be more.
Q.3
[Hint. XL = XC, I =
V
= . ]
R
Q.4
[Hint. W will be less than that calculated for isothermal process.
Wisothermal = 1 (R) (500) ln 2.7 < 5000 J at 500 K.
Q.5
[Hint.
A(tA)
t0
t tA
A0
A0
2
B(tB)
3A 0
3A 0 (2)
t
B
tA
tB
A
1
0
3A 0 (2) t A = (A 0 3A 0 ) . Ans.]
2
3
Q.6
[Hint. min =
Q.7
[Sol.
V
hc
min = 2 and k does not change.
ev
V
Average speed is always less than maximum speed and greater then minimum speed. ]

[Hint.
(i)
Only a concave mirror can form image on same side.
Q.11
[Hint. Force on q due to inner induced charges will be towards left and force on Q due to outer induced
charges will also be towards left.
]
Q.12
[Hint. VA VD = positive

VB = VC as l || v
VD > VB.
]
HINTS & SOLUTIONS
Page # 158
Q.14
[Hint. g will change ]
Q.15
[Hint. vapp > vact only if distance between source and observer decreases.
PART-D
Q.1
Sol.
The emf of the cell or the masured potential difference is proportional to the balance length on the
potentiometer. The emf of the unknown cell is found to be 1.5 V and its internal resistance can be found
as follows :
1 .5
28 = drop across 280 cm of wire
r 28
= 1.4 (in volt)
r = 2
The current through the 48 resilstance, when it is connected across the unknown cell, is
i=
1 .5
A = 0.03A, and the balance length = 200 48 0.03 = 288 cm.
48 2
Q.2
Sol.

B
.d
PAQ

B.d 0 and
B.d

=
RBQ
B.d 0
PCR
0 I (4 10 7 )(2)
R =
=
= 107 S.I. units.
2R 4
16
Q (2,2,0)
A
4 P
C
R
(2,0,0)
I = 2A
Q.4
[Sol.
From conservation of angular momentum about B

2R 10 = RV sin 30
V = 40 m/sec. ]
HINTS & SOLUTIONS
Page # 159
C HE M IST RY
PART-A
Q.1
Sol.
For system ionsisting of two immisible liquids

Psolution = PHo 2O + Pno butyl chloride = 1 atm = 760 mm
Pno butyl chloride = 760 570 = 190 mm of Hg
Also In vapour state
PHo 2O
n ( H 2O )
570
n ( n butyl chloride) = Pno butyl chloride = 190
w H 2O 18
w n butyl chloride 92.5 = 3

w H 2O
w n butyl chloride
Q.2
[Sol.
Bond order :
of CO
3 18 0.58
92.5
1
CO
3
CO+
3.5
1
Bond length Bond order
CO 2
2
Bond length order : CO2 > CO > CO+
Q.3
CH3
CH3
Sol.
O AlCl
3
CH 3
O
CCH2CH2COH
O
Ortho
+
O
CCH2CH2COH
O
O
para
(Major product A)
HINTS & SOLUTIONS
CH3
Hg
Zn
HCl
Clemmenson
Re duction
CH2CH2CH2 COH
O
(B)
HF
Page # 160
CH3
CH3
CH3
H3C
H3C
HO
( i ) CH 3MgBr

( ii ) H3O
C
H2 C
CH2
CH2
(C)
(D)
H
CH3
H3C
CH3
CH3
or
Se
H3C
H3C
(E)
Q.4
Sol.
Q.5
[Sol.
Q.6
Sol.
From the graph

A has 2 radial nodes 4p
B has 0 radial node 3d
C has 1 radial node 5f
During the process of electro-refining of copper, the impurities of silver and gold is removed as a anode
mud. ]
Carbylamine reaction (Isocyanide test) is given by 1 amine
NH2
(A)
Positive isocyanide test
CH3
(B) CH3NH2
O
||
(C) Me C NH 2
Negative isocyanide test
(D) NH2 CH2 CH2 OH

Q.7
[Sol.
(F)
At
T > 1900C
MgO +
C
Mg
+
CO
G = ve
It means above 1900C, MgO can be reduced to metal by carbon.
]
HINTS & SOLUTIONS
Page # 161
Q.8
[Sol.
C(graphite)
C(diamond)
H r H C( graphite) H C( Diamond ) = 394 (396)

= + 2.0 kJ/mol
Sr Sm ( Diamond ) Sm (Graphite) = 2.4 5.8 = 3.4 J/K-mole
G H TS
= 2.0 300 ( 3.4 103)
= 2.0 + 1.02 = 3.02 kJ ]
Q.9
[Sol.
dG = VdP SdT = VdP

