B gio dc v o to

CHNH THC

k thi tuyn sinh i hc, cao ng nm 2003

Mn thi: HA HC Khi B
(Thi gian lm bi: 180 pht)

Cu 1 (1,5 im).
1. Tng s ht proton, ntron, electron trong 2 nguyn t kim loi A v B l 142, trong tng s ht mang in
nhiu hn tng s ht khng mang in l 42. S ht mang in ca nguyn t B nhiu hn ca A l 12.
a) Xc nh 2 kim loi A v B. Cho bit s hiu nguyn t ca mt s nguyn t: Na (Z = 11), Mg (Z = 12),
Al (Z = 13), K (Z = 19), Ca (Z = 20), Fe (Z = 26), Cu (Z = 29), Zn (Z = 30).
b) Vit cc phng trnh phn ng iu ch A t mui cacbonat ca A v iu ch B t mt oxit ca B.
2. Ch dng thm nc, hy nhn bit 4 cht rn: Na2O, Al2O3, Fe2O3, Al cha trong cc l ring bit. Vit cc
phng trnh phn ng.
Cu 2 (1,5 im).
1. Cho hn hp gm FeS2, FeCO3 tc dng ht vi dung dch HNO3 c, nng thu c dung dch A v hn hp
kh B gm NO2, CO2. Thm dung dch BaCl2 vo dung dch A. Hp th hn hp kh B bng dung dch NaOH
d. Vit phng trnh phn t v phng trnh ion rt gn ca cc phn ng xy ra.
2. Trn 200 ml dung dch gm HCl 0,1 M v H2SO4 0,05 M vi 300 ml dung dch Ba(OH)2 c nng a mol/l thu
c m gam kt ta v 500 ml dung dch c pH = 13. Tnh a v m. Cho bit, trong cc dung dch vi dung mi
l nc, tch s nng ion [H+].[OH-] = 10 14 (mol2/l2).
Cu 3 (1,5 im).
1. Cht A c cng thc phn t l C7 H8. Cho A tc dng vi Ag2O (d) trong dung dch amoniac c cht B kt
ta. Khi lng phn t ca B ln hn ca A l 214 v.C. Vit cc cng thc cu to c th c ca A.
2. Ba cht hu c A, B, C cha cng nhm nh chc, c cng thc phn t tng ng l CH2O2, C2H4O2,
C3H4O2.
a) Vit cng thc cu to v gi tn cc cht .
b) Tnh khi lng cht B trong dung dch thu c khi ln men 1 lt ru etylic 9,2o. Bit hiu sut qu
trnh ln men l 80% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml.
Cu 4 (1,5 im).
1. Vit cc phng trnh phn ng (ghi r iu kin) thc hin dy chuyn ho sau:
+Y
+X
C
F
G
to
A
B
E
D
C
H
+Y
+X
Cho bit E l ru etylic, G v H l polime.
2. Vit cc phng trnh phn ng (ghi r iu kin) chuyn ho axetilen thnh axit picric (2,4,6-trinitrophenol).
Cu 5 (2 im).
Hn hp X gm cc kim loi Al, Fe, Ba. Chia X thnh 3 phn bng nhau:
Phn I tc dng vi nc (d), thu c 0,896 lt H2.
Phn II tc dng vi 50 ml dung dch NaOH 1M (d), thu c 1,568 lt H2.
Phn III tc dng vi dung dch HCl (d), thu c 2,24 lt H2.
(Cc phn ng xy ra hon ton, cc th tch kh o iu kin tiu chun).
1. Tnh phn trm khi lng cc kim loi trong hn hp X.
2. Sau phn ng phn II, lc, c dung dch Y. Tnh th tch dung dch HCl 1M cn thm vo dung dch Y :
a) Thu c lng kt ta nhiu nht.
b) Thu c 1,56 g kt ta.
Cu 6 (2 im).
A l hp cht hu c n chc cha C, H, O. Cho mt lng cht A tc dng hon ton vi 500 ml dung
dch KOH 2,4 M ri c cn, c 105 gam cht rn khan B v m gam ru C. Oxi ho m gam ru C bng oxi
(c xc tc) c hn hp X. Chia X thnh ba phn bng nhau:
Phn I tc dng vi Ag2O (d) trong dung dch amoniac, c 21,6 gam Ag.
Phn II tc dng vi dung dch NaHCO3 (d), c 2,24 lt kh (ktc).
Phn III tc dng vi Na (va ), thu c 4,48 lt kh (ktc) v 25,8 gam cht rn khan.
1. Xc nh cng thc cu to ca ru C, bit khi un nng ru C vi H2SO4 (c), 170 oC c anken.
2. Tnh phn trm s mol ru C b oxi ho.
3. Xc nh cng thc cu to ca A.
Cho: H = 1; C = 12; O = 16; S = 32; Na = 23; Al = 27; K = 39; Ca = 40; Fe = 56; Ag = 108; Ba = 137.
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