FULL TEST-6

INSTRUCTIONS :
1) This booklet is your Questions Paper containing 69 questions. Maximum marks: 240
2) The question paper consists of 3 parts (Mathematics, Physics and Chemistry). Each
part has 4 sections.
3) Section I contains 6 Single answer multiple choice type questions. Each question has
4 choices (A), (B), (C) and (D), out of which only one is correct. For each question in
Section I, you will be awarded 3 marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all
other cases, minus one (-1) mark will be awarded.
4) Section II contains 4 Multi answer type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which one or more is/are correct. For each question in Section
II, you will be awarded 4 marks if you have darkened only the bubble corresponding
to the correct answer and zero mark if no bubble is darkened. No negative mark will
be awarded for an incorrectly bubbled answer.
5) Section III contains 4 questions. Each question contains Statement-1 (Assertion) and
Statement-2 (Reason). Each question has 4 choices (A), (B), (C) and (D), out of
which only one is correct. For each question in Section III, you will be awarded 3
marks if you darken only the bubble corresponding to the correct answer and zero
mark if no bubble is darkened. In all other cases, minus one (-1) mark will be
awarded.
6) Section IV contains 3 Linked comprehension type questions. Based upon each
paragraph, 3 multiple choice questions have to be answered. Each question has 4
choices (A), (B), (C) and (D), out of which only one is correct. For each question in
Section IV, you will be awarded 4 marks if you darken only the bubble corresponding
to the correct answer and zero mark if no bubble is darkened. In all other cases,
minus one (-1) mark will be awarded.

IITIANS SPECTRUM

FULL TEST-6

MATHEMATICS
SECTION-I
Section I contains 6 multiple choice questions. Each question has 4 choices A), B), C)
and D), out of which only one is correct. For each question in Section I , you will be
awarded 3 marks if you have darkened only the bubble corresponding to the correct
answer and zero marks if no bubble is darkened. In all other cases, minus one (-1) will
be awarded
01.

Let f x be continuous function on 0,1 and if

1

f x dx 1, xf x dx 2 and x 2 f x dx 3 . Then the number of roots of

1

f x 0 in 0,1 is _____

a) exactly one

b) atleast one
n

02.

Find the value of

a)

03.

6 n
6 1
5

rs

d) none

The number of positive integral solutions x, y, z of the equation

x3 1 x 2 y
xy 2 y3 1
xz 2

yz 2

a) 0
04.

0, if r s
2r 3s where rs
s 1
rs 1, if r s
1
b) 6n 1
c) 6n 1
5

d) zero

r 1

c) atmost one

x 2z
y 2 z 11 is __
z3 1
b) 3

c) 6

d) 12

If f x be positive, continuous and differentiable on the interval a, b . If

1
3
1
then
lim f x 1 and lim f x 3 4 also f ' x f x

f x
xa
xb

a) b a

24

b) b a

24

c) b a

Space for rough work

12

d) b a

24

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FULL TEST-6

05.

a
Consider t 2 8t 13 dt x sin and a, x R 0 x takes the values for
x

which the equation has a solution, then the number of values of a 0,100 is ___
a) 1
06.

b) 2

c) 3

d) 4

If f x sgn sin 2 x sin x 1 has exactly four points of discontinuity for

x 0, n n N then n can be
a) only 4

b) 4 or 5

c) only 5

d) 5 or 6

SECTION-II
Section II contains 4 multiple correct answer type questions. Each question has 4 choices
A), B), C) and D), out of which one or more answers are correct. For each question in
Section II , you will be awarded 4 marks if you have darkened only the bubble
corresponding to the correct answer and zero marks if no bubble is darkened. In all
other cases, no negative marking for wrong answer.

07.

Which of the following statement (s) is/are true?

a) maximum value of P such that 3P divides 100! is 48
b) maximum value of P such that 3P divides 50! is 22
c) maximum value of P such that 3P divides 99 97 95 ......... 51 is 14
d) maximum value of P such that 3P divides 25! is 10

08.