G
d(G ) V dP
GP
G = V (P 1)
m
m
(P 105)
0 3020 = d
graphite d diamond
(since 1 atm = 105 Pa)
1
1
6
5
3020 = 12
10 (P 10 )
2 .3 3 .5
3020 2.3 3.5 106
12 1.2
9
= 1.6881 10 Pa
1.7 109 Pa Ans.]
P = 105 +
Q.10
[Sol.
Q.11
Sol.
Equilibrium pressure is 1.7 109 Pa. Hence, at 1 bar, equilibrium cannot be attained at any temperature.]
Molarity of NH3 solution = 4 M
dsolution = 2.068 g / ml
1 L solution has 4 moles of NH3 = 68 g
Mass of solution = 2068 g
Mass of solvent = 2000 g
4
4
m= =2
2
2
X NH3
4
4
2000 115.11
4
18
w
68
100 = 3.3
w 2068
HINTS & SOLUTIONS
Page # 162
w
68
100 = 6.8
v 1000
Q.12
[Sol.
(A)
K2[NiCl4]
K2[Ni(CN)4]
Hybridisation
sp3
dsp2
Geometry
tetrahedral
square planar
(B)
Na3[CoF6]
[Co(NH3)6]Cl3
sp3d2
d2sp3
octahedral
octahedral
(C)
Ni(CO)4
K2[Ni(CN)4]
sp3
dsp2
tetrahedral
square planar
(D)
[Cu(NH3)4]SO4
[Ni(NH3)6]Cl2
dsp2
sp3d2
square planar
octahedral
]
Q.13
Sol.
(A)
CH3 CH = CH CHO Aldol condensation

C
(B)
O
(C)
(D)
Q.14
[Sol.
Ph CH = CH CHO
absent
IntramolecularAldol condensation
O
No Aldol condensation
OH
Aldehyde + Ketone
Cross Aldol condensation
(involved in carbanion)
Due to the absence of vacant of orbital in N and O, NF5 and OF4 are not possible.
Q.15
Sol.
(A) Ph CH 2 C CH 3
||
O
(B) CH2 = CH CHO
Positive iodoform test
Negative iodoform test
(C) CH3 CH CH2 CH CH 3
Positive iodoform test
Negative iodoform test
OH
OH
O
O
||
||
(D) Ph C CH 2 C Ph
HINTS & SOLUTIONS
Page # 163
PART-B
Q.1
Sol.
(A)
3O
CH2 = C = CH2 H
CH 2 C CH 2 (Enolic) CH 3 C CH 3
||
| |
O
OH H
Keto form
CH2 OH
(B)
CH OH
COOH
+
CH3 C CH
240C
COOH
CH2 OH
(C)
CH2
Hg
( H3O )
Kucherov reaction
CH
CH2OH
[Allyl alcohol]
CH 3 C CH
|
|
OH H
CH 3 C CH 3
||
O
enolic
PART-D
Q.1
Sol.
(90% dissociation)
AB2
A+2
0.3 M
0.3(10.9)
pOH = 7
0
0.3 0.9
2B
0
2 0.30.9 M = 0.54 M
1
1
pKa log C
2
2
1
1
pKa log (0.54)
2
2
pKa + log 0.54 = 2.8
pKa = 3.07 3
5.6 = 7
Q.2
[Sol.
Q.3
Sol.
species 15p, due to the less energy gap between s and p orbital sp mixing is possible.
C2 , B2 , NO, CO, NO+, N2 , N2+, N2
Not possible in O22+, O2+
]
(CH2)6N4
Utropine
6HCHO + 4NH3 (CH2)6N4
HINTS & SOLUTIONS
Page # 164
Q.4
[Sol.
K4[Fe(CN)6]
Ni(CO)4
Fe(CO)5
[Zn(NH3)4]SO4
[Cd(NH3)4]SO4
[Mn2(CO)10]
[Fe(CO)2(NO)2]
Will obeys sidewick E.A.N. rule between E.A.N. is equal to nearest inert gas atomic number.
M AT HEM AT IC S
PART-A
Q.1
[Sol.
Given
f(3x) = f(x)
as
x
x
f (3x) = f(x) = f = .......... = f n
3
3
n
n ; 3
x
0
3n
f(3x) = f(0) f(x) is a constant function.
f(x) = 5 x R
sgnf ( x ) = 1.
5
sgn f (x ) dx = dx
Q.2
[Sol.
Q.3
[Sol.
= 3. Ans.]
f(5) = 3 f 1(3) = 5
g(3) = 5
g '(y) =
1
1
g '(3) =
= 125
f ' (5)
f ' (x)
G'(x) =
( 4 )( 2 )
g '(x)
g3 (x)
G '(3) =
8
8
g '(x) =
125 = 8. Ans.]
125
g (x)
3
Since (a, 2) lies between x 2y + 3 = 0 and x 2y + 4 = 0
(a 1) a < 0 a (0, 1)
loga(x2 2x) > loga(2x 3)
x2 2x < 2x 3 x2 4x + 3 < 0
x (1, 3)
.......(1)
but
x2 2x > 0 x(x 2) > 0 x ( , 0) (2, )
2x 3 > 0 x >
HINTS & SOLUTIONS
3
2
..........(2)
........(3)
Page # 165
Q.4
[Sol.
3
2
(1) (2) (3)

x (2, 3). Ans.]

