For AIEEE/PMET/PPMET

CHAPTER : CHEMICAL BONDING & MOLECULAR

STRUCTURE
Q.1 shape and hybridisation of IF5
(a) trigonal bi-pyramidal, sp3d (b) see saw, sp3d (c) square pyramidal, sp3d2 (d) pentagonal
pyramidal, sp3d3
Q.2 the bond angle and dipole moment of water are
(a) 109.5, 1.84 D (b) 107.5 , 1.56 D (c) 104.5, 1.84 d (d) 102.5 , 1.56 D
Q.3 the calculated bond order of superoxide ion (O 2-) is (a) 1.5 (b) 1 (c) 2.5 (d) 2
Q.4 the number of nodal planes present in s* antibonding orbital is (a) 0 (b) 3 (c) 1 (d) 2
Q.5 which of the following pairs of species have the same bond order (a) O 2-, CN- (b) NO+, CN+ (c)
CN-, NO+ (d) CN-, CN+
Q.6 which one of the following constitutes a group of the iso-electronic species
(a) CN-, N2, O22-, C22- (b) N2, O2-, NO+, CO (c) C22-, O2-, CO, NO (d) NO+, C22-, CN-, N2
Q.7 the angular shape of ozone molecule (O 3) consists of
(a) 1 sigma and 2 pi-bonds (b) 2 sigma and 2 pi-bonds (c) 1 sigma and 1 pi-bond (d) 2 sigma and
1 pi-bond
Q.8 one of the following examples exhibits transient existence (a) H (b) H 2+ (c) H+ (d) He|
Q.9 shape of ClF3 is (a) equilateral tringle (b) pyramidal (c) V-shaped (d) T-shaped
Q.10 the magnetic moment of KO 2 at room temperature is ______BM (a) 1.41 (b) 1.73 (c) 2.23
(d) 2.64
Q.11 which of the following is correctly based on molecular orbital theory for peroxide ion
(a) its bond order is 2 and it is diamagnetic (b) its bond order is 1 and it is paramagnetic
(c) its bond order is 2 and it is diamagnetic (d) its bond order is 1 and it is diamagnetic
Q.12 which of the following is paramagnetic with bond order 0.5 (a) F 2 (b) H2+ (c) N2 (d) B2
Q.13 the hybridisation of oxygen atom in H 2O2 is (a) sp3d (b) sp (c) sp2 (d) sp3
Q.14 in TeCl4, the central atom, Te, involves in the hybridisation (a) sp 3 (b) sp3d (c) sp3d2 (d) dsp2
Q.15 the %age of p-character in the orbitals forming P-P bonds in P 4 is (a) 25 (b) 33 (c) 50 (d)
75
Q.16 the species having bond order different from that of CO is (a) NO - (b) NO+ (c) CN- (d) N2
Q.17 bond order of nitric oxide is (a) 1 (b) 2.5 (c) 2 (d) 1.5
Q.18 the no. of lone pairs of electrons present on the central atom of ClF 3 is (a) 0 (b) 1 (c) 2 (d)
3
Q.19 hydrogen bonding is strongest in (a) S-HO (b) O-H..S
(c) F-H..F (d) O-H..N
Q.20 the correct order regarding the electronegativity of hybrid orbitals of carbon is
(a) sp < sp2 > sp3 (b) sp < sp2 < sp3 (c) sp > sp2 < sp3 (d) sp > sp2 > sp3
Q.21 which of the following is least volatile (a) HF (b) HBr (c) HCl (d) HI
Q.22 the electronegativity difference between N & F is greater than that between N & H yet the
dipole moment of NH3 is larger than that of NF3. This is because
(a) in NH3 as well as NF3, the atomic & bond dipole are in the same direction
(b) in NH3, the atomic dipole & bond dipole are in same direction while in NF 3, these are in opposite
direction
(c) in NH3 as well as NF3, the atomic & dipole moment are in opposite direction
(d) in NH3, the atomic & bond dipole are in the opposite direction while in NF 3 atomic & bond dipole
are in same direction
Q.23 the decreasing value of bond angles from ammonia to SbH 3 down the group is due to
(a) increasing bp-bp repulsion (b) increasing p-orbital character in sp 3
(c) decreasing lp-lp repulsion
(d) decreasing electronegativity
Q.24 what type of bonding is present in Na 2 (g) (a) covalent bond (b) ionic bond (c) metallic bond
(d) molecular bond
Q.25 which of the following has zero dipole moment (a) ClF (b) PCl 3 (c) SiF4 (d) CFCl3