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2.
3.
4.
5.
6.
v u vd
(b)
vd vu
vd + vu
(c)
v u + vd
2
(d)
2vd v u
.
vd + vu
8.
B
(a) A B Y
(b) A B Y
011
001
011
010
101
100
110
110
(c) A B Y
(d) A B Y
000
000
011
010
101
100
111
111
In a radioactive decay process, the negatively
charged emitted -particles are
9.
10.
11.
ratio
will
be
proportional to
(a) 1/R2 (b) R2
(c) R
(d) 1/R
A wheel has angular acceleration of 3.0 rad/sec2
and an initial angular speed of 2.00 rad/sec. In a
time of 2 sec it has rotated through an angle (in
radian) of
(a) 10
(b) 12
(c) 4
(d) 6
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12.
17.
B
B
(a)
(c)
q
20
(b)
3
(d)
18.
14.
A nucleus A
Z X has mass represented by M(A,
Z). If Mp and M n denote the mass of proton and
neutron respectively and B.E. the binding energy
in MeV, then
(a) B.E. = [ZMp + (A Z)Mp M(A, Z)]c2
(b) B.E. = [ZMp + ZMn M(A, Z)]c2
(c) B.E. = M(A, Z) ZMp (A Z)Mn
(d) B.E. = [M(A, Z) ZMp (A Z)Mn]c2
The total power dissipated in watts in the circuit
shown here is
19.
20.
(a) 40
16.
18 V
(b) 54
If the nucleus
3.6 fm, then
27
13 Al
(c) 4
125
32 Te
approximately as
(a) 9.6 fm
(c) 4.8 fm
(d) 16
(b) g/V
(c) V/g
(d) V/(g ).
(a) g /V
t
f, at time t, given by f = f 0 1 , where f0
T
1 q
2 0
13.
15.
21.
(a)
1
f T2
2 0
(b) f0T2
(c)
1
fT
2 0
(d) f0T.
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26.
3 cm
B
A
4 cm
O
coin
23.
24.
25.
27.
(a) LA = LB
(b) the relationship between LA and LB depends
upon the slope of the line AB
(c) LA < LB
(d) LA > LB.
The particle executing simple harmonic motion
has a kinetic energy K 0 cos 2 t . The maximum
28.
ml 2
,
3
the initial angular acceleration of the rod will be
A
l
(a)
qQ
20 L
(c)
mgl
(a)
2
(c)
3g
2l
29.
3
(b)
gl
2
(d)
2g
.
3l
qQ
60 L
(b)
qQ
60 L
(d)
qQ
40 L
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30.
35.
36.
(x = 0, y = 0, z = 0) and (x = a, y = a, z = 0)
(b) qa along the line joining points (x = 0, y = 0,
z = 0) and (x = a, y = a, z = 0)
(c)
(d)
37.
31.
32.
33.
34.
38.
39.
C/2
1
CV 2
4
(b)
3
CV 2
4
1
(d) 2CV2.
CV 2
2
A black body is at 727 C. It emits energy at a
rate which is proportional to
(a) (1000)4
(b) (1000)2
4
(c) 727)
(d) (727)2
The resistance of an ammeter is 13 and its
scale is graduated for a current upto 100 amps.
After an additional shunt has been connected
to this ammeter it becomes possible to measure
currents upto 750 amperes by this meter. The
value of shunt-resistance is
(a) 2
(b) 0.2 (c) 2 k (d) 20
(c)
40.
41.
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43.
44.
45.
46.
48.
49.
(c)
50.
r 2 (t + 273) 4
4R 2
r 2 (t + 273) 4
(b)
(d)
162 r2 t 4
R2
4r 2 t 4
R2
R2
where is the Stefans constant.
In the energy band diagram of a material shown
below, the open circles and filled circles denote
holes and electrons respectively. The material is
Ec
Eg
Ev
1
(a) mg(h + d) kd 2
2
(a)
(b)
(c)
(d)
1
(b) mg(h d) kd 2
2
1
(c) mg(h d) + kd 2
2
47.
1
(d) mg(h + d) + kd 2
2
Under the influence of a uniform magnetic field
a charged particle is moving in a circle of radius
R with constant speed v. The time period of the
motion
(a) depends on both R and v
(b) is independent of both R and v
(c) depends on R and not on v
(d) depends on v and not on R
an insulator
a metal
an n-type semiconductor
a p-type semiconductor
CHEMISTRY
51.
