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Kw, pH
pH
Kw
What is the value of Kw?
It has been measured at 1.0 x 1014 (25 C)
Notice (pg. 600) that by definition:
the solution is
when
[H+] > [OH]
acidic
basic
[H+] < [OH]
neutral
[H+] = [OH]
Pure water is neutral since [H+] and [OH]
must be identical (both come from one H2O)
As temperature increases Kw increases
Q: Rewrite the equilibrium of water with heat as
a product or reactant (based on above point)
Q: Do PE 1 (refer to example 15.1)
Calculations with pH
[H+],
[H+]
pH = log
what is pH if
= 6.3 x
Enter 6.3 x 105 (6.3, exp, 5, +/-)
Then hit log, followed by +/-
105?
[H+] = 10pH
[OH] = 10pOH
pH = log [H+]
pOH = log [OH]
pH + pOH = 14
Read footnote on 601 about significant digits
Do PE 2 4 on pg. 605
Use examples 15.2 15.4 as reference
Measuring pH
Using pH meters