Since v1 , v2 , v 3 are in a plane and equally inclined to each other then angle between any two vectors

is 120 and v1 v2 , v 2 v3 and v3 v1 are parallel
v1 v 2 v 2 v 3 =

v1 v 2

v 2 v3 cos 0 =
3
3
3
=
4
2
2
Similarly
v 2 v 3 v 3 v1 = v 3 v1 v1 v 2 =
]
Q.5
[Sol.
k1 + k2 k3 =
3
4
3
.
4
Ans.
A= event that dice are of different colour.

B = even that one dice is blue and other is red.
6 C1 3C1
13
C 2
P(A B)
1
= 3 6
= . Ans.]
P( B / A ) =
3
4
4
6
P(A)
C1 C1 C1 C1 C1 C1 3
(13 C 2 )
Q.6
[Sol.
Case-I:
3 alike and 2 different perfume bottles
3C
2C 2
5!
= 60.
3!
Case-II :
2 alike of one kind, 2 alike of another kind and one of third kind
3C
5!
1C
2
1
2! 2! = 90.
Total ways of arranging = 150. Ans.]
Q.7
[Sol.
(4x 8)2 + 16y2 = x 3 y 10 2

(x
2)2
y2
1
=
2
HINTS & SOLUTIONS
x 3 y 10
4
Page # 166
e=
1
2
a
ae = distance from (2, 0) to x 3y 10 = 0
e
2a
2 0 10
a
=
= 6.
2
2
3a
= 6 a = 4.
2
Distance between directrices =

Q.8
[Sol.
(i)
8
2a
= 1 2 = 16. Ans.]
e
Putting x2 = 4y in equation of given circle, we get 4y + y2 10 y + (25 r2 ) = 0

y2 6 y + (25 r2 ) = 0
As parabola is tangent to circle, so discriminant of above equation must be zero.
36 = 4(25 r2) r = 4 = radius of circle.
Let y = mx + c be tangent to x2 = 4y, so on solving we get
x2 4mx 4c = 0
2 , 1
Put discriminant to zero, we get m2 = c (condition of tangency)
3 3 Q
y = mx m2 is tangent to parabola x2 = 4y .
But by applying condition of tangency of above tangent with the given circle, we get
| 5 m2 |
1 m2
4 m4 6m2 9 = 0 (m2 3)2 = 0 m =
S
M
2,1
P 3 3
x
O
R (0, 3)
3.
2 1
2 1
2 1 Q 2 , 1
, 2 i.e. P
.
, &
Points of contact to the parabola will be P
, 2 & Q
3 3
3 3
m2 m2
m1 m1
Equation of common tangents will be y = 3x 3 which intersect at R (0, 3)
1
.
3
Equations of latus-rectum and directrix of parabola will be y = 1 and y = 1 respectively which are at
Center of circle is S(0, 5) & equation of chord PQ is y =
distances
4
1 14
2
and respectively . Also distance SM = 5 = .
3
3 3
3
7
20
and area of PQR is
Clearly centroid of PQR is 0,
.]
6
3 3
Q.9
[Sol.
y
x2 = 4y
M
( 4, 4)
The equation of tangent at M( 4, 4) to the parabola x2 = 4y, is
O (0,0)
x ( 4) = 2 (y + 4) 2x + y + 4 = 0
Let the required circle be (x + 4)2 + (y 4)2 + (2x + y + 4) = 0
As above circle passes through (0,0), so 16 + 16 + (4) = 0 4 = 32 = 8
Hence required equation of circle is x2 + y2 8x 16y = 0 Ans.
]
HINTS & SOLUTIONS
Page # 167
Q.10
[Sol.
Clearly circumcircle of the ABC is (x 1) (x 2) + (y + 1) (y + 3) = 0

x2 + y2 3x + 4y + 5 = 0
.....(1)
x 2 y2
2 1 is x2 + y2 = b2 ....(2)
Also auxiliary circle of hyperbola
4
b
A
(1,1)
By using condition of orthogonality, we get b2 = 5 Ans.
]
Q.11
[Sol.
(2, 3)
f(x) = ax2 + bx + c
f(0) = c
f( 2) = 4a 2b + c
f(0) f( 2) = c2 + 4ac 2bc < 0
one root lies between 2 and 0. Ans.]
Q.12
[Sol.
Lim f ( x ) DNE
x0
LHL at x =
Lim
cos 1 cos (sin x ) x

3
Let
x=t
sin x
sin t t
1
=
3
t0
sin t
6
RHL at x =
sin x ( x )
Lim
x
sin 3 x
put
x=t
= Lim
x
sin x ( x )
sin 3 x
( sin x > 0 as x )
Lim
= Lim
t 0
Q.13
[Sol.
( sinx < 0 as x +)
sin t t
1
= .
3
6
sin t
Jump of discontinuity =
1 1 1
= . Ans.]
6 6 3
PM = K
x
y
=1
2 2
x+y=2
Equation of AB :
A(0,2)
x y
=1
2 2
x+y=2
Equation of AC :
1hk2 h k2

