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2,827,502
Patented Mar. 18, 1958
v2
2,827,502
IMANUFACTURE 0F .HALOGENATED AROMATIC
.HYDRQCARBONS
10
the presence ,of a ?xed bed of a suitable catalyst. One 25 the .superheater is preferably passed up through the
to O
chloride.
aromatic hydrocarbon which requires no shutdowns for 65 lyst are removed by treating the catalyst with a-regen
crating gas, such as steam or an oxygen-containing gas,
catalyst regeneration or replacement and which is simpler,
at a temperature within the range offrom about 350. C.
more economical and more ef?cient than prior processes.
to about 500 C. Advantageously, the catalyst inthe
A speci?c object of our invention is to provide an im~
2,827,502 '
-'
'
'
30
i >
chloride recovered from the second stage process-is a _ I ' withdrawn from 'the bottom of column 31 through line
'
process.
40
_ .
Example I
>
so, spent
' reactor. The hot gases from the cyclone separator are
passed to a heat exchanger to recover their useful heat. .
~ About 10% of the benzene is converted to monochloro
2,827,502
5
actor, comprising monochlorobenzene, unconverted ben
a packed column.
addition, our catalyst bed is constantly maintained at a 25 range of 40 to 200 mesh into a reaction zone while main
high level of activity due to the continuous regeneration
taining a temperature in said reaction zone of about 190