The bond angle and dipole moment of water are (a) 109.50, 1. D (b) 107., 1. D (c) 104.50,. 1. D (d) 102. The calculated bond order of superoxide ion (O 2-) is (a) 1. (b) 1 (c) 2. (d) 2 Q. The magnetic moment of KO 2 at room temperature is ______.
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AQ chamical bonding & molecular structure.docx
The bond angle and dipole moment of water are (a) 109.50, 1. D (b) 107., 1. D (c) 104.50,. 1. D (d) 102. The calculated bond order of superoxide ion (O 2-) is (a) 1. (b) 1 (c) 2. (d) 2 Q. The magnetic moment of KO 2 at room temperature is ______.
The bond angle and dipole moment of water are (a) 109.50, 1. D (b) 107., 1. D (c) 104.50,. 1. D (d) 102. The calculated bond order of superoxide ion (O 2-) is (a) 1. (b) 1 (c) 2. (d) 2 Q. The magnetic moment of KO 2 at room temperature is ______.
STRUCTURE Q.1 shape and hybridisation of IF5 (a) trigonal bi-pyramidal, sp3d (b) see saw, sp3d (c) square pyramidal, sp3d2 (d) pentagonal pyramidal, sp3d3 Q.2 the bond angle and dipole moment of water are (a) 109.5, 1.84 D (b) 107.5 , 1.56 D (c) 104.5, 1.84 d (d) 102.5 , 1.56 D Q.3 the calculated bond order of superoxide ion (O 2-) is (a) 1.5 (b) 1 (c) 2.5 (d) 2 Q.4 the number of nodal planes present in s* antibonding orbital is (a) 0 (b) 3 (c) 1 (d) 2 Q.5 which of the following pairs of species have the same bond order (a) O 2-, CN- (b) NO+, CN+ (c) CN-, NO+ (d) CN-, CN+ Q.6 which one of the following constitutes a group of the iso-electronic species (a) CN-, N2, O22-, C22- (b) N2, O2-, NO+, CO (c) C22-, O2-, CO, NO (d) NO+, C22-, CN-, N2 Q.7 the angular shape of ozone molecule (O 3) consists of (a) 1 sigma and 2 pi-bonds (b) 2 sigma and 2 pi-bonds (c) 1 sigma and 1 pi-bond (d) 2 sigma and 1 pi-bond Q.8 one of the following examples exhibits transient existence (a) H (b) H 2+ (c) H+ (d) He| Q.9 shape of ClF3 is (a) equilateral tringle (b) pyramidal (c) V-shaped (d) T-shaped Q.10 the magnetic moment of KO 2 at room temperature is ______BM (a) 1.41 (b) 1.73 (c) 2.23 (d) 2.64 Q.11 which of the following is correctly based on molecular orbital theory for peroxide ion (a) its bond order is 2 and it is diamagnetic (b) its bond order is 1 and it is paramagnetic (c) its bond order is 2 and it is diamagnetic (d) its bond order is 1 and it is diamagnetic Q.12 which of the following is paramagnetic with bond order 0.5 (a) F 2 (b) H2+ (c) N2 (d) B2 Q.13 the hybridisation of oxygen atom in H 2O2 is (a) sp3d (b) sp (c) sp2 (d) sp3 Q.14 in TeCl4, the central atom, Te, involves in the hybridisation (a) sp 3 (b) sp3d (c) sp3d2 (d) dsp2 Q.15 the %age of p-character in the orbitals forming P-P bonds in P 4 is (a) 25 (b) 33 (c) 50 (d) 75 Q.16 the species having bond order different from that of CO is (a) NO - (b) NO+ (c) CN- (d) N2 Q.17 bond order of nitric oxide is (a) 1 (b) 2.5 (c) 2 (d) 1.5 Q.18 the no. of lone pairs of electrons present on the central atom of ClF 3 is (a) 0 (b) 1 (c) 2 (d) 3 Q.19 hydrogen bonding is strongest in (a) S-HO (b) O-H..S (c) F-H..F (d) O-H..N Q.20 the correct order regarding the electronegativity of hybrid orbitals of carbon is (a) sp < sp2 > sp3 (b) sp < sp2 < sp3 (c) sp > sp2 < sp3 (d) sp > sp2 > sp3 Q.21 which of the following is least volatile (a) HF (b) HBr (c) HCl (d) HI Q.22 the electronegativity difference between N & F is greater than that between N & H yet the dipole moment of NH3 is larger than that of NF3. This is because (a) in NH3 as well as NF3, the atomic & bond dipole are in the same direction (b) in NH3, the atomic dipole & bond dipole are in same direction while in NF 3, these are in opposite direction (c) in NH3 as well as NF3, the atomic & dipole moment are in opposite direction (d) in NH3, the atomic & bond dipole are in the opposite direction while in NF 3 atomic & bond dipole are in same direction Q.23 the decreasing value of bond angles from ammonia to SbH 3 down the group is due to (a) increasing bp-bp repulsion (b) increasing p-orbital character in sp 3 (c) decreasing lp-lp repulsion (d) decreasing electronegativity Q.24 what type of bonding is present in Na 2 (g) (a) covalent bond (b) ionic bond (c) metallic bond (d) molecular bond Q.25 which of the following has zero dipole moment (a) ClF (b) PCl 3 (c) SiF4 (d) CFCl3