Professional Documents
Culture Documents
California Provocateur
Cover frame
Nice pictures in the cover article and
Pages 6 and 7 (November 2006) Wow!
I’m never going to hear the end of this
one. I am trying to find out how I might
get a clean copy of the cover and article
to frame. My wife thought that it would
be a great idea. Thank you.
Frank Fernandes
Tulare
Key point
On Page 36 of the November issue, the
third item in the Key Points reads as
follows: “Ammonia contains more hy-
drogen than liquid H2.” I think you may
have taken that statement from the
Hydrogen Engine Center, which reads
as follows: “Ammonia contains more
hydrogen per cubic foot than liquid H2.”
(Underline is mine). So, your quotation
is not a direct quotation. Nonetheless,
both statements, although correct at
face value, can be somewhat (or very,
depending on your point of view) mis-
leading.
Here’s the way I read the technical
aspects of the question:
1. Liquid hydrogen at its atmo-
spheric pressure boiling point of about
minus 252 degrees C weighs about 4.23
pounds per cubic foot, and it is, of
course, all hydrogen, so you have 4.23
pounds of hydrogen.
2. Liquid ammonia at, say, 60 de-
grees F under pressure of about 100
pounds per square inch weighs about
38.5 pounds per cubic foot. Of that 38.5
pounds, nitrogen accounts for ¹⁴⁄₁₇, or
about 82.4%, of the total, or about 31.7
pounds, leaving the difference of about
6.8 pounds for the hydrogen component
of ammonia. OK so far in that a cubic
foot of ammonia does, in fact, contain
about 1.6 times the weight of hydrogen
(on a weight basis) than a cubic foot of
pure liquid hydrogen. But, that does not
tell the whole story.
3. The heat of combustion of am-
monia yields only about 15% of the heat
released by burning the same weight
of pure hydrogen. So, even though am-
monia might have more hydrogen per
cubic foot than pure hydrogen, the
“extra baggage” that the nitrogen com-
ponent of the molecule represents re-
sults in a terrific loss of useful energy.
The “key point” that you (and the
Hydrogen Engine Center) seem to be
so proud of is really not all that great,
as I see it. I do agree, however, that am-
monia is a great carrier of hydrogen.
But, most of the ammonia produced in
the world is made from hydrocarbons
(oil or natural gas), so overall, there is
little or no benefit worldwide — from a
carbon dioxide (greenhouse gas) emis-