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Indian Standard
METHODS OF SAMPLING AND TEST (PHYSICAL
AND CHEMICAL) FOR WATER AND WASTE WATER
PART 14 SPECIFIC CONDUCTANCE (WHEATSTONE BRIDGE, CONDUCTANCE CELL)
( Second Revision )
BIS 2013
Price Group 3
Environment Protection and Waste Management (Excluding Biomedical and Nuclear Waste) Sectional
Committee, CHD 32
NATIONAL FOREWORD
This Indian Standard (Part 14) (Second Revision) which is identical with ISO 7888 : 1985 Water
quality Determination of electrical conductivity issued by the International Organization for
Standardization (ISO) was adopted by the Bureau of Indian Standards on the recommendation of the
Environment Protection and Waste Management (Excluding Biomedical and Nuclear Waste) Sectional
Committee and approval of the Chemical Division Council.
The first revision of this standard was published in 1984 by superseding 9 of IS 3025 : 1964 Methods
of sampling and test (physical and chemical) for water used in Industry. This second revision has
been undertaken to harmonize it with the latest development that have taken place at international
level. The committee has now decided to adopt this standard under dual numbering system.
The text of ISO Standard has been approved as suitable for publication as an Indian Standard without
deviations. Certain conventions are, however, not identical to those used in Indian Standards. Attention
is particularly drawn to the following:
a) Wherever the words International Standard appear referring to this standard, they should be
read as Indian Standard.
b) Comma (,) has been used as a decimal marker while in Indian Standards, the current practice
is to use a point (.) as the decimal marker.
In reporting the result of a test or analysis made in accordance with this standard, if the final value,
observed or calculated, is to be rounded off, it shall be done in accordance with IS 2 : 1960 Rules for
rounding off numerical values (revised).
~-
INTERNATIONAL
STANDARD
Indian Standard
METHODS OF SAMPLING AND TEST (PHYSICAL
AND CHEMICAL) FOR WATER AND WASTE WATER
14 SPECIFIC CONDUCTANCE (WHEATSTONE BRIDGE, CONDUCTANCE CELL)
of electrical
conductivity
WaterPARTquality
- Determination
( Second Revision )
Scope
and field
of application
This International
Standard
specifies
measurement of the electrical conductivity
where
I
a method
for the
of all types of water.
is the length,
in metres,
of an electrical
A
Electrical
conductivity
a)
surface waters;
b)
process waters
c)
waste waters.
the quality
of
and treatment
conductor;
plants;
2.3
The completeness
of analysis for ionic constituents[l
be checked using this method.
10 31 tan
temperature
coefficient
of electrical
conductivity,*)
a: The temperature
coefficient
of conductivity
ae r 25,M
is given by the equation
51
x 100
In some cases absolute values are important,
only relative changes are of concern.
For interferences,
in other
cases
where 25 and 0 OC are the temperatures
at which the electrical
conductivities
~25 and ye respectively were measured.
see clause 9.
2.4
Definitions
correct
tivity.
2.1
specific
conductance;
electrical
conductivity,
y:
The reciprocal of the resistance, measured under specified conditions, between the opposite faces of a unit cube of defined
dimensions of an aqueous Solution. For water quality examinaconductivity
and
tion, this is often expressed as electrical
may be used as a measure of the concentration
of ionizable
solutes present in the Sample.
(Definition
f: Factors used to
of electrical conduc-
conductivity
lt is expressed
conductivity
where
a
2.2
cell constant,
by the equation
K=-
temperature
correction
factors,
for the temperature
dependence
K:
Quantity,
in reciprocal
metres,
given
is the temperature
Yo is the electrical
;
perature,
0 is the measuring
Sample.
1)
1 S/m
2)
The temperature
= IO4 pS/cm
coefficient
of electrical
conductivity
at the
temperature,
conductivity;
measured
tem-
= IO3 mS/m
coefficient
of electrical
conductivity
tan be expressed
in reciprocal
kelvin
or Yo per OC.