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52.
53.
44.
55.
57.
1
O = H2O(l),
2 2(g)
H = X2 kJ mol1
(iii) CO2(g) + H2(g) = CO(g) + H2O,
H = X3 kJ mol1
(ii) H2(g) +
58.
59.
60.
H 2(g) + 2ICl(g)
2HCl(g) + I 2(g)
The reaction is of first order with respect to H2(g)
and ICI(g), following mechanisms were proposed.
Mechanism A:
61.
H 2(g) + 2ICl(g)
2HCl(g) + I 2(g)
H 2(g) + ICl(g)
HI(g) ;slow
HI(g) + ICl(g)
HCl(g) + I 2(g) ;fast
Which of the above mechanism(s) can be
consistent with the given information about the
reaction?
(a) A and B both
(b) neither A nor B
(c) A only
(d) B only
The efficiency of a fuel cell is given by
(a)
G
S
(b)
S
G
(c)
G
H
(d)
5
(iv) C2 H 2(g) + O 2(g) = 2CO2(g) + H2O(l)
2
H = X3 kJ mol1
Enthalpy of formation of H2O (l) is
(a) + X 3 kJ mol 1
(b) X 4 kJ mol 1
1
(c) + X 1 kJ mol
(d) X 2 kJ mol 1
The correct order of increasing thermal stability
of K2CO3, MgCO3, CaCO3 and BeCO3 is
(a) BeCO3< MgCO3 < CaCO3 < K2CO3
(b) MgCO3 < BeCO3 < CaCO3 < K2CO3
(c) K2CO3 < MgCO3 < CaCO3 < BeCO3
(d) BeCO3 < MgCO3 < K2CO3 < CaCO3
In which of the following pairs, the two species
are iso-structure?
(a) SO32 and NO3 (b) BF3 an NF3
(c) BrO3 and XeO3 (d) SF4 and XeF4
Which of the following oxidation states are the
most characteristic for lead and tin respectively?
(a) + 2, + 4
(b) + 4, + 4
(c) + 2, + 2
(d) + 4, + 2
Which of the following statements, about the
advantage of roasting of sulphide ore before
reduction is not true?
(a) The G of of the sulphide is greater than
those for CS2 and H 2S.
Mechanism B:
56.
H
G
62.
(c)
log 2
k
(b)
ln 2
k
(d)
log 2
k 0.5
0.693
0.5k
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COCl
(iii) H 3C
COCl
(iv) OHC
64.
67.
68.
COCl
69.
HI
CH 3CH 2 C CH + HCl
B C
I
|
(a) CH3 CH 2 CH 2 C H
|
Cl
70.
I
|
(b) CH3 CH 2 CH CH 2 Cl
I
|
(c) CH3CH 2 C CH3
|
Cl
(d) CH3 CH CH 2 CH 2 I
|
Cl
65.
66.
71.
72.
73.
C2 H5
|
(b) Cl C CH3
|
H
CH3
|
(c) H C Cl
|
C2 H5
C2 H5
|
(d) H3C C Cl
|
H
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74.
75.
76.
77.
78.
79.
80.
81.
82.
(c) I
(d) HS
83.
2NH3 ; K1
N 2 + 3H 2
2NO; K 2
N 2 + O2
1
H 2 O; K 2
H 2 + O 2
2
The equilibrium constant for the oxidation of NH3
by oxygen to give NO is
84.
85.
86.
87.
(a)
K 2 K32
K1
(b)
K22 K3
K1
(b)
K1K 2
K3
(d)
K 2 K33
K1
88.
89.
(d) C6H5CH2CHO
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91.
97.
CH3
|
Heated
CH3 CH CH 2 O CH 2 CH3 + HI
92.
93.
94.
95.
96.
E = 0.46 V at 298 K is
(a) 2.0 1010
(b) 4.0 1010
15
(c) 4.0 10
(d) 2.4 1010
Which one of the following polymers is prepared
by condensation polymerisation?
(a) Teflon
(b) Natural rubber
(c) Styrene
(d) Nylon-66
The order of decreasing reactivity towards an
electrophilic reagent, for the following would be
(i) benzene
(ii) toluene
(iii) chlorobenzene
(iv) phenol
(a) (ii) > (iv) > (i) > (iii)
(b) (iv) > (iii) > (ii) > (i)
(c) (iv) > (ii) > (i) > (iii)
(d) (i) > (ii) > (iii) > (iv)
Which of the folloiwng anions is present in the
chain structure of silicates?
