DALIC, B.P.

90139, 35501 VITRE CEDEX, FRANCE

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18.04.2009
Codes: 13010, DPM9020, document code: FDS13010

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SAFETY DATA SHEET

1 - IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY
IDENTIFICATION OF THE PREPARATION

INDIAGE N (code: 13010) or INDIUM (code: DPM 9020)

USE OF THE PREPARATION
This solution is used at ambient temperature on most materials to plate Indium with the brush electrolysis process. Indium,
that welds itself to itself just by pressure, is very often used to improve friction properties or as a seal.
As the brush process is applied locally without immersion of the part just where it is necessary, only small quantities of
solution are stored or used.
COMPANY IDENTIFICATION
DALIC - ZI de Plagu - 41, rue des Eaux - B.P. 90139 - 35501 VITRE CEDEX, FRANCE
Manufacturer and Seller, tel.: (33) 2.99.75.36.99, fax: (33) 2.99.74.49.31.
For information: sclaverie@dalicworld.com, tel.: (33) 2.99.75.53.88.
RELEVANT OFFICIAL ADVISORY BODY (France): INRS / Orfila, tel. (33) 1.45.42.59.59.
________________________________________________________________________________________________
2 HAZARDS IDENTIFICATION
CHEMICAL NATURE
Alkaline aqueous preparation containing particularly Indium salts and ethylenediamine.
PRODUCT CLASSIFICATION ACCORDING TO 1999/45/EC and 67/548/EC
Symbol: Xn Risk phrases: R36/38-42/43
MAIN HAZARDS
Adverse physicochemical effects
- Fire or explosion: this product is not classified as flammable or explosive.
Adverse effects on health
According to the above directives, this preparation must be considered as irritating and sensitizing by inhalation and
contact with skin.
Effects on the environment
Is not classified as dangerous for the environment providing that the recommendations of the section 13 relative to disposal
as well as the national or local provisions are followed.
Refer also to the paragraphs 11, 12, 13 and 15.
________________________________________________________________________________________________
3 - COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENTS OR IMPURITIES CONTRIBUTING TO THE HAZARDS (according to 1999/45/EC and 67/548/EC)
Substances present in concentrations higher than the minimal level of danger: YES
sd

Regulated substance
Classification of the pure
substance
Symbols
S phrases
Classification of the
substance according to
its concentration (in %)
Concentration range in
the preparation, in weight

EDA (22 adapt.)

Ethylenediamine
EC index N: 612-006-00-6
EC N: 203-468-6
CAS N: 107-15-3
R10 C R34 - Xn R21/22
R42/43
C
(1/2)-23-26-36/37/39-45
25% C R 21/22-34-42/43
10-25% C R34-42/43
2-10% Xn R36/38-42/43
Xn R42/43
1-2%
< 10%

Substances with the R33 phrase (if 1%), with the R64 phrase (if 1%) or other classified sensitising substances (if
0.1%): NO.
OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.
OTHER INFORMATION: contains also not regulated salts. Indium content: 60 g/L.
________________________________________________________________________________________________

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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18.04.2009

Codes: 13010, DPM9020, Safety Data Sheet, document code: FDS13010

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4 - FIRST AID MEASURES

CONTACT WITH SKIN
Take off contaminated clothing and shoes. Wash immediately with plenty of water.
CONTACT WITH EYES
Rinse immediately with plenty of water for approximately 15 minutes.
It is seriously recommended to consult an ophthalmologist.
INHALATION
Theoretically, not applicable. Under abnormal conditions of use causing considerable inhalation, remove the casualty from
the contaminated area, let him take a rest in a well-ventilated room and seek medical advice to hospitalize the person. A
supervision of the effects may be necessary. Begin an ocular and cutaneous decontamination while waiting for help.
INGESTION
Try to induce vomiting if the person is perfectly conscious. Call immediately the medical service and hospitalize quickly the
person.
PROTECTION OF THE FIRST-AIDERS
Wear gloves and glasses, and according to the situation, wear protective clothes and shoes, a mask
________________________________________________________________________________________________
5 - FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Water spray, powders and special foams for polar liquids.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED
No.
SPECIFIC HAZARDS
Avoid contact with powerful oxidizing agents.
Dangerous thermal decomposition products: emission of ammonia and of oxides (notably of nitrogen, carbon and indium).
Prevent any material from entering drains or waterways or soil.
PROTECTION OF THE FIRE-FIGHTERS
Because of the substances that are produced during thermal decomposition, use approved self-contained breathing
equipment and protective clothing in case of intervention.
________________________________________________________________________________________________
6 - ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Avoid contact with the skin, the clothes and the eyes: wear gloves, glasses and if needed a mask.
Dispose of all contaminated clothing or shoes and wash thoroughly with water.
ENVIRONMENTAL PRECAUTIONS
Do not allow the product to be thrown away. Recover as much as possible for processing within the firm or by an approved
centre.
METHODS FOR CLEANING UP
With water to remove all non-recoverable product. Collect the recoverable rinsing water for processing within the firm or by
an approved centre.
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7 - HANDLING AND STORAGE
HANDLING
Use as supplied. Close containers (in PE) tightly after use with the original cap. Do not re-use containers with another
product.
STORAGE
Store on a spill-retaining vat, away from powerful oxidizing agents. Keep in original containers only, in a room at 5-30C
away from direct sun-light. The maximum recommended shelf life is three years from the date of manufacture under normal
conditions of storage.
________________________________________________________________________________________________
8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
TECHNICAL MEASURES
No drinking, eating or smoking on the workplace.
Maintain the premises and the workplace in a perfect state of cleanliness and clean them frequently.
During brush electrolysis, even if this product is used at room temperature during a short time, it is important to protect the
respiratory system and to avoid contact with skin.
Check that the limit values below are not reached. They depend on the treatment time, the surface area treated and on the
quality of the workshop air extraction.

