Professional Documents
Culture Documents
Lecture
on
Pure substances and steam tables
Dr. Hiralal Bhowmick
Thapar University
Phase:
A phase is defined as having a distinct molecular arrangement that is
homogenous throughout and separated from others (if any) by easily
identifiable boundary surfaces.
Pure Substance:
A pure substance is one whose chemical composition does not change
during thermodynamic processes.
A pure substance has a homogeneous and invariable chemical composition
and may exist in more than one phase or physical state.
Mixtures are not pure substances. (eg: Humid air)
Water and refrigerants are examples of pure substances.
Water :
Measureable properties:
P, v, T
Non-Measurable Properties:
Internal energy, enthalpy and entropy.
Already discussed
Already discussed
Tds Equations:.
Thermodynamic charts
T-v diagram
P-v diagram
P-T diagram
P-v-T diagrams
Temperature-entropy (T-s) charts
pressure-enthalpy (P-h) charts
Let us start with different states of water by a T-v plot, which will
be followed by development of various charts for pure substance.
vg
vf
vg
vf
Characteristics
This temperature will remain constant during
heating until all the liquid boils off.
The saturation temperature of a pure
substance is a function of pressure only.
At atmospheric pressure, the saturation
temperature is called normal boiling point .
Temperature-volume diagram
The locus of all the saturated states gives
the saturated liquid curve AC and the
locus of all the saturated vapor states gives
the saturated vapor curve BC.
The point C represents the critical point.
A liquid below the critical point when
heated first becomes a mixture of liquid
and
vapour and then becomes
saturated vapour and finally a
superheated vapour.
There is a clear-cut meniscus between
liquid and vapour, until all the liquid
evaporates
Critical Point
It is the highest temperature below which the liquid and vapour phases
can coexist.
At critical point there is no distinction between liquid state and vapour
state; these two merge together.
At the critical point
vg = vf
hfg ,ufg and vfg are zero.
The temperature, pressure and specific volume at critical point are
denoted by Tc, Pc and vc, respectively.
At supercritical pressures, the substance is simply termed fluid rather
than liquid or vapor.
For water:
Triple point: 0.1oC, 0.006112 bar
Critical point: 221.2 bar, 647.3K
and 0.00317 m3/kg
Pressure-volume diagram
If we plot P versus v for a large
number of isotherms, we obtain a
pressure-volume diagram
The pressure-volume (P-V) diagram
for a pure substance is shown in
Figure.
The curves AC and BC represent the
saturated liquid curve and saturated
vapor curve, respectively,
Point E represents 100% saturated liquid
Point F represents 100% saturated
vapor
Point C is critical point.
Pressure-volume diagram
The area under the curve ACB
represents the two-phase region.
Any point M in this region is a
mixture of saturated liquid (shown
as f) and saturated vapor (g).
A P-T diagram is the most common way to show the phases of a substance.
The line that separates the solid and vapor phases is called the sublimation line.
The line that separates the solid and liquid phases is called the fusion/melting line.
The line that separates the liquid and vapor phases is called the vaporization line.
The point where the three lines meet is called the triple point.
At the triple point the system becomes invariant
The point where the vaporization line ends is called the critical point.
At temperatures and pressures greater than those at the critical point, no substance
can exist as a liquid no matter how great pressure is exerted upon it.
If the answer to the first question is yes, the state is in the compressed
liquid region, and the compressed liquid tables are used to find the
properties of the state.
If the answer to the second question is yes, the state is in the saturation
region, and either the saturation temperature table or the saturation
pressure table is used to find the properties.
Then the quality is calculated and is used to calculate the other properties, u, h, and s .
If the answer to the third question is yes, the state is in the superheated
region and the superheated tables are used to find the other properties.
he h f
he = hi = h f + xh fg
x=
h fg
Thank You
Further Readings: Books by
Cengel & Boles
PK Nag
YVC Rao