Which of the following statements is / are true ?

a) cos cos 1 x sin 1 x 2 0
1
1

b) sin sin 1 cos 1 1 2 6

2
3

c) minimum value of e
3
d) tan 1 2 tan 1 3
4

cos cos1 x2 tan cot 1 x2

is e2

Space for rough work

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FULL TEST-6

x
y
x
y

2 1 and

1 0 intersect
2
2
2
4
cos sin
sin cos

at four points P,Q, R, S then which of the following statement(s) is /are true ?
a)
PQRS is a square with length of the side sin 2
sin 2
b)
PQRS lie on a circle whose centre is origin and with radius
2
c)
eccentricity of the two given ellipses are same
x2
y2
d)
there are two points on

1 whose reflection in y x lie

sin 2 cos 2
on the same ellipse

1
Consider the equation sin log 3 0
x

Then which of the following statements is /are true ?

a)
there exists, infinitely many solutions for the equation in 0, 2
2

09.

10.

Two ellipses

b)

there exists, finitely many solutions for the equation in 0, 2

c)

x 3 is one of the solution for the given equation in 0, 2

d)

sum of all the solutions of the given equation in 0, 2 is

9
2

SECTION-III
Section III contains 4 Reasoning type questions. Each question contains
STATEMENT1 and STATEMENT2.
Bubble A) if both the statements are TRUE and STATEMENT-2 is the correct
explanation of STATEMENT-1
Bubble B) if both the statements are TRUE but STATEMENT-2 is NOT the
correct explanation of STATEMENT- 1
Bubble C) if STATEMENT-1 is TRUE and STATEMENT-2 is FALSE.
Bubble D) if STATEMENT-1 is FALSE and STATEMENT-2 is TRUE.
For each question in Section III , you will be awarded 3 marks if you have
darkened only the bubble corresponding to the correct answer and zero marks if
no bubble is darkened. In all other cases, minus one (-1) will be awarded

11.

Statement I : when 2323 is divided by 53, the remainder is 30

Statement II : If n is the odd natural number (finite), greater than 1, then the
number of zeroes at the end of 99n 1 is 2

Space for rough work

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12.

13.

14.

FULL TEST-6

Statement I : If the circles x 2 y 2 2 x 4 y 4 0 and x 2 y 2 4 x 2 y c 0

intersect such that the common chord is longest, when c 4 .
Statement II : If two circles intersect, then the common chord so obtained, is
longest when it is a diameter of the smaller circle.
In any triangle ABC,
A
B
C
A
B
C

Statement I : log e cot cot cot log e cot log e cot log e cot
2
2
2
2
2
2

Statement II: In a triangle ABC, cotA.cotB+cotB.cotC+cotC.cotA=1

Let y x 3, y 2 x 3, y 3x 2, y x 3 be four lines.
Statement I : The number of triangles formed is 4 C3 .
Statement II : Number of distinct points of intersection between various lines
will determine the number of possible triangles.

SECTION-IV
Section IV contains 3 sets of Linked Comprehension type questions. Each set
consists of a paragraph followed by 3 questions. Each question has 4 choices A),
B), C) and D), out of which only one is correct.
For each question in Section IV, you will be awarded 4 marks if you have
darkened only the bubble corresponding to the correct answer and zero mark if no
bubble is darkened. In all other cases, minus one (-1) will be awarded
Paragraph for Question Nos.15 to 17
PASSAGE 1:
In a game of chess between two players A and B, either A wins or B wins or game
ends in a drawn. Probability of winning the game by A and B are
1
1
and respectively. They agree to play a chess tournament consisting of 3 games.
2
3

15.

16.

17.