(a) (Si2O52)n
(b) (SiO32)n
4
(c) SiO4
(d) Si2O76
An element, X has the following isotopic
composition:
200X : 90%
199X : 8.0 %
202X : 2.0 %
The weighted average atomic mass of the
naturally occuring element X is closest to
(a) 201 amu
(b) 202 amu
(c) 199 amu
(d) 200 amu
The fraction of total volume occupied by the
atoms present in a simple cube is
(a)
3 2
(c)
(b)
In the reaction:
CH3
|
(c) CH3 CH CH2 OH + CH3 CH 2 I
CH3
|
(d) CH3 CH CH 2 I + CH3CH 2 OH
98.
4 2
(d)
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BIOLOGY
101. ICBN stands for
(a) International Code of Botanical
Nomenclature
(b) International congress of Biological Names
(c) Indian Code of Botanical Nomenclature
(d) Indian Congress of Biological Names.
102. Which pair of the following belongs to
Basidiomycetes
(a) puffballs and Claviceps
(b) peziza and stink borns
(c) Morchella and mushrooms
(d) birds nest fungi and puffballs.
103. Biological organisation starts with
(a) cellular level
(b) organismic level
(c) atomic level
(d) submicroscopic molecular level
104. Identify the odd combination of the habitat and
the particular animal concerned.
(a) sunderbans
- Bengal Tiger
(b) periyar
- Elephant
(c) Rann of kutch
- wild Ass
(d) Dachigam National park - Snow Leopard.
105. If you suspect major deficiency of antibodies in
a person to which of the following would you
look for confirmatory evidence?
(a) serum globulins
(b) fibrinogen in the plasma
(c) haemocytes
(d) serum albumins
106. A common test to find the genotype of a hybrid
is by
(a) crossing of one F2 progeny with female
parent
(b) studying the sexual behaviour of F 1
progenies
(c) crossing of one F1 progeny with male parent
(d) crossing of one F2 progeny with male parent.
107. The okazaki fragments in DNA chain growth
(a) polymerize in the 3 - to - 5 direction and
forms replication fork
(b) prove semi-conservative natuire of DNA
replication
(c) polymerize in teh 5 - to - 3 direction and
explain 3 - to - 5 DNA replication
(d) result in transcription.
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125.
126.
127.
128.
129.
130.
131.
132.
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140.
141.
142.
143.
144.
145.
146.
parts
(b) testa of seeds to enable emergence of
growing embryonic axis during seed
germination
(c) central region of style through which the
pollen tube grows towards the ovary
(d) endodermis of roots facilitating rapid
transport of water from cortex to pericycle.
What is common between parrot, platypus and
kangaroo?
(a) toothless jaws
(b) functional post-end tail
(c) ovoparity
(d) homoiothermy
Bowmans glands are located in the
(a) anterior pituitary
(b) female reproductive system of cockroach
(c) olfactory epithelium of our nose
(d) proximal end of uriniferous tubles.
Which one of the following pairs is wrongly
matched ?
(a) yeast
ethanol
(b) streptomycetes antibiotic
(c) coliforms
vinegar
(d) methanogens
gobar gas.
Which part of ovary in mammals acts as an
endocrine gland after ovulation ?
(a) stroma
(b) germinal epithelium
(c) vetelline membrane
(d) Graafian follicle.
Opening of floral buds into flowers, is a type of
(a) autonomic movement of variation
(b) paratonic movement of growth
(c) autonomic movement of growth
(d) autonomic movement of locomotion.
Which one of the following is a matching pair of
a body feature and the animal possessing it ?
(a) ventral central
- Leech
nervous system
(b) Pharyngeal gill slits - Chamaeleon
absent in embryo
(c) ventral heart
- Scorpion
(d) post-end tail
- Octopus.
All enzymes of TCA cycle are located in the
mitochondrial matrix except one which is located
in inner mitochondrial membranes in eukaryotes
and in cytosol in prokaryotes. This enzyme is
(a) isocitrate dehydrogenase
(b) malate dehydrogenase
(c) succinate dehydrogenase
(d) lactate dehydrogenase.
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188.
189.
190.
191.
192.
193.
(i)
(ii)
(iii)
(iv)
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(a) Since
6.
