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GAS AND
CONDENSED
MATTER
PREPARED BY:
NOR HALIZA YAAKOB,
Faculty of Applied Science
Universiti Teknologi MARA
Campus of Negeri Sembilan
72000 Kuala Pilah, Negeri
Sembilan, MALAYSIA.
PHY 351 (Materials Science)
013-9495135
norhaliza@ns.uitm.edu.my
SCOPE OF STUDY
1.1: Force between particle
1.2: Ideal Law, Real Gas, Van der Waals
of State Equation
1.3: Condensed Matter-solid and liquid
Triple Point
INTRODUCTION
Materials may be defined as substance of which
something is composed or made.
Materials Science is a scientific discipline that
is primarily concerned with the search for basic
knowledge about the internal structure,
properties and processing of materials.
Material engineering is an engineering disciple
that is primarily concerned with the use of
fundamental and applied knowledge of materials,
so that they can be converted into products
needed or desired by society.
ii.
Intramolecular Forces
What would intramolecular forces be?
Forces within molecules e.g covalent,
metallic or ionic.
are stronger
than
Intermolecular Forces
Forces that occur between molecules.
Types of Intermolecular
forces
The three main types of intermolecular forces
are:
i. Dipole-dipole attraction - occur only btw
polar molecules.
ii. H bonding only with Hydrogen and Oxygen,
Fluorine and Nitrogen).
iii. Dispersion forces (London Dispersion
Forces).
DipoleDipole Attraction
Dipole moment molecules with polar bonds
often behave in an electric field as if they
had a center of positive charge and a center
of negative charge.
Molecules with dipole moments can attract
each other electrostatically. They line up so
that the positive and negative ends are close
to each other.
Only about 1% as strong as covalent or ionic
bonds.
Hydrogen Bonding
The electromagnetic attractive interaction
between polar molecules in which Hydrogen
is bound to a highly electronegative atom
nitrogen, oxygen, or fluorine.
Strong dipole-dipole forces.
Hydrogen Bonding
Affects physical properties:
i. Boiling point
Become stronger
as the sizes
of atoms or
molecules
increase.
Strength of Intermolecular
Interactions
Hydrogen Bonding
Dipole Dipole
elastic collision.
4. Average particle speed increases with temperature.
5. The molecules are separated by great distances
relative to their size.
Kinetic Energy
The kinetic energy of a particle is given by
the equation:
Where:
KE
1
mv 2
2
m = particle mass in kg
v = particle velocity in m/s
KE = kgm2/s2 = J (joule)
According to postulate 4 of our kinetic theory
particle velocity increases with temperature.
This means as temperature increases then
kinetic energy increases.
Potential Energy
Potential energy is the sum of the attractive
and repulsive forces between particles.
Alternatively we can say forces between
particles may be either cohesive or disruptive.
Cohesive
forces
include
dipole-dipole
interactions, dispersion forces, attraction
between oppositely charged ions. Cohesive
forces are largely temperature independent.
1
Boyles Law: V (constant n, T )
P
Charless Law: V T (constant n, P)
Avogadros Law: V n (constant P,T )
We can combine these into a general gas law:
nT
V
P
PV nRT
Real Gases behave ideally at low P and high
T.
PV nRT
P, pressure = Pa
V, volume = m3
n, number of moles = moles
R, universal gas constant = J mol-1 K-1
T, temperature = K
= . /
This is called one atmosphere (atm).
1 Pascal (Pa) = 1 N/m2
=
where k is called Boltzmanns constant.
Real Gases:
Deviations from Ideality
Real gases behave ideally at
ordinary temperatures and
pressures.
At low temperatures and high
pressures real gases do not behave
ideally.
The reasons for the deviations
from ideality are:
The molecules are very close to
one another, thus their volume is
important.
The molecular interactions also
become important.
n 2a
V nb nRT
P +
2
V
The van der Waals constants a and b take into account two
things (correction van der Waals made):
1) a accounts for intermolecular attraction
i. For nonpolar gases the attractive forces are
London Forces
ii.For polar gases the attractive forces are dipoledipole attractions or hydrogen bonds.
Corrects for
molecular
volume
General form of the van der Waals equation:
2
n
P a V nb nRT
2
Condensed matter
The three states of matter.
liquid
solid
Compressible.
lots of free space
between particles
flows easily.
particles can move past
one another
flows easily
particles can
move/slide past one
another
Condensed States of
Matter:
.
Liquids
Solids
Like
gases,
the
condensed states of
matter can consist of
atoms,
ions,
or
molecules.
What separates the
three states of matter
is the proximity of the
particles
in
the
substance.
For the condensed
states of matter the
particles are close
enough to interact.
Phase Changes