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Component of Atom
Atom
nucleus
e
electron
11 protons
11 electrons
Na+
11 protons
10 electrons
17 protons
17 electrons
Cl-
17 protons
18 electrons
5
A
ZX
Element Symbol
Example:
How many protons, neutrons, and electrons are in
14
C?
6
11
6
C?
Isotopes
Isotopes
hydrogen
deuterium
tritium
10
Electron Configuration
Show how e- are filled in the orbital
Its describe the arrangement of e- in an atom
number of electrons
in the orbital or subshell
1s1
principal quantum
number n
angular momentum
quantum number l
Orbital diagram
H
1s
(permissible)
As Li (3 e-)
n = 1, l = 0, ml = 0, ms = +
1s
2s
n = 1, l = 0, ml = 0, ms = +
n = 1, l = 0, ml = 0, ms = -
Aufbau Principle
Aufbau German word means building up
Aufbau Principle
1s
1s
2s
Energy level
diagram
1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p < 6s
Hunds Rule
State that e- will occupy all orbitals of
the same energy level singly with
parallel spin before they become paired
Hunds Rule
E.g: N (7 e-)
1s
2s
2p
1s22s22p63s2
2 + 2 + 6 + 2 = 12 electrons
Abbreviated as [Ne]3s2
What are the possible quantum numbers for the last (outermost)
electron in Cl?
Cl 17 electrons
Electronic conf:
1s22s22p63s23p5
l=1
ml = -1, 0, or +1
ms = or -
F = 1s22s22p5
F- = 1s22s22p6 or [Ne]
H = 1s1
H- = 1s2 or [He]
1s
2s
2p
3s
3p
4s
3d
Electron conf: 1s2 2s2 2p6 3s2 3p6 4s2 3d2 or [Ar] 4s2 3d2
or
BUT
the actual
Cr : 24 electrons
1s2 2s2 2p6 3s2 3p6 4s1 3d5
or
Cu : 29 electrons
1s2 2s2 2p6 3s2 3p6 4s2 3d9
turn as
or
24
Fe: [Ar]4s23d6
Mn: [Ar]4s23d5
25
CHAPTER 1.2
CHEMICAL BONDING
Content
Introduction
Ionic Bonding
Covalent Bond
Physical Properties Of Ionic Compound
Physical Properties Of Covalent Compound
Lewis Dot Structure
Resonance
Octet Rule
Exceptions To The Octet Rule
INTRODUCTION
Atoms are made up of smaller sub-particles:
electron, protons & neutrons
Proton + neutron are in small dense nucleus of
atom
Electron are arranged in orbitals outside the
nucleus according to Aufbau principle, Pauli
Exclusion principle & Hunds rule
An atom can gains or loses e- to become ion OR
share e- with other atom to become molecule
Covalent bond
Why do atoms combine??
Combine to form a stable e- configuration similar to
the unreactive and chemically stable noble gas
CHEMICAL BOND
21)types
chemical
bonds:bonds results of
Formation
Ionic of
bond
transfer of electron
2) Covalent bond
e- configuration
# of valence e-
1A
ns1
2A
ns2
3A
ns2np1
4A
ns2np2
5A
ns2np3
6A
ns2np4
7A
ns2np5
7
33
.O.
..
..
35
IONIC BOND
Define as = the electrostatic force that holds
ions together in an ionic compound
Ionic bond form when an atoms:
charged (CATION)
Atom that accept electron will be ve charged (ANION)
Li+ F -
Li + F
Li
LiF
e +
Li+ +
Li+ + e
Li+
38
Try This:
COVALENT BOND
Means = is a chemical bond in which 2 or
more electrons are shared by 2 atoms
Covalent compound = compounds that contain
only covalent bond
In covalent bond,
F
7e-
F F
7e-
8e- 8e-
Lewis structure of F2
single covalent bond
lone pairs
lone pairs
lone pairs
lone pairs
43
Single bond
Double bond
Triple bond
Single bond
or
Double bond
or
double bonds
Triple bond
or
triple bond
electron rich
region
F
e- poor e- rich
H
d+
F
d-
49
electrons unequally, a
bond dipole results.