Vs Ns
=
Vp N p
(c)
At t = 0, (N 0 ) A = (N 0 ) B
Where
Ns = No. of turns across primary coil = 50
Np = No. of turns across secondary coil
= 1500
Given,
1500
4 = 120 V
50
(a) If the electric field is switched off, and the
same magnetic field is maintained, the
electrons move in a circular orbit and
electron will travel a magnetic field to its
velocity.
dx d
(a) Speed v =
= (9t 2 t 3 ) = 18t 3t2
dt dt
For maximum speed
NA
= e(5 )t
NB
..... (2)
1
1
= e 4t =
e
e
x max = 81 27 = 54
t =
1
.
2
( 3,3)
7.
5.
Y'
A
0
0
1
1
s+s
2s
2v u vd
=
=
s
s
t1 + t 2
v
d + vu
+
v u vd
Y = A + B =A +B
Therefore truth table :
3
= 3
3
Y' = A +B
= tan 1 ( 3) = 60
(d) Since average speed
(c)
(0, 0)
4t
4 t = 2
(b)
NA
= e A t ..... (1)
(N 0 ) A
NB
= e B t
(N 0 ) B
dv
= 0 18 6t = 0 t = 3
dt
4.
N
= e t
N0
Vs =
3.
NA 1
=
NB e
d d
= (0 + 4t) = 4
and Vp =
dt dt
2.
A = 5 and B =
8.
B
0
1
0
1
Y
0
1
1
1
n = p + e +
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9.
vinst =
Therefore,
q
= 2 '+ B = 2 '+
0
dy
= A cos t = A sin(t + / 2)
dt
Acceleration = A 2 sin t
= A2sin( + t)
= 0.5
2
(a) In mass spectrometer, when ions are
accelerated through potential V
=
10.
13.
Here, n = 2 1014 Hz
= 5000 = 5000 10 10 m
1
mv2 = qV
..........(i)
2
As the magnetic field curves the path of
the ions in a semicircular orbit
mv 2
BqR
v=
.......... (ii)
R
m
Substituting (ii) in (i)
Bqv =
= c/v =
14.
11.
q
1
m R2
12.
V 2 (18)2
=
= 54 W
R
6
(d) It has been known that a nucleus of mass
number A has radius
R = R0A1/3
Where R0 = 1.2 1015m
and A = mass number
=
16.
In case of 27
13 Al, let nuclear radius be R 1
and for 125
32Te, nuclear radius be R 2
For
1
3(2) 2 = 4 + 6 = 10 rad
2
q
(d) Since total = A + B + C =
0
Where q is the total charge.
As shown in the figure, flux associated with
the curved surface B is = B
Let us assume flux linked with the plane
surfaces A and C be
A = C = '
=3
108
(a) The difference in mass of a nucleus and its
constituents, m, is called the mass defect
and is given by
2
and binding energy = Mc
1 2
(a) Since, = 0 t + t
2
Where is angular aceleration, 0 is the
initial angular speed.
t = 2s
= 2 2+
3 108
M = [ZMp + (A Z)M n ] M
1 BqR
= qV
m
2 m
q
2V
=
or
m B2 R 2
Since V and B are constants,
1 q
2 0
(b) By using v = n
' =
27
13 Al,
R1 = R 0 (27)1/ 3 = 3R 0
1/ 3
For 125
= 5R 0
32Te, R 2 = R 0 (125)
R 2 5R 0 5
5
=
= R1 = 3.6 = 6fm.
R1 3R 0 3
3
17.
v
=t
g
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(c) Here,
20.
f = f 0 1 or, dv = f 1 t
0
T
dt
T
P R
=
Q S
or, dv = f0 1 dt
T
2 2
=
2 S
Therefore, S should be 2.
A resistance of 6 is connected in parallel.
In parallel combination,
t
v = dv = f 0 1 dt
T
t2
or, v = f 0 t
+C
2T
0 = f0 0
+C
2T
1
1
1
=
+
R R1 R 2
1 1 1
= +
2 6 S
21.
C=0
t2
v = f0 t
2T
If f = 0, then
m = 30 10 5 1.5 10 60
= 0.27 gm.
22.
0 = f0 1
T
t =T
4 cm
t
f0 1 T dt
t =0
Since,
t 2
= f 0 t
2T 0
T2
T
= f0 T
= f0 T
2T
2
19.
(b)
23.
200
= 2 = 25
100
200
= 1250.
