Professional Documents
Culture Documents
2N(N/5)
Chemwatch Material Safety Data Sheet
Oct-11-2010
X!293SP
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 1 of 9
PRODUCT NAME
NITRIC ACID, 0.2N(N/5)
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.
NFPA
FLAMMABILITY
HEALTH HAZARD
INSTABILITY
SUPPLIER
Company: Drew Marine
Address:
100 South Jefferson Road
Whippany, NJ 07981
United States of America
Telephone: 973 526- 5700.
Emergency Tel:The numbers below are for EMERGENCY USE ONLY. Use the corporate number above for all
other calls.
Emergency Tel:CHEMWATCH: From within the US and CANADA: 1 877- 715- 9305 OR call + 613 9573 3112.
From outside the US and Canada: + 800 2436 2255 ( +800 CHEMCALL) or +613 9573 3112
PRODUCT USE
Used according to manufacturer's directions.
HAZARD RATINGS
Flammability
Toxicity
Body Contact
Reactivity
Chronic
SCALE:
Min/Nil=0
Low=1
Moderate=2
High=3
Extreme=4
continued...
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 2 of 9
Section 2 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
RISK
Causes burns.
Risk of serious damage to eyes.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.
Even a small amount of nitric acid causes severe corrosion of the stomach, burning pain, vomiting and shock, possibly causing
non-healing scarring of the gastrointestinal tract and stomach.
Death may be delayed 12 hours to 14 days or to several months.
EYE
The material can produce chemical burns to the eye following direct contact.
Vapors or mists may be extremely irritating.
If applied to the eyes, this material causes severe eye damage.
Eye contact with concentrated nitric acid may give no pain, whilst diluted solution causes intense pain and both can cause
permanent eye damage or blindness.
Burns may result in shrinkage of the eyeball, symblepharon (adhesions between tarsal and bulbar conjunctivae), permanent corneal
opacification, and visual impairment leading to blindness.
SKIN
The material can produce chemical burns following direct contactwith the skin.
Open cuts, abraded or irritated skin should not be exposed to this material.
Skin contact with nitric acid causes yellow discolouration of the skin, blisters and scars that may not heal.
The skin may be stained bright-yellow or yellowish brown due to the formation of xanthoproteic acid.
INHALED
Not normally a hazard due to non-volatile nature of product.
Corrosive acids can cause irritation of the respiratory tract, with coughing, choking and mucous membrane damage.
There may be dizziness, headache, nausea and weakness.
CHRONIC HEALTH EFFECTS
Repeated or prolonged exposure to acids may result in the erosion of teeth, swelling and or ulceration of mouth lining.
Irritation of airways to lung, with cough, and inflammation of lung tissue often occurs.
Prolonged or repeated overexposure to low concentrations of nitric acid vapour may cause chronic bronchitis, corrosion of teeth,
even chemical pneumonitis.
CAS RN
7697-37-2
%
<10
SWALLOWED
For advice, contact a Poisons Information Center or a doctor at once.
Urgent hospital treatment is likely to be needed.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
EYE
If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting
continued...
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 3 of 9
Section 4 - FIRST AID MEASURES
continued...
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 4 of 9
MINOR SPILLS
Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or
disposal of material.
Check regularly for spills and leaks.
Clean up all spills immediately.
Avoid breathing vapors and contact with skin and eyes.
Control personal contact by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
MAJOR SPILLS
Clear area of personnel and move upwind.
Alert Emergency Responders and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
STORAGE REQUIREMENTS
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
EXPOSURE CONTROLS
Source
Material
__________
US ACGIH
Threshold Limit
Values (TLV)
__________
(Nitric acid)
TWA
ppm
______
2
TWA
mg/m
______
STEL
ppm
______
4
STEL
mg/m
______
Peak
ppm
______
Peak
mg/m
______
TWA
F/CC
______
Notes
______
TLV Basis: URT
& eye irr;
dental erosion
MATERIAL DATA
NITRIC ACID, 0.2N(N/5):
Not available
NITRIC ACID:
For nitric acid:
Odour Threshold Value: 0.27 ppm (detection)
continued...
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 5 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
NOTE: Detector tubes for nitric acid, measuring in excess of 5 ppm, are commercially available.
The TLV-TWA is protective against corrosion of the skin, tissue and other membranes, against irritation to the eyes and mucous
membranes, and against acute pulmonary oedema or chronic obstructive lung disease. It is not clear whether the TLV-TWA and STEL
values will prevent potentiation of the toxicity of inhaled nitrogen dioxide.
