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INPULSE B10 BRIGHTENER

SAFETY DATA SHEET


According to GB/T 16483-2008/ GB 13690-2009
Print Date: 30.04.2014

Version 3

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING

Product name:

INPULSE B10 BRIGHTENER

English Product Name:

INPULSE B10 BRIGHTENER

Product code:

1671542

Identified uses
Chemical plating of metals / Surface treatment
Uses advised against
No information available

Details of the supplier of the safety data sheet


Atotech Deutschland GmbH
Erasmusstrasse 20
10553 Berlin
++49(0)30/34985-0

Atotech S.E.A. Pte Ltd


20 Tuas West Road
Singapore 638379
Phones: +65 6862 2618
Fax: +65 6862 1506
Email: singapore-cse@atotech.com

Emergency telephone number


CARECHEM24 INTERNATIONAL (MULTILINGUAL SERVICE) +65 3158 1074

Prepared By:
Product Safety Department (PSD), email: HES-Berlin@atotech.com

SECTION 2: HAZARDS IDENTIFICATION


Classification of the substance or mixture
According to "General rule for classification and hazard communication of chemicals" (GB 13690-2009) and "Globally
Harmonized System of Classification and Labelling of Chemicals (GHS)" published by UNO:
Skin corrosion/irritation
Serious eye damage/eye irritation
Chronic aquatic toxicity

SAP Number: 1671542

Category 2
Category 2A
Category 2

Product name: INPULSE B10 BRIGHTENER

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Product name: INPULSE B10 BRIGHTENER

SECTION 2: HAZARDS IDENTIFICATION


Label elements
Hazard Pictograms

Signal word:

Warning

Hazard statements
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H411 - Toxic to aquatic life with long lasting effects
Precautionary statements
P273 - Avoid release to the environment
P280 - Wear protective gloves/eye protection/face protection
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing

Other hazards
None known

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Aqueous solution of chemicals

Description:
Components
sulphuric acid

Weight %
1-2.5

CAS-No
7664-93-9

INDEX No
016-020-00-8

EC-No.
231-639-5

copper sulphate

0.1-1

7758-98-7

029-004-00-0

231-847-6

bis-(3-sulfopropyl)-disulfide, disodium salt

0.1-1

27206-35-5

248-324-3

SAP Number: 1671542

Product name: INPULSE B10 BRIGHTENER

REACH No.
01211945883820
01211952056640

Revision Date: 26.02.2014

GHS Classification
Skin Corr. 1A (H314)
Acute Tox. 5 (H303)
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
Acute Tox. 3 (H301)
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)
Skin Sens. 1 (H317)

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Product name: INPULSE B10 BRIGHTENER


Supplemental component information:
The remaining 100% of the recipe consists of non-hazardous and/or confidential components.

For the full text of the H-Statements mentioned in this Section, see Section 16

SECTION 4: FIRST AID MEASURES


Description of first aid measures
General advice:
Consult a physician.
Inhalation:
Move to fresh air. If symptoms persist, call a physician.
Skin contact:
Wash off immediately with plenty of water for at least 15 minutes. Remove and wash contaminated clothing before re-use. Consult a
physician.
Eye contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician.
Ingestion:
Call a physician or Poison Control Center immediately. Do not induce vomiting without medical advice. Never give anything by mouth to
an unconscious person.
Protection of first-aiders:
Use personal protective equipment.
Most important symptoms and effects, both acute and delayed
Irritation.
Indication of immediate medical attention and special treatment needed
None known

SECTION 5: FIRE-FIGHTING MEASURES


Extinguishing media
Suitable extinguishing media:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Extinguishing media which must not be used for safety reasons:
No information available
Special hazards arising from the substance or mixture:
In case of fire hazardous decomposition products may be produced such as. Carbon oxides. Sulphur oxides.
Precautions for fire-fighters
Water mist may be used to cool closed containers. Dike and collect water used to fight fire. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations.

Flammability Limits in Air:


Lower:
Not applicable.

SAP Number: 1671542

Product name: INPULSE B10 BRIGHTENER

Revision Date: 26.02.2014

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Product name: INPULSE B10 BRIGHTENER


Upper:
Not applicable.