= k2
2
2
2

((k 2) h) (k 2 + h) = 4k2
(k 2)2 h2 = 4k2
k2 + 4 4k h2 = 4k2
3k2 + h2 + 4k 4 = 0
HINTS & SOLUTIONS
P(h,k)
B(2,0)
C(2,0)
Page # 168
2 4
h2 + 3 k k = 4
3
2 4
h2 + 3 k = 4
3 9
2
4
2
h2 + 3 k = 4 +
3
3
k
2
h
3
= 1.
16 3 16 9
2
y
2
x
3
16 3 16 9 = 1
e=
Q.14
[Sol.
2
and centre =
3
2
0,
, Ans.]
3
BOC = 2A
in ABE, ABE =
A
2
M(m)
A(a)
AOM = 2A
c
ei 2 A
b
a
ei ( 2 A )
m
E
O
N(n) F
B(b)
C(c)
L(l)
ac
e i = 1
bm
ac
m=
.
b
Similarly
bc
l=
a
ab
n=
.
c
a 2 b 2 b 2c 2 c 2a 2
. Ans.]
centroid of LMN =
3abc
Q.15
[Sol.
Point P( 2, 0) clearly lies on directrix of y2 = 8x. Thus, slopes of PAand PB are 1 and 1 respectively.
Equation of PA:
y=x+2
Equation of PB :
y=x2
HINTS & SOLUTIONS
Page # 169
Equation ofAB :
x2=0
Let the centre of circle be (h, 0) and radius be r
h2
h2
=r
2
1
h2 + 4 + 4h = 2(h2 + 4 4h)
h2 12h + 4 = 0
=
P(2,0)
h=6 4 2.
O (h,0)
radius = h 2 = 4 2 4 ; 4 2 4 . Ans.]
PART-B
Q.1
[Sol.
(A)
(B)
x3 x + 2 = 0
+ + = 0 ; = 1 ; = 2
( ) ( ) + ( ) ( ) + ( ) ( ) = 2
= ()2 3 = 0 3( 1) = 3. Ans.
AB AI
=
BD
ID
1
c
=
a 1

2
a = 2c
similarly b = 2c
7
a 2 b2 c2
cos C =
=
8
2ab
1 2 sin2
(C)
sin
C
B
C
7
C
1
=
sin2
=
2
8
2
16
C 1
= . Ans.
2
4
z1 = z1 ei1
z2 = z 2 e i 2
2 z1z 2 cos 1 2
z1z2 z1z 2
=
z1z 2
z1z 2
Maximum value = 2 when cos (1 2) = 1. Ans.]
HINTS & SOLUTIONS
Page # 170
PART-D
Q.1
Sol.
G(x) + G x = 5
3
replace x x +
.... (1)
1
3
1
2
Gx + Gx = 5
3
3
From (1) and (2)

2
G(x) = G x
3
... (2)
G(x) is periodic with period =

1200
2/3
I = G ( x ) dx = 1800
2
.
3
G( x) dx
1/ 3
2/3
I = 1800 G ( x ) dx G ( x ) dx
0
1
/ 3

I
I
1
2
1
Put x = y + in I2.
3
1/ 3
1/ 3
G ( x ) dx G y 1 dy
I = 1800
3
0
0
1/ 3
I = 1800 5 dx
0
I = 1800
5
= 3000 Ans.]
3
Q.2
[Sol.
2k
tan x
= Lim x
Lim
x 0 tan x
x0
2013
k 1
2013
x
x
x
Lim
= Lim
= 1.
x 0 tan x
tan x x 0 tan x
1st term of G.P. = 1
3
3
3
e x e tan x x 1 tan 3 x x 3
common ratio = Lim

x 0 2 ln (1 x 3 sin 2 x )
x 3 sin 2 x
3
2
x sin x
HINTS & SOLUTIONS
Page # 171
1
tan x x
= xLim
2 0 x3
Q.3
[Sol.
S=
tan 2 x x 2 x tan x 1 1
= 3 = 1
2
2 3
x
2
1
= 2. Ans.]
1
1
2

V1 V2 0 a 2b + 3c = 0
Now if a = 1 then 3c 2b = 1.
c = 1 and b = 1 only.
a = 1; b = 1 = c.
if a = 0 then 2b = 3c
b=c=0
Hence V 0i 0j 0k is Null vector..