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

service@dalicworld.com

18.04.2009

Codes: 13010, DPM9020, Safety Data Sheet, document code: FDS13010

EXPOSURE LIMIT VALUES IN AIR

Directives 2006/15/EC, 2000/39/EC
Directive 91/322/EC
France: decision of 26 October 2007,
of 30 June 2004 or according to ND
2098 INRS file

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Ethylenediamine
Average value (8 h) = 25
3
mg/m (10 ppm)
Max. limit value (15 min)
3
= 35 mg/m (15 ppm)
(according to INRS file)

PERSONAL PROTECTION
Provide a shower, a powerful tap and sink unit, an eye basin in the vicinity of the work place and a protective breathing
mask for emergency interventions.
Respiratory protection: during brush plating, provide an inhaling of the sprays / vapours where they are created and
extraction out of the premises. Otherwise or if insufficient, wear an A2B2 or A2P3 cartridge (EN 405:2002 standard) in
a ventilated room.
Hand protection: wear gloves (in latex or nitrile for example).
Eye protection: wear glasses with lateral protections or a facial screen. Do not wear contact lenses.
Skin protection: wear overalls and safety shoes.
________________________________________________________________________________________________
9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: pale to yellow liquid.
Odour: odourless.
pH: 8.9.
Relative density: 1.22.
Solubility: miscible in water.
Boiling point: approximately 100C.
Crystallisation / melting point: - 9C.
Flammability: nil.
Oxidising properties: nil.
Risk of explosion and fire: nil.
Other properties: not applicable.
________________________________________________________________________________________________
10 - STABILITY AND REACTIVITY
STABILITY
Good at normal temperature with water evaporation for only risk.
Good in humidity, slight yellowing by light is possible.
CONDITIONS TO AVOID
High temperatures.
MATERIALS TO AVOID
Contact with powerful oxidizing agents, particularly if the product has been concentrated or dehydrated.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS
Notably emission of ammonia, of carbon oxides, nitrogen oxides and indium oxides.
________________________________________________________________________________________________
11 - TOXICOLOGICAL INFORMATION
No data are available regarding the preparation. The evaluation of health hazards has been realised thanks to
directives 67/548/EC, 1999/45/EC and bibliographical data.
SKIN
Irritating. Due to the presence of aliphatic amines, may also cause the appearance of recurring eczemas on some sensitive
people.
EYE MUCOSA
Irritating in case of contact.
RESPIRATORY SYSTEM
Harmful. May cause sensitisation by inhalation (asthma) on some sensitive people because of the presence of
ethylenediamine.
IN CASE OF INGESTION
Gastro-intestinal problems are possible.
OCCUPATIONAL DISEASES: tables n49, 49a (in FRANCE).
________________________________________________________________________________________________

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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18.04.2009