The dipole moment,
Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
54
3 H 1s1
If the bonds form from overlap of 3 2p orbitals on nitrogen with the 1s orbital on each
hydrogen atom, what would the molecular geometry of NH3 be?
If use the
3 2p orbitals
predict 90o
Actual H-N-H
bond angle is
107.3o
55
56
57
58
Predict correct
bond angle
59
60
61
2.
Count the number of lone pairs AND the number of atoms bonded to
the central atom
# of Lone Pairs
+
# of Bonded Atoms
Hybridization
Examples
sp
BeCl2
sp2
BF3
sp3
sp3d
PCl5
sp3d2
SF6
62
63
64
65
of the
66
67
sp Hybridization of Carbon
68
69
70
71
Single bond
Double bond
Triple bond
How many s and p bonds are in the acetic acid (vinegar) molecule CH3COOH?
s bonds = 6
H
+1=7
p bonds = 1
H
72
A bonding molecular orbital has lower energy and greater stability than the
atomic orbitals from which it was formed.
An antibonding molecular orbital has higher energy and lower stability than the
atomic orbitals from which it was formed.
74
75
76
General molecular orbital energy level diagram for the second-period homonuclear
diatomic molecules Li2, Be2, B2, C2, and N2.
77
The number of molecular orbitals (MOs) formed is always equal to the number
of atomic orbitals combined.
2.
The more stable the bonding MO, the less stable the corresponding
antibonding MO.
3.
4.
5.
Use Hunds rule when adding electrons to MOs of the same energy.
6.
The number of electrons in the MOs is equal to the sum of all the electrons on
the bonding atoms.
78
1
bond order =
bond order
Number of
electrons in
bonding MOs
Number of
electrons in
antibonding
MOs
0
79
80
Delocalized p orbitals
81
Electron density above and below the plane of the benzene molecule.
82
83
84
Intermolecular Forces
1.5
Kinetic Energy
II.
neglible in gases
important in solids, liquids
Intermolecular Forces
(Attractive Forces, van der Waal
Forces)
Part II
Intermolecular Forces
Intermolecular forces; attractive forces between diff. Molecules
which bring the molecules in contac with eac other
Intramolecular forces hold atoms together in a molecule.
Intermolecular vs Intramolecular
Generally,
intermolecular forces
are much weaker
than intramolecular
forces.
boiling point
melting point
DHvap
DHfus
DHsub
11.2
Hydrogen Bonds
Intermolecular Forces
I. Dipole-Dipole Forces
Attractive forces between polar molecules
11.2
Intermolecular Forces
11.2
Polarizability
Ease at which the electron distribution in an
atom or molecule can be distorted and a
temporary dipole induced
More electrons (greater Molar Mass) leads to
greater polarizability.
HBr
HBr is a polar molecule: dipole-dipole forces. There are also dispersion forces
between HBr molecules.
CH4
CH4 is nonpolar: dispersion forces.
S
SO2
SO2 is a polar molecule: dipole-dipole forces. There are also dispersion forces
between SO2 molecules.
11.2
Gas
No Intermolecular Forces
CF4
Boiling Point; -150.0C
Molar Mass ~ 88 g/mole
Intermolecular Force;
Dispersion Force
H2Se
Boiling Point; -42.0 C
Molar Mass ~ 81 g/mole
Intermolecular Force; DipoleDipole Force
Boiling Points of
Polar Hydrogen Compounds
Boiling Point;
C
H2O
Approximate
Molar Mass;
g/mole
18
H2S
34
-60
H2Se
81
-42
H2Te
130
-2
+ 100
Hydrogen Bond
Strong Type of DipoleDipole Force. This
Type of Intermolecular
Force Happens When
H is directly bonded to
O, N, or F.
Hydrogen Bond
C
H
ethanol
H
H
NO
H Directly Bonded
to O, N, or F ?
NO
Dispersion/
London Forces
Dipole/Dipole Force
YES
Hydrogen Bonding