The probability that 2 games end in a draw equals to

5
5
25
a)
b)
c)
d)
36
72
72
The probability that A and B wins alternately equals to
5
5
25
a)
b)
c)
d)
36
72
72
The probability that B wins at least 1 game, equals to
5
19
11
a)
b)
c)
d)
9
27
36
Space for rough work

25
36
25
36
25
72
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FULL TEST-6

Paragraph for Question Nos.18 to 20

PASSAGE 2:
Let f : R R be continous function and bijective, defined such that
f 0 0 . The area bounded by y f x , x , x t is equal to area

bounded by y f x , x , x t , t R then
18.

y f x is symmetrical about the point

a) 0, 0
19.

b) 0,

c) , 0

d) ,

c) f 0

d) f 0

c)

d) none

f 2 equal to _______

a) f

b) f

20.

Value of

f t dt ____
1

b) 2

a) 0

Paragraph for Question Nos.21 to 23

PASSAGE 3:
Let A,B,C represent the vertices of a triangle, where A is the origin and B and C
have position vectors b & c respectively. Points M, N and P are taken on sides AB,
BC and CA respectively such that
AM BN CP

, R 0 now
AB
CA
BC

AN BP CM
21.

b) b c
c) 1 b c
d) 0
a) 3 b c

22.
If represents the area enclosed by the three vectors AN , BP, CM then ___

a) 0

b)

b c
2 1
2

b c
d) b c 2 1
2 1

2
The value of for which is least
1
a) 0
b) 1
c)
2
c)

23.

Space for rough work

d)

1
4

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FULL TEST-6

PHYSICS
SECTION-I
Section I contains 6 multiple choice questions. Each question has 4 choices (A), (B),
(C) and (D), out of which only one is correct. For each question in Section I , you
will be awarded 3 marks if you have darkened only the bubble corresponding to
the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (-1) will be awarded
24.
A highly accurate determination of g has a quoted error of 6 parts in 109 . If the
dependence of g on geographical latitude at sea level is given by
g g 0 1 sin 2 where is the latitude and is a dimensionless constant

with a value of 0.0055, estimate the northward displacement near latitude 450
which gives a change in g equal to the quoted error (radius of earth
=R= 6.4 106 m )
a) 6m
b) 9 m
c) 7 m
d) 12m
25.

A
where n is an integer and A is a constant.
n2
Among the spectral lines that the atom can absorb at room temperature are two
adjacent lines with wavelengths 975 A0 and 1028A0 . The value of constant A is,
h 6.63 1034 JS

An atom has energy levels En

a) 2.176 1018 J
c) 2.415 1019 J

b) 5.435 1019 J
d) 1.359 1019 J

26.

A light bulb is constructed from 2 cm of tungsten wire of diameter 50 m and is

enclosed in an evacuated glass bulb. What temperature does the filament reach
when it is operated at a power of 1 watt. (Assume the emissivity of the tungsten
surface is 0.35 Stefans constant = 5.67 108 m 2 K 4 .
a) 2000 K
b) 4000 K
c) 2500 K
d) 1200 K

27.

A chlorine molecule with an initial velocity of 600 m/s absorbs a photon of

wavelength 350 nm and is then dissociated into two chlorine atoms. One of the
atoms is detected moving perpendicular to the initial direction of the molecule
and having a velocity of 1600 m/s Binding energy of the molecule is,
(neglect the momentum of the absorbed photon. Relative atomic mss of chlorine
is 35. 1 amu 1.66 1027 kg )
a) 5 eV
b) 2.5 eV
c) 1.25 eV
d) 4 eV
Space for rough work

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28.

FULL TEST-6

A converging lens of 6 cm focal length is mounted at a distance of 10cm from a

screen placed at right angles to the axis of the lens. A diverging lens of 12 cm
focal length is then placed coaxially between the converging lens and the screen
so that an image of an object 24 cm from the converging lens is focused on the
screen. The distance between the two lenses is
a) 4cm
b) 2 cm
c) 6cm
d) 8cm

29.