ISO 78884985
(El
Principle
Table
Direct determination,
using an appropriate
instrument,
of the
electrical conductivity
of aqueous solutions. The electrical conductivity is a measure of the current conducted by ions present
in the water (phenomenon
of conductors
of the second
kind), and depends on
a)
b)
the concentration
1 -
Electrical
conductivity
chloride
solutions
Concentration
chloride,
of potassium
c( KCI)
of potassium
Electrical
conductivity
at 25 OC, yz5
mol/1
mS/m
7,4
14,7
0,000 5
0,001
of the ions;
0,005
72
0,Ol
141
0,02
277
670
0,05
c)
d)
the temperature
the viscosity
Pure water
conductivity
of the Solution;
stated,
4.1
Water for preparing
solutions
and dilutions.
distilled or de-ionized water; the electrical conductivity
Y25 <O,l mS/m.
4.2
Potassium
chloride
c( KCI) = 0,l mol/l.
Standard
Solution
Double
shall be
Potassium
chloride
c(KCI) = 0,Ol mol/l.
Dilute 100 ml of Solution
Standard
Solution
Standard
Solution
shortly
hexa0,012 5 g
Apparatus
5.1
Instruments
conductivity.
for measurement
of electrical
types:
b)
instrument
Preferably instruments
tinuous measurement
conduc-
of the induction
type.
should be capable of discrete and conboth in the laboratory and in the field.
The recommended
electrode cell constant
table 2 for each measuring range.
C,
Table
2 -
Recommended
cell constants
ranges of electrical
conductivity
Measuring
mS/m
range
for different
Recommended
cell
constant
m-1
before use.
Solution.
A flow-type
conductivity
cell from which air is excluded is
essential for measurements
of conductivities
of less than
1 mS/m.
B,
Platinizing
Potassium
chloride
= 0,001 mol/l.
The conductivity
4.5
a) instrument
equipped with a flow- or dip-type
tivity cell fitted with two or more electrodes;
A, ~1
4.3
c(KCI)
2480
The instrument
4.4
02
Dissolve
1,5 g of hydrogen
hexachloroplatinate(lV1
hydrate (H2PtC16m6H20) in 50 ml of water containing
of lead(ll) acetate [Pb(C2H302121.
Reagents
The conductivity
1 290
of the Solution.
The conductivity
61
of potassium
91
chloride
7888-1985
(El
IS 3025ISO
(Part
14) : 2013
ISO 7888 : 1985
5.2
appropriate
to the desired measuring
range is fitted (sec
table 2). The test Portion depends on the equipment
used.
Electrodes.
are used
Whenever
platinum
electrodes
measurements the electrodes shall be platinized
Unplatinized electrodes
laboratory testing.
precision
for
(sec the note).
NOTE -4 f Platinkation
is necessary,
the ma nufacturers
should be followed,
or proceed as follows
instructions
5.3
Thermometer,
accurate
to
I!I 0,l OC, within
the
temperature
range of measurement,
shall be used for precise
determinations.
For routine measurements,
a thermometer
accurate to + 0,5 OC is satisfactory.
5.4
Thermostatic
bath, capable of being maintained
25,0 + 0,l OC. For routine measurements,
a tolerante
& 0,5 OC is satisfactory.
Sampling
at
of
7.1
Many instruments incorporate cell constant correction as an integral function and thus a direct reading of electrical conductivity is obtained.
Otherwise multiply the conductance
value
obtained by the cell constant to obtain electrical conductivity.
For high precision
trical conductivity
contact with it has
all sources of error
compensators,
or
are eliminated.
7.2
Temperature
correction
and samples
If the cell constant is not accurately known, determine the constant as given in clause 5 using the potassium chloride Standard
solutions (4.2 to 4.4) appropriate
to each desired measuring
range. Check the cell constant at least once every 6 months.
Proceduae
General
Prepare the equipment for use as instructed by the manufacturer and ensure that an electrode cell of known cell constant
If the temperature
coefficient
of the Sample is not known, it
may be derived by substituting
electrical conductivity
values
experimentally
determined at 25,0 & 0,l OC and temperatures
8 k 0,l OC (sec 2.3).
Where instruments do not incorporate a temperature
compensation device, the electrical conductivity
measured at 0 OC shall
be corrected to 25,0 OC using the appropriate correction factor
taken from table 3.