PERSONAL PROTECTION
RESPIRATOR
Type AE-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
EYE
Chemical goggles.
Full face shield.
Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality which vary from
manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can
not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and
has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:
frequency and duration of contact,
chemical resistance of glove material,
glove thickness and
dexterity
Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).
When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time
greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes
according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
Contaminated gloves should be replaced.
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a nonperfumed moisturiser is recommended.
OTHER
Overalls.
PVC Apron.
PVC protective suit may be required if exposure severe.
Eyewash unit.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in special
circumstances.
PHYSICAL PROPERTIES
Mixes with water.
Corrosive.
Acid.
State
Melting Range (F)
Boiling Range (F)
Flash Point (F)
LIQUID
32 approx
212 approx
Not Available
Molecular Weight
Viscosity
Solubility in water (g/L)
pH (1% solution)
Not Applicable
Not Available
Miscible
Not Available
continued...
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 6 of 9
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Not Available
Not Available
Not Available
Not Available
Not Available
pH (as supplied)
Vapour Pressure (mmHg)
Specific Gravity (water=1)
Relative Vapor Density
(air=1)
Evaporation Rate
Not Available
Not Available
1.02- 1.08 approx
Not Available
Not Available
APPEARANCE
Clear, colourless to pale yellow corrosive liquid with slightly pungent odour; mixes with water.
SKIN
nitric acid
D1: skin
irritation/corrosion
3C
continued...
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 7 of 9
Section 11 - TOXICOLOGICAL INFORMATION
Persistence:
Water/Soil
No Data
Available
nitric acid
Persistence: Air
Bioaccumulation
Mobility
No Data
Available
LOW
No Data
Available
DOT:
Symbols:
Identification Numbers:
Label Codes:
G
UN1760
8
Packaging: Exceptions:
Packaging: Exceptions:
154
154
60 L
8
III
IB3, T7,
TP1, TP28
203
5L
A
continued...
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 8 of 9
Section 14 - TRANSPORTATION INFORMATION
8
ICAO/IATA Subrisk:
1760
Packing Group:
A3A803
None
III
856
60 L
852
Y841
Maximum Qty/Pack:
Passenger and Cargo
Maximum Qty/Pack:
Passenger and Cargo Limited Quantity
Maximum Qty/Pack:
5L
1L
REGULATIONS
US EPCRA Section 313 Chemical List
Ingredient
CAS
% de minimus concentration
nitric acid
7697-37-2
1.0
US CERCLA List of Hazardous Substances and Reportable Quantities
Ingredient
CAS
RQ
nitric acid
7697-37-2
Regulations for ingredients
nitric acid (CAS: 7697-37-2) is found on the following regulatory lists;
"Canada - Alberta Occupational Exposure Limits", "Canada - British Columbia Occupational Exposure Limits", "Canada - Northwest
Territories Occupational Exposure Limits (English)", "Canada - Nova Scotia Occupational Exposure Limits", "Canada - Prince Edward
Island Occupational Exposure Limits", "Canada - Quebec Permissible Exposure Values for Airborne Contaminants (English)", "Canada Saskatchewan Industrial Hazardous Substances", "Canada - Saskatchewan Occupational Health and Safety Regulations - Contamination
Limits", "Canada - Yukon Permissible Concentrations for Airborne Contaminant Substances", "Canada CEPA Environmental Registry
Substance Lists - List of substances on the DSL that meet the human health criteria for categorization (English)", "Canada
Ingredient Disclosure List (SOR/88-64)", "Canada National Pollutant Release Inventory (NPRI)", "Canada Toxicological Index
Service - Workplace Hazardous Materials Information System - WHMIS (English)", "FisherTransport Information", "GESAMP/EHS
Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (Annex
II) - List of Noxious Liquid Substances Carried in Bulk", "International Council of Chemical Associations (ICCA) - High
Production Volume List", "OECD List of High Production Volume (HPV) Chemicals", "US - Alaska Limits for Air Contaminants", "US California Air Toxics ""Hot Spots"" List (Assembly Bill 2588) Substances for Which Emissions Must Be Quantified", "US California Occupational Safety and Health Regulations (CAL/OSHA) - Hazardous Substances List", "US - California OEHHA/ARB - Acute