E1 6volt , E2 4 volt
r1 3, r2 2
R 8
The current following through 2 resistor is
a) 0.03amp
b) 0.06 amp
c) 0.09 amp

d) 0.12 amp

SECTION-II
Section II contains 4 multiple correct answer type questions. Each question has 4 choices
(A), (B), (C) and (D), out of which one or more answers are correct. For each
question in Section II , you will be awarded 4 marks if you have darkened only
the bubble corresponding to the correct answer and zero marks if no bubble is
darkened. In all other cases, no negative marking for wrong answer.

30.

A pendulum is constructed from two identical uniform thin rods A and B each of
length L and mass m, connected at right angles to form a T by joining the centre
of rod A to one end of rod B. The T is then suspended from the free end of rod
B and the pendulum swings in the plane of the T.

Space for rough work

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FULL TEST-6

17 2
a) The moment of inertia of the T about the axis of rotation is
mL .
12
13 2
b) The moment of inertia of the T about the axis of rotation is
mL
12
17 L
c) The period of small angular oscillations of T is 2
18 g
18 g
13L
A uniform solid cylinder is placed on a horizontal board. The coefficient of
friction between them is 0.3. The board is imparted a constant acceleration of
a 6m / s 2 in a horizontal direction at right angles of the cylindrical axis. Then
(take g 10m / s 2 )

d) The angular frequency of T for small angular oscillations is

31.

a) The acceleration of the cylinder axis in the absence of slipping

will be 1.5 m / s 2 .
b) The acceleration of the cylinder axis in the absence of slipping will be 2 m / s 2
c) The limiting value of a for which there will be no slipping is 12 m / s 2
d) The limiting value of a for which there will be no slipping is 9 m / s 2
32.

If white light is used in a Youngs double slit experiment,

a) bright white fringe is formed at the centre of the screen.
b) fringes of different colours are observed clearly only in the first order
c) the first order violet fringes are closer to the centre of the screen than the first
order red fringes
d) the first order red fringes are closer to the centre of the screen than the first
order violet fringes

33.

A long straight wire carries a current along the X-axis. Consider four points
P 0,1, 0 , Q 0,1,1 , R 1, 0,1 and S 1,1,1 . Which of the following pairs of
points will have magnetic fields of the same magnitude?
a) P and Q
b) P and R
c) Q and R
Space for rough work

d) Q and S
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FULL TEST-6

SECTION-III

Section III contains 4 Reasoning type questions. Each question contains

STATEMENT1 and STATEMENT2.
Bubble (A) if both the statements are TRUE and STATEMENT-2 is the
correct explanation of STATEMENT-1
Bubble (B) if both the statements are TRUE but STATEMENT-2 is NOT
the correct explanation of STATEMENT- 1
Bubble (C) if STATEMENT-1 is TRUE and STATEMENT-2 is FALSE.
Bubble (D) if STATEMENT-1 is FALSE and STATEMENT-2 is TRUE.

34.

35.

36.

For each question in Section III , you will be awarded 3 marks if you have
darkened only the bubble corresponding to the correct answer and zero marks if
no bubble is darkened. In all other cases, minus one (-1) will be awarded
STATEMENT 1: From the given current voltage graphs for a given metallic wire
at two different temperatures T1 and T2 we may conclude that
T2 is greater than T1 .

STATEMENT 2: The resistance of a metallic wire can be calculated by

V
taking the ratio .
I
STATEMENT 1: A hallow shaft is found to be more stronger than a solid shaft of
same mass, length and made of same material.
STATEMENT 2: The torque due to couple per unit twist for a hollow shaft is
greater than that for a solid shaft of the same material, mass and
length
STATEMENT 1: If T represents the mean life of a radioactive sample, then 75%
of the active nuclei present in the sample initially will decay in
time 2 (loge 2) T
STATEMENT 2: 25% of active nuclei present in a radioactive sample remain
undecayed after 2 half lives and half life is related to mean life
as T1 log e 2 T
2

Space for rough work

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37.

