Adva PII Sol

JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS

FULL TEST II
PAPER-2
Q.NO
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PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
(A) (q, r), (B) (q, r, s)
(A) (r), (B) (p)
(A) (p), (B) (q)
(C) (p), (D) (p)
(C) (s), (D) (q)
(C) (r), (D) (s)
(A) (r), (B) (p, q, r, s)
(A) (p), (B) (q)
(A) (r), (B) (s)
(C) (q), (D) (s)
(C) (r), (D) (s)
(C) (q), (D) (p)
(A) (s)
(A) (p, q, r, s)
(A) (s)
(B) (r)
(B) (p, q, s)
(B) (p)
(C) (p)
(C) (r)
(C) (r)
(D) (q)
(D) (p, r)
(D) (q)
1.
2.
3.
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2
AITS-FT-II(Paper-2)-PCM(Sol)-JEE(Advanced)/14
Physics
3.
According to the question
g
h
g 1
2
R
h
1
Re
h
h2
1 2 0
Re
Re
h=
4.
PART I
5 1 Re
2
From figure it is clear

180 (i r)
sini
and
sinr
r = 30
= 90
i = 60
sin60
3
sinr
i = 60
r
v2
6.
v1
m
M
CM
16.
F = qvB sin = qvB ( = 90)

F
3.2 10 20
So, B =
=
= 5 10-7 T
19
3
qv
1.6 10 4 10
0 Ip Iq
7
5 10
2 5 2
I = 4 amp.
If the distance of point R from third current carrying current is X, then
BR = 0
0 2 2.5
5 107 0
4
Now,
so x = 1 m
19.
dv
dv
2(r+dr)
dr
dr
dv
P(2r)dr = 2 dr
dr
2v 0 r
P(2r) = 2
2
R
2v 0
P=
R2
P(2r)dr = 2r
3
AITS-FT-II (Paper-2)-PCM(Sol)-JEE(Advanced)/14
Chemistry
PART II
OH
1.
H
O
O
H
OH
OH CH2 CH2 OH
2.
(III) is most reactive (resonance activation) followed by N (inductive activation). (II) is more
deactivated (resonance deactivation) followed by (I) (inductive deactivation).
3.
1
KE
KE1 2
KE2
1
0.991
1
2
KE1 0.99 KE2
KE2 1.02 KE1

% change is KE =
KE 2 KE1
100
KE1
2%
4.
H 0, S 0 Reaction may be non-spontaneous at 25oC

G H T S
= 180 298 150 10-3
= 135.3 > 0
= Non-spontaneous
To make it spontaneous G 0 . We have to increase the temperature.
H 180 103
S
150
= 1200 K = 927oC.
T
11.
Above critical temperature (TC), gas can not be liquified on cooling, the average energy of
molecule decreases.
12.
Positive charge on nitrogen of diazo group is stabilized by electron releasing group.
13.
Within amino acid, proton is accepted from COOH group by NH2 group to from
" COO R NH3 " .
14.
More the number of alkyl substitute at double bond, greater its thermodynamic stability.
15.
C H bond is broken in non rate determining step, therefore, substitution of -H by deuterium

doesnt affect the rate of reaction.
4
16.
There are total four types of -H and two types of carbonyl, hence a total of eight aldol would be
formed.
17.
Eocell 2.37 0.8

= 3.17 V
0.059
o
E
logK c
2
logK c 107.45
18.
Maximum work = nFE

= 6 102 kJ
5
Mathematics
1.
Perfect square =
PART III
100 1 = 9(excluding one)
Perfect cubes = 1001 / 3 1 3

th
Perfect 4 powers = 1001/ 4 1 2

powers = 100 1 1
Perfect 5th powers = 1001 / 5 1 1
1/ 6
Perfect 6
Now, perfect 4th powers have already been counted in perfect squares and perfect 6th powers
have been counted with perfect squares as well as with perfect cubes
Hence the total ways = 9 + 3 + 1 1 = 12
th
2.
[sin1x] > [cos1x] x > 0

y
/2
y =1
-1
cos1
1,
Clearly [cos1x] =
0,
0 ,
[sin1x] =
1,
1
x 0,
sin1
cos 1
x (cos 1, 1]
x [0, sin 1)
x sin 1, 1
Hence [sin x] > [cos x] x [sin 1, 1].