100
1
sin i
=
sin 90
1
5
=
sin i 3
Speed, v =
24.
c 3 108
=
= 1.8 108 m / s
5/3
1
f 0 T.
2
r = 90
coin
dv =
t =0
3 cm
(d)
t=T
Hence, particle's velocity in the time interval
t = 0 and t = T is given by
vx =
S = 3
(c) By using m = ZIt
Where, Z is the electrochemical equivalent
of copper.
Poutput
Pinput
100 =
100
100 = 90.9%
220 0.5
[V] [ML2 T 3 I 1 ]
=
= [ML2T3I2]
[I]
[I]
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25.
K0 =
(c)
1
m2 a 2
2
l/2 mg
1
m 2 a 2 = K 0
2
U max = K 0 & E = K 0 .
28.
(c)
= mg
l
2
+q
Also, = I
Where, I is the moment of inertia =
ml 2
3
d
0
27.
VD VC =
2
1 qQ
qQ
=
=
3 4 0 L 60 L
(d) Since p = nh
n=
LA = P A d, LB = PB d
As linear momenta are equal,
therefore, LA = LB.
(c) We have, U + K = E
where, U = potential energy, K = Kinetic
energy, E = Total energy.
Also, we know that, in S.H.M., when
potential energy is maximum, K.E. is zero
and vice-versa.
30.
1
m2 a 2 cos2 t
2
p
2 103
=
h 6.6 1034 6 1014
= 5 1015
(a) Three point charges +q, 2q and +q are
placed at points B (x = 0, y = a, z = 0),
O (x = 0, y = 0, z = 0) and A(x = a, y = 0, z = 0)
The system consists of two dipole moment
vectors due to (+q and q) and again due
to (+q and q) charges having equal
uuur
magnitudes qa units one along OA and
uuur
other along OB . Hence, net dipole moment,
uuur
pnet = (qa)2 + (qa)2 = 2qa along OP
at an angle 45 with positive X-axis.
U max + 0 = E U max = E
Further,
K.E. =
2 Kq
1 2 q
=
.
3 L
4 0 3 L
29.
D
L
Potential difference
2 Kq
q Kq
=
= K +
L
3L
3 L
ml 2
l
3g
= mg =
3
2
2l
C
2L
Potential at C = VC = 0
Potential at D = VD
26.
+q(0, a, 0)
B
A
(2q)
x
(0, 0, 0) O +q(a, 0, 0)
P
B
45
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2
a 2 = a sin t
T
GM
v=
, it does not depend upon the
r
32.
tan = 3 = 60
(a) Mass gets detached at the upper extreme
position when pan returns to its mean
position.
At that point, R = mg m2a = 0
i.e. g = 2a
39.
2 10
200
2
As = = m
40.
41.
750
13
= 1+
100
S
qv
qvR
( R 2 ) =
2R
2
42.
q
2R
Q I = T and T = v
35.
36.
13.6
2
13.6
2
37.
T
1
= 1 2
6
T1
n
2
But K.E. = (Total energy) = +3.4 ev.
(d) Number of emitted electrons NE
Intensity
T 62
1
2 = 1 2
6
T1
2
y = a sin t
T
According to problem y = a/2
.......... (1)
1
(Distance)
T2
T1
According to problem,
= 3.4ev
S 2
(c) Since efficiency of engine is
= 1
1
C 2 1 3C 2 3CV 2
C + V =
V =
2
2
2 2
4
(a) According to Stefan's law,
E T4
(t + 273)4 K
[727C = (727 + 273)K]
(727 + 273)4 K
(1000)4 K
(a) We know
I
G
= 1+
IS
S
a = 1 10 m = 10cm
34.
a = g / 2 = mg / K
a =
2
= t t = T 12
6 T
43.
.......... (2)
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44.
B = B0 sin(t kx)
The electromagnetic waves travel in the
r r
direction of (E B).
(d) Condition for which the current is maximum
in a series LCR circuit is,
46.
49.
Ti + Tc
(d) Since Tn =
=Neutral temperature
2
T + 0 Ti
Tn = i
=
2
2
[Tc = 0C = temperature of cold junction]
(c) Power radiated by the sun at tC
= (t + 273) 4 4r 2
Power received by a unit surface
1
LC
1000 =
45.
48.
50.
L(10 106 )
= L = 100 mH
(d) Beyond curie temperature, ferromagnetic
substances behaves like a paramagnetic
substance.
(a) Gravitational potential energy of ball gets
converted into elastic potential energy of
the spring.