FULL TEST-6

STATEMENT 1: A ball of mass m is suspended on a weightless elastic thread

whose stiffness factor is equal to K. When the ball is lifted so
that the thread is not stretched and let fall with the zero initial
velocity, the maximum stretch of the thread in the process of
2mg
.
the balls motion will be
K
STATEMENT 2: For a freely falling body, in the absence of air-resistance, the
decrease in potential energy is equal to increase in kinetic
energy.
SECTION-IV
Section IV contains 3 sets of Linked Comprehension type questions. Each set
consists of a paragraph followed by 3 questions. Each question has 4 choices (A),
(B), (C) and (D), out of which only one is correct.
For each question in Section IV , you will be awarded 4 marks if you have
darkened only the bubble corresponding to the correct answer and zero mark if
no bubble is darkened. In all other cases, minus one (-1) will be awarded
Paragraph for Question Nos.38 to 40
PASSAGE - 1 : A block of mass m1 1kg is placed on a plank of mass
m2 3 kg , which rests on a smooth horizontal plane. The coefficient of friction
between the surfaces of the block and the plank is equal to, 0.2 . The plank is
subjected to the horizontal force F depending on time t as F 2t newton, t in
second (take g 10m / s 2 )

38.
39.

Find the moment of time t0 at which the plank starts sliding from under the bar.
a) 3 sec
b) 1 sec
c) 2 sec
d) 4 sec
Find the acceleration of the plank in the process of its motion in time t t0 .
a)

2 t 1
m / s2
3

c) 2t 3 m / s 2

b)

2t 1 m / s 2

3
2
t
1 m / s 2
d)
4

Space for rough work

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IITIANS SPECTRUM

40.

FULL TEST-6

If a graph is plotted by taking time t on x-axis and acceleration of block a1 ,

and plank a2 on Y-axis, the nature of graphs will be

41.

a)

b)

c)

d)

Paragraph for Question Nos.41 to 43

PASSAGE - 2 : A coaxial cable consists of two thin coaxial cylinders electrically
connected at one end, an inner cylindrical conducting tube of radius r1 10mm
carrying a steady current I = 1.7 ampere which is screened by at outer cylindrical
conducting sheath of radius r2 20mm which provides a return path. Assume
that there is no dielectric medium present.
Calculate total magnetic energy stored in the space between the conductors of this
cable of length l 1000m log e 2 0.693

a) 0.1 milli Joule

c) 0.2 milli joule

b) 0.4 millijoule
d) 0.3 milli joule

Space for rough work

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IITIANS SPECTRUM

42.

43.

FULL TEST-6

The self inductance L, of this cable is

a) 1.39 104 Henry
c) 6.93 105 Henry

b) 2.78 104 Henry

d) 5.56 104 Henry

If this cable is now employed in a resistanceless LC circuit containing a

capacitance C=1 millifarad, find the period of oscillations (neglect the
capacitance of the cable itself)
a) 1.17 milli second
b) 2.34 milli second
c) 2.69 milli second
d) 3.51 milli second

Paragraph for Question Nos.44 to 46

PASSAGE - 3 : Two moles of an ideal monoatomic gas is taken through a cycle ABCA
as shown in P ~ T diagram.

During the process AB, pressure and temperature of the gas vary such that
PT=constant. T1 300 K (given) R= Universal gas constant

44.

45.

46.

Work done in the process A B is

a) 1200 R
b) 600 R

c) 300 R

Heat absorbed or released in the process B C is

a) 1200 R
b) 900 R
c) 1500 R

d) 900 R

d) 400 R

Heat absorbed or released in the process C A is

a) 1200 R
b) 1200 R (loge 2)
1200 R
c)
d) 600 R (loge 2)
log e 2

Space for rough work

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IITIANS SPECTRUM

FULL TEST-6

CHEMISTRY

47.

