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Article history:
Received 26 March 2008
Accepted 1 September 2008
Available online 9 September 2008
Keywords:
Luffa bres
Electron microscopy
X-ray techniques
Crystallinity
Chemical treatment
a b s t r a c t
Recently, the use of lignocellulosic bres to reinforcing composite has received an increased attention.
However, lack of good interfacial adhesion makes important the treatment of raw materials. Chemical
treatment prepared the raw material to be useful by elimination of gummy and waxy substances. In this
study, the Luffa bres were treated by tow methods: alkali treatment and mixed treatment (sodium
hydroxide and hydrogen peroxide). The effect of these treatments on the structure of bres was showed
using SEM and XRD (X-Ray Diffraction) analysis. The SEM results revealed that both treatments resulted in a
removal of lignin, pectin and hemicellulose substances, and change the characteristics of the surface
topography. The XRD analysis shows the increase of crystallinity index by many treatment conditions. We
nd that the alkali treatment (120 C; 3 h; 4% NaOH) shows a good cleaning and the higher crystallinity index
of treated bres. It is also interesting to note that mixed treatment can change the Luffa bres from mat
structure to brils structure.
2008 Elsevier B.V. All rights reserved.
1. Introduction
The Luffa sponge, collected from Tunisia, used in this study was
washed three times in hot water, then with 0.2% lauryl sulphate solution
under continuous stirring at 60 C for 30 min to ensure good cleaning [14].
Cell-bres of L. cylindrica were extracted from brous stands by
tow methods. In the rst method, a solution containing both sodium
hydroxide and anthraquinone is used to remove waxy and gummy
Table 1
Crystallinity index of untreated and treated Luffa bres
Treatment method
Icr (%)
Untreated
Alkali treatment
Untreated
8038
10038
12034
120112
1001210
1001410
1001610
100185
1001810
1001815
1002810
1003810
10011010
120185
1201810
1201815
50.00
66.32
70.56
70.84
68.18
65.18
65.24
65.72
67.66
67.40
68.88
67.61
67.82
67.09
69.03
66.07
70.10
Mixed treatment
62
Fig. 1. SEM micrographs of a) untreated Luffa bres; b) Alkali treated Luffa bres.
Fig. 2. SEM micrographs of a) gross morphology of untreated Luffa bres; b) brillary structure of treated bres.
substances (Table 1). In the second method, cleaned Luffa bres are
treated by solution containing both sodium hydroxide and hydrogen
peroxide mixed treatment (Table 1). In these two methods the sodium
hydroxide was used as a reagent for the delignication of Luffa bres,
the anthraquinone to catalyse the reaction of delignication and the
hydrogen peroxide as bleaching reagent. The duration of treatment,
the soda concentration, percentage of hydrogen peroxide and the
temperature are variable parameters. The obtained bres are washed
several times with distilled water and dried at 80 C during 2 h.
I002 Iam
100
I002
4. Conclusion
The aim of this work is to investigate the inuences of the chemical
treatment parameters on the structure of Luffa bres. The treatment
should enhance the crystalline structure of bres with the elimination of
amorphous materials. SEM micrographs and XRD patterns show the
change of the bre structure after alkali and mixed treatment. The
crystallinity index of many treated and untreated samples was found
63
and showed that their value depended on the parameter's choice. The
analysis showed that many treatments conditions enhanced the
crystalline structure of technical bres of Luffa. It was shown also that
other treatment conditions of mixed method can damage the crystalline
structure of technical Luffa bres. In this case, a ne structure of Luffa
bre can be obtained.
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