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3 PETROLEUM SYSTEM
Petroleum: Petroleum is a complex mixture of naturally occurring hydrocarbon
compounds found in rock and it can exist as solid, liquid and gaseous according to the
pressure-temperature-composition, with or without impurities such as sulphur, oxygen
and nitrogen; and there is considerable variation in its physicochemical properties like
colour, gravity, odour, sulphur content and viscosity in petroleum from different areas.
Petroleum System: The geologic components and processes necessary to generate and
store hydrocarbons, including a mature source rock, migration pathway, reservoir rock,
trap and seal are collectively called the petroleum system. Appropriate relative timing of
formation of these elements and the processes of generation, migration and accumulation
are necessary for hydrocarbons to accumulate and be preserved. Exploration plays and
prospects are typically developed in basins or regions in which a complete petroleum
system has some likelihood of existing.
hydrogen relative to carbon and oxygen. The hydrogen content of Kerogen is the
controlling factor for oil vs. gas yields from the primary hydrocarbon-generating
reactions.On the basis of chemical composition in the nature of organic matter the
kerogen is classified into four basic types as:
Kerogen Type
Predominant
Potential
Oil prone
Abundant Lacustrine
II
Moderate Marine
III
Gas prone
Small
IV
Terrestrial
Terrestrial(?)
Source seals.
A source rock is a rock that is capable of generating or that has generated movable
quantities of hydrocarbons. Typical source rocks, usually shales or limestone, contain
about 1% organic matter and at least 0.5% total organic carbon (TOC), although a rich
source rock might have as much as 10% organic matter. Rocks of marine origin tend to be
oil-prone, whereas terrestrial source rocks (such as coal) tend to be gas-prone.
Source rocks can be grouped into four basic categories, which are described in the table1. To be a source rock, a rock must have three features:
1. Quantity of organic matter
2. Quality capable of yielding moveable hydrocarbons
3. Thermal maturity.
(Table 2: The most common methods used to determine the potential of a source
rock.)
Generation: The most important factor in the generation of crude oil from the organic
matter from the sedimentary rocks is temperature.A minimum temperatureof 1200 F(500
C) is necessary for the generation of oil under average sedimentary basin condition.The
generation endsat 3500 F (1750 C).Time is also an important factor. The older the
amplitude (e.g. Bombay high), or they may be combination of several small anticlines.
Traps may be stacked vertically on top of each other where alternating reservoir and cap
rocks have been folded in the same anticline. Fault traps are numerous, but only small.
Faults can also be detrimental by breaching the seal of the cap rock and allowing the flow
of petroleum through the fault to the surface, where it may form an oil seep.
(Fig 3(a))
Stratigraphic traps: By juxtaposition of porous reservoir and impermeable cap rock due
to depositional variations in grain-size of different kinds of sediments stratigraphic traps
are formed. This may be due to the thinning of lenses of sand and gravel (wedge-end
traps), the morphology of carbonate reefs in sub-circular mounds (reef traps) or by the
juxtaposition of rock types at unconformity surfaces (unconformity traps). Although
unconformities are numerous, unconformity traps account for only 4% of world reserves,
possibly because petroleum may have already escaped at the ancient surface prior to the
formation of the unconformable beds. In Indian offshore region, especially, in the East
Coast, most of the deep-water traps are stratigraphic traps like pinch-outs, unconformities
etc. In Rudrasagar Oil Field of Assam is an example of stratigraphic trap, where
petroleum exists in shoestring fluvial sandstone.
Migration: Migration implies movement of hydrocarbon through rocks. There are two
types of migration in a petroleum system as described below.
Gas FVF: It is gas volume at reservoir conditions divided by gas volume at surface
conditions. This factor is used to convert surface measured volumes to reservoir
conditions, just as oil formation volume factors are used to convert surface measured oil
volumes to reservoir volumes.
Oil FVF: It is oil and dissolved gas volume at reservoir conditions divided by oil volume
at standard conditions. Since most measurements of oil and gas production are made at
the surface, and since the fluid flow takes place in the formation, volume factors are
needed to convert measured surface volumes to reservoir conditions. Oil formation
volume factors are almost always greater than 1.0 because the oil in the formation usually
contains dissolved gas that comes out of solution in the wellbore with dropping pressure.
Accumulation:Once oil and gas migrates into the trap,it separates according to
density.The gas,being lightest.goes to the top of the trap to from the free gas cap.The oil
goes to the middle,and the water,which is always present,is on the bottom.The oil portion
of the trap is saturated with a certain percentage of oil and water.The gas-oil and oilwater contacts are buoyantand are usually leveled.In some traps ,only gas and water are
found.In other traps only oil and water are found.