2
a = b = c= 0 is rejected.
If a = 1 then 2b 3c = 1
b = 1 and c = 1 and b = 2 and c = 1 satisfy it.
If a = 2 then 2b 3c = 2
b = 1 and c = 0 satisfy it.
If a = 3 then b = 0 and c = 1
and b = 3 and c = 1 satisfy it.
6 such vectors are possible. ]
Q.4
[Sol.
4ax
AB = 10a
6ax 2
2bx 10cx
5b
25c
3bx 2 15cx 2
10x 2 8x 2
2
DC = 5x 1 4 x
20 x 4 16x 2
Since, tr(AB) = tr(DC) x R
4ax 5b 15cx2 = 10x 1 + 16x2 x R
4a = 10 ; 5b = 1 ; 15c = 16
5
1
16
;b= ;c=
.
2
5
15
5
1 16
V1 i j k
2
5
15
2
V2 i 10j 30k
5
V k
a=
5 2 1 5 16 15

5
2 1
2
= 25
V1 V2 V3 = 2 5 10
30 = 10
2
5 5
25
0
0
1

V1 V2 V3 = 24. Ans.]
HINTS & SOLUTIONS
Page # 172
PAPER-2
PHYS IC S
PART-A
Q.1
Sol.
Force acting on wires will not change hence about c remains same.
Q.2
Sol.
Voltage across the other one can be greater equal or less than rated.
Q.3
Sol.
1
0iR 2
2
R
=
for x < < R.

x3
2( R 2 x 2 ) 3 / 2
Q.4
Sol.
nD
d
1 D
y = n
2 d
Q.5
Sol.
In a loop they have no phase difference but consecutive loops have a difference of .
Q.6
Sol.
TA TB
= TD
2
(TB TC )k 2 A
TB TC
(TA TB )k1A
= TE and
=
.
l2
2
l1

[Hint. There are two degrees of freedom along radial direction and only one degree of freedom along axial
direction. ]
Q.11
Sol.
Voltage across C changes during charging hence VA and VB both cahnges.

VA = VB
t
1 e E
E
= 2
t = RC ln 2.
Q.14
Sol.
Upper portion particles have greater speed then lower portion particles.
HINTS & SOLUTIONS
Page # 173
Q.15
[Hint. ma = fup mg
v
ma = g v b g
b

a = g 1 then apply v2 = u2 + 2as.]
b
PART-D
Q.1
Sol.
K1 = 3 MeV
we have,
10.2 = W + Kmax, 1
and
10.2Z2 = W + Kmax, 2
Also
de-Broglie =
1
2 =
...(i)
...(ii)
h
2mK
K2
K1 = 2.3
K2 = 5.25 K1
...(iii)
Also 10.2 Z2 = energy corresponding to longest wavelength of teh Lyman series = 3 13.6
Z=2
From equations (i), (ii) and (iii)

W = 3 eV
Q.2
Sol.
The collision does not alter the vertical component of the velocity of either ball, so
50
50
2u sin 30
+
=
u cos 30
0.7 u cos 30
10
Q.3
Sol.
u 38 m/s
In a double slit interference pattern, the distance x of dark fringe from the central achromatic fringe is
x=
(2n + 1) , n = 0,1,2, .....

d
2
75000
(where n = 0,1,2, ....)
2n 1
Thus in the range 4000 8000 the absent wavelengths are 6818, 5769, 5000, 4421.
Q.4
Sol.
P = v2
mdv
v = v2
dt
2 v0
v0
dv
dt
v m 0
HINTS & SOLUTIONS
Page # 174
ln2 =
t=
t
m
m ln 2
4 2
0.693
0.693
t = 8 seconds
t=
C HE M IST RY
PART-A
Q.1
Sol.
A B
C D
E a I 20 KCal
E a II 30 KCal
E a I E a II
K TI > K TII
K 300
K 300
I
II
K 350
K 350
I
II
Also
K 310
K 310
I
II
300 <
300
KI
K II
K 350
K 300
I
II
300 )
( Since K 350
II K II
&
K 450
K 450
I
II
500
500
KI
K II
K T2
K (when T2 > T1) will be higher for the reaction which has higher Ea.
T1
Q.2
[Sol.
Q.3
Sol.
[Co(dien)Cl3]
Coordination number = 6, Hybridisation : d2sp3
It can show fac-mer isomerism due to presence of plane of symmetry it's isomer are optically inactive.]
Rate of acidic Hydrolysis Stability of Carbocation
H
O
O
O
O
O
H
Intermediate
carbocation
I
Stability of carbocation
I F OR NH 2
Relative rate
O
(I)
(II)
HINTS & SOLUTIONS
O
NH2
(III)
O
OR
(IV)
F
Page # 175
Q.4
[Sol.
Linkages
[Pt(CN)2 (NO2)2]
[Pt(CN)2(NO2) (ONO)]
[Pt(CN)2(ONO)2]
[Pt(CN)(NC)(NO2)2]
[Pt(CN)(NC)(NO2)(ONO)]
[Pt(CN)(NC)(ONO)2]
[Pt(NC)2(NO2)2]
[Pt(NC)2(NO2)(ONO)]
[Pt(NC)2(ONO)2]
All are optically inactive.]
Q.5
Sol.
(A)
(B)
(C)
(D)
Geometrical isomer
2
2
2
2
3
2
2
2
2
AgI / Ag+ positively charged solution (excess AgNO3)

