Question 1: The enthalpy of function of water is 1.435 kcal/mol.

The molar entropy change for the

melting of ice at 0 C is

(a) 5.260 cal /(mol K)

(b) 0.526 cal /(mol K)

(c) 10.52 cal /(mol K)

(d) 21.04 cal /(mol K)

Question 2: Based on the first law of thermodynamics, which one of the following is correct?
(a) For an isothermal process, q = + w

(b) For an isothermal process, U = -q

(c) For an adiabatic process, U = -w

(d) For a cyclic process, q = -w

Question 3: The correct sequence of steps involved in the mechanism of Cannizzaros reaction is ______.
(a) nucleophilic attack, transfer of H- and transfer of H+
(b) electrophilic attack by OH- , transfer of H+ and transfer of H(c) transfer of H- , transfer of H+ and nucleophilic attack
(d) transfer of H+, nucleophilic attack and transfer of H-

Question 4: Which of the following is correct?

(a) Any aldehyde gives secondary alcohol on reduction
(b) Reaction of vegetable oil with H2SO4 gives glycerin
(c) C2H5OH, iodine with NaOH gives iodoform
(d) Sucrose on reaction with NaCl give invert sugar

Question 5: Acetone is treated with excess of ethanol in the presence of hydrochloric acid. The product
obtained is:

(a)

(b)

(c)

(d)

H O ,Hg2

3
?
Question 6: Identify the product in the reaction PhC CMe

(a) PhCH2CH2CHO

(b) PhCOCH2CH3

(c) PhCH2COCH3

(d) PhCOCOMe

Question 7: Which of the following statements is not correct?

(a) Aldehydes and ketones undergo nucleophilic addition
(b) Aldehydes and ketones undergo electrophilic substitution

(c) Aldehydes and ketones contain polar carbonyl group

(d) Lower members of aldehydes and ketones are soluble in water due to hydrogen bonding

Question 8: Compound A undergoes formation of cyanohydrins which on hydrolysis gives lactic acid (
CH3CHOHCOOH). Therefore, compound A is
(a) formaldehyde

(b) acetaldenyde

(c) acetone

(d) benzaldehyde

Q.9: Which systemic diagram represents the correct chemical relations between benzene/ chlorobenzene,
and phenol?

Q.10. Which systemic diagram represents the correct chemical relations between pyrrole and its related
compounds?

Q.11. Which systemic diagram represents the reaction sequence Substitution Substitution EliminationAddition?

Q.12. Which Systemic diagram represents the chemical relations between oxirane, aziridine, ethanolamine,
and ethylene?

Q.13. What is the major product obtained from the following reaction?

Question 14: t1/4 can be taken as the time taken for the concentration of a reactant to drop to of its
initial value. If rate constant for a first order reaction is k, then t1/4 can be written as
(a) 0.01 / k

(b) 0.29 /k

(c) 0.69 /k

(d) 0.75 / k

Question 15: In a first reaction, the concentration of the reactant decreases from 0.8 M to 0.4 M in 15
minutes. The time taken for the concentration to change from 0.1 M to 0.025 M is
(a) 7.5 min

(b) 15 min

(c) 30 min

(d) 60 min