Professional Documents
Culture Documents
EX-1654-294
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The information herein is provided in good faith, but no warranty, either expressed or implied,
is made by King Engineering.
marshbellofram.com king-gage.com
1,1,2,2-Tetrabromoethane
Synonym(s)
Chemical formula
C 2 H 2 Br 4
Molecular weight
345.7
Supplier
Emergency Telephone
Chemtrec (800)424-9300
2. Hazards identification
Emergency overview
Irritant
- Skin contact
Irritant
- Inhalation
- Ingestion
Chronic effects/Carcinogenicity
CAS No.
Weight %
1,1,2,2TETRABROMOETHANE
79-27-6
98.6
4. First-aid measures
Eye contact
Holding the eyelids apart, flush eyes promptly with copious flowing water for at least
20 minutes. Get medical attention immediately.
Skin contact
Remove contaminated clothing. Wash skin thoroughly with mild soap and plenty of
water for at least 15 minutes. Wash clothing before re-use.
Get medical attention immediately.
Inhalation
In case of mist inhalation or breathing fumes released from heated material, remove
person to fresh air.
Keep him quiet and warm. Apply artificial respiration if necessary and get medical
attention immediately.
Ingestion
If swallowed, wash mouth thoroughly with plenty of water and give water to drink.
Get medical attention immediately.
************************************************************************
NOTE: Never give an unconscious person anything to drink.
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Cool containers with water spray. In closed stores, provide fire-fighters with selfcontained breathing apparatus in positive pressure mode
Will decompose from ca. 239C releasing poisonous and corrosive fumes of
Hydrogen bromide, bromine and carbonyl bromide.
Evacuate area.
Full protective clothing, including self-contained breathing apparatus, must be used.
Keep containers tightly closed. Avoid breathing vapours and any other bodily
contact.
Storage
Store in a dry, cool, well-ventilated area away from incompatible materials (see
"materials to avoid").
ACGIH-TLV Data
1,1,2,2TETRABROMOETHANE
79-27-6
0.1 ppm
1 ppm, 14 mg/m3
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Ventilation requirements
Approved respirator
Protective gloves
Chemical safety goggles
Body covering clothes and boots
Do not eat, smoke or drink where material is handled, processed or stored. Wash
hands carefully before eating or smoking.
Safety shower and eye bath should be provided.
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Conditions to avoid
Hazardous decomposition
products
Hazardous polymerization
1200 mg/kg
5250 mg/kg
549 mg/m3/4 hour
Prolonged exposure may cause liver and kidney damage.
Mutagenicity
Carcinogenicity
Reproductive toxicity
No information available
Aquatic toxicity :
19 mg/l, 48 Hours (orange red-killifish)
29% (2 weeks)
Bioaccumulative potential
Observe all federal, state and local environmental regulations when disposing of this
material.
2504
DOT
IMO
ICAO/IATA
- Massachusetts right-to-know
list
Listed
Listed
Listed
Canada
Listed in DSL
EU
Reported in EINECS
EC No.
201-191-5
Japan
Australia
Listed in AICS
Listed in NZIoC
China inventory
Listed
Korea
Philippines
Listed in PICCS
Switzerland
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Revision Number 1
1-Heptanol
120360000; 120360010; 120360050; 120362500
Heptyl alcohol
Relevant identified uses of the substance or mixture and uses advised against
Laboratory chemicals
Recommended Use
No Information available
Uses advised against
Details of the supplier of the safety data sheet
Company
Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
begel.sdsdesk@thermofisher.com
E-mail address
Emergency Telephone Number
For information in the US, call: 800-ACROS-01
For information in Europe, call: +32 14 57 52 11
Emergency Number, Europe: +32 14 57 52 99
Emergency Number, US: 201-796-7100
CHEMTREC Phone Number, US: 800-424-9300
CHEMTREC Phone Number, Europe: 703-527-3887
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
REGULATION (EC) No 1272/2008
Acute dermal toxicity
Acute Inhalation Toxicity - Vapors
Serious Eye Damage/Eye Irritation
Category 4
Category 4
Category 2A
Signal Word
Warning
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ACR12036 - 1-Heptanol
Revision Date 16-Nov-2010
_____________________________________________________________________________________________
Hazard Statements
H312 - Harmful in contact with skin
H319 - Causes serious eye irritation
H332 - Harmful if inhaled
Precautionary Statements - EU (28, 1272/2008)
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing
Other Hazards
No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component
n-Heptyl alcohol
111-70-6
EC No.