Factual information
Tyndall effect is more dominating in lyophobic solution
Extent of physisorption decreases with increase in temperature.
Q.6
Fa
F
[Sol.
Fb
F
P
Fa
Fb
F
F
square pyramidal
Fa
P
F
Fa
Due to the berry - pseudolation it seems to like all the PF bond length in PF5 are same.]
Q.7
OH H H N
Sol.
H2 N
NH
N
Q.8,9,10
[Sol. NH4NO3 (A) + NaOH NH3(B) + H2O + NaNO3 (C)
O
P
N2O + H2O
(D)
N2O + P4 P4O10 + N2
Covalency of phosphorous is 5.
N2O Oxidation state of N is +1
NaNO3 + Zn + 2NaOH Na2ZnO2 + H2
NaNO3 on reduction gives NH3 gas(B)]
HINTS & SOLUTIONS
O
O
O
O
O
P
O
Page # 176
Q.11
Sol.
Doping as by Si yield 'n' type semiconductor

Anion can not occupy interstitial voids as anion is bigger in size.
Q.12
O
Sol.
(A)
Ozonolysis
O
O
O H
H
(B)
O O
OO
O
H
H
(C)
O O
O O
H
O
O
OO
O
(D)
Ozonolysis
O
O
Q.13
F
[Sol.
S
F
F
sp3d, dz2 orbital take part in hybridisation
Q.14
Sol.
*
/ OH
CH3CHDCONH2 + PhCO N H2 Br
2
Hoffmann Degradation
(Hoffmann Bromamide test)
*
CH3 CHD + NH2 + Ph N H2
HINTS & SOLUTIONS
Page # 177
Q.15
[Sol.
K4[Fe(CN)6] and K3[Fe(CN)6]

7 linkage isomers and total 10 isomers ]
PART-B
Q.1
Sol.
(A)
(B)
(C)
8 a
TC 27 Rb
8
1
a
TB
27
Rb
At Boyle's temperature ( for low to moderate pressure) gas behaves likes an ideal gas
Slope of PV v/s V curve = 0
At high pressure, pressure correction terms is negligible, hence
Pb
RT
Z > 1 , depends on type of gas (B)
Z=1+
PART-D
Q.1
Sol.
To just prevent precipitating ofAgBr

[Ag+] [Br] = Ksp
[Ag+] 106 = 1013
[Ag+]left = 107
Let the moles of NH3 added be 'a'
Ag+ +
2NH3
Intial conc.
0.016
a
at equilim
107
a 2 0.016
108 =
Ag(NH3)2+
0
0.016
K = 108
0.016
10 7 (a 2 0.016) 2
0.016
= 0.0016
10
a 2 0.016 = 0.04
a = 0.072
Millimoles of NH3 = 72]
(a 2 0.016)2 =
Q.2
Sol.
(a)
(b)
(c)
Rate of SN2
Rate = K [Substrate] [Nucleophile]
So Doubling the concentration of substrate dobles rate of SN2 reaction.
SN1 is favoured by protic solvent (as it favours the formation of intermediate carbocation)
Ethanol + H2O H+ (protic solvent)
SN2 increasing number of R groups on C bonded to leaving group decreases tendency of SN2
Rate of SN2
HINTS & SOLUTIONS
Page # 178
(d)
Q.3
[Sol.
R
|
R
C
X
CH3X > RCH2X > R CH X >
|
|
R
R
Increasing concentration of nucleophile does not effect rate of SN1
Rate = K [Substrate]
SN1 is independent of nucleophile concentration.
Fe2(SO4)3 + KCN(Xs)
K3[Fe(CN)6] (A)
Oxidation state (Primary valency)= 3
Coordination numbers (Secondary valency) = 6
Q.4
NH
N
[Ans.
N
M AT HEM AT IC S
PART-A
Q.1
[Sol.
Let P (t + 2, t) be a point on y x + 2 = 0.
Tangents are drawn to parabola y2 = 4x from P(t + 2, t)
chord of contact is given by
yy1 = 2(x + x1)
yt = 2(x + t + 2)
t
(2 y) = 0
2
point is ( 2, 2). Ans.]
(x + 2) +
Q.2
[Sol.
Q.3
[Sol.
Radical centre is the point of intersection of perpendicular lines i.e., orthocentre of triangle. Since the
triangle formed by given lines is a right .
Orthocentre will be point of intersection of 4x + 3y 17 = 0 and 3x 4y + 6 = 0 i.e., (2, 3). Ans.]
Using (1 + cot ) (1 cot (45 + )) = 2
The given expression simplifies to (1 + cot 45) 219 = 220. Ans.]
Q.4
[Sol.
1
2f(x) + 3f = 5x
x
1
x
HINTS & SOLUTIONS
.........(1)
Page # 179
5
1
2f + 3f(x) =
x
x
Solving (1) and (2)
.......(2)
15 10 x 2
5x
f(x) = f( x)
f(x) =
15 10 x 2
15 10 x 2
=
5x
5x
3
2
(15 10x2) = 0 x2 =
2
5x
3
. Ans.]
2
x=
Q.5
x
[Sol.
f 4(x) =
t f
2 3
( t ) dt
differentiating both sides wrt x,