Whichever form of temperature
compensation
is applied to the
measurement
of electrical conductivity
at 8 OC, the result will
be less accurate than that actually measured at the reference
temperature
of 25,0 OC.
In some aspects of routine field work, it may not be necessary
to transpose values measured at 0 OC to 25,0 OC. However,
such measurements
should be interpreted with great care and
comparison with other values may be difficult or even meaningless.
3
3
ISO 7888-1985
(El
3 -
Temperature
correction
factor,
e
J
1,912
1,851
1,794
1,740
1,688
1,638
1,591
1,547
1,504
1,463
1,424
1,387
1,351
1,317
1,284
1,253
1,222
1,193
1,166
1,139
1,113
1,088
1,064
1,041
1,019
0,998
0,977
0,957
0,938
0,920
0,902
0,884
0,867
0,851
0,835
0,820
1,906
1,845
1,788
1,734
1,683
1,634
1,587
1,542
1,500
1,459
1,420
1,383
1,347
1,313
1,281
1,249
1,219
1,191
1,163
1,136
1,111
1,086
1,062
1,039
1,017
0,996
0,975
0,955
0,936
0,918
0,900
0,883
0,866
0,850
0,834
0,819
,o
NOTES
1,918
1,857
1,800
1,745
1,693
1,643
1,596
1,551
1,508
1,467
1,428
1,390
1,354
1,320
1,287
1,256
1,225
1,196
1,168
1,141
1,116
1,091
1,067
1,044
1,021
1,000
0,979
0,959
0,940
0,921
0,903
0,886
0,869
0,853
0,837
0,822
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
TO TABLE
,3
1,899
1,840
1,783
1,729
1,678
1,629
1,582
1,538
1,496
1,455
1,416
1,379
1,344
1,310
1,278
1,246
1,216
1,188
1,160
1,134
1,108
1,083
1,060
1,037
1,015
0,994
0,973
0,953
0,934
0,916
0,898
0,881
0,864
0,848
0,832
0,817
Cations
Predominant
Ca*+
HC03
Mg*+
SO;-,
Cl-,
NO3
qe
1125
=A+exp
waters
-a)
,6
,5
,4
1,893
1,834
1,777
1,724
1,673
1,624
1,578
1,534
1,491
1,451
1,413
1,376
1,341
1,307
1,274
1,243
1,214
1,185
1,157
1,131
1,105
1,081
1,057
1,035
1,013
0,992
0,971
0,952
0,933
0,914
0,896
0,879
0,863
0,846
0,831
0,816
1,887
1,829
1,772
1,719
1,668
1,619
1,573
1,529
1,487
1,447
1,409
1,372
1,337
1,303
1,271
1,240
1,211
1,182
1,155
1,128
1,103
1,079
1,055
1,032
1 ,011
0,990
0,969
0,950
0,931
0,912
0,895
0,877
0,861
0,845
0,829
0,814
,8
1,881
1,822
1,766
1,713
1,663
1,615
1,569
1,525
1,483
1,443
1,405
1,369
1,334
1,300
1,268
1,237
1,208
1,179
1,152
1,126
1,101
1,076
1,053
1,030
1,008
0,987
0,967
0,948
0,929
0,911
0,893
0,876
0,859
0,843
0,828
0,813
1,875
1,817
1,761
1,708
1,658
1,610
1,564
1,521
1,479
1,439
1,401
1,365
1,330
1,297
1,265
1,234
1,205
1,177
1,149
1,123
1,098
1,074
1,051
1,028
1,006
0,985
0,965
0,946
0,927
0,909
0,891
0,874
0,858
0,842
0,826
0,811
1,869
1,811
1,756
1,703
1,653
1,605
1,560
1,516
1,475
1,436
1,398
1,362
1,327
1,294
1,262
1,231
1,202
1,174
1,147
1,121
1,096
1,071
1,048
1,026
1,004
0,983
0,963
0,944
0,925
0,907
0,889
0,872
0,856
0,840
0,825
0,810
19
1,863
1,805
1,750
1,698
1,648
1,601
1,555
1,512
1,471
1,432
1,394
1,358
1,323
1,290
1,259
1,228
1,199
1,171
1,144
1,118
1,093
1,069
1,046
1,024
1,002
0,981
0,961
0,942
0,923
0,905
0,888
0,871
0,854
0,839
0,823
0,808
correction
+a
B+
(s)]
&)
factors,
f2+
x 1,116
r~
is the viscosity
of the Solution;
8 is the temperature
made.