PART-III
SECTION-I
Section I contains 6 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D), out of which only one is correct. For each question in Section I ,
you will be awarded 3 marks if you have darkened only the bubble corresponding
to the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (-1) will be awarded
For a hypothetical elementary reaction (both k1 and k2 first order rate constants)

2B

k1

where

A
k2

k1
k2

1
2

2C

Initially only two moles of A are present. Then total number of moles of
A, B and C at the end of 50% reaction are
a) 2
b) 3
c) 1
d) 4
48
O O
Ph

H
Me

H 2SO 4

A B ; A and B are

Me
a)

Me

b)

OH

CH3

and

COMe

and

OH

c)

Me

Me

d)

Me
O

and MeOH

Me
OPh

Me

OPh

Space for rough work

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IITIANS SPECTRUM

49

FULL TEST-6

Suppose POCl3 hydrolyses in water to give H 3 PO4 and HCl only. What volume

of 2M Ca OH 2 is needed to completely neutralise 50ml 0.1M POCl3 solution?

b) 7.5ml
d) 10ml

a) 5ml
c) 15ml
50

The correct order of temperatures of a real gas is

I) Boyles temperature
II) Critical temperature
III) Inversion temperature
b) I II III
a) III I II
d) I III II
c) II I III

51

Which of the following is correct ?

a)When FeCl3 is treated with K3 Fe CN 6 a brown colored complex is formed
b) When Fe3 salt treated with CH 3COONa solution, reddish brown ppt is

formed i.e. Fe3 OH 2 CH 3COO 6

c) Fe3 salt forms Fe2 Fe CN 6 on treating with K 4 Fe CN 6
d) Fe3 salt forms deep-red coloured precipitate with NH 4 SCN
52

The value of H 0 for the reaction 2 A g B g A2 B g for which

Kp 1.0 1010 atm2 and S 0 5 JK 1 and T 300 K is

b) 58.94kJ
a) 53.93kJ
d) 68.24kJ
c) 56.24kJ

Space for rough work

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FULL TEST-6

SECTION-II
Section II contains 4 multiple correct answer type questions. Each question has 4 choices
(A), (B), (C) and (D), out of which one or more answers are correct. For each question in
Section II , you will be awarded 4 marks if you have darkened only the bubble
corresponding to the correct answer and zero marks if no bubble is darkened. In all other
cases, no negative marking for wrong answer.

53

In which of the following reactions, a phenolic compound is formed as product ?

CH2

CH

CH2

NO 2

K 3 Fe CN 6

NaOH

a)

b)
CH3

CHO
H2O2 / OH

H Excess

c)
54

d)

NHOH

Which of the following compounds do not give Cannizaro reaction ?

CHO
CHO
Cl

a) OH

Cl

b)

H2C

CHO

H C
c) 2

CHO

CHO

d)

CHO

55
+

N Cl

Nu

Nu

+
G

N2

Which of the following is not correct regarding above reaction ?

a) If G is a +R group and present at para position, it will increase the rate of
reaction
b) If G is a R group and present at para position, it will increase the rate of
reaction
c) If G is +I group and present at meta position, it will increase the rate of
reaction
d) If G is I group and present at meta position, it will increase the rate of
reaction
Space for rough work

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56

FULL TEST-6

Which of the following statement is/are correct ?

a) Fraction of radioactive atoms decayed 1 e t
24
b) 11
N emits radiation
c) The number of -particles emitted during the change ca X bd Y is equal to
a b
d
c
2
d) The total number of particles emitted during thorium series is equal to six
SECTION-III
Section III contains 4 Reasoning type questions. Each question contains STATEMENT1
and STATEMENT2.
Bubble (A) if both the statements are TRUE and STATEMENT-2 is the correct explanation
of STATEMENT-1
Bubble (B) if both the statements are TRUE but STATEMENT-2 is NOT the correct
explanation of STATEMENT- 1
Bubble (C) if STATEMENT-1 is TRUE and STATEMENT-2 is FALSE.
Bubble (D) if STATEMENT-1 is FALSE and STATEMENT-2 is TRUE.
For each question in Section III , you will be awarded 3 marks if you have darkened only
the bubble corresponding to the correct answer and zero marks if no bubble is darkened.
In all other cases, minus one (-1) will be awarded

57

Statement-1: Trisilyl amine is stronger base than trimethyl amine

Statement-2: In trisilyl amine a p d back bonding exists which leads to
decrease in the electron density on nitrogen atom

58

Statement-1: C-F bond length in the given species CF , CF , CF is as follows

CF CF CF

Statement-2: In CF , there is no electron in *2 p orbitals while in CF and CF ,

there are one and two electrons respectively.