203-897-9
Weight %
98
CAS-No
111-70-6
Classification
GHSCLAS
REACH Reg. No.
Xn; R20/21/22
Eye Irrit. 2 (H319) Xi; R36
Acute Tox. 4
(H302)
Acute Tox. 4
(H312)
Acute Tox. 4
(H332)
For the full text of the R phrases mentioned in this Section, see Section 16
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes Obtain
medical attention
Skin Contact
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes Obtain medical attention
Ingestion
Do not induce vomiting Clean mouth with water Get medical attention
Inhalation
Remove from exposure, lie down Move to fresh air If breathing is difficult, give oxygen If not
breathing, give artificial respiration Obtain medical attention
Notes to Physician
Treat symptomatically
5. FIRE-FIGHTING MEASURES
Extinguishing media
Suitable Extinguishing Media
Carbon dioxide (CO2) Dry chemical Use water spray to cool unopened containers chemical foam Do not use a solid water stream as it
may scatter and spread fire
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ACR12036 - 1-Heptanol
Revision Date 16-Nov-2010
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Extinguishing media which must not be used for safety reasons
No information available.
Special hazards arising from the substance or mixture
Combustible material Flammable
Advice for fire-fighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear
This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
No information available.
No information available.
Ensure adequate ventilation, especially in confined areas Ensure that eyewash stations and
safety showers are close to the workstation location
Ey
Ha
e Protection
nd Protection
Skin and body protection
Resp
iratory Protection
Goggles
Protective gloves
Wear appropriate protective gloves and clothing to prevent skin exposure
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits
are exceeded or if irritation or other symptoms are experienced
Hygiene Measures
Environmental exposure controls
_____________________________________________________________________________________________
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ACR12036 - 1-Heptanol
Revision Date 16-Nov-2010
_____________________________________________________________________________________________
Liquid
Clear
slight
No information available.
0.5 mbar @ 20 C
3.9
176C / 348.8F@ 760 mmHg
-35C / -31F
73C / 163.4F
2.85 g/L (100C)
0.822
C7 H16 O
116.2
Conditions to Avoid
Incompatible products.
Incompatible Materials
Strong oxidizing agents, Strong acids, Acid anhydrides, Acid chlorides.
Hazardous Decomposition Products
Carbon monoxide (CO). Carbon dioxide (CO2).
Component Information
Component
n-Heptyl alcohol
LD50 Oral
500 mg/kg ( Rat )
LD50 Dermal
2 g/kg ( Rabbit )
LC50 Inhalation
Chronic Toxicity
Carcinogenicity
_____________________________________________________________________________________________
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ACR12036 - 1-Heptanol
Revision Date 16-Nov-2010
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Sensitization
Mutagenic Effects
Reproductive Effects
Developmental Effects
Target Organs
Other Adverse Effects
Endocrine Disruptor Information
No information available.
No information available
No information available.
No information available.
No information available.
The toxicological properties have not been fully investigated. See actual entry in RTECS for
complete information
None known
Component
n-Heptyl alcohol
Contains no substances known to be hazardous to the environment or that are not degradable
in waste water treatment plants
Freshwater Algae
Freshwater Fish
33.1-36 mg/L LC50 96
h
Microtox
Water Flea
UN2810
6.1
III
TOXIC LIQUIDS, ORGANIC, N.O.S.
ADR
Not regulated
IATA
UN-No
Hazard
Packin
Class
g Group
UN2810
6.1
III
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ACR12036 - 1-Heptanol
Revision Date 16-Nov-2010
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EINECS ELINCS
203-897-9
-
NLP TSCA
DSL
X
NDSL PICCS
X
ENCS
X
CHINA
X
AICS
X
KECL
KE-18302
X
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
EINECS/ELINCS - European Inventory Lists
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
PICCS - Philippines Inventory of Chemicals and Chemical Substances
ENCS - Japan Existing and New Chemical Substances
CHINA - China Inventory of Existing Chemical Substances
AICS - Inventory of Chemical Substances
KECL - Existing and Evaluated Chemical Substances
Chemical Safety Assessment
_____________________________________________________________________________________________
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