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In this paper, nitrile butadiene (NBR)/chloroprene (CR) blends added compatibilizers (made
from Cashew nut shell liquid - DLH order tung oil-D01) were prepared for improving the
mechanical properties, environmental resistance and the thermal stability of material. The
characterization of the mechanical properties was performed according to the Vietnamese
Standards. The thermal stability, the morphology of the materials depending on the blend
composition were investigated by the thermal gravimetric analysis (TGA) and scanning electron
microscopy (SEM). The results show that blend NBR/CR (50/50) added 1% compatibilizers
(specially DLH) are better compatible, well-dispersed and compact structure are obtained. The
mechanical properties, environmental resistance and the thermal stability of the materials were
considerablely improved.
I - M u
Vt liu cao su blend trn c s cao su
nitilbutadien (NBR) vi cao su clopren (CR) c
tnh nng c l k thut kh cao bi n khc
phc c nhng yu im v phi hp c u
im ca hai cao su thnh phn [1, 2]. T nhng
nghin cu ca mt s tc gi cho thy rng,
blend trn c s NBR/CR vi t l khong 50/50
c tnh nng c l, k thut cao [3]. Mt khc,
qua thc t nghin cu chng minh c rng
t l ny, blend NBR/CR c kh nng tng
hp vi nhau tt hn cc t l khc [4].
nng cao hn na cc tnh nng c l, k thut
cho vt liu ny, chng ti tip tc s dng mt
s cht bin i cu trc, lm tng hp bin
tnh vt liu ny.
56
dn di khi
t, %
mi mn,
cm3/1,61 km
cng,
Shore A
NBR/CR
21,56
538
0,782
69,0
NBR/CR/D01
23,83
580
0,727
68,0
NBR/CR/DLH
24,22
598
0,685
69,0
Tnh cht
Mu vt liu
Nhit phn hu
mnh nht 1, oC
Mu
NBR
377,62
434,03
43,164
CR
240,16
260,03
49,281
NBR/CR (50/50)
330,06
356,54
36,80
NBR/CR/DHL
NBR/CR/D01
331,93
332,86
356,72
356,15
37,49
38,92
Ch tiu
58
(hnh 2 v 3).
khng nh thm v kh nng bn mi
trng ca vt liu, h s gi ha 100oC sau
thi gian 72 gi ca vt liu c xc nh theo
TCVN 2229-77. Kt qu thu c c th c
trnh by trong bng sau.
H s gi ha
(bc x, nhit, m) sau 10 chu k
H s gi ha 100oC sau 72
gi
NBR
0,85
0,75
NBR/CR (50/50)
0,93
0,85
NBR/CR/DLH (50/50/1)
0,95
0,88
60
4.
5.
6.
7.
Helaly.
Polymers
for
Advanced
Technologies, Vol. 11(1), 1 - 8 (2000).
Quang Khng v cc ng tc gi. Bo
co tng kt ti cp thnh ph H Ni
"Nghin cu ch to v ng dng vt liu
cao su blend trong lnh vc k thut cao
thay th hng nhp ngoi"; 14 - 29, H Ni,
thng 10-2008.
Nguyn Vit Bc. Keo dn k thut; Nxb.
Qun i nhn dn; trang 14-21, H Ni
(2003).
R. Gaechter, H. Mueller. KunststoffAdditive; 3. Ausgabe; S. 180-340; Carl
Hanser Verlag Muenchen Wien (1989).
Quang Khng, Trn Kim Lin, Lng
Nh Hi, Quang Minh. VAST Proceedings
International
Scientific
Conference on Chemistry for Development
and Integration, 960-968, Hanoi (2008).