1 2
mg(h + d) = kd
2
(t + 273)4 4r 2
r 2 (t + 273) 4
4R 2
R2
(d) For a P-type semiconductor, the acceptor
energy level, as shown in the diagram, is
slightly above the top Ev of the volume
band. With very small supply of energy an
electron from the valence band can jump to
the level EA and ionise acceptor negatively.
Chemistry
51.
1 2
Net work done = mg(h + d) kd = 0
2
e.g.,
r
LiAlH 4
CH3 N = C + 4[H]
CH3 NH CH3
dimethyl amine
52.
z v
x
v
47.
(b)
O
HOCH2
OH
H
H
OH
OH
D()ribose
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O
HOCH2
26
= 3(Q) + 2(R) = 5
8
hybridization = dsp3
hybridization of Xe in XeO3
Total valence electrons
=
OH
H
H
OH
61.
26
= 3(Q) + 2(R) = 5
8
Hybridization = dsp3
In both cases, the structure is trigonal
pyramidal.
(a) All the group IV elements show
tetravalency which can be explained on the
basis of shifting of one e of ns to the vacant
np orbital.These four orbitals give rise to
four sp3 hybrid orbitals.
When ns2 electrons of the outermost shell
do not participate in bonding it is called
inert pair and the effect is called inert pair
effect. The last three elements of group 4
i.e. Ge, Sn and Pb, have a tendency to form
divalent as well as tetravalent ions. Since
the inert pair effect increases from Ge to Pb,
the stability of tetravalent ion decreases
and that of divalent ion increases that is
why Pb++ is more stable than Pb4+ and Sn4+
ions is more stable than Sn2+.
(d) The sulphide ore is roasted to oxide before
62.
= 8 + 3 6 = 26 =
2-deoxyD()ribose
53.
54.
KA
1 10 5
=
= 102 = 1%
C
0.100
(d) As the slowest step is the rate determining
step thus the mechanism B will be more
consistent with the given information also
because it involve one molecule of H2 and
one molecule of ICl it can expressed as
r = k [H2][ICl]
Which shows that the reaction is first order
w.r.t. both H2 & ICl.
60.
() =
55.
56.
57.
58.
59.
G
H
(d) This reaction shows the formation of H 2O,
and the X 2 represents the enthalpy of
formation of H2O because as the definition
suggests that the enthalpy of formation is
the heat evolved or absorbed when one
mole of substance is formed from its
constituent atoms.
(a) As the basicity of metal hydroxides
increases down the group from Be to Ba,
the thermal stability of their carbonates also
increases in the same order. Further group
1 compounds are more thermally stable than
group 2 because their hydroxide are much
basic than group 2 hydroxides therefore,
the order of thermal stability is
BeCO3 < MgCO3< CaCO3< K2CO3.
(c) Hybridisation of Br is BrO3
Total valence elctrons = 7 + 3 6 = 25
Charge = 1 hence
(b) Efficiency of a fuel cell ( ) =
2.303
a
log10
t
ax
when t = t
k=
k=
2.303
a
log10
t
aa/2
2.303
ln 2
log10 2 =
k
k
(c) The degree of hydrolysis increases as the
magnitude of positive charge on carbonyl
group increases. Electron withdrawing
or t =
63.
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COCl
COCl
>
COCl
>
NO2
64.
COCl
H HCl =
90 =
68.
>
CHO
CH3
69.
CH3 CH 2 C CH + HCl
CH3 CH 2 C = CH 2
|
Cl
OH
(Plane of symmetry)
OH
98 1000
1.84 = 18.4
98 100
Suppose V ml of this H2SO4 is used to
prepare 1 lit. of 0.1M H2SO4
V 18.02 = 1000 0.1
=
or V =
66.
(d)
C=O
C=O
CH3
67.
(b)
C2H5
3
(b)
CH3
Cl C CH3
H 4
R-configuration
CH2 + H2 O
Clemmensen reduction
Zn-Hg /
conc. HCl
e.g.
CH3
COOH
70.
1000 0.1
= 5.55 ml.
18.02
1
1 1
430 + + 240 B.E. of HCl
2
2 2
COOH
I
|
CH3 CH 2 C CH 2
|
Cl
(c) Molarity of H 2SO4 solution
HI
65.
B.E. of reactant
B.E. of products
71.
72.
CH2 + H2 O
CH3
1
1
H 2 + Cl2
HCl
2
2
73.