Codes: 13010, DPM9020, Safety Data Sheet, document code: FDS13010

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12 - ECOLOGICAL INFORMATION
There are no ecological data on the preparation.
Prevent any material from entering drains or waterways or earth.
Bibliographic data concerning ethylenediamine:
ECOTOXICITY
FISHES - CL50 (96 h) = 116 mg/L; DAPHNIA MAGNA - CE50 (24 h) = 19 mg/L; MICRO-ORGANISMS: Pseudomonas
putida/CE50 (17 h): 29 mg/L.
MOBILITY - PERSISTENCE AND DEGRADABILITY - BIOACCUMULATIVE POTENTIAL OTHER ADVERSE EFFECTS
Method : OCDE 301C ; ISO 9408 ; 92/69/CEE, C.4-F, activated muds
Destruction level: 93 - 95 % (28 days), easily biodegradable.
Bibliographic data concerning the indium salts in solution:
No information.
According to the applicable EC directives, it is not appropriate to apply theN symbol DANGEROUS FOR THE
ENVIRONMENT to this preparation.
________________________________________________________________________________________________
13 - DISPOSAL CONSIDERATIONS
This product and water used for rinsing must not be thrown away notably because of their metal content. They must be
processed within the firm or destroyed by an approved organization.
Contaminated packaging if not re-used with the same product is also special waste to be sent to an approved organization
for recycling or disposal.
Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular
2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.
06 03 13* Solid salts and solutions containing heavy metals
11 01 11* Aqueous rinsing liquids containing dangerous substances
15 01 10* Packaging containing residues of or contaminated by dangerous substances
As the volume of rinsing water is small, it can be added to the waste solutions.
NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or local provisions
on this topic.
________________________________________________________________________________________________
14 - TRANSPORT INFORMATION
A.D.R. (road transport)
Amines, liquid, corrosive, n.o.s. (ethylenediamine, mixture), class 8, classification code C7, packaging group III, hazard
label model n 8, restricted quantities LQ7, hazard identification n 80, material identification n 2735.
I.M.D.G. (sea transport)
Amines, liquid, corrosive, n.o.s.* (ethylenediamine, mixture), UN N 2735, class 8, packaging group III, subsidiary risk
label: not applicable, restricted quantities: 5 L, stowing and separation: category A, away from acids, safety sheets F-A, S-B.
I.A.T.A. (air transport)
Amines, liquid, corrosive, n.o.s.* (ethylenediamine, mixture), UN N 2735, class 8, subsidiary risk: not applicable, risk
label: CORROSIVE, packaging group III, Passenger- and Cargo aircraft: packaging instructions 818, maximum quantity per
package: 5 L, Cargo aircraft only: packaging instructions 820, maximum quantity per package: 60 L, instruction IDC 8L.
________________________________________________________________________________________________
15 - REGULATORY INFORMATION
This safety data sheet has been established in accordance with the Corrigendum to Regulation (EC) n 1907/2006 of the
European Parliament and of the Council of December 18, 2006, OJ L136, 29.05.2007.
th
The preparation labelling has been established in compliance with the directive 67/548/EC (until the 29 adaptation:
directive 2004/73/EC of April 29, 2004) and the directive 1999/45/EC reviewed in last in January 23, 2006 by the directive
2006/8/EC.
EC LABELLING: HARMFUL
Alkaline aqueous preparation containing particularly indium salts and ethylenediamine
R36/38: irritating to eyes and skin.
R42/43: may cause sensitization by inhalation and skin contact.
S23 : do not breathe gas / fumes / vapours / spray.
S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37: wear suitable protective clothing and gloves.
S45: in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
HEALTH SURVEILLANCE
Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to
chemical agents at work
An appropriate health surveillance of workers must be carried out according to the risk.

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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18.04.2009

Codes: 13010, DPM9020, Safety Data Sheet, document code: FDS13010

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For each worker who undergoes this health surveillance, individual health and exposure records are to be made and kept
up-to-date.
See please the specific legislative and administrative, national or local provisions on the following topics:
occupational diseases (in France: table 49),
health surveillance,
work in another company,
administrative declarations and rules (in France: none if all volumes for the electrolysis process is below 200 L).
environment laws regarding rinsing water treatment.
Additional information is provided in paragraphs 8, 11, 12, 13 and 14.
________________________________________________________________________________________________
16 - OTHER INFORMATION
RESTRICTION OF USE
For industrial use only.
We remain available to bring you the training or advice you may need.
R PHRASES OF THE PURE COMPONENTS LISTED IN SECTION 3
R10: flammable.
R21/22: harmful in contact with skin and if swallowed.
R34: causes burns.
R42/43: may cause sensitization by inhalation and skin contact.
R PHRASES OF THE PREPARATION ACCORDING TO THE SECTIONS 2 AND 15
R36/38: irritating to eyes and skin.
R42/43: may cause sensitization by inhalation and skin contact.
BIBLIOGRAPHIC REFERENCES
European directives, INRS files, safety data sheets of the components established by their manufacturers or distributors,
information of European Office of the chemical substances (ECB).
MODIFICATIONS
Updating in relation to the corrigendum to regulation (EC) n 1907/2006 published in May 29, 2007 and French decisions of
October 26, 2007.
Revised paragraphs: all.
OTHER INFORMATION
This sheet is provided to complement, not replace, the user instructions.
Information contained herein is bona fide and based on current knowledge relating to the product on the date of
publication. Furthermore, the attention of the user is drawn to the risks which may be incurred when the product is used for
purposes other than those for which it is designed.
Information provided herein relates to this product only; it cannot take account of every situation which may arise at every
work place. This safety data sheet therefore represents only a part of the information required for establishing a safety
programme.
Under no circumstances does this sheet dispense the user from the need to know and to apply all of the regulations
governing its activity, which are not all necessarily quoted herein in an exhaustive manner.
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