Professional Documents
Culture Documents
Answer the following questions 3-6 with the help of the hypothetical reaction and its rate law:
3A(g)
B(g)
2C(g)
D(g)
2E(g)
b. 3
c. 4
d. 9
b. 3
c. 4
d. 9
5. If the volume of the container is suddenly reduced to one-half its original volume the rate will increase
by a factor of
a. 2
b. 4
c. 8
d. 16
7. At 250C, the half-life for the decomposition of N2O5 is 5.7 hours, and is independent of the initial
pressure of N2O5, the specific reaction rate constant is
a. ln 2
d. (ln 2/5.7)- hr -
8. Which one of the following rate laws has an overall order of 0.5 for the reactions involving substances
X, Y, Z?
a. Rate = k (Cx) (Cy) (Cz)
b. Rate = k (Cx)0.5 (Cy)0.5 (Cz)0.5
9. In which of the following cases does reaction go farthest to completion? (Note: k is the equilibrium
constant)
a. k = 102
b. k = 10-2
c. k = 10
d. 1
10. It states that the rate of a chemical reaction is proportional to the activity of the reactants
a. law of mass action
b. Hess Law
c. Le Chateliers Principle
d. Second law of thermodynamics
12. Sum of the powers of the concentration terms in the rate equation is called the
a. order of the reaction
d. none of these
b. consecutive reaction
d. none of these
c. (time) n 1 (concentration)
b. (time)-1 (concentration) n - 1
d. none of these
15. The reaction in which rate equation corresponds to a stoichiometric equation is called
a. elementary reaction
c. non-elementary reaction
b. parallel reaction
d. auto0kinetic reaction
d. both b and c
c. total pressure
18. Concentration of the limiting reactant (with initial concentration of a moles/L) after time t is (a x),
then t for a first order reaction is given by
a. kt = ln (a/(a x)
b. kt = x/(a(a x)
c. kt = ln ((a x)/a)
d. kt = a(a x)/x
c. temperature
d. time of reaction
20. Which of the following factors does not influence the rate of a reaction?
a. Concentration of the reactants
b. Nature of reactants
d. Temperature
21. For the reaction A + B 2C, when CA is doubled the rate doubles when CB is doubled the rate
increases four fold. The rate law is
a. rA = k CA2 CB4
b. rA = k CA CB2 c. rA = k CA
d. rA = k CB2
c. 1/concentration
b. concentration/time
d. 1/(concentration-time)
24. Chemical reaction rates in solution do not depend to any extent upon
a. pressure
2.
a.
b.
b. rA
c. 2rA
d. -1/2 rA
c. temperature
d. time of reaction
2. Which of the following factors does not influence the rate of a reaction?
a. Concentration of the reactants
b. Nature of reactants
d. Temperature
Answer the following questions 5-8 with the help of the hypothetical reaction and its rate law:
3A(g)
B(g)
2C(g)
D(g)
2E(g)
b. 3
c. 4
d. 9
b. 3
c. 4
d. 9
7. If the volume of the container is suddenly reduced to one-half its original volume the rate will increase
by a factor of
a. 2
b. 4
c. 8
d. 16
9. At 250C, the half-life for the decomposition of N2O5 is 5.7 hours, and is independent of the initial
pressure of N2O5, the specific reaction rate constant is
a. ln 2
d. (ln 2/5.7)- hr -
10. If the reaction is independent of the concentration of the reactant, the reaction is of
a. zero order
b. first order
11. Which one of the following rate laws has an overall order of 0.5 for the reactions involving substances
X, Y, Z?
c. Rate = k (Cx)1.5 (Cy)-1 (Cz)0
12. In which of the following cases does reaction go farthest to completion? (Note: k is the equilibrium
constant)
a. k = 102
b. k = 10-2
c. k = 10
d. 1
14. It states that the rate of a chemical reaction is proportional to the activity of the reactants
a. law of mass action
c. Le Chateliers Principle
b. Hess Law
16. For the reaction A + B 2C, when CA is doubled the rate doubles when CB is doubled the rate
increases four fold. The rate law is
a. rA = k CA2 CB4
b. rA = k CA CB2 c. rA = k CA
d. rA = k CB2
c. 1/concentration
b. concentration/time
d. 1/(concentration-time)
19. Chemical reaction rates in solution do not depend to any extent upon
a. pressure
b. rA
c. 2rA
d. -1/2 rA
b. consecutive reaction
d. none of these
c. (time) n 1 (concentration)
b. (time)-1 (concentration) n - 1
d. none of these
4. Sum of the powers of the concentration terms in the rate equation is called the
a. order of the reaction
d. none of these
5. Molecularity of a reaction
a. always equal to the overall order of rxn
d. both b and c
c. non-elementary reaction
b. parallel reaction
d. auto0kinetic reaction
8. In a first order reaction, the time required to reduce the concentration of reactant from 1 mole/L to 0.5
mole/L will be the __________ that required reducing it from 10 moles/L to 5 moles/L in the same volume.
a. more than
b. same as
d. both b and c
9. Half life period for a first order reaction is __________ the initial concentration of the reactant.
a. directly proportional to
c. inversely proportional to
b. independent of
d. none of these
10. Concentration of the limiting reactant (with initial concentration of a moles/L) after time t is (a x),
then t for a first order reaction is given by
a. kt = ln (a/(a x)
b. kt = x/(a(a x)
c. kt = ln ((a x)/a)
d. kt = a(a x)/x
Problem Solving
1. (25 points) The reaction
k1
A
k2
k3
1.
2.
A ten minute experimental run shows that 75% of liquid reactant is converted to product by a
order rate. What would be the fraction converted in a half-hour run?
Enzyme E catalyzes the transformation of reactant A to product as follows:
A
enzymes
2 + CA L-min
If we introduce enzyme (CEO = 0.001 mol/L) and reactant (CAO = 10 mol/L) into a batch reactor and let
the reaction proceed, find the time needed for the concentration of reactant to drop to 0.025 mol/L.
Note that the concentration of enzyme remains unchanged during the reaction.
k2 = 6 min-1
M is the desired product, B and F are foul pollutants that are expensive to get rid of.
a. Derive the rate law expressions for each species. (5 points)
b. Determine the time in seconds, to achieve 90% conversion of R (X R) for a feed of 3.0 lbmol/ft3.
(20 points)
1. (10 points) Chemicals A, B and D combine to give R and S with stoichiometry A + B + D = R + S, and
after the reaction has proceeded to a significant extent, the observed rate is
rR = kCACBCD/CR
a. What is the order of the reaction?
The following two mechanisms involving formation of active intermediate have been proposed to explain
the observed kinetics.
Mechanism I:
A + B X* + R
Mechanism II: A + D Y* + R
D + X* S
B + Y* S