3.
As roots are of opposite sign, product of roots < 0

a2 + b2 1 < 0
a2 + b2 < 1
|a + ib| < 1
So, the point a + ib lies inside a circle of centre (0, 0) and radius 1.
6
4.
|z 2 + 3i| = 6 is a circle with centre (2, 3) and radius 6

and |z 4 i| = |z 12 i| is the perpendicular bisector
of (4, 1) and (12, 1) is a line parallel to axis imaginary.
Now this line
The line is tangent to circle at complex number (8 3i).
Hence only one complex number satisfies the above
equation.
(4, 1)
(8, 1)
(12, 1)
1
(8, -3)
(2, -3)
6.
Coordinates of point T (a cos , 0) so distance from focus of the point T is a (e cos )
7.
There are 8 even and 9 odd numbers. So probabilities of getting first even number is
8.
BI = r cosec
8
and
17
9
8
9
72
probabilities of getting second odd number =
, so required probabilities =
17
17 17 729
C
2
C
2
A
II1 = (BI)2 (BI)2 = 4R sin
2
A
15
II1 = 4R
sin R =
2
8
B
A
= 4R sin
sin
2
2
B
A
BI1 = r1 sec
= 4R sin
cos
2
2
90
I1
9.
1 2 3
n 1
yr = 1 1 1 ....... 1
r
r
r
r
n1
log y =
1
p
log 1
r p 1
r
lim log y =
log(1 x)
dx = (k + 1) log(1 + k) k
11.
px + 4xy + qy + 4a(x + y + 1) = 0 represents pair of straight lines iff

4apq + 16a2 4a2p 4a2q 16 a2 = 0
42 4a + ap + aq pq = 0.
For real , 16a2 4.4(ap + aq pq) 0
(a p)(a q) 0 a p or a q
12.
f(x) = ax bx + 2
f(0) = 2
f( 1) = a + b + 2 < 0 ( a + b + 4 < 0)
7
f(0) f( 1) < 0
One root lie between ( 1, 0)
Nothing can be said about ab
13.
Here only one condition is given. So degree is 2.
14.
Any point on the parabola is (t , t). Shift the origin to (4, 0) so that the line becomes X + y = 0
2
2
2
and the point (t , t) becomes (4 + t , t) where X = x + 4. If (X1, y1) is the image of (4 + t , t) in
X 0 1 4 t 2
X + y = 0, then 1
y1 1 0 t
X1 = t, y1 = (4 + t2) and in the original coordinates x1 = 4 t, y1 = 4 t2

2
the equation of image is (x + 4) = (y + 4).
15.
Shift the origin to the point (0, 3) so that any point (x 1, y1) on the reflected line is given by
1 q(h 3)
x1 1 0
(since m = 0)
p
y 3
1 q(h 3)
, y1 3 h px1 = qy1 + 1 6q
p
and hence the reflected line is px qy = 1 6q.
x1
16.
Equation of the tangent to the given circle at (2, 1) is 2x + y 3 = 0.

Shift the origin to the point (2, 0) so that the two lines becomes y = X and 2X + y 7 = 0. Any
X 0 1 h
point on the line is (h, 7 2h) and its reflection in y = X is given by 1
y1 1 0 y 2h
X1 = 7 2h, y1 = h X1 = 7 2y1
x1 + 2 = 7 2y1 and hence the reflection of the tangent is
x 5
2
2y + x 5 = 0 or y =
(2) which touch the parabola y = 5x.
2 4
17.
In the new definition l =
18.
d(O, P) = k
|x| + |y| + |z| = k
which represents a set of 9 planes making
intercepts of lengths k on positive as well
negative sides of all three axes. See the
adjacent figure.
x
, etc.
x y z
(0, 0, k)
(k, 0, 0)
(0, k, 0)
Y
(0, k, 0)
(0, 0, k)
X
Z
19.
The maximum value of d(O, P) = circumradius of sphere = a.
8
SECTION B
1.
(A) I =
dx
2
a x
a x
2I 2a2
dx
2
x
2
x
x
2 2
1
2a2
2xdx
2 2
x
2
a x
a2 x2 a2
a 2 x 2 2
dx
dx
2
x2
dx
2
x2
c.
2a2 a2 x2
(B) Put x = a sec
dx = a sec tan d
I=
a sec tan d
x 2 a2
c .
sec 2 a tan a2
a2 x
(C) Put x = a sin
dx = a cos d
a cos acos d
I=
cot 2 d = cot + c
a2 sin2
2
sin c
a2 x 2
x
a2 x 2
x
sin1 c
cos1 c .
x
a
x
a
(D) Put x = a sec
dx = a sec tan d
a tan a sec tan d
I=
a tan2 d
a sec
= a tan a + c
x
= x 2 a2 a sec 1 c .
a
2.
(A) Required area = 2
xdx
1
44
2
4
4
8
= x 3 / 2 0 8
3
3
/2
(B)
sin
x cos5 x dx
/2
= 2
sin
0
4 2 16
xdx 2
5 3 15
(C) For equation S + k = 0 to represent pair of lines