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HX
t=0
1
teq (1 0.20)
74.
0
0.20
0
0.20
78.
Cr++ (3d4) =
= 4 unpaired e .
Mn++ (3d5) =
= 5 unpaired e .
Fe++ (3d6)=
= 4 unpaired e .
Ag 2S + 4NaCN 2Na[Ag ( CN )2 ] + Na 2S
Ni++ (3d8) =
4Au + 8KCN + 2H 2 O + O 2
4K[Au ( CN )2 ] + 4KOH
75.
79.
2.303
a
log
t
ax
when t = 60 and x = 60%
k=
2.303
100
2.303
100
log
=
log
60
100 60
60
40
Now,
k=
t =
2.303
100
2.303
=
log 2
log
0.0153
100 50 0.0153
104
6.023 1023 = 6.023 1017
100
(b) Lesser is the number of unpaired electrons
smaller will be the paramagnetic behaviour.
As Cr++, Mn++, Fe++ & Ni++ contains.
=
= 2 unpaired e .
As Ni++ has minimum no. of unpaired e
thus this is least paramagnetic.
(a) The solubility of sulphates of alkaline earth
metals decreases as we move down the
group from Be to Ba due to the reason that
ionic size increases down the group. The
lattice energy remains constant because
sulphate ion is so large, so that small
change in cationic sizes do not make any
difference. Thus the order:
BeSO 4 > MgSO 4 > CaSO 4 > SrSO 4 > BaSO 4
80.
2.303
0.3010 = 45.31 min .
0.0153
(b) Non superimposable mirror images are
called optical isomers and may be described
as chiral. They are also called enantiomers
and rotate plane polarised light in opposite
directions.
=
76.
O3
H3C
N
N
Co
Cl
Cl
77.
H
C
CH3
O
acetaldehyde
81.
Co
N
N
Cl
O
C
O
H 2O
H2O2
H3C
Cl
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82.
83.
(ii)
but K1 =
[NH3 ]2
[N 2 ] [H 2 ]3
86.
87.
[NO]2
[N 2 ] [O2 ]
[H 2 O]3
84.
85.
+1
+3
+5
+7
90.
K 2 . K 33
K1
..
: C O :
: C = O:
10 14
10 10
= 10 4
91.
OH
= 104 = 10 p
Now, [OH ] = 10p
OH
p =4
(b) (ii) is not possible for any value of n because
l varies from 0 to (n 1) thus for n = 2, l can
be only 0, 1, 2.
(iv) is not possible because for l = 0, m = 0.
(v) is not possible because for l = 2, m varies
from 2 to +2.
OH
=K
[OH ] =
..
89.
[H2 O]3
[N ] [H 2 ]3
[NO]2
. 2
[N2 ] [O2 ] [H 2 ]3 [O2 ]3 / 2
[NH3 ]2
K=
C6 H 5COONa + C6 H 5CH 2 OH
(a) Nucleophilicity increases down the periodic
table.
[H 2 ]3 [O2 ]3/ 2
[NH3 ]2 [O 2 ]5 / 2
..
88.
[H 2 ] [O2 ]
[NO]2 [H 2 O]3
50% NaOH
K 2 . K33
K1
2 C6 H 5 CHO + NaOH
Now operate,
or K3 =
:O
CO:
..
[H2 O]
& K3 =
[NO] [H 2 O]
, K2 =
=C=O
:
:O C O
:
(iii) : O
..
..
..
[NH3 ]2 [O 2 ]5 / 2
H2 +
o
(c) As Ecell =
0.46 =
0.0591
log K c
n
0.0591
log K c
2
2 0.46
= 15.57
0.0591
or Kc = Antilog 15.57 = 3.7 1015 4 1015
log K c =
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CH3 CH CH 2 O CH 2 CH3 + HI
|
CH3
O
||
O
||
( C (CH 2 ) 4 C NH (CH 2 ) 6 NH ) n
Nylon 66
93.
94.
95.
19996
= 199.96 amu
100
(d) Number of atoms per unit cell = 1
Atoms touch each other along edges.
=
96.
a
2
( r = radius of atom and a = edge length)
Hence r =
97.
4 3
r
98.