4 f 3(x) f '(x) = x2 f 3 (x)
x2
4
Integrate both sides :
f '(x) =
x3
C , since f(0) = 0
f(x) =
12
C = 0.
f(x) =
x3
12
4 3
x3
x
dx +
A=
dx
12
12
1
0
x4
A=
48
1
0
x4
48 0
257
1 4
A=
=
. Ans.]
48
48 48
HINTS & SOLUTIONS
Page # 180
Q.6
[Sol.
3 0 5 a sec
h=
35
h=
B(0, a tan )
5a
sec
2
.........(1)
k=
3 a tan 5 0
35
k=
3a
tan
2
tan2
2
x
R(h,k)
........(2)
2
sec2
A(a sec, 0)
O
2 h 2k
= =1
5a 3a
3
B(0, a tan)
A(a sec, 0)
4h
4k
2 = 1.
2
25a
9a
2
2
36x 100y = 225a2. Ans.]
R(h,k)
Q.7
[Sol.
1
x n cos
1
x
x n m cos
Lim
= xLim
m
0
x 0 tan x
x
m
x
x
But
n m > 0 so that f(x) is continuous at x = 0

f(x) is non-derivable at x = 0, so
1
x n cos
x
f '(0) = Lim
= Lim x n m 1 cos
m
x 0 tan x
x0
x
m
x x
x
n m 1 0 for f '(0) not existing
n m 1. Ans.]
[Sol.
y
7/2
3
5/2
2
3/2
1
7 3 5 2 3 1 1 0
2
2
2
2
HINTS & SOLUTIONS
1 1 3 2
2
2
5 3 7
2
2
Page # 181
L = 7, M = 14
(L + M) = 21. Ans.]
Q.11
[Sol.

v 2 v3 15
v 2 v3 sin 15
sin =
15
4
cos = .
4
v 2 2v3 kv1
v 2 2v3 k 2 v12
v22 4v32 4v 2 v3 = k 2 v12
16 + 4 4 v2 v3 cos = k2
1
= k2
4
k2 = 16 k = 4. Ans.]
20 4 (1) (4)
Q.12
[Sol.
We must have
2 3 < 0 ( 3) < 0
(0, 3)
.......(1)
y-axis
2
> 0 > 0
2
2
and
< 0 or >
(1) (2) gives
1
2
y=3x
P(, 2)
O(0,0)
y=
x
2
x-axis
........(2)
1
, 3 . Ans.]
2
Q.13
[Sol.
f(x) =
1
x 3 ( x 1)
f '(x) =
1
2
3x 3
4x 1
f(x) is increasing for x >
Local minima at x =
1
1
and decreasing for x < .
4
4
1
4
HINTS & SOLUTIONS
Page # 182
4 3 1 3
f '(x) = 3 x 3 x
f '(x) does not exist at x = 0
f ' (0) and f '(0+) both tends to .
vertical tangent at x = 0.
2 2x 1
.
2
x
9x 3
f "(x) =
1
(Inflection point)
2
f "(x) = 0 at x =
Graph of f(x) is
1/4
1
4
3
A = x x 3 dx +
1
3 3 3 4
A = x7 x3
7
4
(1,0)
1/2
1
4
x 3 x 3 dx
3 3 3 4
+ x7 x3
7
4
3 3
3 3
+
A=0
7 4
7 4
A=
12 21 9
28
28
A=
42
3
= . Ans.]
28
2
Q.14
[Sol.
r xi yj
r 8i 10j r = 40
x2 + y2 + 8x 10y + 40 = 0
circle with centre C( 4, 5) and radius = 1.
Let
M = max r 2i 3j
m = min ( x 2) 2 ( y 3) 2 =
(M + m) = 18. Ans.]
Q.15
I & SOLUTIONS
HINTS
(4,5) C
2
2
= max ( x 2) ( y 3) =
P(2,3)
8 1
8 1
Page # 183
[Sol.
Middle term
= 12C
sin6x =
x6
6237
sin x
=
16
x
3
2
sin x =
sin1 sin x =
. Ans.]
3
PART-B
Q.1
[Sol.
(A)
Put x = 1 to get sum of the coefficients 1

3
9
(B)
x } dx =
2012
(3)2013 = 3. Ans.
x dx
(C)
4
9
1
0 dx 1 dx 2 dx = 18 13 = 5. Ans.
1
4
0
32
3
2

f = 1
4
4
f '(x) = 1 + 3 tan2x sec2 x
f ' = 1 + 3(1)2
4
= 7.
1
1

g ' 1 =
=
7
4 f '
4

56 g ' 1 = 56 = 8. Ans.]
7
4
HINTS & SOLUTIONS
Page # 184
PART-D
Q.1
[Sol.
Lim f ( x ) g ( x ) = 0
x 3
Lim sin 1
x
2x 5 6
ax 2 b