SECTION 6: ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures
Avoid contact with skin, eyes and clothing Prevent unauthorized access For personal protection see section 8
Environmental precautions
Should not be released into the environment.
Methods and materials for containment and cleaning up
Avoid formation of aerosol. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Clean contaminated
surface thoroughly. Dispose of in accordance with local regulations.
Prevent further leakage or spillage if safe to do so.
Reference to other sections
For personal protection see section 8. See also section 13.

SECTION 7: HANDLING AND STORAGE


Precautions for safe handling
Use only in area provided with appropriate exhaust ventilation.
Do not breathe vapours/dust. Remove and wash contaminated clothing before re-use. Handle in accordance with good industrial
hygiene and safety practice. Do not ingest. For personal protection see section 8.
Handle in accordance with good industrial hygiene and safety practise.
Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a dry, cool and well-ventilated place. See chapter: 10.
Storage Temperature.
Keep above
-5 C
Keep below
40C
Specific end uses
None known

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

National occupational exposure limits

Components
sulphuric acid

Austria
TWA: 0.1 mg/m3
STEL: 0.2 mg/m3

copper sulphate

STEL: 0.4 mg/m3

SAP Number: 1671542

Australia
STEL: 3 mg/m3
TWA: 1 mg/m3

Product name: INPULSE B10 BRIGHTENER

Bahrain
TWA: 1 mg/m3
STEL: 3 mg/m3

China
Carcinogenic to
humans
STEL: 2 mg/m3
TWA: 1 mg/m3

Revision Date: 26.02.2014

Czech Republic
TWA: 1 mg/m3
Ceiling: 2 mg/m3

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Product name: INPULSE B10 BRIGHTENER


Components
sulphuric acid

Denmark
TWA: 1 mg/m3

Finland
TWA: 0.2 mg/m3
STEL: 1 mg/m3

France
TWA: 0.05 mg/m3
STEL: 3 mg/m3

Germany
MAK: 0.1 mg/m3
Carcinogen: Category
4
Peak: 0.1 mg/m3
inhalable fraction
Pregnancy: no risk to
embryo/fetus if
exposure limits
adhered to
MAK: 0.1 mg/m3
Peak: 0.2 mg/m3
inhalable fraction
Pregnancy: no risk to
embryo/fetus if
exposure limits
adhered to

Hong Kong
TWA: 1 mg/m3
STEL: 3 mg/m3

TWA: 1 mg/m3

copper sulphate

Components
sulphuric acid
copper sulphate
Components
sulphuric acid

Hungary
TWA: 1 mg/m3
STEL: 1 mg/m3
STEL: 4 mg/m3

India
TWA: 1 mg/m3

Indonesia
NAB: 1 mg/m3

Ireland
TWA: 1 mg/m3

Italy

Japan

Korea
STEL: 0.6 mg/m3
TWA: 0.2 mg/m3
1A - Known Human
Carcinogen based on
human evidence,
limited to strong acid
mist

Lithuania
TWA: 1 mg/m3
STEL: 3 mg/m3

Malaysia
TWA: 1 mg/m3

The Netherlands

TWA: 0.2 mg/m3

copper sulphate
Components
sulphuric acid

Norway
TWA: 0.1 mg/m3
Carcinogen
STEL: 0.3 mg/m3

Philippines
TWA: 1 mg/m3

Poland
TWA: 1 mg/m3
NDSCh: 3 mg/m3
Corrosive substance
Fetotoxicity
TWA: 0.2 mg/m3

Portugal
A2 - Suspected
Human Carcinogen
TWA: 0.2 mg/m3

Singapore
1 mg/m3 PEL
STEL: 3 mg/m3

Components
sulphuric acid

Slovakia
TWA: 0.1 mg/m3
Ceiling: 0.1 mg/m3

Slovenia
TWA: 0.05 mg/m3

Sweden
LLV: 1 mg/m3
STEL: 3 mg/m3

Spain
VLA ED: 1 mg/m3
VLA EC: 3 mg/m3

Taiwan
TWA: 1 mg/m3
STEL: 2 mg/m3

Components

Thailand

Turkey

United Arab
Emirates
TWA: 1 mg/m3
STEL: 3 mg/m3

United Kingdom

Vietnam

TWA: 1 mg/m3

TWA: 1 mg/m3
STEL: 2 mg/m3
TWA: 0.5 mg/m3
STEL: 1 mg/m3

copper sulphate

sulphuric acid
copper sulphate

Exposure controls

Appropriate engineering controls:


Ensure adequate ventilation

Individual protection measures


Hygiene measures
Handle in accordance with good industrial hygiene and safety practise