CH3
|
CH3 CH CH 2 OH + CH3CH 2 I
(a) Aldehydes and ketones having at least one
-hydrogen atom in presence of dilute alkali
give -hydroxy aldehyde or -hydroxy
ketone
O
||
H
Acetaldehyde
OH
dil.NaOH
CH3 C CH 2 CHO
|
H
Aldol
CH3 CH = CH.CHO
H 2O
99.
Crotonaldehyde
2Mn ++ + 5SO4 + 3H 2 O
From the equation it is clear that
Moles of MnO4 require to oxidise 5 moles
of SO3 are 2
Moles of MnO4 require to oxidise 1 mole
of SO3 are 2/5.
100. (b) There is a steady decrease in the radii as
the atomic number of the lanthanide
elements increases. For every additional
proton added in nucleus the corresponding
electron goes to 4f subshell.
The shape of f -orbitals is very much
diffused and they have poor shielding effect.
The effective nuclear charge increases
which causes the contraction in the size of
electron charge cloud. This contraction in
size is quite regular and known as
Lanthanoid contraction.
Since the change in the ionic radii in the
lanthanide series is very small, thus their
chemical properties are similar.
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Biology
107. (c)
Rr
RR
Rr
111. (d)
112. (c)
(green)
Rr
Red
F1-progeny
110. (c)
rr
(red)
Rr
Red
108. (c)
109. (b)
Rr
Red
Rr
Red
RR
Rr
F1-progeny
113. (d)
RR
red
red
red
red
(pure)
(dominant)
(dominant)
(pure)
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X CH3 in Chl a
CHO in Chl b
CH3
H3C
II
N
Porphyrin
ring
(Head)
Mg
N
H 3C
N
N
III
CH3
IV
0
Ester
linkage
H3C
CH3
CH3
CH3
CH3
Phytol
(Tail)
H3C
H3C
H3C
H3C
CH3
Carotene
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132. (a)
126. (c) The finches of galapagos is lands provides
an evidence in favour of biogeographical
evolution
127. (a) Physarum polycephalum belongs to
phylum Amoebozoa, infraphylum
Mycetozoa, and class Myxogastrea. P.
polycephalum, often referred to as the
many-headed slime, is a slime mold that
inhabits shady, cool, moist areas, such as
decaying leaves and logs.
128. (b) If a population ( e.g reindeer population )
is allowed to grow in a predator free
environment, the population grows
beyond carrying capacity and there occurs
population crash due to sudden shortage
of food. such growth curves also occur in
insect populations during rainy season,
and in Algal blooms.
129. (d) It is also know as Australian pine, which is
a deciduous tree with a soft, wispy, pinelike appearance that can grow to 100 feet
or more in height. Also known as ironwood,
beefwood, she oak and horsetail tree, it
bears a superficial resemblance to the
conifer genus Pinus because of its small,
round, cone-like fruits and its branchlets
of scale-like leaves that look like pine
needles.
130. (c) Pongamia pinnata is one of the few
nitrogen fixing trees (NFTS) to produce
seeds containing 30-40% oil. It is often
planted as an ornamental and shade tree
but now-a-days it is considered as
alternative source for Bio- Diesel. This
species is commonly called pongam,
karanja, or a derivation of these names.
Pongami, jatropa, Euphorbia are
133. (c)
134. (d)
135. (d)
136. (c)
137. (d)
138. (c)
139. (d)
140. (d)
141. (c)
142. (c)
143. (d)
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144. (c)
145. (a)
146. (c)
147. (c)
148. (a)
149. (b)
150. (d)
151. (d)
152. (d)
153. (d)
154. (c)
155. (d)
156. (d)
157. (c)
158. (a)
159. (b)
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160. (d)
161. (b)
162. (c)
163. (b)
164. (d)
165. (d)
166. (a)
167. (a)
clotting.
168. (d) They are found in the equatorial regions
rainfall exceeds 140 cm.) The warm humid
climatesupportsbroad leaved evergreen
plants. Productivity is very high ( 12000 k.
cal/m 2 / year The vegetation show
stratification into two or more well defined
layers.
169. (d) Floating ribs are 2- pairs ( 11th and 12th
pair ) which are not attached to sternum
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175. (a)
176. (a)
177. (a)
178. (d)
184. (b)
185. (b)
186. (b)
187. (d)
Gg
gg
gg
( yellow )
183. (a)
gg
Gg
182. (b)
188. (a)
Bb
a
189. (c)
AB
Ab
aB
ab
190. (d)
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191. (d)
192. (b)
193. (d)
194. (d)
195. (a)
196. (b)
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