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3.2.3
Describe the physical differences between the solid, liquid and gaseous
phases in terms of molecular structure and particle motion.
3.2.4
3.2.5
E
C
B
A
3.2.6
At low temperature and high pressure (A) the molecules are close together
and attractive forces are not negligible compared with low kinetic energy; the
substance can exist only as a solid.
If the pressure stays constant and heat is added, the temperature rises to B, at
which point more heat is added but the temperature does not rise; this
additional energy is used to change state (temperature remains constant until
all the solid has melted).
Further heat increases temperature (C) until point D, where the next phase
change occurs (vaporization). Again, temperature remains constant until
vaporization is complete. Additional heat now increases the temperature of
the gas (E).
The temperature at which a phase change occurs usually depends on
additional variables, such as pressure.
Phase diagrams demonstrate the macroscopic relationship between pressure,
temperature and phase changes (compare B and B1, D and D1).
The molecules of a fluid move about with a distribution of speeds. The most
energetic (fastest) molecules may escape if during random motion they find
themselves at the surface of the liquid.
Unlike boiling, where molecules from anywhere within the volume can
escape, only surface molecules can evaporate.
The average speed of the remaining molecules is reduced, resulting in a
lower temperature.
The rate of evaporation increases with greater surface area and higher
molecular temperature.
If the substance is in an enclosed area, the molecules which escape collect
over the liquid; the resulting vapor pressure increases until equilibrium is
reached
3.2.7
The energy absorbed or liberated in a phase change is called the latent heat.
The latent heat of fusion (Lf) is the heat required to melt a mass of material;
the latent heat of vaporization (Lv) is the heat required to evaporate a unit
mass
Q = mLf or Q = mLv
At atmospheric pressure, Lf (ice) is 333 kJ kg-1 and Lv (water) is 2255 kg kg-1.
3.2.8