1 2 2
2 3
1 0
2 1 1 k
3(1 + k) 1 2(2 + 2k + 2) 2(2 + 6) = 0
k = 22
9
(D) Let p.v. of given points be A i j k , B 2i 2j k and C 3i k , so that two vectors in
the plane may be AB i j and AC 2i j 2k

2 1
Thus, 1 1 0 0
2 1 2
2 2(2) + (1 2) = 0
1
=
2
3.
(A) The equation will have roots of opposite sign if it has real roots and product of roots is
negative 4 (b2 + 1)2 12 (b2 3b + 2) 0 and
b2 3b 2
0
3
1<b<2
(B) The probability of problem being solved is 1 P A P B P C
1
1
= 1 1 1 1
2
3
2 2
= , 1
3 3 3
(C) x = 5 (y + z)
yz + x (y + z) = 8
yz + (y + z) (5 (y + z)) 8 = 0
y2 + y (z 5) + (z2 5z + 8) = 0
For real solution, (z 5)2 4 (z2 5z + 8) 0
7
(z 1) z 0
3
7
1z
3

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JEE(Advanced)-2014

ANSWERS, HINTS & SOLUTIONS

ALL INDIA TEST SERIES

(A) (q, r), (B) (q, r, s)

(A) (r), (B) (p)

(A) (p), (B) (q)

(C) (p), (D) (p)

(C) (s), (D) (q)

(C) (r), (D) (s)

(A) (r), (B) (p, q, r, s)

(A) (p), (B) (q)

(A) (r), (B) (s)

(C) (q), (D) (s)

(C) (r), (D) (s)

(C) (q), (D) (p)

According to the question

From figure it is clear

F = qvB sin = qvB ( = 90)

KE1 0.99 KE2

KE2 1.02 KE1

H 0, S 0 Reaction may be non-spontaneous at 25oC

Positive charge on nitrogen of diazo group is stabilized by electron releasing group.

" COO R NH3 " .

C H bond is broken in non rate determining step, therefore, substitution of -H by deuterium

Eocell 2.37 0.8

Maximum work = nFE

100 1 = 9(excluding one)

Perfect cubes = 1001 / 3 1 3

Perfect 5th powers = 1001 / 5 1 1

[sin1x] > [cos1x] x > 0

Hence [sin x] > [cos x] x [sin 1, 1].

As roots are of opposite sign, product of roots < 0

|z 2 + 3i| = 6 is a circle with centre (2, 3) and radius 6

Coordinates of point T (a cos , 0) so distance from focus of the point T is a (e cos )

px + 4xy + qy + 4a(x + y + 1) = 0 represents pair of straight lines iff

Here only one condition is given. So degree is 2.

X1 = t, y1 = (4 + t2) and in the original coordinates x1 = 4 t, y1 = 4 t2

Equation of the tangent to the given circle at (2, 1) is 2x + y 3 = 0.

In the new definition l =

The maximum value of d(O, P) = circumradius of sphere = a.

(A) Required area = 2

(C) For equation S + k = 0 to represent pair of lines

(D) Let p.v. of given points be A i j k , B 2i 2j k and C 3i k , so that two vectors in

the plane may be AB i j and AC 2i j 2k

(B) The probability of problem being solved is 1 P A P B P C

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