Space for rough work

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IITIANS SPECTRUM

FULL TEST-6
O

OH

CH3

H3C

59.

Statement-1:

undergoes dehydration more rapidly

O

OH

CH3

H3C
Cl

compared to
Statement-2: Both compounds undergo dehydration by E1cb mechanism where
O

OH

CH3

H3C

X F or Cl is the intermediate is formed.

Statement-1: When the tube of bicycle tyre is filled with air at constant
temperature the pressure as well as the volume of air increases.
Statement-2: Boyles law is not verified using the expandable vessels like rubber
tubes.
SECTION-IV
X

60.

Section IV contains 3 sets of Linked Comprehension type questions. Each set consists of a
paragraph followed by 3 questions. Each question has 4 choices (A), (B), (C) and (D), out
of which only one is correct. For each question in SectionIV , you will be awarded 4
marks if you have darkened only the bubble corresponding to the correct answer and zero
mark if no bubble is darkened. In all other cases, minus one (-1) will be awarded

Paragraph for Question Nos.61 to 63

Passage 1:

61.
62.

63.

Diamond is a crystalline allotrope of carbon, which crystallizes in a 3dimensional lattice. Each carbon forms four bonds with other carbon atoms. The
unit cell of the diamond lattice can be thought of containing carbon atoms present
at all CCP positions as well in alternate tetrahedral voids. Assuming contact
between nearest atoms, answer the following .
Number of carbon atoms per unit cell of diamond structure is
a) 4
b) 8
c) 12
d) data insufficient
What is the fraction of length covered along the body diagonal of the cubic unit
cell by carbon atoms?
a) 0.50
b) 0.34
c) 0.75
d) 0.25
How much fraction of area of one face is covered by atoms?
3
6
9
3
b)
c)
d)
a)
32
32
32
64
Space for rough work

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IITIANS SPECTRUM

FULL TEST-6

Paragraph for Question Nos.64 to 66

Passage 2:

64

An orange colored compound (X) on heating decomposes to form a solid and

gases mixture which contains a gas (Y) and H 2O vapour. (Y) on treatment with
CaC2 gives (Z). (Z) on hydrolysis with hot water liberates a gas (P) which when
added to Hg 2Cl2 results in the formation of black precipitate
The compound X is
b) K 2Cr2O7
a) NH 4 CO3
2

65

66

c) NH 4 2Cr2O7

d) Na2Cr2O7

The compound (Y) is

a) NO2
c) NH 3

b) N 2O
d) N 2

What would be the colour if solution of (P) is added in excess to Ni 2 solution

a) red
b) green
c) colour less
d) blue

Paragraph for Question Nos.67 to 69

Passage 3:
CH3

Zn Hg HCl
HF
Se
1)MeMgI
H
3 A
CH 2CO O
B
C
E
D
H F
H O

AlCl

67

2)H3O

Ozonalysis
OH ,
' E '

major product

CHO

Me

Me
CH3

a)

b)

Me
CO

Me
c)

OH

d)
Space for rough work

CH3
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IITIANS SPECTRUM

68
69

FULL TEST-6

No. of possible structural isomers for F is

a) 2
b) 10

mononitration produces
F

c) 14

d) 6

(Major product)

CH3

H3C

H3C
NO2

a)

CH3
NO2

b)

NO2

CH3

CH3

H3C
c)

CH3

Space for rough work

d)

NO2

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