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Product identity :
5214011480
Product type :
alkyd paint
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application :
Identified uses :
Company details :
Date of issue :
10 November 2014
No previous validation.
Mixture
GHS Classification
FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
AQUATIC TOXICITY (CHRONIC) - Category 2
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms :
Signal word :
Danger
Hazard statements :
Precautionary statements :
General :
If medical advice is needed, have product container or label at hand. Keep out of reach of children.
Prevention :
Do not breathe gas, vapor or spray. In case of inadequate ventilation wear respiratory protection. Keep
away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Response :
Get medical attention if you feel unwell. In case of fire: Use alcohol-resistant foam to extinguish.
Storage :
Disposal :
Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazardous ingredients :
white spirit
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5214011480
None known.
Identifiers
white spirit
*64742-88-7
>=35 - <50
xylene
1330-20-7
>=1 - <5
2-butanone oxime
96-29-7
>=0.1 - <1
68409-81-4
>=0.25 - <1
zirconium octoate
22464-99-9
<0.5
GHS Classification
FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
(central nervous system (CNS)) (inhalation) - Category 1
ASPIRATION HAZARD - Category 1
AQUATIC TOXICITY (CHRONIC) - Category 2
FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
ACUTE TOXICITY (dermal) - Category 4
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
ACUTE TOXICITY (oral) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SKIN SENSITIZATION - Category 1
AQUATIC TOXICITY (CHRONIC) - Category 2
TOXIC TO REPRODUCTION (Fertility) - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation :
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and seek medical advice.
Skin contact :
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion :
If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness.
Skin contact :
Ingestion :
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5214011480
No specific data.
Inhalation :
Skin contact :
No specific data.
Ingestion :
No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician :
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments :
No specific treatment.
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Decomposition products may include the following materials: carbon oxides metal oxide/oxides
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5214011480
xylene
zirconium octoate
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Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
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Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: safety glasses with side-shields.
Hand protection :
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / 4H gloves, polyvinyl alcohol (PVA), Viton
May be used: nitrile rubber
Not recommended: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)
Body protection :
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection :
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. When the product is applied by spraying and for
continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an approved/certified
respirator or equivalent.
Liquid.
Color :
Grey.
Odor :
Solvent-like
pH :
-49C This is based on data for the following ingredient: white spirit
Flash point :
Evaporation rate :
Flammability :
Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Vapor density :
Relative density :
0.996 g/cm
Solubility(ies) :
Very slightly soluble in the following materials: cold water and hot water.
Auto-ignition temperature :
Decomposition temperature :
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0.4 kPa This is based on data for the following ingredient: white spirit
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5214011480
Explosive properties :
Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties :
Weighted average: 43 %
Water % by weight :
Weighted average: 0 %
VOC content :
430.8 g/l
TOC Content :
Solvent Gas :
2-butanone oxime
zirconium octoate
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Result
LC50 Inhalation Gas.
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
LC50 Inhalation Dusts and mists
LD50 Dermal
LD50 Oral
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Species
Rat
Rat
Rabbit
Rat
Rabbit
Rat
Rat
Rabbit
Rat
Dose
5000 ppm
6350 ppm
>2000 mg/kg
4300 mg/kg
1001 mg/kg
930 mg/kg
>8800 mg/m
>2000 mg/kg
>2000 mg/kg
Exposure
4 hours
4 hours
1 hours
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5214011480
ATE value
Dermal
Inhalation (gases)
56355.3 mg/kg
256160.7 ppm
Irritation/Corrosion
Product/ingredient name
Result
xylene
Species
2-butanone oxime
Score
Rabbit
Rabbit
Rabbit
Exposure
24 hours 5 milligrams
24 hours 500 milligrams
100 microliters
Category
white spirit
Route of exposure
Category 3
Target organs
Not applicable.
Narcotic effects
Category
white spirit
Route of exposure
Category 1
Target organs
Inhalation
Aspiration hazard
Product/ingredient name
Result
white spirit
Carcinogenic effects
Mutagenic effects
Developmental effects
Fertility effects
2-butanone oxime
zirconium octoate
Carc. 2, H351
-
Sensitization :
Contains 2-butanone oxime, cobalt(2+) salts of C6-19 branched fatty acids. May produce an allergic
reaction.
Other information :
Test
Result
Product/ingredient name
xylene
Dose
Photolysis
Inoculum
-
Biodegradability
Readily
LogPow
xylene
2-butanone oxime
3.12
0.63
BCF
8.1 to 25.9
2.5 to 5.8
Potential
low
low
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Mobility :
Not applicable.
vPvB :
Not applicable.
14.2
Proper shipping name
ADR/RID
Class
UN1263
PAINT
IMDG
Class
UN1263
14.3
Transport hazard class(es)
3
14.4
PG*
14.5
Env* Additional information
III
Yes.
III
Emergency schedules
(EmS)
F-E, S-E
IATA
Class
UN1263
PAINT
III
No.
The environmentally
hazardous substance mark
may appear if required by
other transportation
regulations.
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GHS Classification
Classification
FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
AQUATIC TOXICITY (CHRONIC) - Category 2
Justification
On basis of test data
Calculation method
Calculation method
Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
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