Lim sin 1 2
x
x 5 6
Hence sin1(a) =
a=
1
2
x 3
sin 1
= sin1
Now, as Lim
x0
2x 5
3

5
ax 2 b
3
= sin 1
Lim sin 1 2
x 0
5
x 5 4
b
sin 1 = tan1 1 tan1
5
3

5
1
b
sin 1 = sin 1
5
50
Q.2
[Sol.
1
1
b2 =
2
2
b=
5a + 3b2 =
5
3
+ = 4. Ans.]
2
2
The given system is consistent if

1
1 2
2
1 c = 0
=
b 2b c
3bc + c 10b = 0
10 b
3b 1
Since c < 2
c=
10 b
<2
3b 1
10b 6b 2
0
3b 1
HINTS & SOLUTIONS
Page # 185
4b 2
0
3b 1
1 1
b ,
3 2
m=
1
1
,n=
3
2
5
6
24 (n m) = 20. Ans.]
nm=
Q.3
[Sol.
16l2 + 9m2 = 24lm + 6l + 8m + 1

25 (l2 + m2) = (3l + 4m + 1)2
3l 4m 1
=5
l 2 m2
Equation of S1 = 0 is (x + 4)2 + (y + 3)2 = 52
S1 : x2 + y2 + 8x + 6y = 0
Equation of family of circle touching S1 = 0 at (0, 0) is given by
S2 : (x 0)2 + (y 0)2 + (4x + 3y) = 0
S2 = 0 passes through (3, 1)
9 + 1 + (12 + 3) = 0
10
2
=
.
15
3
S2 : x2 + y2
8x
2y = 0
3
8
;b=2;c=0
3
3a + 4b + 5c = 8 + 8 + 0 = 16. Ans.]
a=
Q.4
[Sol.
Area of ABG =
1
Area of ABC
3
1 32
1
AG BG =
3 3 3
2
32
1
( AG ) ( AG cot 60) =
9 3
2
A
30
64
=
9
(AG)2
8
AG =
3
2
AD = AG..
3
AD = 4. Ans.]
HINTS & SOLUTIONS
E
60
B
G
D
Page # 186

MOCK TEST PAPER 1 PHYSICS SECTION

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MOCK TEST PAPER 1 PHYSICS SECTION

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CODE

Max. Marks: 240

(A) W < 5000 J

(B) 5000 J < W < 6000 J

Mock Test-1 [Paper-I]

Paragraph for question nos. 8 to 10

(B) concave mirror

(D) all the three are possible

[MULTIPLE CORRECT CHOICE TYPE]

Consider a conductor with a cavity as shown. There is a the charge +Q

Mock Test-1 [Paper-I]

(A) The acceleration of m w.r.t. plank is

(B) The acceleration of m w.r.t ground is

(C) time taken by m to seperate from M is

(D) time taken by m to seperate from M is

from the girl.

(C) The girl could be moving towards a fixed reflector

Mock Test-1 [Paper-I]

Consider a rectangular vessel containing ideal liquid which is

Mock Test-1 [Paper-I]

The incorrect option among the following is :

(Dipole moment order)

The compounds (C) and (F) are respectively.

Mock Test-1 [Paper-I]

(A) A - 3p, B - 3d, C - 3s

(B) A - 3s, B - 3d, C - 4p

(D) NH2 CH2 CH2 OH

Mock Test-1 [Paper-I]

H combustion of graphite = 394 kJ/mole

Sm graphite = 5.8 J/K mole

H combustion of diamond = 396 kJ/mole

The value of G 300 for the reaction C(graphite)

(B) Mole fraction of ammonia =

(C) % w/w of NH3 = 4%

(D) % w/v = 6.8%

Which of the following is/are correct?

as major product when treated with KOH

Mock Test-1 [Paper-I]

Which of the following is / are not possible?

(B) CH2 = CH CHO

(C) CH3 CH CH2 CH CH3

Column II (Major product)

(Q) CH2 = CH CH2 OH

s p mixing is not possible in among the following :

Mock Test-1 [Paper-I]

Suppose g is the inverse function of a differentiable function f and G(x) =

Mock Test-1 [Paper-I]

Which of the following statement(s) is/are TRUE?

(B) Distance between chord PQ and directrix of the parabola is

cos 1 cos (sin x ) x

(B) f(x) has removable discontinuity at x =

(A) Lim f ( x ) does not exist

(C) jump of discontinuity at x = is

Mock Test-1 [Paper-I]

(D) f(x) is discontinuous at all x = n, n I

(B) locus of P is ellipse with eccentricity

(C) locus of P is hyperbola with eccentricity

Consider a ABC whose circumcircle is | z | = r in the argand plane with A, B, C be represented by

(A) centroid of LMN is

If , , are roots of x3 x + 2 = 0, then the value of

In ABC, if incentre I is the mid point of median

If z1, z2 C then the maximum value of