SAP Number: 1671542

Product name: INPULSE B10 BRIGHTENER

Revision Date: 26.02.2014

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Product name: INPULSE B10 BRIGHTENER


Respiratory protection:
In case of insufficient ventilation wear suitable respiratory equipment
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Recommended Filter
type: ABEK P3
Eye protection:
Tightly fitting safety goggles. face-shield. Ensure that eyewash stations and safety showers are close to the workstation location.
Skin protection
Suitable safety glove for not intended contact with the product during use pursuant to section 1:
Product name: e.g. KCL Camapren 720
Material: Chloroprene
Thickness in mm: 0,65 +/- 0,1
Breakthrough time in min: 120
The applied gloves must be in accordance with the specifications of EC 89/686/EEC and the resulting standard EN 374.
Increased temperature, reduced thickness through elongation, abrasion and/or repeated use of gloves leads to a modified
breakthrough-time.
Furthermore, breakthrough times may also vary if the product delivered is diluted and/or used in conjunction with other chemicals.
Therefore, please contact a supplier of CE-approved gloves to find the suitable glove for your conditions and to ensure safe use it is
recommended to replace used gloves frequently.
Thermal hazards:
None known
Environmental exposure controls:
None known

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


Form

liquid

Colour:

light blue
light green

Odour:

No information available

Odour Threshold

No information available

Melting point (C):

No information available

Boiling point (C):

> 100

Flash point (C):

Not applicable

Evaporation rate:

No information available

Flammability

No information available

Lower explosion limit

No information available

Upper explosion limit

No information available

Vapour pressure:

ca. 23 hPa

SAP Number: 1671542

Product name: INPULSE B10 BRIGHTENER

Revision Date: 26.02.2014

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


Relative vapour density

No information available

Water solubility

miscible

Partition coefficient: n-octanol/water

No information available

Autoignition temperature (C):

No information available

Decomposition temperature (C):

No information available

Viscosity:

No information available

Explosive properties:

Not applicable

oxidising properties

No information available

pH:

0.00 - 2.00

Relative density

1.010 - 1.030

Other information
VOC Content(%):
Not applicable
Solubility in other solvents:
No information available
Bulk density
No information available
Ignition temperature (C):
No information available
Solidification point (C):
Not required

SECTION 10: STABILITY AND REACTIVITY


Reactivity
None under normal processing
Chemical stability
Stable at normal conditions
Possibility of hazardous reactions
None under normal processing
Conditions to avoid:
To avoid thermal decomposition, do not overheat.
Incompatible materials
(see section "Possibility of hazardous reactions")

SAP Number: 1671542

Product name: INPULSE B10 BRIGHTENER

Revision Date: 26.02.2014

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SECTION 10: STABILITY AND REACTIVITY


Hazardous decomposition products:
See chapter: 5

SECTION 11: TOXICOLOGICAL INFORMATION


Information on toxicological effects
Skin contact
Irritating to skin
Eye contact
Causes serious eye irritation.
Inhalation
May cause irritation of respiratory tract
Ingestion
May be harmful if swallowed
Sensitisation
No information available
carcinogenic effects
No information available.
mutagenic effects
No information available
Reproductive toxicity
No information available.
STOT - single exposure
No information available
STOT - repeated exposure
No information available
Aspiration hazard
No information available
Delayed and immediate effects and also chronic effects from short and long term exposure
None known
Other information on acute toxicity
Components
sulphuric acid - 7664-93-9
copper sulphate - 7758-98-7
bis-(3-sulfopropyl)-disulfide, disodium salt - 2720635-5

LD50/oral/rat
2140 mg/kg
300 mg/kg
> 2000 mg/kg

LC50/inhalation/rat
510 mg/m3 2h
No information available
-

LD50/dermal/rabbit
No information available
1000 mg/kg
-

Other information
Irritation

SECTION 12: ECOLOGICAL INFORMATION


Toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to the environment.