Values
of the Solution
at which
measurements
were
of the constants
0,962 144
0,965 078
A=
-0,198
058
B=
- 1,992 186
C =
231,17628
86,391 23
D=
exp
is the exponential
logarithms)]
a=
n=
Anions
Minor
=[tl
of natura1
where
f25
values
.f25
OC
of conductivity
are calculated
by the
function
[e = 2,718
28 (base of natura1
IS 3025
(Part
14) : 2013
ISO
78884985
(El
ISO 7888 : 1985
8
8.1
Expression
of results
8.4
8.4.1
Calculation
The result is read directly from the instrument and shall be expressed with reference to this International
Standard as ~25, in
millisiemens per metre, or other units (see 2. l), i.e. as electrical
conductivity
at 25 OC and with reference to the calibration of
the apparatus with potassium chloride Standard solutions. For
measurements
not carried out directly at the temperature
25,0 + 0,l OC the method of correction
to 25,0 OC (sec 7.2)
shall be noted in addition to the actual measuring temperature
(for examples see 8.4).
8.2
Standard
deviation
of reported
Example
results
Example
Repeatability
8.3
Examples
correction
Example
by means of a temperature
compensation
device
l)
lnterferences
4 -
Standard
(Kl
deviation
of synthetic
solutions)
*
Values
Mean
conductivity
Within
batch
(Repeatability
Standard
deviation)
6,67
12,67
25,74
50,09
samples
in millisiemens
Betvween
batch
per metre
Inter-ferences caused by such effects are not, in routine operation, easily recognized. They may Cause a Change in cell constant, but this tan only be ascertained by checking with the appropriate potassium chloride Standard Solution (4.2 to 4.4).
Total
0,087
0,075
0,039
0,068
0,067
0,081
0,175
0,163
0,110
0,110
0,179
0,176
Table
5 -
Standard
deviation
of natura1
Values
Mean
conductivity
IO,08
24,78
25,ll
42,23
Within
batch
(Repeatability
Standard
deviation)
0,079
0,150
0,098
0,223
waters
in millisiemens
Between
batch
0,250
0,258
0,308
0,277
**
Measurements
of waters with electrical conductivities
less than
1 mS/m are influenced by atmospheric carbon dioxide and ammonia. In these cases measurement shall be carried out in flowtype equipment.
When dealing with water of very low ion content the contribution of the electrical conductivity
of highly pure water may be
significant.
per metre
10
Test report
Total
**
For the within batch measurements
there were 30 degrees of freedom and for the between batch measurements
there were 9 degrees
of freedom.
1)
on the elec-
Authority,
a)
reference
b)
precise identification
c)
the following
to this International
information:
Standard;
of the Sample;
in clause 8;
instrument
and a dip-type
or any cir-
cell.
5
5
ISO3025
7888-1985
(El: 2013
IS
(Part 14)
ISO 7888 : 1985
Bibliograpt
ROSSUM, J.R. Checking
204-205.
LAXEN, D.P.H.
pp. 91-94.
Correctness
31.
the accuracy
A specific
of Analyses.
conductance
Standard
method
Methods
for quality
control
der elektrischen
Leitfhigkeit
WAGNER, R. Temperaturkorrekturfaktoren
El
OTTEN, G. Measuring
r71
ROBINSON, R.A.,
BI
191
resistance.
Salutions.
in water
In : Water
analyses.
Research,
Vol.
r51
fr die elektrische
Leitfhigkeit
von Wssern.
von Wssern.
67 1975:
11, 1977,
15 1980:
Z. Wasser- Abwasserforsch.
(2) 1980.
Press, 1969.
Temperatur-Kompensation
of conductance
cells at various
unter Bercksichtigung
temperatures.
J.
Sohtion
der
Chem.
2323 7617
{ 2323
3841
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