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Temperature
Size of Reactant
of Reactant
FACTORS
Concentration Pressure
of Reactant of Reactant
Catalyst
SIZE
When size of reactants decrease, the total surface area of reactant will increase.
Time taken for reaction is lesser. Rate of reaction is higher.
CONCENTRATION
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When concentration of reactants increase, the higher number of particles per unit
volume.
Will cause time taken to finished the reaction become lesser. Rate of reaction is
higher.
TEMPERATURE
When temperature of reactants increase, kinetic energy of particles increase.
Time taken to complete the reaction is lesser. Rate of reaction is higher
CATALYST
When using catalyst, it will provide alternative pathway to complete the reaction
Time taken to complete the reaction is lesser. Rate of reaction is higher
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RATE OF REACTION CHEMISTRY FORM 5
SIZE OF REACTANTS
Exp 1.
20 cm3 of 0.5 mol dm-3 hydrochloric acid + excess of calcium carbonate (small chips)
Equation
2HCl + CaCO3 CaCl2 + H2O + CO2
Exp 2.
20 cm3 of 0.5 mol dm-3 hydrochloric acid + excess of calcium carbonate (large chips)
Equation
2HCl + CaCO3 CaCl2 + H2O + CO2
Result
Volume of CO2 gas \cm3
Exp 1.
Exp 2.
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Time taken / s
** When small substances are used, total surface area of substances are increase, so rate of reaction
increased.
The volume of CO2 gas for both experiments are same because the number of mol of reactant in Exp. 1
and Exp. 2 are same.
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RATE OF REACTION CHEMISTRY FORM 5
TEMPERATURE
Exp
50 cm3 of 0.2 mol dm-3 sodium thiosulphate solution + 5 cm3 of 1.0 mol dm-3 sulphuric acid. Experiment is
repeated at different temperature of sodium sulphate, 40 oC, 45 oC, 50 oC and 55 oC.
Equation
Na2S2O3 + H2SO4 2NaSO4 + SO2 + S + H2O
Result
Temperature / oC
Time taken / s
Temperature / oC
1/time.
1/time represents the Rate of Reaction
Hence,
Temperature is directly propotional to the
rate of reaction.
1
𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 ∝
𝑇𝑖𝑚𝑒
1
/s-1
𝑇𝑖𝑚𝑒 𝑡𝑎𝑘𝑒𝑛
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RATE OF REACTION CHEMISTRY FORM 5
CONCENTRATION
Exp
50 cm3 of 0.2 mol dm-3 sodium thiosulphate solution + 5 cm3 of 1.0 mol dm-3 sulphuric acid. Experiment is
repeated at different concentration (using dilution method to dilute the sodium thiosulphate)
Equation
Na2S2O3 + H2SO4 2NaSO4 + SO2 + S + H2O
Result
Time taken / s
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1/time.
1/time represents the Rate of Reaction
Hence,
Concentration is directly propotional to the
rate of reaction.
1
𝐶𝑜𝑛𝑐𝑒𝑛𝑡𝑟𝑎𝑡𝑖𝑜𝑛 ∝
𝑇𝑖𝑚𝑒
1
/s-1
𝑇𝑖𝑚𝑒 𝑡𝑎𝑘𝑒𝑛
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RATE OF REACTION CHEMISTRY FORM 5
CATALYST
Exp
25 cm3 0.1 mol dm-3 hydrochloric acid react with 5g granulated zinc with presence of 5 cm 3 0.5 mol dm-3
copper (II) sulphate solution as catalyst.
Repeat experiment wihtout presence of catalyst
Equation
CuSO
2HCl + Zn 4 ZnCl2 + H2
Volume of gas, cm3
Time taken / s
Note
Amount of catalyst used in experiment will affect the time taken for the reaction to complete, but it
does not affect the amount of product produced.
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