Professional Documents
Culture Documents
THERMOCHEMICAL TREATMENT
UDC 669.14.018.298:621.785.062
The process of creation and subsequent hardening of a gradient carburized layer in low-carbon martensitic
steel 17Kh2G2NMFTB is studied. It is shown that the structure and properties of the carburized layer can be
optimized due to formation of reverted austenite hardened by quenching from the intercritical temperature
range.
Key words: gradient layer, reverted austenite, lath martensite, low-carbon martensitic steels
(LCMS).
INTRODUCTION
Low-carbon martensitic steels (LCMS) possess a number
of unique features distinguishing them from other structural
steels traditionally used in machine building [1 5]. Rational
alloying and low content of carbon in LCMS promote elevation of the stability of supercooled austenite and yield a martensite structure in large cross sections after comparatively
slow cooling in air.
In order to widen the range of application of LCMS to
operation under conditions of contact friction it is necessary
to develop processes of their surface hardening. LCMS of
grades 07Kh3GNMYuA, 10Kh3GNM, and 08Kh2G2F operating under contact friction (gears, turbodrill parts) are subjected to surface hardening by carburizing and nitriding.
However, grades 12Kh2G2NMFT, 15Kh2G2NMFB, and
17Kh2G2NMFTB having the highest strength are not used in
a surface-hardened state [7 10].
1
METHODS OF STUDY
We studied low-carbon martensitic steel 17Kh2G2NMFTB
and (for comparison) 12Kh2G2NMFT. The chemical compositions, the hardness, and the structures of the steels in the
initial state are presented in Tables 1 and 2.
Gas carburizing of the steels was performed in a Ts-75
shaft furnace at 900 910C for 4 h at benzene feeding rate
of 80 100 drops/min. Subsequent heat treatment was performed in a SNOL-type laboratory furnace. The carburized
specimens were placed into a container with waste carburizer
in order to avoid decarburization.
17Kh2G2NMFTB
12Kh2G2NMFT
Si
Mn
Cr
Ni
Mo
Nb
Ti
S, at most
P, at most
0.17
0.13
0.37
0.24
2.07
2.24
2.42
2.39
1.50
1.38
0.39
0.45
0.17
0.12
0.10
0.22
0.04
0.011
0.119
0.015
0.004
562
0026-0673/11/1112-0562 2011 Springer Science + Business Media, Inc.
563
Initial condition
Structure
HRC
hardness
Lath martensite
Lath martensite
37
39
(1)
where I(311)g and I(311)a are the intensities of the lines of retained austenite and martensite, respectively.
The microstresses and the sizes of subgrains in austenite
and martensite were computed by the method of approximation from x-ray lines (110) (211) of martensite and (111)
(311) of austenite. The approximating functions were [6]
y = 1/(1 + ax 2 )
and
y = 1/(1 + ax 2 )2.
(2)
100 mm
564
A. S. Ivanov et al.
Aret , %
100
90
80
70
60
50
40
30
20
10
Aret , %
17Kh2G2NMFTB
12Kh2G2NMFT
80
17Kh2G2NMFTB
17Kh2G2NMFTB
12Kh2G2NMFT
70
60
50
40
30
20
10
0.35
0.05
0.15
0.25
h, mm
HV, kgf/mm2
HV, kgf/mm2
1200
17Kh2G2NMFTB
12Kh2G2NMFT
800
600
600
400
400
200
200
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
h, mm
Matrix
17Kh2G2NMFTB
17Kh2G2NMFTB
12Kh2G2NMFT
1000
800
0.45
h, mm
1200
1000
0.35
0.4
h, mm
Fig. 2. Distribution of retained austenite and of microhardness over the thickness of surface layer (h is the distance from the surface) in steels 17Kh2G2NMFTB and 12Kh2G2NMFT: a, b ) after carburizing; c, d ) after carburizing and hardening from 810C in oil (:, =) and in air (&).
565
Q, mm
Aret , %
0,25
40
35
30
0,20
0,15
25
0,10
20
0,05
15
0.1
0.2
0.3
0.4
10
0.5
h, mm
sm , P
0
0.06
0.16 0.26
0.36
0.46 Matrix
400
350
300
250
200
150
100
50
h, mm
HV, kgf/mm2
1200
b
1000
2
0.1
0.2
0.3
0.4
0.5
h, mm
800
600
2
400
200
0
0.9 1.0
1.2
h, mm
sm , P
500
400
300
200
2
1
100
0.1
0.2
0.3
0.4
0.5
h, mm
Fig. 5. Microstresses in austenite in steel 17Kh2G2NMFTB after
carburizing and hardening by different regimes: 1 ) from 750C in oil;
2 ) from 819C in oil; 3 ) from 750C in air; 4 ) from 810C in air.
The variation of the parameters of the subgrain structure of the austenite in the carburized layer of steel
17Kh2G2NMFTB after hardening from the ITR (750C)
presents special interest. The sizes of the blocks and the
microstresses in the austenite differ substantially after air
cooling and after oil cooling (Fig. 4).
After air cooling the block sizes are much smaller and
the level of the microstresses is higher than after oil cooling.
This may be connected with the fact that the reverted austenite (the retained austenite not decomposed and newly formed
during heating to the ITR temperature) undergoes precipitation hardening in air, i.e., segregation of dispersed carbides
that harden the austenite and increase in the stresses.
Figure 5 presents the curves of variation of microstresses
in austenite over the thickness of the layer after hardening
from 750 and 810C in oil and in air. After hardening from
750C in air the level of the microstresses is considerably
566
A. S. Ivanov et al.
a, nm
HV, kgf/mm2
0.362
1200
1000
0.361
800
0.360
600
0
0.05
0.10
0.15
1
0.20
0.25
0.30
0.35
0.359
h, mm
Fig. 6. Distribution of microhardness over the thickness of surface
layer (h is the distance from the surface) of steel 17Kh2G2NMFTB
after carburizing and hardening from 650C in air: 1 ) hardness of
austenite (target measurement); 2 ) hardness of austenite and martensite.
2
3
0
0.1
0.2
0.3
0.4
0.5
0.6
h,
a, nm
0.362
0.361
1
0.360
0.359
4
5
0
0.1
0.2
0.3
0.4
0.5
0.6
h,
Fig. 7. Variation of the lattice parameter of austenite over the thickness of hardened layer (h is the distance from the surface) of steel
17Kh2G2NMFTB after carburizing and hardening from 750C (a)
and from 810C (b ): 1 ) after carburizing; 2, 3 ) after carburizing
and hardening from 750C in oil and in air respectively; 4, 5 ) after
carburizing and hardening from 810C in oil and in air respectively.
567