Reference Exposure Levels and Target Organs (RELs)", "US - California Permissible Exposure Limits for Chemical Contaminants", "US
- California Toxic Air Contaminant List Category II", "US - Connecticut Hazardous Air Pollutants", "US - Delaware Pollutant
Discharge Requirements - Reportable Quantities", "US - Hawaii Air Contaminant Limits", "US - Idaho - Limits for Air Contaminants",
"US - Louisiana Minimum Emission Rates Toxic Air Pollutants", "US - Louisiana Toxic Air Pollutant Ambient Air Standards", "US Massachusetts Oil & Hazardous Material List", "US - Massachusetts Toxics Use Reduction Act (TURA) listed chemicals", "US Michigan Exposure Limits for Air Contaminants", "US - Minnesota Hazardous Substance List", "US - Minnesota Permissible Exposure
Limits (PELs)", "US - New Jersey Environmental Hazardous Substances List", "US - New Jersey Right to Know - Special Health Hazard
Substance List (SHHSL): Corrosives", "US - New Jersey Right to Know - Special Health Hazard Substance List (SHHSL): Reactive
Materials", "US - New Jersey Right to Know Hazardous Substances (English)", "US - New York List of Hazardous Substances", "US North Dakota Air Pollutants - Guideline Concentrations", "US - Oregon Hazardous Materials", "US - Oregon Permissible Exposure
Limits (Z-1)", "US - Pennsylvania - Hazardous Substance List", "US - Rhode Island Hazardous Substance List", "US - Tennessee
Occupational Exposure Limits - Limits For Air Contaminants", "US - Vermont Permissible Exposure Limits Table Z-1-A Final Rule
continued...
CHEMWATCH 24-9824
Version No:2.1.1.1
Page 9 of 9
Section 15 - REGULATORY INFORMATION
Limits for Air Contaminants", "US - Vermont Permissible Exposure Limits Table Z-1-A Transitional Limits for Air Contaminants",
"US - Washington Permissible exposure limits of air contaminants", "US - Washington Toxic air pollutants and their ASIL, SQER and
de minimis emission values", "US - Wisconsin Control of Hazardous Pollutants - Emission Thresholds, Standards and Control
Requirements (Hazardous Air Contaminants)", "US - Wisconsin Control of Hazardous Pollutants - Substances of Concern for Sources
of Incidental Emissions of Hazardous Air Contaminants", "US - Wyoming List of Highly Hazardous Chemicals, Toxics and Reactives",
"US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants", "US ACGIH Threshold Limit Values (TLV)", "US
American Cleaning Institute Cleaning Product Ingredient Inventory", "US Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF)
- List of Explosive Materials", "US CWA (Clean Water Act) - List of Hazardous Substances", "US CWA (Clean Water Act) - Reportable
Quantities of Designated Hazardous Substances", "US Department of Homeland Security Chemical Facility Anti-Terrorism Standards Chemicals of Interest", "US Department of Transportation (DOT) List of Hazardous Substances and Reportable Quantities - Hazardous
Substances Other Than Radionuclides", "US DOE Temporary Emergency Exposure Limits (TEELs)", "US EPA Acute Exposure Guideline
Levels (AEGLs) - Interim", "US EPA High Production Volume Chemicals Additional List", "US EPCRA Section 313 Chemical List", "US
FDA Indirect Food Additives: Adhesives and Components of Coatings - Substances for Use Only as Components of Adhesives Adhesives", "US FDA List of ""Indirect"" Additives Used in Food Contact Substances", "US List of Lists - Consolidated List of
Chemicals Subject to EPCRA, CERCLA and Section 112(r) of the Clean Air Act", "US NFPA 1 Annex B Typical Oxydizers", "US NFPA Fire
Hazard Properties of Flammable Liquids, Gases, and Volatile Solids Table", "US NFPA Hazardous Chemical Data Sheets Information",
"US NIOSH Recommended Exposure Limits (RELs)", "US OSHA List of Highly Hazardous Chemicals, Toxics and Reactives", "US OSHA
Permissible Exposure Levels (PELs) - Table Z1", "US SARA Section 302 Extremely Hazardous Substances", "US Toxic Substances
Control Act (TSCA) - Chemical Substance Inventory", "USA: Chemical Facility Anti-Terrorism Standards - List Appendix A - 6CFR 27"
No data for Nitric Acid, 0.2N(N/5) (CW: 24-9824)
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Oct-11-2010
Print Date: Apr-29-2013