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FACULTY OF ENGINEERING
CIVIL DEPARTMENT
CE-547
Corrosion of Plain &Reinforced concrete
Report #4 About :
(Test Methods for measurement and monitoring of corrosion )
Submitted to:
2014 45056
Date : 26.03. 2015
List of contents :
What is Corrosion Monitoring?
The Need for Corrosion Monitoring
Methods of measurements
*Open circuit potential (half-cell) MEASUREMENTS
* Surface Potential (SP) Measurements
* concrete resistivity - Resistivity Meter
*Lnear Polarization Resistance (LPR)
Conclusions
Analytical Chemistry
pH measurement
Dissolved gas (O2, CO2, H2S)
Metal ion count (Fe2+, Fe3+)
Microbiological analysis
Operational Data
pH
Flow rate (velocity)
Pressure
Temperature
Fluid Electrochemistry
Potential measurement
Potentiostatic measurements
Potentiodynamic
measurements
A.C. impedance
Corrosion Monitoring
Weight loss coupons
Electrical resistance
Linear polarization
Hydrogen penetration
Galvanic current
Some corrosion measurement techniques can be used on-line, constantly exposed to the process
stream, while others provide off-line measurement, such as that determined in a laboratory analysis.
Some techniques give a direct measure of metal loss or corrosion rate, while others are used to
infer that a corrosive environment may exist.
Corrosion monitoring is the practice of measuring the corrosivity of process stream conditions by the
use of "probes" which are inserted into the process stream and which are continuously exposed to
the process stream condition.
Corrosion monitoring "probes" can be mechanical, electrical, or electrochemical devices.
Corrosion monitoring techniques alone provide direct and online measurement of metal
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In a well controlled and coordinated program, data from each source will be used to draw
meaningful conclusions about the operational corrosion rates with the process system and how
these are most effectively minimized.
Methods of measurements:
Many of the strategic reinforced and prestressed concrete structures have
started showing signs of distress with in a short period usually the condition
of the structures is monitored by visual inspection and remedial measures are
resorted to only when the condition becomes very serious by
way to heavy rusting of steel reinforcements followed by cracking and
spalling on concrete.
It is desirable to, monitor the condition of such strategic structures right from
the construction stage by carrying out periodic corrosion surveys and
maintaining a record of data. For measurement of the corrosion rate of
reinforcing steel in concrete, many electrochemical and non-destructive
techniques are available for monitoring corrosion of steel in concrete
structures.
The role of the half-cell is to insure constant reference potential. The metal rod is
connected with reinforcement steel by a voltmeter, and the ion solution is
connected to the pore water via moist porous plug. Measuring method is based on
many measurements of potential and correlation of measured potentials with
observed corrosion rate at reinforcement. Table 2 presents criteria according to
ASTM C-876 standard for cooper-cooper sulphate electrode, and also for calomel
and silver-silver chloride. The main application of this method is in situ.
Cu/CuSO4
Calomel (SCE)
Ag/AgCl
E>-200mV
E>-126mV
E>-119mV
Interpretation
Greater than 90% probability that no
corrosion is occurring
-200mV < E < - -126mV < E < - -119mV < E < Corrosion activity is uncertain
350mV
276mV
269mV
E<-350mV
E<-276mV
E<-269mV
he Surface Resistivity (SR) test is a much quicker and easier test for estimating
concrete permeability. The traditional testing method, Rapid Chloride Penetration was
laboratory based and very labour intensive, taking 4 days of preparation and testing
including cutting, epoxying, desiccation and testing. A study initiated in 2002 by the
Florida Department of transport has determined a strong correlation between Rapid
Chloride Penetration [RCP] measurements and resistivity measurements (see image
below). This discovery now means permeability testing can now be done in 10
minutes instead of 10 days using the same cylinders or cores used to determine
compressive strength.
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Principle of Operation
This allows the Resipod to measure much higher resistivitys than a basic Wenner
Probe.
The contact extension cable kit can also be used to attain variable spacing for the
contacts. Spacing from 20-85mm can be achieved using the kit, which is bought as an
optional accessory.
Features
Despite being extremely simple to use, ResiPod provides a variety of features that are
unique in a concrete surface resistivity instrument.
ResipodLink Software
The collected measurement values can then be analysed comfortably with the ResiPod
Link PC tool.
System requirements: Windows XP, Windows Vista, Windows 7, USB-Connector.
An internet connection is necessary for soft- and firmware (using PqUpgrade) updates
if available.
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The ResiPod can now be upgraded to take bulk resistivity of 102 x 204 mm cylinders
using the Bulk Resistivity Module. Bulk Resistivity measurements are taken in such a
way that the whole of the cylinder informs the result and are able to be correlated to
surface resistivity measurements. The module includes 2 metal and sponge contacts
and a convenient stand for the ResiPod.
With this widely used technique in corrosion monitoring, the polarization resistance of a
material is defined as the slope of the potential-current density (DE/Di) curve at the free
corrosion potential, yielding the polarization resistance Rp that can be related
(forreactions under activation control) to the corrosion current by the Stern-Geary
equation:
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where:
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Conclusions
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Regards...
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