SAP Number: 1671542

Product name: INPULSE B10 BRIGHTENER

Revision Date: 26.02.2014

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SECTION 12: ECOLOGICAL INFORMATION


Components
copper sulphate - 7758-98-7

Freshwater Algae

Freshwater Fish Species


96 h LC50 (Oncorhynchus mykiss) = 0.1
mg/L
96 h LC50 (Oncorhynchus mykiss) = >1000
mg/L

bis-(3-sulfopropyl)-disulfide, disodium salt 27206-35-5

Components
copper sulphate
7758-98-7
bis-(3-sulfopropyl)-disulfide, disodium salt
27206-35-5

Water Flea
48 h EC50 0.02 mg/L

Log Pow

- 3.68

Persistence and degradability


No information available
Bioaccumulative potential:
Not determined

Mobility in soil
No known effect based on information supplied
Results of PBT and vPvB assessment
No information available
Other adverse effects
None known based on information supplied

SECTION 13: DISPOSAL CONSIDERATIONS


Waste treatment methods
Waste from residues / unused products:
Dispose of in accordance with local regulations
Contaminated packageing:
Empty containers should be taken for local recycling, recovery or waste disposal

SECTION 14: TRANSPORT INFORMATION

IMDG
UN-No (IMO/IMDG):
Proper shipping name (IMDG):
Technical Name (IMDG):
Ems no.:
Hazard Class (IMO/IMDG):
Packing group (IMO/IMDG):
Marine pollutant:
Hazard Label (IMO/IMDG):
ADR/RID
UN-No:
Proper shipping name:
Technical Name (ADR):
Hazard Class:

SAP Number: 1671542

UN3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
copper sulfate
F-A,S-F
9
III
P
9

3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
copper sulphate
9

Product name: INPULSE B10 BRIGHTENER

Revision Date: 26.02.2014

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SECTION 14: TRANSPORT INFORMATION


III
M6
90
9

Packing group:
Classification Code:
Kemler Number (ADR):
ADR/RID-Labels

ICAO/IATA
UN3082
UN-No (IATA):
Proper shipping name (IATA): ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
copper sulfate
Technical Name (IATA):
9
Hazard Class (IATA):
III
Packing group (IATA):
9
Hazard Label:
Environmentally hazardous
Marine pollutant
Special precautions for users
None known
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: REGULATORY INFORMATION


Safety, health and environmental regulations/legislation specific for the substance or mixture
Take note of Dir 94/33/EC on the protection of young people at work
Take note of Directive 96/82/EC on the control of major-accident hazards involving dangerous substances

Further Information:

German storage class (VCI)

10-13

Water contaminating class (Germany)

Substances currently restricted by WEEE/RoHS (European Directive 2012/19/EC , 2011/65/EC) or ELV (European Directive
2000/53/EC):

PBDE
-

PBB
-

CrVI
-

Hg
-

Pb
-

Cd
-

Please note: Current legislation restricting the use of certain substances applies to homogeneous material in finished
articles being supplied to the market. Substances deposited during surface finishing may have a composition (weight
percent) higher than the weight percent of the substance in the operating solution from which the deposit is made.
Atotech encourages its customers to implement systems to ensure their finished products comply with the regulations in
force.
All of the components in this product are on or exempt from the following inventories:
US TSCA, CANADA DSL / NDSL, Europe (EINECS/ELINCS/NLP), Australia, Korea, China, Japan.

SAP Number: 1671542

Product name: INPULSE B10 BRIGHTENER

Revision Date: 26.02.2014

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International Inventory Legend
TSCA: US - Toxic Substance Control Act
DSL: Canada - Domestic Substance List
NDSL: Canada - Non-Domestic Substance List
IECSC: China - Inventory of Existing Chemical Substances China
EINECS: EU Inventory of Existing Commercial Chemical Substances
ELINCS: EU List of Notified Chemical Substances
ECL: Korea - Existing Chemicals List
AICS: Australia - Inventory of Chemical Substances
ENCS: Japan - Existing and New Chemical Substances
PICCS: Phillipines - Inventory of Chemicals and Chemical Substances

SECTION 16: OTHER INFORMATION


This safety data sheet has been prepared according to following regulations:
General rule for classification and hazard communication of chemicals (GB 13690-2009)
Safety Data Sheet for Chemical Products Content and Order of Sections (GB/T 16483-2008)
Globally Harmonized System of Classification and Labelling of Chemicals (UNO GHS)
Full text of H-Statements referred to under sections 2 and 3:
H301 - Toxic if swallowed
H303 - May be harmful if swallowed
H314 - Causes severe skin burns and eye damage
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects

Revision

This data sheet contains changes from the previous version in section(s) - 3

Revision Date:

26.02.2014

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal
and release and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in
the text

SAP Number: 1671542

Product name: INPULSE B10 BRIGHTENER

Revision Date: 26.02.2014

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